| LIPID_ID | FA0128 |
| CHEM_NA | (METHYL)- |
| 8,15-DIHYDROPEROXY-5,9,11,13-EICOSATETRAEN |
| OIC ACID(EICOSATETRAENOATE) |
| COMMON_NA |
| MOL_FORMULA | C20H32O6 |
| MOL_WT | 368 |
| ABBREVIATION | 20:4(ω7,9,11,15)(8,15-OOH) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | UV(ME-ESTER)(114) CONJUGATED TRIENE:270nm |
| AND 281nm |
| IR_SPEC | IR(ME-ESTER)(114) OOH GROUP:3400cm-1 |
| IR(AFTER REDUCTION)(124) TRANS |
| UNSATURATION:968cm-1, OH |
| GROUP:1040,3540cm-1 |
| NMR_SPEC | 1H-NMR(ME-ESTER)(114) OOH:8.3ppm |
| 1H-NMR(AFTER REDUCTION)(124) C8,C15:4.2ppm; |
| OH:6.3ppm |
| MS_SPEC | EI-MS(ME-ESTER;AFTER |
| REDUCTION)(124):M/E=350[M];332[M-H2O];301[332 |
| -OCH3];261[332-(CH2)4CH3];209[M-CH=CH(CH2)4C |
| OOCH3];191[209-H2O];GC-EI-MS(ME-ESTERAFTER |
| REDUCTION,HYDROGENATION AND |
| TMS)(112/113/114):M/E=487[M-CH3];431[M-(CH2) |
| 4CH3];359[M-(CH2)6COOCH3];245 |
| NOTE_SPEC |
| SOURCE | ｱﾗｷﾄﾞﾝの自動酸化(113) |
| ｱﾗｷﾄﾞﾝの15-HYDROPEROXIDESの鉄ｲｵﾝ-ｱｽｺﾙﾋﾞﾝ酸 |
| 存在下での分解物中(112) |
| ｱﾗｷﾄﾞﾝの一重項酸素酸化(114)生体中で15-HPETEより |
| 酵素的に生成(8,15-DHPETE)(119/120) |
| 大豆ﾘﾎﾟｷｼｹﾞﾅｰｾﾞにより15-HPETEより生成(124) |
| BIOL_ACTIV |
| NOTE |
| 1998年8月24日 | 128 / 513 ページ |