| Mycolic acid |
| LIPID_ID | MA0032 |
| CHEM_NA | 2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPAN |
| OYL-C58:0 ACID |
| COMMON_NA | DICYCLOPROPANOYL-α-MYCOLIC ACID |
| MOL_FORMULA | C82H160O3 |
| MOL_WT | 1192 |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC |
| IR_SPEC |
| NMR_SPEC |
| MS_SPEC | [M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ |
| (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion |
| resulting from C2 -C3 cleavage),[A-90]+ (loss of |
| trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene |
| carboxylic acid ester resulting from C3 -C4 |
| cleavage),[B-29]+ (loss of CHO from |
| [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および |
| Hydrigenation後にGC-MSを行う)(004/001/005) |
| NOTE_SPEC |
| SOURCE | Mycobacterium bovis (001/004/005) |
| M.tuberculosis H37Rv (001/005) |
| M.simiae (004) |
| BIOL_ACTIV |
| NOTE | ･Mycobacterium tuberculosisには, |
| diΔのミコール酸が存在する(011) |
| α-unitが C24:0,C26:0 で, l=17,18,19, M=10, |
| n=15,17,19,21 のミコール酸が存在する(diΔ)(016) |
| α-unit C26:0 で C84のもの(005) |
| C84(α-unit C26:0) も存在(005) |
| ･M.microti には α-unitが C26:0で |
| l+m+n=42,44,46,48,50,52のもの(008) |
| ･M.kansaii には C80H156O3がある(017) |
| ･M.diernhoferi には α-unit C22:0で C70(001), |
| C71(004)のものが存在する｡ |
| 1998年7月17日 | 256 / 256 ページ |