| LIPID_ID | FA0115 |
| CHEM_NA | METHYL-10,12,13,16-BISEPIDIOXY-9-HYDROPEROX |
| Y-14-OCTADECENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O8 |
| MOL_WT | 388 |
| ABBREVIATION | 18:1(ω4)(10,12,13,16-Bisepidioxy)(9-OOH)(Me-Ester |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC |
| IR_SPEC |
| NMR_SPEC | 1H-NMR(106): C8:1.6ppm; C9:4.08ppm; |
| C10,12,13,16:4.45ppm; C11:2.1-2.7ppm; |
| C14,15:5.68ppm; OOH:8.45ppm |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION(PH3P) AND |
| TMS-DERIVATIZATION)(106): |
| M/E=259[SMTO=CH(CH2)7COOCH3]; 185[M-259]; |
| GC-EI-MS(AFTER REDUCTUIN,HYDROGENATION, |
| AND |
| TMS-DERIVATIZATION)(106):M/E=389[M-259-HOTM |
| S]; |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの12-PEROXY |
| RADICALの1,3-CYCLIZATIONで生ずる10,12-EPIDIOX |
| Y-9-HYDROPEROXIDESへの一重項酸素の1,4-付加で |
| BIOL_ACTIV |
| NOTE |
| 1998年8月24日 | 115 / 513 ページ |