| LIPID_ID | FA0144 |
| CHEM_NA | METHYL-18-HYDROPEROXY-5,8,11,14,16-ICOSAPE |
| NTAENOATE |
| COMMON_NA |
| MOL_FORMULA | C21H32O4 |
| MOL_WT | 348 |
| ABBREVIATION | 20:5(ω4,6,9,12,15)(18-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | CONJUGATED DIEME:λmax=235.5nm (125) |
| IR_SPEC | OOH GROUP:3400cm-1 (125) |
| NMR_SPEC | 1H-NMR(125): OOH PROTON:8.5ppm |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION AND |
| TMS-DERIVATIZATION)(125):M/E=404[M];389[M-CH |
| 3] 314[M-HOTMS] GC-EI-MS(AFTER REDUCTION, |
| HYDROGENATION AND TMS-DERIVATIZATION)(125): |
| M/E=399[M-CH3];385[SMTO=CH(CH2)16COOCH3];3 |
| 83[M-OCH3];367[399-CH3OH]; |
| 131[SMTO=CHCH2CH |
| NOTE_SPEC |
| SOURCE | ｱｲｺｻﾍﾟﾝﾀｴﾝの自動酸化(125) |
| ｱｲｺｻﾍﾟﾝﾀｴﾝの一重項酸素酸化(125) |
| ｱｲｺｻﾍﾟﾝﾀｴﾝのﾐｵｸﾞﾛﾋﾞﾝ存在下での酸化(127) |
| BIOL_ACTIV |
| NOTE | 自動酸化によりｱｲｺｻﾍﾟﾝﾀｴﾝから生成するﾋﾄﾞﾛﾍﾟﾙｵｷｼﾄﾞ |
| の異性体比：5-,18-ISOMER(OUTER |
| HYDROPEROXIDES)は他の異性体(8-,9-,11-,12-,14-, |
| 15-ISOMER [INNER |
| HYDRO-PEROXIDES])よりその組成比が大(127) |
| 1998年8月24日 | 144 / 513 ページ |