"LIPID_ID"	"CLASSIFICA"	"CLASS"	"CHEM_NA"	"COMMON_NA"	"SYMBOL"	"GROUP_NA"	"MOL_FORMULA"	"FORMULA_C"	"FORMULA_H"	"FORMULA_O"	"FORMULA_N"	"FORMULA_P"	"FORMULA_S"	"MOL_WT"	"STRUCTURE"	"STR_1"	"STR_2"	"STR_3"	"STR_4"	"STR_5"	"STR_6"	"STR_7"	"STR_8"	"STR_9"	"STR_10"	"STR_11"	"C_No"	"ABBREVIATION"	"FATTY ACID"	"REF_STR"	"MELT_PT"	"BOIL_PT"	"OPT_ROT"	"REFRA_IND"	"DENSITY"	"SOLUBILITY"	"REF_PRP"	"UV_SPEC"	"IR_SPEC"	"NMR_SPEC"	"MS_SPEC"	"NOTE_SPEC"	"REF_SPC"	"SOURCE"	"REF_SOU"	"BIOL_ACTIV"	"REF_BA"	"NOTE"	"REF_NOTE"	"Page"
"BA0001"	5.00		"3α,19-DIHYDROXY-5β-CHOLAN-24-OIC ACID"	"19-HYDROXYLITHOCHOLIC ACID"	"19-OH-LCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                          (REF:   )"	"                  ＼／＼"	"                    �ﾓH �ｵ"	"        HO    ／＼�ｫ＼  COOH"	"          ＼�ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／"	"     H  OH  H"							"220-222ﾟC(FROM AcOEt)(206)"		"[α]23/D=+35.8ﾟ(C=0.62,MeOH)(206)"				"206/"		"(NUJOL) 3350, 2700, 1710cm-1(206)"	"1H-NMR(PYRIDINE-d6)  0.62(s,18-Me), 0.96(d,21-Me), 3.72,4.12(d,19-Me), 4.00(m,3β-H)(206)"	"Me-TMS: M/E 535(M-15),460(M-90),370(M-90x2),357(M-90-103),255 (207)       
Me-DMES: 549,461(M-117),371,357(M-104-117),255(206)"		"206/207/"	"ヒト胎児の肝臓とリトコール酸をインキュベートすることにより生じる｡(207/208)"	"207/208/"					"bileaci.html"
"BA0002"	5.00		"3α,7α,19-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"19-HYDROXYCHENODEOXYCHOLIC ACID"	"19-OH-CDCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                          (REF:   )"	"                  ＼／＼"	"                    �ﾓH �ｵ"	"        HO    ／＼�ｫ＼  COOH"	"          ＼�ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H  OH  H   H OH"							"129-130ﾟC(FROM AcOEt)(206)"		"[α]20/D=+21.1ﾟ(C=0.59,MeOH)(206)"				"206/"		"(NUJOL) 3350, 2650, 1700cm-1(206)"	"1H-NMR(PYRIDINE-d6)  0.72(s,18-Me), 1.04(d,21-Me), 3.88,4.23(d,19-Me), 3.94(m,3β-H),4.07(brs,7β-H)(206)"	"Me-DMES M/Z 651,547,472,459(M-104-117),369,355(M-2x104-117),253 (206)"		"206/"							"bileaciPage2.html"
"BA0003"	5.00		"3α,12α,19-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"19-HYDROXYDEOXYCHOLIC ACID"	"19-OH-DCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                          (REF:   )"	"              H HO＼／＼"	"              �ﾒ�ﾄ  �ﾓH �ｵ"	"        HO    ／＼�ｫ＼  COOH"	"          ＼�ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／"	"     H  OH  H"							"138-140ﾟC(FROM AcOEt)(206)"		"[α]23/D=+58.5ﾟ(C=1.36,MeOH)(206)"				"206/"		"(NUJOL) 3350, 2650, 1690cm-1(206)"	"1H-NMR(PYRIDINE-d6)  0.73(s,18-Me), 1.16(d,21-Me), 3.57,3.82(d,19-Me), 3.90(m,3β-H), 4.16(brs,12β-H)(206)"	"Me-DMES M/Z 472,459(M-104-117),369,355(M-2x104-117),253 (206)"		"206/"							"bileaciPage3.html"
"BA0004"	5.00		"3α-HYDROXY-6-OXO-5α-CHOLAN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390			"                 ＼／＼                        (REF:077)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾊ／"	"    H OH  H ‖"	"            O"					"077/"	"187-188ﾟC(077)"		"[α]/D=-9ﾟ  (078)"				"077/078/"			"1H-NMR(CDCl3)  (079)  18-CH3=0.67(s), 19-CH3=0.73(s), 21-CH3=0.95, 3β-H=4.16(W1/2=12Hz)"	"Me-TMS 476, 461, 447(BASE PEAK), 386, 371, 305, 229 (003)"		"079/003/"	"ブタ胆汁(080)"	"080/"					"bileaciPage4.html"
"BA0005"	5.00		"3α-HYDROXY-7-OXO-5β-CHOLAN-24-OIC ACID"	"7-KETOLITHOCHOLIC ACID"	"7-KLCA"		"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390			"                 ＼／＼                        (REF:081)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ｸ"	"    H OH  H      O"						"081/"	"202-203ﾟC(081)"		"[α]25/D=-28ﾟ (DIOXANE)(081)"				"081/"			"IH-NMR(CDCl3) (082) 3α-Oac, 24-CO2Me 18-CH3=0.67(s), 19-CH3=0.72(s), 21-CH3=0.95(d), 3β-H=  4.5-4.9(b), 3α-OCOCH3=2.04(s), 24-COOCH3=3.70(s)"	"Me-TMS 476, 461, 458, 386(BASE PEAK), 368, 313, 293, 253 (003)"		"082/003/"	"ブタ胆汁(083)，COYPU （カイサネズミ，ヌートリア）の胆汁(084/085/086)，ニワトリの胆汁(087)，哺乳動物の胆汁(087)，ヒト糞便(004/018/019)"	"083/084/085/086/087/004/018/019/"					"bileaciPage5.html"
"BA0006"	5.00		"7α-HYDROXY-3-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390			"                 ＼／＼                        (REF:058)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ｷ＼／�ﾚ／�ﾗ"	"    O      H   H OH"						"058/"	"125ﾟC(Me ESTER)(058)"						"058/"			"1H-NMR(PYR-d5) Me ESTER (023) 18-CH3=0.71(s), 19-CH3=1.02(s), 7β-H=3.92(brm), 24COOMe=3.68(s)"	"Me-TMS 476, 461, 386(BASE PEAK), 371, 353, 316, 271, 253 (003)"		"023/003/"	"ヒト糞便(015/018)"	"015/018/"					"bileaciPage6.html"
"BA0007"	5.00		"3α-HYDROXY-12-OXO-5β-CHOLAN-24-OIC ACID"	"12-KETOLITHOCHOLIC ACID"	"12-KLCA"		"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390			"               O ＼／＼"	"              ‖   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H OH   H"							"164-165ﾟC, 111-112ﾟC(Me ESTER )(088)"		"[α]/D=+86.6ﾟ (DIOXANE)(088)"				"088/"			"IH-NMR (CDCl3) Me ESTER (089)18-CH3, 19-CH3=1.02, 3β-H=2.29(b)"	"Me-TMS 476, 386, 371, 321, 271, 253, 231(BASE PEAK) (003)"		"089/003/"	"最初に牛の胆汁中より確認(090)，SEVERAL SPECIESの糞便(052)，ヒト糞便(015)， 肝胆道疾患患者の尿(021/061/091/092)および糞便(092)"	"090/052/015/021/061/091/092/"					"bileaciPage7.html"
"BA0008"	5.00		"3β-HYDROXY-12-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390			"              O  ＼／＼              (REF:093)"	"              ‖   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    OH H   H"						"093/"	"218-219ﾟ, 129-130ﾟC(Me ESTER)(093)"						"093/"				"Me-TMS 476, 386, 271, 231, 229, 121  (021)"		"021/"	"ヒト(015/018/093)  ウサギの糞便(017)  肝胆道疾患患者の尿(021/037)"	"015/018/093/017/021/037/"					"bileaciPage8.html"
"BA0009"	5.00		"12α-HYDROXY-3-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ｷ＼／�ﾚ／"	"    O      H"							"112-120(094),111(aq.EtOH)OR 119(EtOAc)BUBBLING(095)"		"[α]/D=+48ﾟ  (094)"				"094/"		"cm-1 1720(C=0) (095)"	"1H-NMR (CDCl3) (095) 18-CH3=0.72(s), 19-CH3=1.00(s), 21-CH3=1.00(d), 12β-H=4.03(brs)"	"Me-TMS 461, 431, 386, 271(BASE PEAK), 253, 208 (003)"		"095/003/"	"ヒト糞便(004/015/018)"	"004/015/018/"					"bileaciPage9.html"
"BA0010"	5.00		"3,12-DIOXO-5β-CHOLAN-24-OIC ACID"	"DEHYDRODEOXYCHOLIC ACID"			"C24H36O4"	24.00	36.00	4.00	0.00	0.00	0.00	388			"              O  ＼／＼"	"              ‖   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ｷ＼／�ﾚ／"	"    O      H"							"187ﾟC, 129-130ﾟC(Me ESTER)(052)"		"[α]/D=+92ﾟ  (052)"				"052/"			"1H-NMR (CDCl3) COOMe (089), 18-CH3=1.07(s), 19-CH3=1.12(s)13C-NMR(CDCl3) Me ESTER (030), C1=36.8,C2=36.8,C3=211.6,C4=42.0,C5=43.7, C6=25.5,C7=26.6,C8=35.4,C9=44.3,C10=35.6,C11=38.3,C12=213.7,C13=57.5,C14=58.5,C15=24.2,C16=27.4,C17=46.5,C18=11.7"	"Me-TMS 402, 384, 329, 269, 247(BASE PEAK), 229 (003)"		"089/030/003/"	"ヒト糞便(015/018)"	"015/018/"					"bileaciPage10.html"
"BA0011"	5.00		"3α,6α,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"HYOCHOLIC ACID"	"HCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H OH  H �ﾗH OH"	"             HOH"						"187-188ﾟC(031)"		"[α]27/D=+8ﾟ (031)"			"0.0045mM(WATER SOLUBILITY IN PROTONATED FORM)(012)"	"031/012/"		"cm-1 1718(C=0) 3430, 1050(OH) (012)"	"1H-NMR(CDCl3+10%DMSO-d6), 18-CH3=0.65(s), 19-CH3=0.90(s), 21-CH3=0.93(d,J= 5.4Hz), 3β-H=3.39(brm), 6β,7β-H=3.82(m) 13C-NMR(CDCl3) Me ESTER, C1=35.5,C2=30.4,C3=71.7,C4=32.6,C5=47.8,C6=71.9,C7=69.6,C8=38.6,C9=32.5,C10=35.9,C14=58.5,C15=24.2,C16=27.4,C17"	"Me-TMS 548, 533, 458(BASE PEAK), 443, 405, 369, 253 (003)"		"096/003/"	"ブタ胆汁(097/098)，肝胆道疾患患者の尿(021/036/037/038/043/066)および 血漿  (036/043)"	"097/098/021/036/037/038/043/066/"					"bileaciPage11.html"
"BA0012"	5.00		"3α,6β7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"α-MURICHOLIC ACID"	"α-MCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H OH  H �ﾗH OH"	"            OH H"						"199-200ﾟC, 97-98ﾟC(Me ESTER)(099)"		"[α]/D=+38ﾟ  (099)"				"099/"		"cm-1 1710(C=0) 3400, 1045, 1018 (OH) (096)"	"1H-NMR(CDCl3+10%DMSO-d6), 18-CH3=0.69(s), 19-CH3=1.08(s), 21-CH3=0.94(d,J= 5.4Hz), 3β-H=3.40(brm), 6α,7β-H=3.69(m) 13C-NMR(CDCl3) Me ESTER, C1=35.7,C2=30.1,C3=71.4,C4=36.1,C5=48.0,C6=76.5,C7=72.7,C8=35.3,C9=32.9,C10=34.7,C11=20.4,C12=39.5,C13=42.6,C14"	"Me-TMS 638, 548, 458(BASE PEAK), 443, 403, 368, 285, 195 (003)"		"096/003/"	"マウス，ラット胆汁(100)"	"100/"					"bileaciPage12.html"
"BA0013"	5.00		"3α,6β,7β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"β-MURICHOLIC ACID"	"β-MCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"                 ＼／＼                        (REF:031)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H OH  H �ﾗOHH"	"            OH H"					"031/"	"225-226ﾟC(031)"		"[α]/D=+62ﾟ  (031)"				"031/"		"cm-1 1695 (C=0) 3425, 1052 (OH) (096)"	"1H-NMR(CDCl3+20%DMSO-d6), 18-CH3=0.68(s), 19-CH3=1.08(s), 21-CH3=0.94(d,J= 6.3Hz), 3β,7α-H=3.50(brm),6α-H=3.61(m) 13C-NMR(CDCl3) Me ESTER, C1=35.4,C2=29.9,C3=70.9,C4=35.4,C5=47.2,C6=75.4,C7=73.5,C8=38.5,C9=39.6,C10=33.8,C11=20.8,C12=39.9,C13=43.7,C14="	"Me-TMS 548, 533, 458, 369, 351, 285, 253, 195(BASE PEAK) (003)"		"096/003/"	"マウス，ラット胆汁(100)，黄疸ラットの尿(101)"	"100/101/"					"bileaciPage13.html"
"BA0014"	5.00		"3α,6α,7β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"ω-MURICHOLIC ACID"	"ω-MCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"                 ＼／＼                        (REF:096)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H OH  H �ﾗOHH"	"             H OH"					"096/"	"162-164ﾟC(096)"						"096/"		"cm-1 1690(C=0) 3400, 1045(OH) (096)"	"1H-NMR(CDCl3+10%DMSO-d6), 18-CH3=0.66(s), 19-CH3=0.93(s), 3β,7α-H=3.40   (brm), 6β-H=3.68(brm)  13C-NMR(CDCl3) Me ESTER, C1=35.3,C2=30.9,C3=71.2,C4=29.9,C5=47.6,C6=73.0,C7=75.4,C8=41.7,C9=39.7,C10=35.3,C11=21.2,C12=40.0,C13=43.8,C14=55.0,C15=26.7,C16="	"Me-TMS 548, 533, 458, 369, 285, 253, 195(BASE PEAK) (003)"		"096/003/"	"ラット糞便，胆汁(052)"	"052/"					"bileaciPage14.html"
"BA0015"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"CHOLIC ACID"	"CA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H OH  H   H OH"							"197-198ﾟC, 156-157ﾟC(Me ESTER)(053)"		"[α]/D=+37ﾟ (053)"			"0.273mM(WATER SOLUBILITY IN PROTONATED FORM)(012)"	"053/012/"			"1H-NMR(CD3OD)(002),18-CH3=0.71(s),19-CH3=0.92(s),21-CH3=1.01(d),3β-H=3.45 (brm),7β-H=3.80(m),12β-H=3.96(m),23-CH2=2.20  13C-NMR(CDCl3)Me ESTER, C1=35.3,C2=30.1,C3=71.7,C4=39.4,C5=41.4,C6=34.7,C7=68.3,C8=39.4,C9=26.2,C10=34.7,C11=28.0,C12=73.0,C13=46.3"	"Me-TMS 638, 548, 458, 368, 353, 343, 253(BASE PEAK), 226 (003)"		"002/060/003/"	"たいていの脊椎動物の胆汁，糞便中に存在（魚類，ヘビ，鳥類，哺乳類）(052)"	"052/"	"もっともCOMMONな胆汁酸"				"bileaciPage15.html"
"BA0016"	5.00		"3α,7α,12β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             OH H＼／＼                      (REF:102)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H OH  H   H OH"						"102/"	"200-201.5ﾟC(102)"		"[α]/D=+30.5ﾟ (EtOH) (102)"				"102/"			"1H-NMR(ACETONE-d6:D2O) (102), 18-CH3=0.71(s), 19-CH3=0.91(s), 3β-H,12α-H=3.40(brm) 13C-NMR(CDCl3) Me ESTER, C1=34.8,C2=30.6,C3=71.4,C4=39.3,C5=41.2,C6=35.2,C7=67.7,C8=38.0,C9=32.0,C10=34.8,C11=29.3,C12=78.9,C13=47.5,C14=48.5,C15=22.9,C16=23.7,C17=57.0,"	"Me-TMS 623, 548, 458, 368, 343, 253(BASE PEAK), 227 (003)"		"102/060/003/"							"bileaciPage16.html"
"BA0017"	5.00		"3α,7β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"URSOCHOLIC ACID"	"UCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H OH  H  OH H"							"127-129ﾟC(103)"					"1.67mM (WATER SOLUBILITY IN PROTONATED FORM)  (012)"	"103/012/"		"cm-1(KBr) 1704(C=0) 3448, 1042, 1010, 957(OH) (103)"	"1H-NMR(CDCl3+10%Me2SO-d6+D2O)(103),18-CH3=0.69(s),19-CH3=0.91(s),3β-H,7α-H=3.51(brm),12β-H=3.91(m), 13C-NMR(CDCl3) Me ESTER (060),C1=34.2,C2=29.1, C3=71.0,C4=36.9,C5=42.6,C6=36.6,C7=71.0,C8=43.5,C9=31.2,C10=33.9,C11=27.7,C12=72.2,C13=47.5,C14=47.2,C15"	"Me-TMS 623, 548, 458, 433, 368, 343, 253(BASE PEAK), 208 (003)"		"103/060/003/"	"犬(104)，ラット(105)，ヒトの糞便(015/106/107)，ヒト胆汁(108)，ラットの胆汁 （コール酸の腸内細菌の代謝物として）(105)，肝胆道疾患患者の尿(036/021/037/ 038/066)および血清 (036)"	"104/105/015/106/107/108/036/021/037/038/066/036/"					"bileaciPage17.html"
"BA0018"	5.00		"3β,7α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    OH H   H   H OH"							"196.5-197ﾟC, 185-187ﾟC(Me ESTER)(102)"						"102/"			"1H-NMR(CDCl3) Me ESTER(102),18-CH3=0.68(s),19-CH3=0.91(s),3α-H,12β-H=4.01(m),7β-3.86(m),COOCH3=3.64(S), 13C-NMR(CDCl3) Me ESTER (109),C1=29.8,C2=  27.7,C3=66.9,C4=36.6,C5=35.9,C6=35.2,C7=68.5,C8=39.5,C9=25.9,C10=34.3,C11=28.6,C12=72.8,C13=46.6,C14=41."	"Me-TMS 623, 548, 458, 368, 343, 285, 261, 253(BASE PEAK) (003)"		"102/109/003/"	"ヒト(107)，犬(104)の糞便"	"107/104/"					"bileaciPage18.html"
"BA0019"	5.00		"3α,7β,12β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             HO H＼／＼                      (REF:103)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H OH   H   OHH"						"103/"	"191.5-193ﾟC(103)"						"103/"		"cm-1 1701(C=0) 3636, 3448, 1049, 1010, 954(OH) 103)"	"1H-NMR (CDCl3+10%Me2SO+D2O)(103),18-CH3=0.71(s),19-CH3=0.92(s),3β-H,7α-H,12α-H=3.44(brm), 13C-NMR (CDCl3) Me ESTER (060), C1=34.8,C2=30.1,C3=70.6, C4=36.9,C5=42.1,C6=36.9,C7=70.6,C8=42.1,C9=37.9,C10=33.8,C11=29.1,C12=79.1,C13=48.6,C14=54.2,C15=26.2,C1"	"Me-TMS 623, 548, 458, 433, 368, 343, 253(BASE PEAK) (003)"		"103/060/003/"							"bileaciPage19.html"
"BA0020"	5.00		"3β,7α,12β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             OH H＼／＼                      (REF:102)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    OH H   H   H OH"						"102/"	"225-226ﾟC(102)"		"[α]/D=+23.4ﾟ(EtOH)(102)"				"102/"			"1H-NMR(CD3COCD3-D2O) (102),18-CH3=0.73(s),19-CH3=0.95(s),3α-H=3.97(m),7β-H=3.82(m),12α-H=3.43(brm)  13C-NMR(CDCl3) Me ESTER (060), C1=29.8,C2=27.7,C3=66.6,C4=36.5,C5=35.7,C6=35.4,C7=68.2,C8=38.0,C9=31.3,C10=34.4,C11=29.3,C12=79.0,C13=47.6,C14=48.6,C15"	"Me ESTER  422(M+), 420(M-2), 404(M-18) (102)"		"102/060/"							"bileaciPage20.html"
"BA0021"	5.00		"3β,7β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             H OH＼／＼                      (REF:110)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    OH H   H   OHH"						"110/"	"164.5-165.5ﾟC(110)"						"110/"		"cm-1(KBr) 1730(C=0) 3636,3509,1031,1020,990,954(OH) (110)"	"1H-NMR (CDCl3+10%Me2SO-d6+D2O)(110),18-CH3=0.70(s),19-CH3=0.94(s),7α-H=3.56(brm),3α-H,12β-H=3.96(m), 13C-NMR(CDCl3) Me ESTER (060),C1=29.3,C2=27.7,C3=66.2,C4=34.3,C5=36.9,C6=36.6,C7=71.0,C8=43.5,C9=31.2,C10=33.9,C11=29.2,C12=72.2,C13=47.5,C14=47.2,C15"	"Me-TMS 623, 458, 433, 368, 343, 253  (021)"		"110/060/021/"	"ヒト糞便(107)，肝胆道疾患患者の尿(021/037/066)"	"107/021/037/066/"					"bileaciPage21.html"
"BA0022"	5.00		"3β,7β,12β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             OH H＼／＼                      (REF:103)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    OH H   H   OHH"						"103/"	"164.5-167ﾟC(103)"						"103/"		"cm-1(KBr) 1695(C=0) 3448, 3333, 1020, 1004, 957(OH) (103)"	"1H-NMR(CDCl3+10%Me2SO-d6-D2O) (103),18-CH3=0.70(s),19-CH3=0.94(s),7α-H, 12α-H=3.40(brm),3α-H=3.93(m),13C-NMR(CDCl3) Me ESTER (060),C1=29.0,C2=27.6,C3=66.1,C4=34.4,C5=36.9,C6=36.7,C7=71.0,C8=42.1,C9=37.2,C10=34.4,C11=29.5,C12=72.2,C13=47.5,C14=47.2,C15"			"103/060/"							"bileaciPage22.html"
"BA0023"	5.00		"3α,12α,16α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"PYTHOCHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                        COOH"	"             H OH＼／＼／"	"             �ﾒ�ﾄ  �ﾓH OH"	"             ／�ｪ／＼�ﾄ"	"             �ｵ ｜ �ｺ�ﾔ"	"       ／＼�ｫ＼�ﾋ�ｼ    H"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H OH   H"							"186-187ﾟC, 146-148ﾟC (Me ESTER)(111)"		"[α]/D=+28ﾟ (111/112)"				"111/112/"				"Me-TMS 638, 548, 462, 301, 281, 253, 191, 73(BASE PEAK)   (003)"		"003/"	"ニシキヘビ(111)"	"111/"	"デオキシコール酸(DCA)の水酸化物(113)"	"113/"	"PYTHOCHOLIC ACID のこの名はPYTHON（ヘビ）の主胆汁酸なのでついた．"		"bileaciPage23.html"
"BA0024"	5.00		"3α,12α,23-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"BITOCHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                         OH"	"             H OH＼／＼／"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H OH   H"							"AMORPHOUS, 114-123ﾟC (Me ESTER)(052)"		"[α]/D=+48ﾟ (052)"				"052/"				"Me-TMS 623, 458, 345, 309, 283, 255(BASE PEAK), 143  (003)"		"003/"	"ヘビ(BITIS ARIETANTS, BITIS GABONICA, RUSSELL'S VIPER)(052/114),クサリヘビ"	"052/114/"					"bileaciPage24.html"
"BA0025"	5.00		"3α,7α,12α-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"	"ALLOCHOLIC ACID"	"allo-CA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾊ／�ﾗ"	"    H OH   H   H OH"							"239-241ﾟC, 227-228.5ﾟC (Me ESTER)(115)"		"[α]/D=+23ﾟ (115)"				"115/"		"cm-1 1700(C=0) 3400, 1008(OH) (116)"	"1H-NMR(CDCl3+20%DMSO-d6)(116),18-CH3=0.67(s),19-CH3=0.75(s),21-CH3=0.99(d,J=5.4Hz),7β-H=3.74(m),12β-H=3.89(m),3β-H=3.96(m), 13C-NMR(CDCl3) Me ESTER(007),C1=31.9,C2=28.8,C3=66.3,C4=35.5,C5=31.5,C6=36.3,C7=67.9,C8=39.8,C9=39.2,C10=35.8,C11=28.1,C12=72.8"	"Me-TMS 638, 623, 548, 458(BASE PEAK), 368, 343, 261, 253, 243 (003)"		"116/007/003/"	"魚胆汁(115)，GIGI FISH(117), 鳥，哺乳動物の胆汁(052)，トカゲ，ヒト糞便(107)肝胆道疾患患者の尿(014/021/037/038/066)および血漿中(043)"	"115/117/052/107/014/021/037/038/066/043/"					"bileaciPage25.html"
"BA0026"	5.00		"7α,12α-DIHYDROXY-3-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ｷ＼／�ﾚ／�ﾗ"	"    O      H   H OH"							"180-181ﾟC(095)"		"[α]/D=+38ﾟ (118)"				"095/118/"		"cm-1 1708(C=0) (095)"	"1H-NMR (CDCl3) (095) 18-CH3=0.70(s), 19-CH3=0.98(s), 21-CH3=0.98(d), 7β-H=3.90(brs), 12β-H=4.01(brm)"	"Me-TMS 564, 549, 474, 384, 269(BASE PEAK), 251, 242  (003)"		"095/003/"	"牛胆汁(134)"	"134/"					"bileaciPage26.html"
"BA0027"	5.00		"3α,12α-DIHYDROXY-7-OXO-5β-CHOLAN-24-OIC ACID"	"7-KOTODEOXYCHOLIC ACID"	"7-KDCA"		"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ｸ"	"    H OH   H     O"							"200ﾟC, 157-162ﾟC (Me ESTER)(001)"		"[α]/D=+1.5ﾟ (001)"				"001/"	"λMETHANOL/MAX=267nm (ε=44), 220nm (ε=57) (119)"		"1H-NMR (DMSO-d6) (119) 18-CH3=0.61(s), 19-CH3=0.93(s), 21-CH3=0.93(d), 23-CH2=2.11(m),  3β-H=3.30(m), 12β-H=3.74(m)"	"Me-TMS 564, 549, 474, 456, 366, 359, 341(BASE PEAK), 269, 251 (003)"		"119/003/"	"牛胆汁(134)，ヘビ胆汁(120)，サル胆汁(121)，ラット胆汁(105)，ヒト(104/106/  107) ，犬(104)，ラットの糞便(105)，胆汁うっ滞患者尿(014/122)，肝硬変患者の 糞便(092)"	"134/120/121/105/104/106/107/014/122/092/"					"bileaciPage27.html"
"BA0028"	5.00		"3α,7α-DIHYDROXY-12-OXO-5β-CHOLAN-24-OIC ACID"	"12-KETOCHENODEOXYCHOLIC ACID"	"12-KCDCA"		"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406			"              O  ＼／＼"	"              ‖   �ﾓH �ｵ"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H OH   H   H OH"							"219ﾟC(123)"		"[α]/D=+81ﾟ (123)"				"123/"	"λMETHANOL/MAX=287nm(ε=41), 220nm(ε=42) (119)"		"1H-NMR (DMSO-d6) (119) 18-CH3=0.94(s), 19-CH3=0.96(s), 21-CH3=0.76(d,J=5Hz), 3β-H=3.25(brm), 7β-H=3.70(m), 23-CH2=2.16(m)(119)"	"Me-TMS 564, 474, 384, 319, 251, 243, 229(BASE PEAK), 154  (003)"		"119/003/"	"ヒト糞便(015/107)，肝胆道疾患患者の糞便(092)，尿(092)，胆汁(124)"	"015/107/092/124/"					"bileaciPage28.html"
"BA0029"	5.00		"3α,7α,12α,23-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                         OH"	"             H OH＼／＼／"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H OH   H   H OH"							"152-154ﾟC(SOLVATED)(125), 184-185ﾟC(Et ESTER)(021)"		"[α]/D=+36ﾟ (125)"				"021/125/"				"Me-TMS 546, 456, 343, 253, 143 (021)"		"021/"	"アザラシ，トド，ヘビ（クサリヘビ）の胆汁(114/126)，肝胆道疾患患者の尿(021/037)， CTX患者尿(127)"	"114/126/021/037/127/"			"ノルコール酸の前駆体"		"bileaciPage29.html"
"BA0030"	5.00		"1β,3α,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"       HO H  ／�ｪ／＼  COOH"	"       �ﾒ�ﾄ  �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H OH   H   H OH"							"288-290 ﾟC(128)"						"128/"		"cm-1 (NUJOL) 1705(C=0) 3400, 3300 (OH) (128)"	"1H-NMR(PYR.d5) (128),18-CH3=0.81(s),19-CH3=1.40(s),1α-H,7β-H,12β-H=4.03-4.38(m),3β-H=4.48-4.86(m),13C-NMR(CD3OD) Me ESTER (129),C1=74.1,C2=38.0,  C3=67.3,C4=40.0,C5=37.0,C6=35.5,C7=68.8,C8=41.3,C9=29.5,C10=40.3,C11=29.6,C12=73.8,C13=47.3,C14=42.9,C15"	"Me-TMS 636, 546, 456, 366, 314, 251, 217(BASE PEAK)(003)"		"128/129/003/"	"胆汁うっ滞症患者尿(021/037/066/129)，正常人尿(128)，腎障害患者尿(128)，ヒト胎便(130/131)，羊水および新生児尿(131/132)"	"021/037/066/129/128/130/131/132/"			"１β-水酸化胆汁酸は胎児肝において１β-水酸化酵素によって生成するものと考え られ，また，胎児-新生児期に多量に存在することから，胎児胆汁酸と呼ばれる。"		"bileaciPage30.html"
"BA0031"	5.00		"3α,6α,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H OH  H  �ﾗH OH"	"             H OH"						"161-163ﾟC(WITH PREVIOUS SOFTENING AT 121-124ﾟC)(133)"		"[α]26/D=+23.3ﾟ (133)"				"133/"			"IH-NMR(CD3OD) Me ESTER, 18-CH3=0.71, 19-CH3=0.91, 21-CH3=1.00, 3β-H=3.30, 6β-H=3.77,7β-H=3.77, 12β-H=3.94   13C-NMR(CD3OD) Me ESTER,C1=36.7,C2=31.2,C3=72.8,C4=33.2,C5=49.5,C6=70.7,C7=72.8,C8=40.3,C9=27.7,C10=36.7,C11=29.7,C12=73.7,C13=47.5,C14=42.9,C"	"Me-TMS 711, 636, 621, 546(BASE PEAK), 531, 456, 367(CA-6α-OL), 353, 351  (003)"		"129/003/"	"胆汁うっ滞症患者尿(021/037/066/129)，新生児尿(132/133/136)，胎便(130/133)"	"021/037/066/129/132/133/136/130/133/"			"CHOLIC ACIDはCHENODEOXYCHOLIC ACID の場合と異なり，主として１β位が水酸化され，６β水酸化は副経路(133)"	"133/"	"bileaciPage31.html"
"BA0032"	5.00		"3α,7β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"	"ALLOURSODEOXYCHOLIC ACID"	"ALLO-UDCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"    H OH   H  OH H"						"243.5〜245ﾟC(069)"								"cm-1 1677(C=0)  3300,1032,1003(OH) (069)"	"1H-NMR(CDCl3+20%DMSO-d6)0.68(s,18-CH3),0.78(s,19-CH3),0.93(d,J=5.4Hz,      21-CH3),3.40(brm,7αｰH),3.95(m,3βｰH)(069) 13C-NMR(CDCl3)Me ESTER C1 32.2, C2 29.0,C3 65.9,C4 35.7,C5 36.4,C6 38.4,C7 74.9,C8 43.6,C9 52.8,C10 35.4, C11 20.9,C12 40.0,C13 43.6,C14"			"007/069/"							"bileaciPage32.html"
"BA0033"	5.00		"3β,7α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｱ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"   HO  H   H   H OH"						"271〜272ﾟC,160〜161ﾟC(Me ESTER)(069)"						"069/"		"cm-1 1715(C=0)  3550,1042,1024(OH) (069)"	"1H-NMR(CDCl3+20%DMSO-d6)0.65(s,18-CH3),0.78(s,19-CH3),0.92(d,J=5.4Hz,      21-CH3),3.53(brm,3αｰH),3.74(m,7βｰH)(069) 13C-NMR(CDCl3)Me ESTER C1 36.8, C2 31.1,C3 70.8,C4 37.5,C5 36.6,C6 36.3,C7 67.5,C8 39.3,C9 45.6,C10 35.3, C11 20.8,C12 39.3,C13 42.4,C14"			"007/069/"							"bileaciPage33.html"
"BA0034"	5.00		"3β,7β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"                 �ｲ�ｱ�ｲ"	"                   �ﾓ  �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"   HO  H   H   OH H"						"245.0〜246.5ﾟC,159〜160ﾟC(Me ESTER)(069)"						"069/"		"cm-1 1690(C=0)  3400,1034(OH) (069)"	"1H-NMR(CDCl3+20%DMSO-d6)0.67(s,18-CH3),0.91(s,19-CH3),0.93(d,J=6.3Hz,21-CH3),3.35(brm,3αｰH AND 7α-H) (069) 13C-NMR(CDCl3)Me ESTER C1 36.8, C2 31.3, C3 70.4,C4 37.7,C5 42.1,C6 38.5,C7 74.6,C8 43.3,C9 52.5,C10 34.8,C11 21.1, C12 39.9,C13 43.3,C14 55.8,C1"			"007/069/"							"bileaciPage34.html"
"BA0035"	5.00		"3α,12β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"            HO  H�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ"	"    H  OH  H"						"206.5〜207.5ﾟC,143〜144ﾟC(Me ESTER)(070)"						"070/"		"cm-1 1680(C=0)  3440,1050,1028,1013,1000,970(OH) (070)"	"1H-NMR(CDCl3+20%Me2SO-d6)0.72(s,18-CH3),0.79(s,19-CH3),1.03(d,J=7.2Hz,21-  CH3),3.39(brm,12αｰH),3.99(m,3β-H) (070) 13C-NMR(CDCl3)Me ESTER C1 32.1,  C2 28.8, C3 66.2,C4 35.7,C5 38.9,C6 28.4,C7 32.1,C8 34.1,C9 53.0,C10 35.8, C11 29.4,C12 79.3,C13 47.7,C1"			"007/070/003/"							"bileaciPage35.html"
"BA0036"	5.00		"3β,12α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"             H HO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ"	"   HO  H  H"						"228.5〜229.5ﾟC,140〜142ﾟC(Me ESTER)(070)"		"[α]/D=+37.8ﾟ (METHANOL)            (137)"				"070/137/"		"cm-1 1715(C=0)  3530,1042,1017,982,958(OH) (070)"	"1H-NMR(CDCl3+20%Me2SO-d6)0.68(s,18-CH3),0.80(s,19-CH3),1.00(d,J=5.4Hz,21-  CH3),3.52(brm,3αｰH),3.92(m,12β-H) (070) 13C-NMR(CDCl3)Me ESTER C1 36.7,  C2 31.5, C3 70.8,C4 37.9,C5 44.6,C6 28.4,C7 31.2,C8 35.5,C9 47.2,C10 34.9 C11 28.7,C12 72.8,C13 46.2,C14"	"Me-TMS 535,460,445,370,355,345,323,255(BASE PEAK) 213 (003)"		"003/007/070/137/"	"肝胆道疾患患者の尿 (021/037/066)"	"021/037/066/"					"bileaciPage36.html"
"BA0037"	5.00		"3β,12β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"            OH  H�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ"	"   HO  H  H"						"223.5〜225.5ﾟC,159.0〜160ﾟC(Me ESTER)(070)"						"070/"		"cm-1 1715(C=0)  3250,1075,1040,1027,975(OH) (070)"	"1H-NMR(CDCl3+20%Me2SO-d6)0.71(s,18-CH3),0.81(s,19-CH3),1.03(d,J=7.2Hz,21-  CH3),3.38(brm,3αｰH AND 7α-H) (070)    13C-NMR(CDCl3)  Me ESTER C1 36.8,  C2 31.4, C3 70.7,C4 37.9,C5 44.6,C6 28.4,C7 32.0,C8 34.0,C9 52.9,C10 35.2,C11 29.3,C12 79.1,C13 47.6,C14"	"Me-TMS 535,460,445,355,345(BASE PEAK),323,255,208 (003)"		"003/007/070/"							"bileaciPage37.html"
"BA0038"	5.00		"7α,12α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"             H HO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"       �ｲ�ｱ�ﾊ�ｱ�ﾗ"	"           H   H OH"						"225〜227ﾟC,165〜166ﾟC(Me ESTER)(138)"		"[α]25/D=+22.0ﾟ (139)"				"138/139/"		"cm-1 1719(C=0)  3400,1028(OH) (138)"	"1H-NMR(CDCl3+20%DMSO-d6)  0.67(s,18-CH3),0.77(s,19-CH3),0.99(d,J=5.4Hz,21- CH3),3.74(m,7β-H),3.89(m,12β-H) (138)    13C-NMR(CDCl3)Me ESTER C1 38.2, C2 22.0,C3 26.6,C4 28.6,C5 39.1,C6 36.8,C7 67.9,C8 39.7,C9 39.7,C10 35.9 C11 28.3,C12 72.8,C13 46.5,C14"			"007/138/139/"							"bileaciPage38.html"
"BA0039"	5.00		"7α,12β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"             HO H�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"       �ｲ�ｱ�ﾊ�ｱ�ﾗ"	"           H   H OH"						"168〜170ﾟC,147.5〜148.0ﾟC(Me ESTER)(138)"						"138/"		"cm-1 1708(C=0)  3425,1032,1015(OH) (138)"	"1H-NMR(CDCl3+20%DMSO-d6)  0.68(s,18-CH3),0.77(s,19-CH3),1.02(d,J=6.3Hz,21- CH3),3.27(brm,12α-H),3.74(m,7β-H) (138)  13C-NMR(CDCl3)Me ESTER C1 38.3, C2 21.9,C3 26.5,C4 28.4,C5 39.1,C6 36.8,C7 67.6,C8 38.2,C9 45.2,C10 36.2, C11 29.5,C12 78.9,C13 47.6,C14"			"007/138/139/"							"bileaciPage39.html"
"BA0040"	5.00		"7β,12α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"             H HO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"       �ｲ�ｱ�ﾊ�ｱ�ﾗ"	"           H   OH H"						"207.5〜208.5ﾟC,133.5〜134.0ﾟC(Me ESTER)(138)"						"138/"		"cm-1 1685(C=0)  3300,1028,990(OH)  (138)"	"1H-NMR(CDCl3+20%DMSO-d6)  0.68(s,18-CH3),0.78(s,19-CH3),0.99(d,J=6.3Hz,21- CH3),3.26(brm,7α-H),3.90(m,12β-H) (138)  13C-NMR(CDCl3)Me ESTER C1 38.5, C2 22.0,C3 26.5,C4 28.5,C5 44.0,C6 38.7,C7 74.9,C8 43.6,C9 45.7,C10 35.2,C11 28.6,C12 72.4,C13 47.3,C14"			"007/138/"							"bileaciPage40.html"
"BA0041"	5.00		"7β,12β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392				"             HO H�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"       �ｲ�ｱ�ﾊ�ｱ�ﾗ"	"           H   OH H"						"208〜210ﾟC,154.5〜156.0ﾟC(Me ESTER)(138)"						"138/"		"cm-1 1677(C=0)  3275,1036,1008,990(OH) (138)"	"1H-NMR(CDCl3+20%DMSO-d6)  0.72(s,18-CH3),0.80(s,19-CH3),1.00(d,J=6.3Hz,21- CH3),3.26(brm,7α-H AND 12α-H) (138)    13C-NMR(CDCl3)Me ESTER  C1 38.6,  C2 21.9,C3 26.4,C4 28.5,C5 44.2,C6 38.7,C7 74.8,C8 42.1,C9 51.6,C10 35.5,C11 29.1,C12 79.4,C13 48.5,C14"			"007/138/"							"bileaciPage41.html"
"BA0042"	5.00		"3α,7α,12β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408				"             HO H�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"    H OH   H   H OH"						"210.5〜212.0ﾟC,126.0〜127.5ﾟC(Me ESTER)(116)"						"116/"		"cm-1 1700(C=0)  3450,1010,995(OH) (116)"	"1H-NMR(CDCl3+DMSO-d6) 0.66(s,18-CH3),0.74(s,19-CH3),1.00(d,J=6.3Hz,21-CH3),3.32(brm,12α-H),3.69(m,7β-H),3.90(m,3β-H)(116) 13C-NMR(CDCl3)Me ESTER   C1 32.2,C2 28.8,C3 66.2,C4 35.4,C5 31.4,C6 36.4,C7 67.5,C8 38.3,C9 44.8,C10 36.0,C11 29.5,C12 78.9,C13 4"			"007/116/"							"bileaciPage42.html"
"BA0043"	5.00		"3α,7β,12α-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408				"              HHO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"    H OH   H   OH H"						"269〜271,166〜167ﾟC(Me ESTER)(116), 253〜255ﾟC(140)"		"[α]27/D=+57ﾟ(METHANOL)           (140)"				"116/140/"		"cm-1(KBr) 1675(C=0)  3500,1025,1000(OH) (116)"	"1H-NMR(CDCl3+50%DMSO-d6) 0.66(s,18-CH3),0.74(s,19-CH3),0.97(d,J=5.4Hz,21-  CH3),3.24(brm,7α-H),3.88(m,3β-H AND 12β-H)(116) 13C-NMR(CDCl3)Me ESTER  C1 31.9,C2 28.8,C3 65.7,C4 35.4,C5 36.1,C6 38.2,C7 74.6,C8 43.4,C9 45.1,C1034.8,C11 28.4,C12 72.1,C13 47"	"Me-TMS 458,343,253 (021)"		"007/021/116/"	"肝胆道疾患患者の尿(021)"	"021/"					"bileaciPage43.html"
"BA0044"	5.00		"3β,7α,12α-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408				"              HHO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"    OH H   H   H OH"						"236〜238ﾟC ,200〜202ﾟC(Me ESTER)(116)"		"[α]25/D=+25.2ﾟ (139)"				"116/139/"		"cm-1(KBr) 1705(C=0)  3420,1035(OH) (116)"	"1H-NMR(CDCl3+20%DMSO-d6)0.68(s,18-CH3),0.79(s,19-CH3),0.99(d,J=5.4Hz,21-CH3),3.53(brm,3α-H),3.78(m,7β-H),3.91(m,12β-H)(116) 13C-NMR(CDCl3)Me ESTER C1 36.6,C2 31.3,C3 71.0,C4 37.7,C5 37.1,C6 36.5,C7 67.7,C8 39.8,C9 39.3,C10 35.1,C11 28.6,C12 72.8,C13 4"			"007/116/139/"							"bileaciPage44.html"
"BA0045"	5.00		"3α,7β,12β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408				"             HO H�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"    H OH   H   OH H"						"243〜244ﾟC,178〜179ﾟC(Me ESTER)(116)"						"116/"		"cm-1(KBr) 1735,1710(C=0)  3280,1028,1005(OH) (116)"	"1H-NMR(CDCl3+50%DMSO-d6)0.67(s,18-CH3),0.75(s,19-CH3),0.97(d,J=6.3Hz,21-CH3),3.27(brm,7α-H AND 12α-H),3.86(m,3β-H)(116) 13C-NMR(CDCl3)Me ESTER     C1 31.5,C2 28.1,C3 64.4,C4 34.8,C5 35.5,C6 38.0,C7 73.4,C8 41.2,C9 50.5,C10 34.5,C11 28.6,C12 78.4,C13 4"			"007/116/"							"bileaciPage45.html"
"BA0046"	5.00		"3β,7α,12β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408				"             HO H�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"    OH H   H   H OH"						"242〜243ﾟC,110〜111ﾟC(Me ESTER)(116)"						"116/"		"cm-1(KBr) 1675(C=0)  3200,1010(OH) (116)"	"1H-NMR(CDCl3+20%DMSO-d6)0.68(s,18-CH3),0.78(s,19-CH3),1.01(d,J=6.3Hz,21-CH3),3.36(brm,3α-H AND 12α-H),3.73(m,7β-H)(116) 13C-NMR(CDCl3)Me ESTER  C1 36.6,C2 31.0,C3 70.3,C4 37.3,C5 36.9,C6 36.4,C7 66.8,C8 38.0,C9 44.4,C10 35.2,C11 29.3,C12 78.4,C13 47.3"			"007/116/"							"bileaciPage46.html"
"BA0047"	5.00		"3β,7β,12α-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408				"             H HO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"    OH H   H   OH H"						"252〜254ﾟC,149〜151ﾟC(Me ESTER)(116)"						"116/"		"cm-1(KBr) 1680(C=0)  3440,1027(OH) (116)"	"1H-NMR(CDCl3+20%DMSO-d6)0.67(s,18-CH3),0.79(s,19-CH3),0.98(d,J=5.4Hz,21-CH3),3.34(brm,3α-H AND 7α-H),3.87(m,12β-H)(116) 13C-NMR(CDCl3)Me ESTER  C1 36.7,C2 31.3,C3 70.9,C4 37.7,C5 42.1,C6 38.3,C7 74.8,C8 43.5,C9 45.1,C10 34.5,C11 29.0,C12 72.4,C13 47.4"	"Me-TMS 458,368,343,253 (021)"		"007/021/116/"	"肝胆道疾患患者の尿(021)"	"021/"					"bileaciPage47.html"
"BA0048"	5.00		"3β,7β,12β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408				"             HO H�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ  �ｵ  �ｵ  H"	"     �ﾕ�ﾊ�ｱ�ﾊ�ｱ�ﾗ"	"    OH H   H   OH H"						"227〜228ﾟC,165〜166ﾟC(Me ESTER)(116)"						"116/"		"cm-1(KBr) 1673(C=0)  3450,1035,1003(OH) (116)"	"1H-NMR(CDCl3+50%DMSO-d6) 0.65(s,18-CH3),0.77(s,19-CH3),0.96(d,J=6.3Hz,21-  CH3),3.31(brm,3α-H,7α-H AND 12α-H)(116)  13C-NMR(CDCl3)Me ESTER C1 36.4,C2 30.9,C3 70.5,C4 37.1,C5 41.4,C6 37.8,C7 74.3,C8 41.6,C9 50.7,C10 34.4,C11 28.7,C12 78.9,C13 48.1,C14"			"007/116/"							"bileaciPage48.html"
"BA0049"	5.00		"3β,6α,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ﾗ"	"   HO  H   H �ﾗH OH"	"             H OH"							"214〜217ﾟC(096)"						"096/"		"cm-1(KBr) 1708(C=0)  3440,1048(OH) (096)"	"1H-NMR(CDCl3+10%DMSO-d6)  0.66(s,18-CH3),0.92(d,J=5.4Hz,21-CH3),0.94(s,19- CH3)3.84(m,7β-H),3.90(brm,6β-H),4.08(m,3α-H)  13C-NMR(CDCl3)Me ESTER  C130.0,C2 27.4,C3 66.0,C4 29.3,C5 42.4,C6 71.8,C7 69.5,C8 38.4,C9 32.0,C1036.4,C11 20.9,C12 39.4,C13 42.7,"	"Me ESTER m/z(RELATIVE INTENSITY) 422(7%,M+),404(34%,M-H2O),386(57%, M-2H2O),371(11%,M-2H20-Me) (096)"		"096/"							"bileaciPage49.html"
"BA0050"	5.00		"3β,6α,7β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ﾗ"	"   HO  H   H �ﾗOH H"	"             H OH"							"129〜131ﾟC(096)"						"096/"		"cm-1(KBr) 1710(C=0)  3410,1025(OH) (096)"	"1H-NMR(CDCl3+10%DMSO-d6)0.66(s,18-CH3),0.92(d,J=5.4Hz,21-CH3),0.95(s,19-CH3)3.33(brm,7α-H),3.74(brm,6β-H),4.00(m,3α-H) 13C-NMR(CDCl3)Me ESTER  C1  29.9,C2 27.3,C3 65.6,C4 27.8,C5 42.3,C6 73.0,C7 75.6,C8 41.6,C9 38.9,C10 35.8,C11 21.5,C12 40.1,C13 43.8"	"Me ESTER m/z(RELATIVE INTENSITY) 422(8%,M+),404(60%,M-H2O),386(73%, M-2H2O),371(13%,M-2H20-Me),368(16%,M-3H2O) (096)"		"096/"							"bileaciPage50.html"
"BA0051"	5.00		"3β,6β,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ﾗ"	"   HO  H   H �ﾗH OH"	"             OH H"							"214〜216ﾟC(096)"						"096/"		"cm-1(KBr) 1720(C=0)  3420,1038,1020(OH) (096)"	"1H-NMR(CDCl3+10%DMSO-d6)0.69(s,18-CH3),0.94(d,J=5.4Hz,21-CH3),1.11(s,19-CH3)3.66(m,6α-H AND 7β-H),4.02(m,3α-H) 13C-NMR(CDCl3) Me ESTER  C1 30.6,   C2 27.7,C3 66.3,C4 33.2,C5 42.8,C6 76.6,C7 73.0,C8 35.2,C9 33.0,C10 35.2,C11 20.8,C12 39.5,C13 42.6,C14"	"Me ESTER m/z(RELATIVE INTENSITY) 422(3%,M+),404(84%,M-H2O),386(24%, M-2H2O),371(7%,M-2H20-Me) (096)"		"096/"							"bileaciPage51.html"
"BA0052"	5.00		"3β,6β,7β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ﾗ"	"   HO  H   H �ﾗOH H"	"             OH H"							"165〜167ﾟC,RESOLIDIFIED AT ABOUT 170ﾟC, AND THEN REME"	"LTED AT 189〜190ﾟC (096)"					"096/"		"cm-1(KBr) 1713(C=0)  3425,1038(OH) (096)"	"1H-NMR(CDCl3+10%DMSO-d6)0.69(s,18-CH3),0.94(d,J=6.3Hz,21-CH3),1.12(s,19-CH3)3.43(brm,7α-H),3.61(m,6α-H),4.03(m,3α-H) 13C-NMR(CDCl3)Me ESTER C1 30.1, C2 27.4,C3 65.7,C4 32.5,C5 42.4,C6 75.0,C7 73.4,C8 38.5,C9 39.2,C10 34.2,C11 21.0,C12 39.9,C13 43.5,C1"	"Me ESTER m/z(RELATIVE INTENSITY) 422(6%,M+),404(86%,M-H2O),386(40%,  M-2H2O),371(9%,M-2H20-Me)(096)"		"096/"							"bileaciPage52.html"
"BA0053"	5.00		"3α,6β,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	6.00	0.00	0.00	0.00	424		"             H HO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ﾗ"	"    H  OH  H �ﾗH OH"	"             OH H"							"165〜167ﾟC(133)"		"[α]26/D=+36.3ﾟ(IN MeOH)"				"133/"			"1H-NMR(PYRIDINE-d5) 1.52(s,19-CH3),4.30(bs,7β-H) (133)"	"Me-TMS: 711(M+-15),636(M+-90),546(M+-90X2),456(M+-90X3),366(M+-90X4), 341,255(M+-90X3-115) (133)"		"133/"	"ﾋﾄ胎便(TRACE)(133)"	"133/"					"bileaciPage53.html"
"BA0054"	5.00		"3α,6β,7β,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"             H HO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ﾗ"	"    H  OH  H �ﾗOH H"	"             OH H"							"240〜242ﾟC(133)"		"[α]26/D=+68.5ﾟ( IN MeOH)(133)"				"133/"			"1H-NMR(PYRIDINE-d5) 1.45(s,19-CH3),3.85(dd,J=3 AND 11Hz,7α-H) (133)"	"Me-TMS 711(M+-15),636(M+-90),546(M+-90X2),456(M+-90X3),367(M+-90X3-89), 285,195 (133)"		"133/"							"bileaciPage54.html"
"BA0055"	5.00		"1β,3α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"       HO H  �ｱ�ｲ�ｫ�ｲ  COOH"	"       �ﾒ�ﾄ  �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ"	"    H  OH  H"								"274〜278ﾟC(128)"						"128/"		"cm-1(NUJOL) 1705(C=0),3400,3300(OH) (128)"	"1H-NMR(PYRIDINE-d6) 0.62(s,18-CH3),1.28(s,19-CH3),4.12〜4.28(m,1α-H), 4.61〜4.99(m,3β-H) (128)"	"Me-TMS 535(M-15),460,370,318,255,217(BASE PEAK)(128)"		"128/"							"bileaciPage55.html"
"BA0056"	5.00		"1β,3α,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"       HO H  �ｱ�ｲ�ｫ�ｲ  COOH"	"       �ﾒ�ﾄ  �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ﾗ"	"    H  OH  H   H OH"								"266〜270ﾟC(128)"						"128/"		"cm-1(NUJOL) 1705(C=0),3380,3280(OH) (128)"	"1H-NMR(PYRIDINE-d5) 0.69(s,18-CH3),1.30(s,19-CH3),3.92〜4.10(m,7β-H), 4.12〜4.28(m,1α-H),4.40〜4.78(m,3β-H) (128)"	"Me-TMS 623(M-15),548,458,368,316,253,217(BASE PEAK)(128)"		"128/"	"ﾋﾄ胎便(128)"	"128/"					"bileaciPage56.html"
"BA0057"	5.00		"1β,3α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"             H HO�ｲ�ｱ�ｲ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"       HO H  �ｱ�ｲ�ｫ�ｲ  COOH"	"       �ﾒ�ﾄ  �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ"	"    H  OH  H"								"262〜264ﾟC(128)"						"128/"		"cm-1(NUJOL) 1705(C=0),3400,3300(OH) (128)"	"1H-NMR(PYRIDINE-d5) 0.75(s,18-CH3),1.34(s,19-CH3),4.10〜4.36(m,1αｰH AND 12β-H),4.58〜4.96(m,3β-H) (128)"	"Me-TMS 623(M-15),548,458,368,316,253,217(BASE PEAK)(128)"		"128/"	"ﾋﾄ健常者の尿(136)，腎疾患患者の尿(136)"	"136/"					"bileaciPage57.html"
"BA0058"	5.00		"3α,4β,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ﾗ"	"    H HO �ﾗH   H OH"	"        HO H"							"128〜130ﾟC(Me ESTER)(141)"						"141/"			"1H-NMR(CDCl3) Me ESTER 0.66(s,18-CH3),0.92(d,J=4.5Hz,21-CH3),0.94(s,19-CH3),3.26(brm,3β-H),3.66(s,COOCH3),3.88(m,7β-H),4.15(dd,J 1.2=10.8Hz,J2,4=   9.0Hz,4αｰH)      (141)"""	"Me-TMS 548(M-90),533,458,443,403,369,329,281,253,181(BASE PEAK)(141)"		"141/"	"ﾋﾄ胎児の胆汁(141/142)"	"141/142/"					"bileaciPage58.html"
"BA0059"	5.00		"3α-HYDROXY-5β-CHOL-6-EN-24-OIC ACID"				"C24H38O3"	24.00	38.00	3.00	0.00	0.00	0.00	374		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｷ"	"    H HO   H"								"218〜219ﾟC,104〜105ﾟC(Me ESTER)(096)"						"096/"		"cm-1 1708(C=0),3330,1062(OH) (096)"	"1H-NMR(CDCl3+10%DMSO-d6) 0.69(s,18-CH3),0.84(s,19-CH3),0.93(d,J=5.4Hz,21-  CH3),3.52(brm,3β-H),5.46(s,6H AND 7H) (096)"			"096/"							"bileaciPage59.html"
"BA0060"	5.00		"3β-HYDROXY-5β-CHOL-6-EN-24-OIC ACID"				"C24H38O3"	24.00	38.00	3.00	0.00	0.00	0.00	374		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｷ"	"   HO  H   H"								"119〜120ﾟC(Me ESTER)(096)"						"096/"		"cm-1 (Me ESTER) 1740(C=0),3280,1042(OH) (096)"	"1H-NMR(CDCl3) Me ESTER 0.70(s,18-CH3),0.89(s,19-CH3),0.93(d,J=6.3Hz,21-CH3),3.66(s,COOMe),4.06(m,3α-H),5.47(s,6H AND 7H)"			"096/"							"bileaciPage60.html"
"BA0061"	5.00		"3α,6α-DIHYDROXY-7-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                 �ｲ�ｱ�ｲ"	"                   �ﾓH �ｵ"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ�ｱ�ﾚ�ｱ�ｸ"	"    H HO   H �ﾗ  O"	"             H OH"							"184〜186ﾟC(096)"		"[α]25/D=-42ﾟ(IN MeOH)(031)"				"096/031/"		"cm-1 1718(C=O),3400,1055,1018(OH) (096)"	"1H-NMR(CDCl3) 0.66(s,18-CH3),0.94(d,J=6.3Hz,21CH3),1.23(s,19-CH3),  3.55(brm,3β-H),4.52(d,J=6.3Hz,6β-H) (096)"			"096/"							"bileaciPage61.html"
"BA0062"	5.00		"3α,6α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ  �ｵ  H"	"    �ﾕ�ﾊ／�ﾚ／"	"   H  OH  H �ﾗ"	"            H OH"						"135-137ﾟC(143)"		"[α]23/D : +20.3ﾟ(IN DIOXANE) (144/145)"				"143/144/145/"		"3401,1037cm-1(OH),  1709cm-1(C=O) (143)"	"1H-NMR(CDCl3): 0.67(s,18-Me),089(s,19-Me),0.99(d,J=5.4Hz,21-Me),3.58(brm, 3β-H),4.03(m AND brm,6β- AND 12β-H)(143) 13C-NMR(CDCl3)Me ESTER: C1 35.66,C2 30.08,C3 71.53,C4 29.18,C5 48.53,C6 68.08,C7 34.81,C8 35.10,C9 32.97,C10 35.60,C11 28.62,C12 7 C20 35.27,C21 17.32,C22 31.18,C23 30.96,C24 174.85,CCOOMe 51.59(143)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 404(7%),386(81%),368(23%),289(20%), 271(100%),253(67%) (143)"		"143/"	"妊婦および 肝障害妊婦の尿中(066/146) 正常人尿中のグルクロン酸抱合画分(147)"	"066/146/147/"					"bileaciPage62.html"
"BA0063"	5.00		"3α,6β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ  �ｵ  H"	"    �ﾕ�ﾊ／�ﾚ／"	"   H HO   H �ﾗ"	"           HO H"						"137-139ﾟC(039/143)"		"[α]26/D : +36ﾟ(95%EtOH) (039)"				"039/143/"		"3401,1045cm-1(OH),  1711cm-1(C=O) (143)"	"1H-NMR(CDCl3): 0.71(s,18-Me),098(d,J=6.3Hz,21-Me),1.09(s,19-Me),3.62(brm,  3β-H),3.74(m,6α-H),3.98(m,12β-H)(143) 13C-NMR(CDCl3)Me ESTER: C1 35.76,C2 30.12,C3 71.30,C4 36.44,C5 48.68,C6 73.13,C7 34.45,C8 30.96,C9 34.06,C10 33.97,C11 28.51,C12 73.1C20 35.16,C21 17.43,C22 31.17,C23 30.96,C24 174.78,CCOOMe 51.59(143)"	"ME ESTER  M/Z(RELATIVE INTENSITY,%) 404(4%),386(28%),368(12%),289(19%),  271(100%),253(34%) (143)"		"143/"	"正常人の尿中(021)肝障害患者の尿中(021/037) 妊婦の尿中(066/146)肝内胆汁うっ滞患者の尿(148)"	"021/037/066/146/148/"					"bileaciPage63.html"
"BA0064"	5.00		"3β,6α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ  �ｵ  H"	"    �ﾕ�ﾊ／�ﾚ／"	"  HO  H   H �ﾗ"	"            H OH"						"135-137ﾟC,115-117ﾟC (143)"						"143/"		"3412,1036,976cm-1(OH),  1709cm-1(C=O) (143)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.67(s,18-Me),0.92(s,19-Me),0.96(d,J=7.2Hz,21-Me)3.96(m,12β-H),4.00(brm,6β-H),4.08(m,3α-H)(143) C20 35.13,C21 17.40, C22 31.12,C23 30.93,C24 174.78,CCOOMe 51.59(143) 13C-NMR  Me ESTER: C1 30.08,C2 27.43,C3 66.09,C4 26.25,C5 43.05,C6 67.85,  C7 34.37,C8 34.93,C9 32.33,C10 36.05,C11 28.93,C12"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 404(6%),386(42%),289(79%),271(100%), 253(39%) (143)"		"143/"							"bileaciPage64.html"
"BA0065"	5.00		"3β,6β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ  �ｵ  H"	"    �ﾕ�ﾊ／�ﾚ／"	"  HO  H   H �ﾗ"	"           HO H"						"131-133ﾟC,196-197ﾟC (Me ESTER)(143)"						"143/"		"3408,1023cm-1(OH),  1709cm-1(C=O) (143)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.70(s,18-Me),0.98(d,J=5.4Hz,21-Me),1.11(s,19-Me)3.66(m,6α-H),3.99(m,3α- AND 12β-H)(143) 13C-NMR  Me ESTER: C1 29.43,C2 26.50,C3 64.44,C4 32.24,C5 42.23,C6 71.38,  C7 33.42,C8 29.91,C9 32.86,C10 33.48,C11 28.04,C12 71.58, C20 34.37,C21 16.36,C22 30.09,C23 29.91,C24 173.65,CCOOMe 50.49(143)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 404(2%),386(18%),289(14%),271(100%), 253(19%) (143)"		"143/"							"bileaciPage65.html"
"BA0066"	5.00		"3α,6α,7β,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗH"	"   H  OH  H �ﾗOH"	"            H OH"						"148-151ﾟC,100-102ﾟC (Me ESTER)(149)"						"149/"		"3421,1040,952cm-1(OH),  1708cm-1(C=O) (149)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.65(s,18-Me),0.90(s,19-Me),0.98(d,J=5.4Hz,21-Me)3.34(brm,3β- AND 7α-H),3.60(brm,6β-H),3.87(m,12β-H)(149)    13C-NMR  Me ESTER: C1 35.1,C2 30.9,C3 71.1,C4 29.9,C5 47.7,C6 73.1,C7 75.2,C8 41.8,C9 32.1,C10 34.8,C11 27.8,C12 C23 31.0,C24 174.7,CCOOMe 51.4(149)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 402(24%),384(26%),366(6%),305(69%), 287(35%),269(82%),251(22%) (149)"		"149/"							"bileaciPage66.html"
"BA0067"	5.00		"3α,6α,7β,12α-TETRAHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾊ／�ﾗH"	"   H  OH  H �ﾗOH"	"            H OH"						"149-152ﾟC,181-182ﾟC (Me ESTER)(149)"						"149/"		"3418,1012cm-1(OH),  1711cm-1(C=O) (149)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.68(s,18-Me),0.79(s,19-Me),0.99(d,J=5.4Hz,21-Me)3.45(brm,7α-H),3.66(brm,6β-H),3.91(m,12β-H),4.03(m,3β-H)(149)        13C-NMR  Me ESTER: 12.2(C-18),12.7(C-19),65.6(C-3),72.3(C-12),75.2(C-7),80.5(C-6)(149)"""	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 438[M+](1%),420(2%),402(21%),384(12%), 305(100%),287(39%),269(61%),251(17%) (149)"		"149/"							"bileaciPage67.html"
"BA0068"	5.00		"3α,12α-DIHYDROXY-5β-CHOL-6-EN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ�ｷ"	"   H  OH  H"							"160-162ﾟC(149)"			"[α]21/D : 36±2ﾟ(DIOXANE)(150)"			"149/150/"		"3392cm-1(OH),  1695cm-1(C=O) (149)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.69(s,18-Me),0.81(s,19-Me),1.00(d,J=5.4Hz,21-Me)3.39(brm,3β-H),3.95(m,12β-H),5.45(s,6- AND 7-H)(149)"""			"149/"							"bileaciPage68.html"
"BA0069"	5.00		"3α,4β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"   H�ﾕ�ﾊ／�ﾚ／"	"    HO�ﾕ�ﾂH"	"     HO H"						"156-168ﾟC,174-175ﾟC(Me ESTER)(151)"						"151/"		"3456,1019cm-1(OH),  1703cm-1(C=O) (151)"	"1H-NMR(CDCl3): 0.65(s,18-Me),0.93(d,J=6.3Hz,21-Me),0.96(s,19-Me),3.41(brm,3β-H),3.68(brm,4α-H)(151)  42.7,C14 56.5,C15 24.1,C16  28.1,C17 56.0,C18 12.0,C19 23.5,C20 35.3,C21 18.2,C22 31.0,C23 31.0,C24 174.6,CCOOMe 51.3(151) C23 31.0,C24 174.6,CCOOMe 51.3(151)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 406[M+](6%),388(100%),370(23%), 264(18%),249(21%) (151)"		"151/"	"新生児の胎便および糞便(141/152)"	"141/152/"					"bileaciPage69.html"
"BA0070"	5.00		"3β,4β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／"	"  HO H�ﾕ�ﾂH"	"     HO H"						"189-191ﾟC(151),191-192ﾟC,128-129ﾟC(Me ESTER)(153)"						"151/153/"		"3412,1028cm-1(OH),  1708cm-1(C=O) (151)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.65(s,18-Me),0.92(d,J=6.3Hz,21-Me),0.96(s,19-Me)3.71(brm,4α-H),3.93(m,3α-H)(151) 13C-NMR Me ESTER: C1 29.2,C2 25.8,C3 68.4,C4 69.5,C5 44.0,C6 21.1,C7 26.0, C8 35.5,C9 41.6,C10 36.6,C11 20.7,C12 40.1,C13 42.6,C14 56.  C23 31.0,C24 174.6,CCOOMe 51.4(151)"	"Me ESTER M/Z(RELATIVE INTENSITY,%) 406[M+](76%),388(100%),370(26%), 264(60%),249(33%)(151)"		"151/"							"bileaciPage70.html"
"BA0071"	5.00		"3β,4β,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  HO H�ﾕ�ﾂH   H OH"	"     HO H"						"212-214ﾟC, 203-205ﾟC(Me ESTER)(151)"						"151/"		"3372cm-1(OH),  1712cm-1(C=O) (151)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.65(s,18-Me),0.92(d,J=5.4Hz,21-Me),0.94(s,19-Me)3.87(m,3α- AND 7β-H),4.33(brm,4α-H)(151) 13C-NMR  Me ESTER: C1 29.2,C2 25.9,C3 69.5,C4 71.4,C5 42.9,C6 28.0,C7 68.6, C8 39.3,C9 34.0,C10 36.9,C11 20.9,C12 39.6,C13 42.7, C23 31.0, C24 174.6,CCOOMe 51.3(151)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 404(100%),386(39%),289(19%),271(11%), 253(5%)(151)"		"151/"							"bileaciPage71.html"
"BA0072"	5.00		"3α,4β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"   H�ﾕ�ﾊ／�ﾚ／"	"    HO�ﾕ�ﾂH"	"     HO H"						"151-152ﾟC(151)"						"151/"		"3402,1036cm-1(OH),  1706cm-1(C=O) (151)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.67(s,18-Me),0.93(s,19-Me),0.97(d,J=6.3Hz,21-Me)3.30(brm,3β-H),3.75(brm,4α-H),3.92(m,12β-H)(151)                      13C-NMR  Me ESTER: C1 34.6,C2 27.4,C3 76.7,C4 72.5,C5 48.5,C6 20.8,C7 25.8 C8 35.9,C9 35.4,C10 36.4,C11 C23 30.9,C24 174.6,CCOOMe 51.4(151)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 404(9%),386(9%),368(5%),289(100%), 271(23%),253(14%)(151)"		"151/"							"bileaciPage72.html"
"BA0073"	5.00		"3β,4β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"  HO�ﾕ�ﾊ／�ﾚ／"	"     H�ﾕ�ﾂH"	"     HO H"						"202-203ﾟC, 189-190ﾟC(Me ESTER)(151)"						"151/"		"3412,1029cm-1(OH),  1705cm-1(C=O) (151)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.66(s,18-Me),0.93(s,19-Me),0.97(d,J=6.3Hz,21-Me)3.76(brm,4α-H),3.90(m,3α- AND 12β-H)(151) 13C-NMR  Me ESTER: C1 29.1,C2 25.7,C3 68.3,C4 69.5,C5 43.9,C6 20.6,C7 25.7, C8 35.7,C9 34.9,C10 36.1,C11 28.9,C12 73.1,C13 46.4,C14  C23 30.9,C24 174.6,CCOOMe 51.4(151)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 404(4%),289(100%),271(23%),253(13%) (151)"		"151/"							"bileaciPage73.html"
"BA0074"	5.00		"3α,4β,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"   H�ﾕ�ﾊ／�ﾚ／�ﾗ"	"    HO�ﾕ�ﾂH   H OH"	"     HO H"						"150-152ﾟC, 146-148ﾟC(Me ESTER)(141)"						"141/"		"3396,1028cm-1(OH),  1703cm-1(C=O) (151)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.66(s,18-Me),0.91(s,19-Me),0.99(d,J=6.3Hz,21-Me)3.20(brm,3β-H),3.85(m,7β- AND 12β-H),4.13(brm,4α-H)(151)    13C-NMR  Me ESTER: C1 34.6,C2 28.1,C3 76.0,C4 75.3,C5 47.9,C6 27.5,C7 68.5, C8 39.2,C9 28.1,C10 36.8,C11 28.1,C12 C23 31.0,C24 174.7,CCOOMe 51.4(151)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 420(4%),402(21%),384(25%),287(35%), 269(100%)(151)"		"151/"	"ヒト胎児の胆汁(141/154) 新生児の糞便(141)  ヒト胎児の羊水(155)"	"141/154/155/"					"bileaciPage74.html"
"BA0075"	5.00		"3β,4β,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  HO H�ﾕ�ﾂH   H OH"	"     HO H"						"148-149ﾟC, 216-218ﾟC(Me ESTER)(151)"						"151/"		"3385,1023cm-1(OH),  1708cm-1(C=O) (151)"	"1H-NMR(CDCl3+20%DMSO-d6): 0.68(s,18-Me),0.94(s,19-Me),0.98(d,J=6.3Hz,21-Me)3.93(m,3α-,7β-, AND 12β-H),4.36(brm,4α-H)(151) 13C-NMR  Me ESTER: C1 29.2,C2 25.6,C3 69.7,C4 71.1,C5 42.7,C6 28.6,C7 68.9, C8 39.4,C9 27.4,C10 36.6,C11 28.0,C12 73.1,C13 4 C23 30.9,C24 174.7,CCOOMe 51.4(151)"	"Me ESTER  M/Z(RELATIVE INTENSITY,%) 420(29%),402(65%),384(24%),287(100%), 269(44%)(151)"		"151/"							"bileaciPage75.html"
"BA0076"	5.00		"3β,7β-DIHYDROXY-CHOL-5-EN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ｸ／�ﾗ"	"  HO H       HO H"							"237ﾟC(075), 223-225ﾟC(071), 124-125ﾟC(Me ESTER)(075/071)"		"[α]20/D : +10.4ﾟ(DIOXANE)(071)"				"075/071/"		"(NUJOL) 3470,3200cm-1(OH),  1725,1700cm-1(COOH) (075)"	"1H-NMR(PYRIDINE-d5) : 0.70(s,18-Me), 0.95(s,19-Me), 3.67(m,3α-H), 3.92(d,J=9Hz,7α-H), 5.48(bs,6-H) (075)"	"Me-TMS  M/Z(RELATIVE INTENSITY,%) 458(100%),368(2%),253(0%)(075)"		"075/"	"肝障害患者の尿(156)"	"156/"					"bileaciPage76.html"
"BA0077"	5.00		"1α,3α,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"VULPECHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"       H  OH／＼�ﾇ＼  COOH"	"      �ﾒ�ﾄ  �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H   H OH"							"150-152ﾟC(157)"						"157/"			"1H-NMR Me ESTER(CDCl3): 0.76(s,18-Me),0.90(bd,21-Me),1.11(s,19-Me),2.5-3.5 (br),3.30(bd),3.68(s,COOMe),3.85(bs)(157) 13C-NMR (MeOH-d4): C1 79.9,C2 40.2,C3 68.7,C4 39.8,C5 41.4,C6 35.2,C7 70.2,  C8 41.1,C9 34.9,C10 41.1,C11 24.1,C12 41.2,C13 43.2,C1 C23 32.4,C24 178.9(157)"	"FREE ACID M/Z(RELATIVE INTENSITY,%) 390(88%),372(100%),357(14%),354(10%), 302(72%),262(18%),244(24%)(157)"		"157/"	"袋ネズミの胆汁(157/158)"	"157/158/"					"bileaciPage77.html"
"BA0078"	5.00		"1α,3α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"      H   OH／＼�ﾇ＼  COOH"	"      �ﾒ�ﾄ  �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／"	"   H  OH  H"							"148-150ﾟC(Me ESTER)(159)"		"[α] /D : 21ﾟ(CHCl3) (Me ESTER)(159)"				"159/"		"Me ESTER 3500cm-1(OH), 1730cm-1(C=O)"	"1H-NMR Me ESTER : 3.15(d,3β-H),3.30(d,1β-H),3.60(s,Ome)(159)"	"Me-TMS M/Z 217,142,143(1,3-DIHYDROXY-5β-CHOLAN-24-OATE)(159)"		"159/"							"bileaciPage78.html"
"BA0079"	5.00		"3α,6α-DIHYDROXY-6β-METHYL-5β-CHOLAN-24-OIC ACID"	"6β-METHYL-HYODEOXYCHOLIC ACID"	"6β-Me-HDCA"		"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H     OH"							"186.5-188.0ﾟC(160)"						"160/"			"1H-NMR(PYRIDINE-d5) :0.65(s,18-Me), 0.93(d,J=6Hz,21-Me), 1.02(s,19-Me), 1.65(s,6β-Me), 3.70-4.10(m,3β-H) (160)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 564(13%),549(2%),384(3%),337(100%) (160)"	"HPLC: MORE HYDROPHILIC THEM THE CORRESPONDING COMPOUND WITHOUT A 6-METHYL  GROUP(160)"	"160/"			"動物モデルにおける胆石溶解剤"				"bileaciPage79.html"
"BA0080"	5.00		"3α,6β-DIHYDROXY-6α-METHYL-5β-CHOLAN-24-OIC ACID"	"6α-METHYL MURIDEOXYCHOLIC ACID"	"6α-Me-MDCA"		"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H  HO"																"1H-NMR(PYRICINE-d5): 0.64(s,18-Me),0.92(d,J=6Hz,21-Me),1.32(s,19-Me),1.42(s,6α-Me),3.50-3.98(m,3β-H)(160)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 564(19%),549(6%),459(4%),384(5%),369(2%), 353(2%),337(100%)(160)"	"HPLC: MORE HYDROPHILIC THEM THE CORRESPONDING COMPOUND WITHOUT A 6-METYL  GROUP(160)"	"160/"							"bileaciPage80.html"
"BA0081"	5.00		"3α,7β-DIHYDROXY-7α-METHYL-5β-CHOLAN-24-OIC ACID"	"7α-METHYL-URSODEOXYCHOLIC ACID"	"7α-Me-UDCA"		"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H  HO"							"102.5-105ﾟC(161)"						"161/"			"1H-NMR : 0.77(s,18-Me), 1.06(d,J=6Hz,21-Me), 1.09(s,19-Me), 1.40(s,7α-Me), 3.62(m,3β-H)(161)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 564[M+](8%),549(7%),474(2%),459(2%), 384(4%),257(100%)(161)"		"161/"							"bileaciPage81.html"
"BA0082"	5.00		"3α,7α-DIHYDROXY-7β-METHYL-5β-CHOLAN-24-OIC ACID"	"7β-METHYL-CHENODEOXYCHOLIC ACID"	"7β-Me-CDCA"		"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H     OH"							"95-98ﾟC(161)"						"161"			"1H-NMR : 0.79(s,18-Me), 0.97(s,19-Me), 1.05(d,J=6Hz,21-Me), 1.32(s,7β-Me), 3.56(m,3β-H)(161)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 564[M+](8%), 549(13%), 474(3%), 459(5%), 384(12%), 257(100%)(161)"		"161/"							"bileaciPage82.html"
"BA0083"	5.00		"3α-HYDROXY-7-METHYL-5β-CHOL-6-EN-24-OIC ACID"	"7-METHYL-△6-LITHOCHOLIC ACID"	"7-Me-△6-LCA"		"C25H40O3"	25.00	40.00	3.00	0.00	0.00	0.00	388		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ�ｷ＼"	"   H  OH  H"							"121-122ﾟC(161)"						"161/"			"1H-NMR : 0.82(s,18-Me), 0.89(s,19-Me), 1.06(d,J=6Hz,21-Me), 1.77(s,7-Me), 3.64(m,3β-H), 5.42(d,J=4Hz,6-H)(161)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 474[M+](1%), 459(2%), 384(100%), 369(9%), 269(5%)(161)"		"161/"							"bileaciPage83.html"
"BA0084"	5.00		"3α-HYDROXY-7-METHYLENE-5β-CHOLAN-24-OIC ACID"	"7-METHYLENE-LITHOCHOLIC ACID"	"7-METHYLENE-LCA"		"C25H40O3"	25.00	40.00	3.00	0.00	0.00	0.00	388		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ｹ"	"   H  OH  H     CH2"							"104-105ﾟC(161)"						"161/"			"1H-NMR : 0.77(s,18-Me), 1.05(d,J=6Hz,21-Me), 1.14(s,19-Me), 3.70(m,3β-H),  4.72 AND 4.76(m,C=CH2)(161)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 474[M+](1%), 459(3%), 384(100%), 369(41%), 269(31%)(161)"		"161/"							"bileaciPage84.html"
"BA0085"	5.00		"3α,7β,12α-TRIHYDROXY-7α-METHYL-5β-CHOLAN-24-OIC ACID"	"7α-METHYL-URSOCHOLIC ACID"	"7α-Me-UCA"		"C25H42O5"	25.00	42.00	5.00	0.00	0.00	0.00	422		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H  HO"							"141-142ﾟC(162)"						"162/"			"1H-NMR : 0.82(s,18-Me), 1.01(s,19-Me), 1.20(d,J=6Hz,21-Me), 1.46(s,7α-Me), 3.66(m,3β-H), 4.14(m,12β-H)(162)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 652[M+](5%),637(4%),562(2%),547(2%), 492(6%),472(18%),382(7%),357(11%),267(17%),257(100%) (162)"		"162/"			"腸で効率よく吸収される(163) 7-Me GROUPは腸内細菌の7位の脱水酸化反応に抵抗する(163)"	"163/"			"bileaciPage85.html"
"BA0086"	5.00		"3α,7α,12α-TRIHYDROXY-7β-METHYL-5β-CHOLAN-24-OIC ACID"	"7β-METHYL-CHOLIC ACID"	"7β-Me-CA"		"C25H42O5"	25.00	42.00	5.00	0.00	0.00	0.00	422		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H     OH"							"221-223ﾟC(162)"						"162/"			"1H-NMR : 0.81(s,18-Me),0.94(s,19-Me),1.21(d,J=6Hz,21-Me),1.37(s,7β-Me),  3.64(m,3β-H),4.09(m,12β-H)(162)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 652[M+](4%),637(7%),562(2%),492(7%), 472(16%),382(9%),367(3%),357(6%),342(4%),267(10%),257(100%)(162)"		"162/"			"腸で効率よく吸収される(163) 7-Me GROUPは腸内細菌の7位の脱水酸化反応に抵抗する(163)"	"163/"			"bileaciPage86.html"
"BA0087"	5.00		"3α,12α-DIHYDROXY-7-METHYL-5β-CHOL-7-EN-24-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｳ    H"	"    �ﾕ�ﾊ／�ﾚ／＼"	"   H  OH  H"							"160-163ﾟC(162)"						"162/"			"1H-NMR : 0.79(s,18-Me),0.86(s,19-Me),1.16(d,J=6Hz,21-Me),1.73(s,7-Me), 3.70(m,3β-H),4.13(m,12β-H)(162)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 547(2%),472(37%)457(5%),441(2%),382(14%), 367(10%),357(41%),267(100%)(162)"		"162/"							"bileaciPage87.html"
"BA0088"	5.00		"3α,12α-DIHYDROXY-7-METHYL-5β-CHOL-6-EN-24-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ�ｷ＼"	"   H  OH  H"							"144-148ﾟC(162)"						"162/"			"1H-NMR : 0.79(s,18-Me),0.89(s,19-Me),1.22(d,J=6Hz,21-Me),1.69(s,7-Me), 3.70(m,3β-H),4.13(m,12β-H),5.36(m,6-H)(162)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 547(2%),472(23%),457(1%),441(1%),382(23%), 367(15%),357(5%),267(100%)(162)"		"162/"							"bileaciPage88.html"
"BA0089"	5.00		"3α,12α-DIHYDROXY-7-METHYLENE-5β-CHOLAN-24-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ｹ"	"   H  OH  H     CH2"							"199-202ﾟC(162)"						"162/"			"1H-NMR : 0.79(s,18-Me),1.05(s,19-Me),1.20(d,J=6Hz,21-Me),3.75(m,3β-H), 4.16(m,12β-H),4.61 AND 4.74(m,C=CH2)(162)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 547(4%),472(21%),457(2%),441(2%),382(44%), 367(14%),357(12%),267(100%) (162)"		"162/"							"bileaciPage89.html"
"BA0090"	5.00		"3-OXO-CHOL-1,4-DIEN-24-OIC ACID"				"C24H34O3"	24.00	34.00	3.00	0.00	0.00	0.00	370		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      �ｴ＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ｴ＼�ｷ＼／"	"    O"							"224-226ﾟC(164)"						"164/"	"λMAX(ε) : 245(15,000) (164)"			"M/Z  370[M+], 355, 269, 122(100%) (164)"		"164/"							"bileaciPage90.html"
"BA0091"	5.00		"7α-HYDROXY-3-OXO-CHOL-1,4-DIEN-24-OIC ACID"				"C24H34O4"	24.00	34.00	4.00	0.00	0.00	0.00	386		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      �ｴ＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ｴ＼�ｷ＼／�ﾗ"	"   O          H OH"							"235-238ﾟC(164)"						"164/"	"λMAX(ε) : 246(14,500) (164)"			"M/Z  386[M+], 368, 267, 122(100%)"		"164/"							"bileaciPage91.html"
"BA0092"	5.00		"12α-HYDROXY-3-OXO-CHOL-1,4-DIEN-24-OIC ACID"				"C24H34O4"	24.00	34.00	4.00	0.00	0.00	0.00	386		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      �ｴ＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ｴ＼�ｷ＼／"	"   O"							"232-234ﾟC(164)"						"164/"	"λMAX(ε) : 244(14,300) (164)"			"M/Z  386[M+], 368, 353, 267(100%) (164)"		"164/"							"bileaciPage92.html"
"BA0093"	5.00		"7α,12α-DIHYDROXY-3-OXO-CHOL-1,4-DIEN-24-OIC ACID"				"C24H34O5"	24.00	34.00	5.00	0.00	0.00	0.00	402		"                                                                (REF:   )"	"            H HO＼／＼"	"            �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      �ｴ＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ｴ＼�ｷ＼／�ﾗ"	"   O          H OH"							"237-240ﾟC(164)"						"164/"	"λMAX(ε) : 246(15,500) (164)"			"M/Z  384, 366, 265(100%) (164)"		"164/"							"bileaciPage93.html"
"BA0094"	5.00		"3α,7α-DIHYDROXY-7β-ETHYL-5β-CHOLAN-24-OIC ACID"	"7β-ETHYL-CHENODEOXYCHOLIC ACID"	"7β-Et-CDCA"		"C26H44O4"	26.00	44.00	4.00	0.00	0.00	0.00	420		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗOH"	"   H  OH  H H5C2"							"102-103ﾟC(165)"						"165/"			"1H-NMR(PYRIDINE-d5) : 0.74(s,18-Me),0.94(s,19-Me),0.98(t,J=6Hz,-CH2CH3), 0.99(d,J=6Hz,21-Me),3.73(m,3β-H)(165)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 549(1%), 459(23%), 398(36%), 369(21%), 271(100%), 157(86%) (165)"		"165/"							"bileaciPage94.html"
"BA0095"	5.00		"3α,7α-DIHYDROXY-7β-N-PROPYL-5β-CHOLAN-24-OIC ACID"	"7β-PROPYL-CHENODEOXYCHOLIC ACID"	"7β-Pr-CDCA"		"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                                (REF:   )"	"                ＼／＼"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗOH"	"   H  OH  H H7C3"							"102-103ﾟC(165)"						"165/"			"1H-NMR(PYRIDINE-d5) : 0.73(s,18-Me), 0.92(s,19-Me), 0.97(t,J=6Hz,   7β-CH2CH2CH3),1.00(d,J=6Hz,21-Me),3.69(m,3β-H) (165)"	"Me-TMS M/Z(RELATIVE INTENSITY,%) 549(24%), 459(79), 412(79%), 369(45%), 285(100%), 171(74%) (165)"		"165/"							"bileaciPage95.html"
"BA0096"	5.00		"(23R)-3α,7α,23-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"PHOCAECHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                     R  COOH                                    (REF:   )"	"                �ﾅ／＼／"	"                �ｶ�ﾄH �ﾂ"	"            ／＼�ﾇ＼  OH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H   H OH"							"225ﾟC, Me ESTER 110ﾟC(166)"		"[α]20/D : +21(EtOH) (166)"			"250μM (167)"	"166/167/"			"1H-NMR(CDCl3+CD3OD) Me ESTER : 0.81(s,18-Me), 0.90(s,19-Me), 1.01(d,J=6Hz, 21-Me),3.38(m,3β-H),3.78(s,CO2Me),3.98(s,3xOH),4.24(m,23-CHOH) (166)"""		"CRITTCAL MICELLAR CONCENTRATION:  12μM  HYDROPHILICITY(C-18 HPLC) : 0.95  pKa : 3.8 (167)"	"166/167/"	"アザラシ、セイウチの胆汁(168/169)"	"168/169/"					"bileaciPage96.html"
"BA0097"	5.00		"(23S)-3α,7α,23-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                     S  COOH                                    (REF:   )"	"                �ﾅ／＼／"	"                �ｶ�ﾄH �ﾐ"	"            ／＼�ﾇ＼  OH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H   H OH"							"215ﾟC, 196-197ﾟC(Me ESTER)(166)"		"[α]20/D : +15(EtOH) (166)"			"180μM (167)"	"166/167/"			"1H-NMR(CDCl3+CD3OD) Me ESTER : 0.69(s,18-Me), 0.91(s,19-Me), 1.01(d,J=6Hz, 21-Me),3.38(m,3β-H),3.76(s,CO2Me),4.00(s,3xOH),4.24(m,23-CHOH) (166)"""		"CRITTCAL MICELLAR CONCENTRATION: 13μM  HYDROPHILICITY(C-18 HPLC) : 0.91  pKa : 3.8 (167)"	"166/167/"							"bileaciPage97.html"
"BA0098"	5.00		"(23S)-3α,12α,23-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                     S  COOH                                    (REF:   )"	"            H HO�ﾅ／＼／"	"            �ﾒ�ﾄ�ｶ�ﾄH �ﾐ"	"            ／＼�ﾇ＼  OH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ�ｶ    H"	"    �ﾕ�ﾊ／�ﾚ／"	"   H  OH  H"							"225ﾟC, 143-144ﾟC(Me ESTER)(166)"		"[α]20/D : +38(EtOH) (166)"			"90μM (167)"	"166/167/"			"1H-NMR(CDCl3+CD3OD) Me ESTER : 0.69(s,18-Me), 0.91(s,19-Me), 1.07(d,J=6Hz, 21-Me), 3.17(m,3xOH AND 3β-H), 3.97(s,CO2Me), 4.01(m,12β-H), 4.24(m,     23-CHOH) (166)"""		"CRITTCAL MICELLAR CONCENTRATION: 12μM  HYDROPHILICITY(C-18 HPLC) :1.08  pKa : 3.8 (167)"	"166/167/"							"bileaciPage98.html"
"BA0099"	5.00		"(22S,23S)-3α,7β-DIHYDROXY-22,23-METHYLENE-5β-CHOLAN-24-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                   H                                            (REF:   )"	"                  �ﾒ�ﾄ�ﾂH"	"                �ﾅ／＼�ﾈ"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ  �ｵ  H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H  HO H"						"248-251ﾟC(170)"		"[α]25/D : +56.4(EtOH) (171)"			"2.5μM (171)"	"170/171/"		"(NUJOL) 3380cm-1(OH), 1700cm-1(C=O) (170)"	"PMR(CD3OD+CDCl3) : 0.67(s,18-Me), 0.93(s,19-Me), 1.00(d,21-Me),3.30-3.70 (m,CHOH),4.53(s,OH AND CO2H)(170)  CMR Me ESTER : C-16 28.9,C-17 57.6,C-20 34.8,C-21 21.3,C-22 17.8,C-23 30.6, C-24 175.8,C CO2Me 16.3 (170)    C-24 175.8,C CO2Me 16.3 (170)"""		"CRITTCAL MICELLAR CONCENTRATION: 25μM  HYDROPHILICITY(C-18 HPLC) : 0.21 pKa : 5.06 (171)"	"170/171/"							"bileaciPage99.html"
"BA0100"	5.00		"(22R,23R)-3α,7β-DIHYDROXY-22,23-METHYLENE-5β-CHOLAN-24-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                 H                                              (REF:   )"	"                  �ﾅ／�ｵH"	"                �ﾅ／＼�ﾓ"	"                �ｶ�ﾄH �ｵ"	"            ／＼�ﾇ＼  COOH"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ  �ｵ  H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H  HO H"						"252-255ﾟC(170)"		"[α]25/D : +7.5(EtOH) (171)"			"6μM (171)"	"170/171/"		"(NUJOL) 3380cm-1(OH), 1700cm-1(C=O) (170)"	"PMR(CDCl3+CDCl3) : 0.70(s,18-Me), 0.97(s,19-Me), 1.07(d,21-Me),3.30-3.67 (m,CHOH), 4.80(s,OH AND CO2H)(170) CMR Me ESTER : C-16 27.7,C-17  C-24 176.1,C CO2Me 12.0 (170)57.7,C-20 31.8,C-21 21.8,C-22 30.5,C-23 29.9, C-24 176.1,C CO2Me 12.0 (170)"""		"CRITTCAL MICELLAR CONCENTRATION: 20μM  HYDROPHILICITY(C-18 HPLC) : 0.80 pKa : 5.02 (171)"	"170/171/"							"bileaciPage100.html"
"BA0101"	5.00		"(22S,23R)-3α,7β-DIHYDROXY-22,23-METHYLENE-5β-CHOLAN-24-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                   H                                            (REF:   )"	"                  �ﾒ�ﾄ�ﾂCOOH"	"                �ﾅ／＼�ﾈ"	"                �ｶ�ﾄH �ﾐ"	"            ／＼�ﾇ＼  H"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ  �ｵ  H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H  HO H"						"133-136ﾟC(170)"		"[α]25/D : +14.5(EtOH) (171)"			"6μM (171)"	"170/171/"		"(NUJOL) 3380cm-1(OH), 1700cm-1(C=O) (170)"	"PMR(CD3OD+CDCl3) : 0.67(s,18-Me), 0.97(s,19-Me), 3.17-3.73(m,CHOH), 4.63(s,OH AND CO2H)(170) CMR Me ESTER : C-16 28.7,C-17 57.2,C-20 39.7,C-21 20.1,C-22 31.1,C-23 19.1,    C-24 177.9,C CO2Me 17.5 (170)"""		"CRITTCAL MICELLAR CONCENTRATION: 14μM  HYDROPHILICITY(C-18 HPLC) : 1.30 pKa : 5.01 (171)"	"170/171/"							"bileaciPage101.html"
"BA0102"	5.00		"(22R,23S)-3α,7β-DIHYDROXY-22,23-METHYLENE-5β-CHOLAN-24-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                   H                                            (REF:   )"	"                  �ﾃ／�ｵCOOH"	"                �ﾅ／＼�ﾇ"	"                �ｶ�ﾄH �ﾂ"	"            ／＼�ﾇ＼  H"	"            �ｵ�ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／�ﾅ"	"      �ｵ  �ｵ  �ｵ  H"	"    �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   H  OH  H  HO H"						"168-170ﾟC(170)"		"[α]25/D : +59.9ﾟ(EtOH) (171)"			"5μM (171)"	"170/171/"		"(NUJOL) 3380cm-1(OH), 1700cm-1(C=O) (170)"	"PMR(CD3OD+CDCl3) : 0.67(s,18-Me), 0.97(s,19-Me), 1.00(d,21-Me), 3.37-3.82 (m,CHOH), 4.37(s,OH AND CO2H)(170) CMR Me ESTER : C-16 28.5,C-17 57.2,C-20 39.4,C-21 20.0,C-22 30.3,C-23 23.3,      C-24 177.3,C CO2Me 12.7 (170)"""		"CRITTCAL MICELLAR CONCENTRATION: 10μM  HYDROPHILICITY(C18 HPLC) : 2.05 pKa : 5.02 (171)"	"170/171/"							"bileaciPage102.html"
"BA0103"	5.00		"3α,6α,7β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"	"ALLO ω-MURICHOLIC ACID"	"ALLO ω-MCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                          (REF:172)"	"               ＼／＼"	"               �ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾊ／�ﾗH"	"  H  OH  H �ﾗOH"	"           H OH"					"172/"	"242-244ﾟC(from EtOAc),192-193ﾟC(Me ESTER)(172)"						"172/"		"1685cm-1(C=O), 3481,1007cm-1(OH)(172)"	"1H-NMR(CDCl3+DMSO-d6) 0.67(s,18-Me), 0.79(s,19-Me), 0.93(d,J=6.3Hz,21-Me), 3.02(brm,6β- and 7α-H), 4.00(m,3β-H)C17=56.18,C18=12.25,C19=12.54,C20=35.50,C21=18.47,C22=31.20, C23=31.27,C24=175.56,CCOOMe=51.93 (172)13C-NMR(Me ESTER)(CDCl3+10% MeOH-d4) C1=32.62,C2=28.66,C3=65.76,C4=30.06,     C5=42.10,C6=75.27,C7=80.64"	"Me ESTER M/Z(RELATIVE INTENSITY) 404(54%,M-H2O), 386(100%,M-2H2O), 368(48%,M-3H2O), 289(34%), 271(49%), 262(21%), 253(20%)(172)"		"172/"							"bileaciPage103.html"
"BA0104"	5.00		"3α,6β,7β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"	"ALLO β-MURICHOLIC ACID"	"ALLO β-MCA"		"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                          (REF:172)"	"               ＼／＼"	"               �ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾊ／�ﾗH"	"  H  OH  H �ﾗOH"	"          HO H"					"172/"	"242-245ﾟC(from aq･EeOH),130-132ﾟC(Me ESTER)(172)"						"172/"		"1710cm-1(C=O), 3412,1035,1009cm-1(OH)(172)"	"1H-NMR(CDCl3+20% DMSO-d6) 0.69(s,18-Me), 0.96(s,19-Me), 3.26(brm, 7α-H),  3.54(m,6α-H),4.08(m,3β-H) (172)   13C-NMR(Me ESTER) C1=33.01,C2=29.16,C3=66.58,C4=34.14,C5=40.20,C6=74.92,    C7=76.86,C8=38.26,C9=52.47,C10=35.35,C11=20.56,C12=39.90, C17=55.47,C18=12.24,C19=15.04,C20=35.45,C21=18.48,C22=31.13, C23=31.09,C24=174.88,CCOOMe=51.59 (172)"	"Me ESTER M/Z(RELATIVE INTENSITY) 404(100%,M-H2O), 386(83%,M-2H2O), 368(38%,M-3H2O), 289(22%), 271(45%), 262(71%), 253(19%)(172)"		"172/"							"bileaciPage104.html"
"BA0105"	5.00		"3α,6β,7β,12α-TETRAHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                          (REF:172)"	"           H HO＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾊ／�ﾗH"	"  H  OH  H �ﾗOH"	"          HO H"					"172/"	"235-237ﾟC(FROM EtOAc/HEXANE),151-152ﾟC(Me ESTER)(172)"						"172/"		"1698cm-1(C=O), 3525,1033,1014cm-1(OH)(172)"	"1H-NMR(CDCl3+20% DMSO-d6)0.69(s,18-Me),0.93(s,19-Me),0.99(d,J=6.3Hz,21-Me), 3.25(brm,7α-H),3.51(m,6α-H),3.92(m,12β-H),4.06(m,3β-H)(172) 13C-NMR(Me ESTER) C1=32.95,C2=29.04,C3=66.45,C4=34.06,C5=40.38,C6=75.02,    C7=76.58,C8=38.23,C9=45.33,C C17=47.13,C18=12.90,C19=14.81,C20=35.14,C21=17.48,C22=31.00, C23=31.18,C24=174.86,CCOOMe=51.61 (172)"	"Me ESTER M/Z(RELATIVE INTENSITY) 420(2%,M-H2O), 402(16%,M-2H2O),  384(10%,M-3H2O), 305(100%), 287(57%),  269(91%), 251(18%)(172)"		"172/"							"bileaciPage105.html"
"BA0106"	5.00		"3α,7β-DIHYDROXY-6-OXO-5α-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                                                          (REF:172)"	"               ＼／＼"	"               �ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾊ／�ﾗH"	"  H  OH  H �ｾOH"	"           O"					"172/"	"223-224ﾟC(FROM aq･EtOH),136-139ﾟC(Me ESTER)(172)"						"172/"		"1719,1686cm-1(C=O), 3540,1007cm-1(OH)(172)"	"1H-NMR(CDCl3+20% DMSO-d6)0.67(s,18- and 19-Me),0.94(d,J=5.4Hz,21-Me),  3.71(d,J=9.0Hz,7α-H),4.00(m,3β-H) (172)"			"172/"							"bileaciPage106.html"
"BA0107"	5.00		"3α,7β,12α-TRIHYDROXY-6-OXO-5α-CHOLAN-24-OIC ACID"				"C24H38O6"	24.00	38.00	6.00	0.00	0.00	0.00	422		"                                                          (REF:172)"	"           H HO＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾊ／�ﾗH"	"  H  OH  H �ｾOH"	"           O"					"172/"	"219-221ﾟC(FROM EtOAc),167-168ﾟC(Me ESTER)(172)"						"172/"		"1713,1687cm-1(C=O), 3528,1039,1014,990cm-1(OH)(172)"	"1H-NMR(CDCl3+20% DMSO-d6)0.67(s,18- and 19-Me),1.00(d,J=5.4Hz,21-Me),  3.80(d,J=9.0Hz,7α-H),3.95(m,12β-H),4.05(m,3β-H) (172)"			"172/"							"bileaciPage107.html"
"BA0108"	5.00		"3α,6β,7α,12β-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                          (REF:173)"	"          HO  H＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H �ﾗH OH"	"          HO H"					"173/"	"168-170ﾟC(FROM EtOAc)(173)"		"[α]25/D=+30.2 (173)"				"173/"		"1717cm-1(C=O), 3410,998cm-1(OH)(173)"	"1H-NMR(CDCl3+DMSO-d6)0.76(s,18-Me),1.02(d,J=5.6Hz,21-Me),1.08(s,19-Me), 3.39(brm,3β- and 12α-H),3.67(m,6α- and 7β-H)(173)"	"Me-TMS M/Z(RELATIVE INTENSITY) 711(3%,M-15),636(3%,M-90),546(56%,M-2x90), 456(87%,M-3x90),366(34%,M-4x90),341(100%),  285(7%),251(81%)(173)"		"173/"							"bileaciPage108.html"
"BA0109"	5.00		"3α,6β,7β,12β-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                          (REF:173)"	"           HO H＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗH"	"  H  OH  H �ﾗOH"	"          HO H"					"173/"	"204-206ﾟC(FROM EtOAc)(173)"		"[α]25/D=+60.3 (173)"				"173/"		"1718cm-1(C=O), 3410,1005cm-1(OH)(173)"	"1H-NMR(CDCl3+DMSO-d6)0.74(s,18-Me),1.00(d,J=5.6Hz,21-Me),1.07(s,19-Me), 3.39(brm,3β-,7α-,and 12α-H),3.55(m,6α-H)(173)"	"Me-TMS M/Z(RELATIVE INTENSITY) 711(0.4%,M-15),636(1%,M-90),546(4%,M-2x90), 456(11%,M-3x90), 366(5%,M-4x90),341(16%),  285(75%), 251(10%)(173)"		"173/"							"bileaciPage109.html"
"BA0110"	5.00		"3α,12β-DIHYDROXY-5β-CHOL-6-EN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                          (REF:173)"	"           HO H＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ�ｷ"	"  H  OH  H"						"173/"			"[α]25/D=+28.1(Me ESTER) (173)"				"173/"		"Me ESTER   1740cm-1(C=O), 3400,1002cm-1(OH)(173)"	"1H-NMR(Me ESTER)(CDCl3+DMSO-d6) 0.72(s,18-Me), 0.87(s,19-Me), 1.00(d,J=5.4Hz,21-Me), 3.50(bm,3β- and 12α-H),3.67(s,-COOMe), 5.45(s,6- and 7-H)(173)"	"Me-TMS M/Z(RELATIVE INTENSITY) 533(2%), 458(13%), 368(9%), 343(45%), 281(3%), 253(100%) (173)"		"173/"							"bileaciPage110.html"
"BA0111"	5.00		"3α-HYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"NORLITHOCHOLIC ACID"	"norLCA"		"C23H38O3"	23.00	38.00	3.00	0.00	0.00	0.00	362		"                                                          (REF:174)"	"               ＼／＼"	"               �ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／"	"  H  OH  H"						"174/"	"183.5-184.5ﾟC(FROM ACETONE),107-108ﾟC(Me ESTER)(174)"						"174/"			"1H-NMR(CDCl3+10% DMSO-d6)0.71(s,18-Me),0.93(s,19-Me),0.99(d,J=6.0Hz,21-Me), 3.53(m,3β-H)(174) 13C-NMR(Me ESTER)(CDCl3) C1=35.2, C2=30.4, C3=71.6, C4=36.3, C5=42.0,  C6=27.1, C7=26.3, C8=35.7, C9=40.3, C10=34.5, C11=20.7, C12=40.0, C13=42.C14=56.4, C15=24.1, C16=28.2, C17=56.0, C18=12.0, C19=23.3, C20=33.7, C21=19.4, C22=41.4, C23=174.0, C/COOMe=51.3 (174)"			"174/"							"bileaciPage111.html"
"BA0112"	5.00		"3α,7α-DIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"NORCHENODEOXYCHOLIC ACID"	"norCDCA"		"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                          (REF:174)"	"               ＼／＼"	"               �ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H   H OH"						"174/"	"204-205ﾟC(FROM ACETONE),83.5-85ﾟC(Me ESTER)(174)"						"174/"			"1H-NMR(CDCl3+DMSO-d6) 0.69(s,18-Me),0.88(s,19-Me),0.98(d,J=6.0Hz,21-Me),3.32(m,3β-H),3.73(bs,7β-H) (174)13C-NMR(Me ESTER)(CDCl3) C1=35.2, C2=30.5, C3=71.8, C4=39.4, C5=41.3,  C6=34.6, C7=68.3, C8=39.3, C9=32.7, C10=34.9, C11=20.4, C12=39. C14=50.3, C15=23.5, C16=28.1, C17=55.8, C18=11.7, C19=22.7, C20=33.7, C21=19.4, C22=41.3, C23=174.0, C/COOMe=51.2 (174)"			"174/"							"bileaciPage112.html"
"BA0113"	5.00		"3α,7β-DIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"NORURSODEOXYCHOLIC ACID"	"norUDCA"		"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                          (REF:174)"	"               ＼／＼"	"               �ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H  HO H"						"174/"	"248-250ﾟC(FROM ACETONE-MeOH),178-180ﾟC(Me ESTER)"						"174/"			"1H-NMR(CDCl3+10% DMSO-d6)0.70(s,18-Me),0.93(s,19-Me),0.98(d,J=5.5Hz,21-Me), 3.41(m,3β- and 7α-H)(174) 13C-NMR(Me ESTER) C1=34.7, C2=30.1, C3=71.0, C4=37.1, C5=42.3, C6=36.9,   C7=71.0, C8=43.5, C9=39.0, C10=33.9, C11=21.0, C12=39.9, C17=54.9, C18=12.0, C19=23.2, C20=33.5, C21=19.5, C22=41.3, C23=173.8, C/COOMe=51.2 (174)"	"Me ESTER M/Z(RELATIVE INTENSITY)392(3%,M+),374(25%,M-H2O),356(55%,M-2xH2O),341(50%),302(20%),283(56%),255(53%)(174)"		"174/"							"bileaciPage113.html"
"BA0114"	5.00		"3α,12α-DIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"NORDEOXYCHOLIC ACID"	"norDCA"		"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                          (REF:174)"	"           H HO＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／"	"  H  OH  H"						"174/"	"212-213.5ﾟC(FROM ACETONE),166.5-167.5ﾟC(Me ESTER)(174)"						"174/"			"1H-NMR(CDCl3+10% DMSO-d6)0.69(s,18-Me),0.89(s,19-Me),1.03(d,J=3.0Hz,21-Me), 3.50(m,3β-H),3.90(bs,12β-H)(174)  13C-NMR(Me ESTER) C1=35.1, C2=30.3, C3=71.5, C4=36.3, C5=41.9, C6=27.0,   C7=26.0, C8=35.9, C9=33.5, C10=34.0, C11=28.5, C12=72.8, C17=47.2, C18=12.6, C19=23.0, C20=33.5, C21=18.4, C22=41.2, C23=173.9, C/COOMe=51.3 (174)"			"174/"							"bileaciPage114.html"
"BA0115"	5.00		"3α,7α,12α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"NORCHOLIC ACID"	"norCA"		"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                          (REF:174)"	"           H HO＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H   H OH"						"174/"	"188-190ﾟC(FROM ACETONE),157.5-158ﾟC(Me ESTER)(174)"						"174/"			"1H-NMR(CDCl3+10% DMSO-d6) 0.70(s,18-Me), 0.87(s,19-Me), 1.06(bs,W1/2 6Hz,  21-Me),3.32(m,3β-H),3.75(bs,7β-H),3.87(bs,12β-H)(174)  13C-NMR(Me ESTER) C1=35.2, C2=30.0, C3=71.6, C4=39.3, C5=41.4, C6=34.6,C7=68.2, C8=39.3, C9=26.1, C10=34.5, C11=27.9, C12 C17=46.9, C18=12.3, C19=22.3, C20=33.6, C21=18.4, C22=41.2, C23=174.0, C/COOMe=51.3 (174)"			"174/"	"ＣＴＸ患者の尿(175)"	"175/"					"bileaciPage115.html"
"BA0116"	5.00		"3α,6α-DIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"NORHYODEOXYCHOLIC ACID"	"norHDCA"		"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                          (REF:174)"	"               ＼／＼"	"               �ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／"	"  H  OH  H �ﾗ"	"           H OH"					"174/"	"218-219.5ﾟC(FROM AcOEt)(174)"						"174/"			"1H-NMR(CDCl3+10% DMSO-d6)0.67(s,18-Me),0.89(s,19-Me),1.00(d,J=5.8Hz,21-Me), 3.51(m,3β-H),3.97(m,W1/2 24Hz,6β-H)(174) 13C-NMR(Me ESTER) C1=35.6, C2=29.9, C3=71.3, C4=29.2, C5=48.4, C6=67.8,  C7=34.6, C8=34.7, C9=39.8, C10=35.8, C11=20.7, C12=39.8, C17=56.0, C18=12.0, C19=23.5, C20=33.7, C21=19.4, C22=41.3, C23=173.9, C/COOMe=51.3 (174)"			"174/"							"bileaciPage116.html"
"BA0117"	5.00		"3α,7α-DIHYDROXY-7β-METHYL-24-NOR-5β-CHOLAN-23-OIC ACID"	"7-METHYL-NORCHENODEOXYCHOLIC ACID"	"7-Me-norCDCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                          (REF:176)"	"               ＼／＼"	"               �ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H  Me OH"						"176/"	"232-234ﾟC (FROM EtOAc)(176)"						"176/"			"1H-NMR 0.72(s,18-Me), 0.87(s,19-Me), 0.99(d,J=6.1Hz,21-Me), 1.23(s,7β-Me),  2.18(q,J=12Hz,4α-H), 2.43(q,J1=14.3Hz,J2=2.9Hz,22-CH2),     3.49(sep,3β-H) (176)"""	"Me-TMS M/Z(RELATIVE INTENSITY) 550(11%,M+),535(16%,M-15),445(8%,M-(90+15)), 370(15%,M-2x90),257(100%)"		"176/"							"bileaciPage117.html"
"BA0118"	5.00		"3β-HYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"				"C23H38O3"	23.00	38.00	3.00	0.00	0.00	0.00	362		"                                                          (REF:177)"	"               ＼／＼"	"               �ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／"	" HO  H   H"						"177/"	"178-179ﾟC(FROM aq･ACETONE)(177)"						"177/"			"1H-NMR(Me ESTER) 0.69(s,18-Me),0.97(s,19-Me),0.97(d,21-Me), 2.40(d,J=10Hz,22-CH2),3.66(s,COOMe),4.10(bs,3α-H)(177) 13C-NMR(Me ESTER)C1=30.03,C2=28.35,C3=67.24,C4=33.66,C5=36.67,C6=26.72,C7=26.34,C8=35.75, C17=56.29,C18=12.17,C19=23.96,C20=33.88,C21=19.60,C22=41.55, C23=174.14,C/COOMe=51.38 (177)"	"M/Z(RELATIVE INTENSITY) 362(4%,M+),347(4%,M-Me),344(16%,M-H2O),329(18%,M-H2O-Me),248(4%),233(13%),215(19%)(177)"		"177/"							"bileaciPage118.html"
"BA0119"	5.00		"3α-AMINO-7α,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H41O4N"	24.00	41.00	4.00	1.00	0.00	0.00	407		"                                                          (REF:178)"	"           H HO＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  NH2 H   H OH"						"178/"	"219ﾟC (178)"						"178/"			"1H-NMR(CD3OD) 0.72(s,18-Me),0.97(s,19-Me),1.02(d,J=6Hz,21-Me),  2.93(m,3β-H),3.82(m,7β-H),3.98(m,12β-H)(178)"			"178/"							"bileaciPage119.html"
"BA0120"	5.00		"3β-AMINO-7α,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H41O4N"	24.00	41.00	4.00	1.00	0.00	0.00	407		"                                                          (REF:178)"	"           H HO＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"H2N  H   H   H OH"						"178/"	"205ﾟC (178)"						"178/"			"1H-NMR(CD3OD) 0.70(s,18-Me),0.94(s,19-Me),1.01(d,J=6Hz,21-Me),  3.47(m,3α-H),3.85(m,7β-H),4.00(m,12β-H)(178)"			"178/"							"bileaciPage120.html"
"BA0121"	5.00		"7α-AMINO-3α,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H41O4N"	24.00	41.00	4.00	1.00	0.00	0.00	407		"                                                          (REF:178)"	"           H HO＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H   H NH2"						"178/"	"209ﾟC (178)"						"178/"			"1H-NMR(CD3OD) 0.60(s,18-Me),0.83(s,19-Me),0.91(d,J=5Hz,21-Me),  3.02(m,7β-H),3.22(m,3β-H),3.77(m,12β-H)(178)"			"178/"							"bileaciPage121.html"
"BA0122"	5.00		"7β-AMINO-3α,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H41O4N"	24.00	41.00	4.00	1.00	0.00	0.00	407		"                                                          (REF:178)"	"           H HO＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H H2N H"						"178/"	"200ﾟC (178)"						"178/"			"1H-NMR(CD3OD) 0.60(s,18-Me),0.83(s,19-Me),0.91(d,J=5Hz,21-Me),  2.88(m,7α-H),3.36(m,3β-H),3.77(m,12β-H)(178)"			"178/"							"bileaciPage122.html"
"BA0123"	5.00		"12α-AMINO-3α,7α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H41O4N"	24.00	41.00	4.00	1.00	0.00	0.00	407		"                                                             (REF:178)"	"          H H2N＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H   H OH"						"178/"	"210ﾟC (178)"						"178/"			"1H-NMR(CD3OD) 0.64(s,18-Me),0.80(s,19-Me),0.90(d,J=5Hz,21-Me),  3.02(m,12β-H),3.18(m,3β-H),3.60(m,7β-H)(178)"			"178/"							"bileaciPage123.html"
"BA0124"	5.00		"12β-AMINO-3α,7α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H41O4N"	24.00	41.00	4.00	1.00	0.00	0.00	407		"                                                          (REF:178)"	"         H2N  H＼／＼"	"           �ﾒ�ﾄ�ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H   H OH"						"178/"	"198ﾟC (178)"						"178/"			"1H-NMR(CD3OD) 0.69(s,18-Me),0.84(s,19-Me),0.94(d,J=5Hz,21-Me),   2.80(m,12α-H),3.22(m,3β-H),3.61(m,7β-H)(178)"			"178/"							"bileaciPage124.html"
"BA0125"	5.00		"3α-AMINO-5β-CHOLAN-24-OIC ACID"				"C24H41O2N"	24.00	41.00	2.00	1.00	0.00	0.00	375		"                                                          (REF:179)"	"               ＼／＼"	"               �ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／"	"  H  NH2 H"						"179/"	"265-267ﾟC(HYDROCHLORIDE) (179)"		"[α]/589 = +31ﾟ (179)"				"179/"													"bileaciPage125.html"
"BA0126"	5.00		"3β-AMINO-5β-CHOLAN-24-OIC ACID"				"C24H41O2N"	24.00	41.00	2.00	1.00	0.00	0.00	375		"                                                          (REF:179)"	"               ＼／＼"	"               �ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／"	"H2N  H   H"						"179/"	"285-287ﾟC(HYDROCHLORIDE) (179)"		"[α]/589 = +24ﾟ (179)"				"179/"													"bileaciPage126.html"
"BA0127"	5.00		"3α,7α-DIHYDROXY-25-HOMO-5β-CHOLAN-25-OIC ACID"	"HOMOCHENODEOXYCHOLIC ACID"	"homoCDCA"		"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                                                          (REF:180)"	"               ＼／＼"	"               �ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  ＼"	"           �ｵ�ｶ�ｽ�ｺ    COOH"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H   H OH"						"180/"	"210-212ﾟC(FROM aq･ACETONE),94-95ﾟC(Me ESTER)(180)"						"180/"		"2935,2865,1692,1365,1265,1068,965cm-1(180)"		"M/Z  406(M+), 388(M-H2O), 370(M-2xH2O), 355(M-(2xH2O+Me)), 301, 255 (180)"		"180/"	"ハムスターにおける HOMOCHENODEOXYCHOLIC ACID の代謝物(181)"	"181/"					"bileaciPage127.html"
"BA0128"	5.00		"3α,5β,7α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"				"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                          (REF:181/182)"	"               ＼／＼"	"               �ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  OH  H OH"						"181/182/"										"1H-NMR(CDCl3)[Me ESTER] 0.70(s,18-Me),0.88(s,19-Me),0.98(d,J=6.0Hz,21-Me), 2.43(bd,J=11.5Hz,22-CH2), 2.54(t,J=12.2Hz,4α-H), 3.67(s,COOMe),3.91(m,3β- and 7β-H) (182)13C-NMR(CDCl3)[Me ESTER] C1=29.8, C2=29.9, C3=67.7, C4=44.0, C5=75.0,C6=45.C11=20.7, C12=39.9, C13=42.4, C14=50.2, C15=23.6, C16=28.1, C17=55.7, C18=11.6, C19=15.8, C20=33.7, C21=19.4, C22=41.3, C23=173.8, C/COOMe=51.3 (182)"	"Me-TMS M/Z  534(M-90), 444(M-2x90), 355(M-(2x90+89)), 259, 253 (181/182)"		"182/181/"	"ハムスターに投与した HOMOCHENODEOXYCHOLIC ACID の代謝物(181)  ハムスターに投与した 24-NORCHENODEOXYCHOLIC ACID の代謝物(182)"	"181/182/"					"bileaciPage128.html"
"BA0129"	5.00		"3α,5β,7β-TRIHYDROXY-24-NOR-CHOLAN-23-OIC ACID"				"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                          (REF:182)"	"               ＼／＼"	"               �ｶ�ﾄH COOH"	"           ／＼�ｫ＼"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  OH HO H"						"182/"										"1H-NMR(CDCl3)[Me ESTER] 0.71(s,18-Me),0.90(s,19-Me),0.98(d,J=6.1Hz,21-Me), 2.43(bd,J=12.2Hz,22-CH2), 3.50(m,7α-H), 3.66(s,COOMe),4.03(m,3β-H) (182)13C-NMR(CDCl3)[Me ESTER] C1=29.7, C2=29.4, C3=67.5, C4=42.9, C5=74.9,C6=46.0, C7=72.2,C11=21.1, C12=39.6, C13=43.5, C14=55.7, C15=26.7, C16=28.6, C17=54.8, C18=12.0, C19=16.2, C20=33.6, C21=19.5, C22=41.3, C23=173.8, C/COOMe=51.3 (182)"	"Me-TMS M/Z  534(M-90), 444(M-2x90), 355(M-(2x90+89)), 259, 253 (182)"		"182/"	"ハムスター, ラットに投与した 24-NORURSOCHENODEOXYCHOLIC ACID の代謝物(182) ５β−水酸化は胆汁酸では初めて｡(182) ウサギ, 犬, 人では起こらない｡(182)"	"182/"					"bileaciPage129.html"
"BA0130"	5.00		"(22R)-3α,7α,22-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                  H  OH                                   (REF:183/184)"	"                 �ﾒ�ﾄ"	"               �ﾅ／＼"	"               �ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H   H OH"					"183/184/"	"141-142ﾟC(183),133-136ﾟC(184)"		"[α]/D=+1.0ﾟC (C=1.3,MeOH)(183)"				"183/184/"		"3400cm-1(OH), 1720cm-1(C=O) (183)"	"1H-NMR(CD3OD) 0.72(s,18-Me),0.92(s,19-Me),0.97(d,21-Me), 3.20-3.50(brm,3β-H),3.70-3.85(m,7β-H),4.00-4.30(brm,22-H),4.76(s,3α-,7α-,and 22-OH and 24-CO2H)(184)13C-NMR(CD3OD) C1=36.5, C2=31.4, C3=72.9, C4=40.6, C5=43.1, C6=35.9, C7=69.1, C8=40 C11=21.7, C12=40.8, C13=43.9, C14=51.2, C15=24.7, C16=28.4, C17=54.6, C18=12.1, C19=23.4, C20=43.1, C21=12.8, C22=71.2, C23=36.5, (183)"	"Me ESTER M/Z  422(M+), 404(M-H2O), 386(M-2xH2O) (183)"		"183/"							"bileaciPage130.html"
"BA0131"	5.00		"(22S)-3α,7α,22-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"HAEMULCHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 HO  H                                    (REF:183/184)"	"                 �ﾒ�ﾄ"	"               �ﾅ／＼"	"               �ｶ�ﾄH �ｵ"	"           ／＼�ｫ＼  COOH"	"           �ｵ�ｶ�ｽ�ｺ"	"     ／＼�ｫ＼／�ﾅ"	"     �ｵ  �ｵ  �ｵ  H"	"   �ﾕ�ﾊ／�ﾚ／�ﾗ"	"  H  OH  H   H OH"					"183/184/"	"247-250ﾟC(183),248-251ﾟC(184)"		"[α]/D=+2.4ﾟC (C=1.3,MeOH)(183)"				"183/184/"		"3400cm-1(OH), 1720cm-1(C=O) (183)"	"1H-NMR(CDCl3/CD3OD) 0.68(s,18-Me),0.92(s,19-Me),0.95(d,21-Me), 3.17-3.50(brm,3β-H), 3.68-3.87(m,7β-H),3.97-4.27(m,22-H),4.57(s,3α-,7α-,and 22-OH and 24-CO2H)(184)13C-NMR(CD3OD) C1=36.6, C2=31.5, C3=73.0, C4=40.6, C5=43.2, C6=36.0,C7=69.2 C11=21.8, C12=41.2, C13=43.5, C14=51.4, C15=24.7, C16=28.7, C17=53.8, C18=12.1, C19=23.4, C20=42.0, C21=12.4, C22=70.9, C23=41.5, (183)"	"Me ESTER M/Z  422(M+), 404(M-H2O), 386(M-2xH2O) (183)"		"183/"	"MARINE TELEOST, PARAPRISTIPOMA TRILINEATUM の胆汁中(185) 淡水魚，POLYPTERUS SENEGALUS および MORMYRUS CABALLUS の胆汁中(186)"	"185/186/"			"HAEMULCHOLIC ACIDの構造は(22S)-3α,7α,22-TRIHYDROXY-5β-CHOLAN-24-OIC ACIDであると決定(183/184)"	"183/184/"	"bileaciPage131.html"
"BA0132"	5.00		"12β-HYDROXY-3-KETO-5β-CHOLAN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                             (REF:187)"	"                   HO H＼／＼"	"                   �ﾒ�ﾄ  �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ｴ＼／�ﾚ／"	"          O      H"						"187/"			"[α]/D = +44ﾟ (187)"				"187/"			"1H-NMR (CDCl3) 0.76(s,18-Me),0.98(s,21-Me),1.00(s,19-Me AND 21-Me),  3.48(m,12α-H) 13C-NMR(CDCl3) 7.61(C18,Me),79.46(C12,CHOH),179.78(C24,COOH),213.91(C3,C=O) (187)"""			"187/"	"化学合成品"						"bileaciPage132.html"
"BA0133"	5.00		"7α,12β-DIHYDROXY-3-KETO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                                                             (REF:187)"	"                   HO H＼／＼"	"                   �ﾒ�ﾄ  �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ｴ＼／�ﾚ／�ﾗ"	"          O      H   H OH"						"187/"	"142-145ﾟC(CH2Cl2/PETROLEUM ETHER) (187)"		"[α]/D = +26.8ﾟ (187)"				"187/"			"1H-NMR (CDCl3) 0.77(s,18-Me),1.01(s,19-Me),1.01(d,J=6.5Hz,21-Me), 3.52(m,12α-H),3.94(br,7β-H) 13C-NMR(CDCl3) 7.82(C18,Me),68.03(C7,CHOH),79.00(C12,CHOH),178.85(C24,COOH)  213.43(C3,C=O)(187)"""			"187/"	"化学合成品"						"bileaciPage133.html"
"BA0134"	5.00		"3,12-DIKETO-7α-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H36O5"	24.00	36.00	5.00	0.00	0.00	0.00	404		"                                                             (REF:187)"	"                    O  ＼／＼"	"                   �ｳ    �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ｴ＼／�ﾚ／�ﾗ"	"          O      H   H OH"						"187/"	"192-194ﾟC(CH2Cl2/PETROLEUM ETHER)(187),193-195ﾟC(188)"		"[α]/D = +74ﾟ (187)"				"187/188/"			"1H-NMR (CDCl3) 0.84(d,J=5.8Hz,21-Me),1.04(s,18-Me),1.07(s,19-Me), 3.99(br,7β-H) 13C-NMR(CDCl3) 11.55(C18,Me),67.79(C7,CHOH),178.00(C24,COOH),213.17(C3,C=O)  214.34(C12,C=O) (187)"""			"187/"	"化学合成品"						"bileaciPage134.html"
"BA0135"	5.00		"3α,6α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"	"ALLOHYODEOXYCHOLIC ACID"	"allo HDCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／"	"          H  OH  H �ﾗ"	"                   H OH"					"189/"	"238-240ﾟC(FROM aq･MeOH)(189),227-228ﾟC(190), 176-177ﾟC(Me ESTER)(189)176-177ﾟC(Me ESTER)(189)"						"189/190/"		"cm-1  1704(C=O), 3468, 1041, 1002, 984 (OH) (189)"	"1H-NMR (CDCl3+20%DMSO-d6) 0.65(s,18-Me),0.77(s,19-Me),0.92(d,J=5.4Hz,21-Me) 3.29(brm,6β-H),4.05(m,3β-H) 13C-NMR(Me ESTER)(CDCl3)  C3 65.97,C5 46.15,C6 69.82,C24 174.80,  CcooMe 51.55 (189)"""	"Me ESTER m/z(RELATIVE INTENSITY) 388(94%,[M-H2O]+),373(15%,[M-H2O-15]+),   370(55%,[M-2H2O]+),255(17%) (189)"		"189/"	"化学合成品"						"bileaciPage135.html"
"BA0136"	5.00		"3α,6β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／"	"          H  OH  H �ﾗ"	"                  HO H"					"189/"	"256-259ﾟC(FROM MeOH)(189),247-248ﾟC(190),168-171ﾟC(Me ESTER)(189)168-171ﾟC(Me ESTER)(189)"						"189/190/"		"cm-1 1703(C=O), 3435, 1026, 1009 (OH) (189)"	"1H-NMR (CDCl3+20%DMSO-d6) 0.69(s,18-Me),0.93(d,J=6.3Hz,21-Me),0.98(s,19-Me) 3.65(m,6α-H),4.05(m,3β-H) 13C-NMR(Me ESTER)(CDCl3)  C3 66.71,C5 41.76,C6 72.28,C24 174.88,  CcooMe 51.56 (189)"""	"Me ESTER m/z(RELATIVE INTENSITY) 406(1%,M+),388(100%,[M-H2O]+),    373(13%,[M-H2O-15]+),370(59%,[M-2H2O]+),273(12%),255(9%) (189)"		"189/"	"化学合成品"						"bileaciPage136.html"
"BA0137"	5.00		"3β,6α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／"	"         HO  H   H �ﾗ"	"                   H OH"					"189/"	"247-249ﾟC(FROM MeOH)(189),233-234ﾟC(190),228-229ﾟC(191),180-182ﾟC(Me ESTER)(189)228-229ﾟC(191),180-182ﾟC(Me ESTER)(189)"						"189/190/191/"		"cm-1 1708(C=O), 3378, 1043, 1009 (OH) (189)"	"1H-NMR (CDCl3+20%DMSO-d6) 0.65(s,18-Me),0.79(s,19-Me),0.92(d,J=5.4Hz,21-Me) 3.45(brm,3α-and 6β-H)  13C-NMR(Me ESTER)(CDCl3)  C3 71.28,C5 51.74,C6 69.50,C24 174.83,CcooMe 51.56 (189)"""	"Me ESTER m/z(RELATIVE INTENSITY) 406(3%,M+),388(94%,[M-H2O]+),   370(20%,[M-2H2O]+),355(13%),273(18%),264(28%),255(11%) (189)"		"189/"	"化学合成品"						"bileaciPage137.html"
"BA0138"	5.00		"3β,6β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／"	"         HO  H   H �ﾗ"	"                  HO H"					"189/"	"286-289ﾟC(FROM aq･MeOH)(189),273-274ﾟC(190),189-190ﾟC(Me ESTER)(189)MPの続き 189-190ﾟC(Me ESTER)(189)"						"189/190/"		"cm-1 1712(C=O), 3409, 1039(OH) (189)"	"1H-NMR (CDCl3+40%DMSO-d6) 0.68(s,18-Me),0.91(d,J=5.4Hz,21-Me),0.98(s,19-Me) 3.45(brm,3α-H),3.65(m,6α-H) 13C-NMR(Me ESTER)(CDCl3)  C3 71.76,C5 47.45,C6 72.08,C24 174.84,CcooMe 51.56 (189)"""	"Me ESTER m/z(RELATIVE INTENSITY) 406(1%,M+),388(100%,[M-H2O]+),  370(17%,[M-2H2O]+),355(9%),273(12%),264(10%),255(6%) (189)"		"189/"	"化学合成品"						"bileaciPage138.html"
"BA0139"	5.00		"6α-HYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"             ＼／�ﾊ／"	"                 H �ﾗ"	"                   H OH"					"189/"	"246-248ﾟC(FROM aq･MeOH)(189)"						"189/"		"cm-1 1711(C=O), 3383, 1034, 1004(OH) (189)"	"1H-NMR (CDCl3+40%DMSO-d6) 0.64(s,18-Me),0.76(s,19-Me),0.90(d,J=5.4Hz,21-Me)  3.30(brm,6β-H)"	"Me ESTER m/z(RELATIVE INTENSITY) 390(4%,M+),372(100%,[M-H2O]+),357(18%), 257(18%),215(49%) (189)"		"189/"	"化学合成品"						"bileaciPage139.html"
"BA0140"	5.00		"6β-HYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"             ＼／�ﾊ／"	"                 H �ﾗ"	"                  HO H"					"189/"	"227-230ﾟC(FROM MeOH),87-90ﾟC(Me ESTER)(189)"						"189/"		"cm-1 1708(C=O), 3390, 1022, 1004(OH) (189)"	"1H-NMR (CDCl3+20%DMSO-d6) 0.68(s,18-Me),0.93(d,J=5.4Hz,21-Me),1.00(s,19-Me) 3.72(m,6α-H) 13C-NMR(Me ESTER)(CDCl3)  C5 49.70,C6 72.55,C24 174.81,CcooMe 51.53 (189)"	"Me ESTER m/z(RELATIVE INTENSITY) 390(2%,M+),372(100%,[M-H2O]+),357(15%), 257(14%),215(47%) (189)"		"189/"	"化学合成品"						"bileaciPage140.html"
"BA0141"	5.00		"3β-HYDROXY-6-OXO-5α-CHOLAN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／"	"         HO  H   H �ｾ"	"                   O"					"189/"	"247-249ﾟC(FROM aq･MeOH)(189),243ﾟC(190) 244-245ﾟC(191),149-151ﾟC(Me ESTER)(189)244-245ﾟC(191),149-151ﾟC(Me ESTER)(189)"						"189/190/191/"		"cm-1 1726,1690(C=O), 3435,1022,997(OH) (189)"	"1H-NMR (CDCl3) 0.67(s,18-Me),0.73(s,19-Me),0.93(d,J=5.4Hz,21-Me), 3.53(brm,3α-H)(189)"			"189/"	"化学合成品"						"bileaciPage141.html"
"BA0142"	5.00		"6α-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"             ＼／�ﾚ／"	"                 H �ﾗ"	"                   H OH"					"189/"	"226-228ﾟC(FROM MeOH)(189)"						"189/"		"cm-1 1703(C=O), 3348,1022,992(OH) (189)"	"1H-NMR (CDCl3+20%DMSO-d6) 0.64(s,18-Me),0.90(s,19-Me),0.92(d,J=5.4Hz,21-Me) 4.01(brm,6β-H)(189)"			"189/"	"化学合成品"						"bileaciPage142.html"
"BA0143"	5.00		"6-OXO-5α-CHOLAN-24-OIC ACID"				"C24H38O3"	24.00	38.00	3.00	0.00	0.00	0.00	374		"                                                             (REF:189)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"             ＼／�ﾊ／"	"                 H �ｾ"	"                   O"					"189/"	"162-164ﾟC(FROM aq･MeOH),85-87ﾟC(Me ESTER)(189)"						"189/"		"cm-1 1710(C=O) (189)"	"1H-NMR (CDCl3) 0.69(s,18-Me),0.72(s,19-Me),0.94(d,J=6.3Hz,21-Me) (189)"			"189/"	"化学合成品"						"bileaciPage143.html"
"BA0144"	5.00		"3β-HYDROXY-24-NORCHOL-5-EN-23-OIC ACID"				"C23H36O3"	23.00	36.00	3.00	0.00	0.00	0.00	360		"                                                             (REF:192)"	"                       ＼／＼"	"                         �ﾓH COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ｸ／"	"         HO  H"						"192/"	"228-232ﾟC(FROM EtOAc),143-144ﾟC(Me ESTER)(192)"		"[α]/D=-42.0ﾟ (192)"				"192/"		"Me ESTER cm-1(CS2), 3610(OH), 1735(COOMe) (192)"				"192/"	"TOBACCO HORNWORM,MANDUCA SEXTA(JOHANNSON)中"	"192/"					"bileaciPage144.html"
"BA0145"	5.00		"3α-HYDROXY-12-OXO-24-NOR-5β-CHOLAN-23-OIC ACID"				"C23H36O4"	23.00	36.00	4.00	0.00	0.00	0.00	376		"                                                             (REF:193)"	"                    O  ＼／＼"	"                   �ｳ    �ﾓH COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／"	"          H  OH  H"						"193/"	"248-250ﾟC(FROM MeOH)(193)"		"[α]/D= 69.7ﾟ (193)"				"193/"							"化学合成品"						"bileaciPage145.html"
"BA0146"	5.00		"3α,7α,12α-TRIHYDROXY-24-NOR-5α-CHOLAN-23-OIC ACID"	"ALLONORCHOLIC ACID"	"allonorCA"		"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                             (REF:194)"	"                   H HO＼／＼"	"                   �ﾒ�ﾄ  �ﾓH COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／�ﾗ"	"          H  OH  H   H OH"						"194/"	"248-250ﾟC(FROM ACETONE),232-234ﾟC(Me ESTER)(194)"		"[α]/D=+25.6ﾟ (194)"				"194/"		"cm-1 3465-3365, 2924, 1704 (194)"	"1H-NMR(Me ESTER) (CDCl3)0.72(s,18-Me),0.76(s,19-Me),1.02(d,J=4Hz,21-Me) 2.50-2.75(m,3α,7α,12α-OH),3.66(s,COOMe),   3.50-4.16(m,3β,7β,12β-H) (194)"""	"Me ESTER m/z(RELATIVE INTENSITY) 408(0.4%,M+),390(6%,M-18),372(71%,M-2x18), 354(19%,M-3x18),271(100%,M-(2x18+101)),253(49%,M-(3x18+101))(194)"		"194/"	"健常者の胆汁(195),ＣＴＸ患者の胆汁(195/196),ＣＴＸ患者の尿(196/175)"	"195/196/175/"					"bileaciPage146.html"
"BA0147"	5.00		"3β,7α,12α-TRIHYDROXY-24-NOR-5α-CHOLAN-23-OIC ACID"				"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                             (REF:194)"	"                   H HO＼／＼"	"                   �ﾒ�ﾄ  �ﾓH COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／�ﾗ"	"         HO  H   H   H OH"						"194/"	"235-237ﾟC(FROM ACETONE),175-177ﾟC(Me ESTER)(194)"		"[α]/D=+27.60ﾟ (194)"				"194/"		"cm-1 3490-3370, 2925, 1700 (194)"	"1H-NMR(Me ESTER) (CDCl3)0.73(s,18-Me),0.80(s,19-Me),1.02(d,J=4Hz,21-Me)"	"Me ESTER m/z(RELATIVE INTENSITY) 408(0.4%,M+),390(5%,M-18),372(63%,M-2x18), 354(3%,M-3x18),271(100%,M-(2x18+101)),253(20%,M-(3x18+101))(194)"		"194/"	"化学合成品"						"bileaciPage147.html"
"BA0148"	5.00		"3β,7α,12α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"				"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                             (REF:194)"	"                   H HO＼／＼"	"                   �ﾒ�ﾄ  �ﾓH COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／�ﾗ"	"         HO  H   H   H OH"						"194/"	"Me ESTER 208-210ﾟC(FROM ETHER) (194)"		"[α]/D=+28.2ﾟ(Me ESTER) (194)"				"194/"		"Me ESTER  cm-1 3340, 2860, 1725, 1590 (194)"	"1H-NMR(Me ESTER) (CDCl3) 0.68(s,18-Me),0.87(s,19-Me),3.66(s,COOMe) (194)"	"Me ESTER m/z(RELATIVE INTENSITY) 408(2%,M+),390(20%,M-18),372(80%,M-2x18), 354(23%,M-3x18),271(100%,M-(2x18+101)),253(61%,M-(3x18+101))(194)"		"194/"	"化学合成品"						"bileaciPage148.html"
"BA0149"	5.00		"7α,12α-DIHYDROXY-3-OXO-24-NOR-5α-CHOLAN-23-OIC ACID"				"C23H36O5"	23.00	36.00	5.00	0.00	0.00	0.00	392		"                                                             (REF:194)"	"                   H HO＼／＼"	"                   �ﾒ�ﾄ  �ﾓH COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ｷ＼／�ﾊ／�ﾗ"	"          O      H   H OH"						"194/"	"199-200ﾟC(Me ESTER)(194)"		"[α]/D=+20.0ﾟ(Me ESTER) (194)"				"194/"		"Me ESTER cm-1 3500-3400,1740(Me ESTER),1695(SIX MEMBER KETONE RING A)(194)"	"1H-NMR(Me ESTER)(CDCl3) 0.68(s,18-Me),1.01(s,19-Me),1.06(d,J=4Hz,21-Me), 2.66(s,7α,12α-OH),3.70(s,COOMe),3.88-3.95(m,7β-H), 3.92-4.26(m,12β-H) (194)"""	"Me ESTER m/z(RELATIVE INTENSITY) 406(2%,M+),388(7%,M-18),370(24%,M-2x18), 333(10%,M-73),269(100%,M-(2x18+101)),251(5%,M-(3x18+101))(194)"		"194/"	"化学合成品"						"bileaciPage149.html"
"BA0150"	5.00		"7α,12α-DIHYDROXY-3-OXO-24-NOR-5β-CHOLAN-23-OIC ACID"				"C23H36O5"	23.00	36.00	5.00	0.00	0.00	0.00	392		"                                                             (REF:194)"	"                   H HO＼／＼"	"                   �ﾒ�ﾄ  �ﾓH COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ｷ＼／�ﾚ／�ﾗ"	"          O      H   H OH"						"194/"	"177-178ﾟC(Me ESTER)(194)"		"[α]/D=+41.7ﾟ(Me ESTER) (194)"				"194/"		"Me ESTER cm-1 3500-3400,2900,1738,1700(SIX MEMBER KETONIC RING)(194)"	"1H-NMR(Me ESTER)(CDCl3) 0.77(s,18-Me),1.00(s,19-Me),1.08(d,J=4Hz,21-Me), 3.68(s,COOMe),4.66-5.00(m,7β,12β-H) (194)"	"Me ESTER m/z(RELATIVE INTENSITY) 406(13%,M+),388(15%,M-18),370(15%,M-2x18), 269(100%,M-(2x18+101)),251(9%,M-(3x18+101))(194)"""		"194/"	"化学合成品"						"bileaciPage150.html"
"BA0151"	5.00		"7α,12α-DIHYDROXY-3-OXO-24-NORCHOL-4-EN-23-OIC ACID"				"C23H34O5"	23.00	34.00	5.00	0.00	0.00	0.00	390		"                                                             (REF:194)"	"                   H HO＼／＼"	"                   �ﾒ�ﾄ  �ﾓH COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ｷ＼�ｷ＼／�ﾗ"	"          O          H OH"						"194/"	"202-203ﾟC(Me ESTER)(194)"		"[α]/D=+50.0ﾟ(Me ESTER) (194)"				"194/"		"Me ESTER  cm-1 3330-3400, 2866, 1725,    1680(α,β-UNSATURATED KETONE SIX MEMBER), 1625 (194)"	"1H-NMR(Me ESTER)(CDCl3) 0.68(s,18-Me),1.03(d,J=4Hz,21-Me),1.16(s,19-Me), 2.63(m,7β,12β-OH),3.66(s,COOMe),3.75-4.08(m,7α,12α-H),       5.80(m,C-4) (194)"""	"Me ESTER m/z(RELATIVE INTENSITY) 404(5%,M+),386(2%,M-18),368(26%,M-2x18),   267(100%,M-(2x18+101)),249(8%,M-(3x18+101))(194)"		"194/"	"化学合成品"						"bileaciPage151.html"
"BA0152"	5.00		"3α,7β-DIHYDROXY-6-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                                                             (REF:197)"	"                       ＼／＼"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／�ﾗ"	"          H  OH  H �ｾOH H"	"                   O"					"197/"	"178-182ﾟC(Me ESTER)(197)"		"[α]20/D=-1.69ﾟ(Me ESTER) (197)"				"197/"		"Me ESTER  cm-1(CHCl3) 3606, 3458, 2951, 2870, 1730, 1705, 1460,   1095, 1050 (197)"	"Me ESTER 1H-NMR(CDCl3); 0.66(s,18-Me),0.81(s,19-Me),0.93(d,J=5.9Hz,21-Me), 3.66(s,COOMe),4.04(d,J7α,8β=10.0Hz,7α-H) (197)13C-NMR(CDCl3); C3 69.9,C5 57.6,C6 213.9,C7 76.3,C24 174.8, CcooMe 51.6 (197)"""	"Me ESTER m/z(RELATIVE INTENSITY) 420(18%,M+),402(34%,M-18),305(14%,M-115), 287(50%,M-18-115),269(50%,M-(2x18+115))(197)"		"197/"	"化学合成品"						"bileaciPage152.html"
"BA0153"	5.00		"7α,12α-DIHYDROXY-3α-[2-(β-D-GLUCOPYRANOSYL)ACETYL]-5β-CHOLAN-24-OIC ACID"	"CHOLIC ACID C-GLUCOSIDE"	"CA-GLUCOSIDE"		"C32H52O10"	32.00	52.00	10.00	0.00	0.00	0.00	596		"                   H HO＼／＼                             (REF:198)"	"                   �ﾒ�ﾄ  �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／�ﾗ"	"          H  C   H   H OH"	"           ／�ｾ"	"Glcpβ1-CH2  O"					"198/"	"172ﾟC(198)"		"[α]20/D=+36.6ﾟ (198)"				"198/"			"1H-NMR(500MHz,CD3OD)  0.73(s,18-Me),0.79(d,J=6.3Hz,21-Me) 0.93(s,19-Me),2.21(dddd,J=11.1,11,1,4.5,and 4.5Hz,3β-H), 4.17(ddd,J=7.7,3.5,and 3.5Hz,7β-H),4.42(dd,J=2.8 and 2.8,12β-H)(198)"""	"m/z  596(M+), 578(M-18), 560(M-36) (198)"		"198/"	"化学合成品"						"bileaciPage153.html"
"BA0154"	5.00		"3α-HYDROXY-6α-O-(β-D-GLUCOPYRANOSYL)-5β-CHOLAN-24-OIC ACID"	"HYODEOXYCHOLIC ACID 6-GLUCOSIDE"	"HDCA 6-GLUCOSIDE"		"C30H50O9"	30.00	50.00	9.00	0.00	0.00	0.00	554		"                       ＼／＼                             (REF:199)"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／"	"          H  OH  H �ﾗ"	"                   H O"	"                     |"	"               Glcpβ1"				"199/"	"184-187ﾟC(FROM EtOH-EtOAc)(199)"						"199/"		"cm-1 3387, 1711, 1078, 1039 (199)"	"1H-NMR(CDCl3)  0.65(s,18-Me),0.90(s,19-Me),0.93(d,J=6.3Hz,21-Me), 3.55(brm,3β-H),(6β-H overlaps with H2O signal),4.33(d,J=7.5Hz,anomeric H) (199)"""			"199/"	"化学合成品"						"bileaciPage154.html"
"BA0155"	5.00		"6α-HYDROXY-3α-O-(β-D-GLUCOPYRANOSYL)-5β-CHOLAN-24-OIC ACID"	"HYODEOXYCHOLIC ACID 3-GLUCOSIDE"	"HDCA 3-GLUCOSIDE"		"C30H50O9"	30.00	50.00	9.00	0.00	0.00	0.00	554		"                       ＼／＼                             (REF:199)"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／"	"          H  O   H �ﾗ"	"             |     H OH"	"       Glcpβ1"					"199/"	"195-198ﾟC(FROM EtOH-EtOAc)(199)"						"199/"		"cm-1 3385, 1651, 1078, 1032 (199)"	"1H-NMR(CDCl3+20%CD3OD)  0.65(s,18-Me),0.91(s,19-Me),0.92(d,J=7.0Hz,21-Me), 3.62(brm,3β-H),(6β-H overlaps with H2O signal),"			"199/"	"化学合成品"						"bileaciPage155.html"
"BA0156"	5.00		"6β-HYDROXY-3α-O-(β-D-GLUCOPYRANOSYL)-5β-CHOLAN-24-OIC ACID"	"MURIDEOXYCHOLIC ACID 3-GLUCOSIDE"	"MDCA 3-GLUCOSIDE"		"C30H50O9"	30.00	50.00	9.00	0.00	0.00	0.00	554		"                       ＼／＼                             (REF:199)"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／"	"          H  O   H �ﾗ"	"             |    HO H"	"       Glcpβ1"					"199/"	"207-210ﾟC(FROM EtOH-EtOAc)(199)"						"199/"		"cm-1 3406, 1652, 1077, 1023 (199)"	"1H-NMR(CDCl3+20%CD3OD)  0.68(s,18-Me),0.93(d,J=6.3Hz,21-Me),1.10(s,19-Me), 3.66(brm,3β-H),3.71(m,6α-H),   4.41(d,J=7.8Hz,anomeric H) (199)"""			"199/"	"化学合成品"						"bileaciPage156.html"
"BA0157"	5.00		"6α-HYDROXY-3α-O-(β-D-GLUCOPYRANOSYL)-5α-CHOLAN-24-OIC ACID"	"ALLOHYODEOXYCHOLIC ACID 3-GLUCOSIDE"	"allo HDCA 3-GLUCOSIDE"		"C30H50O9"	30.00	50.00	9.00	0.00	0.00	0.00	554		"                       ＼／＼                             (REF:199)"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／"	"          H  O   H �ﾗ"	"             |     H OH"	"       Glcpβ1"					"199/"	"233-236ﾟC(FROM EtOH-ACETONE)(199)"						"199/"		"cm-1 3418, 1652, 1081, 1046 (199)"	"1H-NMR(CDCl3+10%CD3OD)  0.64(s,18-Me),0.79(s,19-Me),0.92(d,J=6.0Hz,21-Me), (3β-and 6β-H overlapped with other signals), 4.31(d,J=8.0Hz,anomeric H) (199)"""			"199/"	"化学合成品"						"bileaciPage157.html"
"BA0158"	5.00		"6β-HYDROXY-3α-O-(β-D-GLUCOPYRANOSYL)-5α-CHOLAN-24-OIC ACID"	"ALLOMURIDEOXYCHOLIC ACID 3-GLUCOSIDE"	"allo MDCA 3-GLUCOSIDE"		"C30H50O9"	30.00	50.00	9.00	0.00	0.00	0.00	554		"                       ＼／＼                             (REF:199)"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾊ／"	"          H  O   H �ﾗ"	"             |    HO H"	"       Glcpβ1"					"199/"	"206-209ﾟC(FROM EtOH-EtOAc)(199)"						"199/"		"cm-1 3358, 1715, 1081, 1044 (199)"	"1H-NMR(CDCl3+10%CD3OD)  0.70(s,18-Me),0.93(d,J=6.0Hz,21-Me),1.00(s,19-Me), (6α-H overlapped with other signals),4.07(m,3β-H), 4.33(d,J=8.0Hz,anomeric H) (199)"""			"199/"	"化学合成品"						"bileaciPage158.html"
"BA0159"	5.00		"3α-HYDROXY-6α-O-(β-D-GLUCOPYRANURONOSYL)-5β-CHOLAN-24-OIC ACID"	"HYODEOXYCHOLIC ACID 6-GLUCURONIDE"	"HDCA 6-GLUCURONIDE"		"C30H48O10"	30.00	48.00	10.00	0.00	0.00	0.00	568		"                       ＼／＼                             (REF:199)"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／"	"          H  OH  H �ﾗ"	"                   H O"	"                     |"	"              GlcUpβ1"				"199/"	"222-225ﾟC(FROM MeOH-EtOAc)(199)"						"199/"		"cm-1 3405, 1638(s), 1034 (199)"	"1H-NMR(CD3OD)  0.66(s,18-Me),0.93(s,19-Me),0.94(d,J=6.0Hz,21-Me), 3.59(brm,3β-H),4.10(brm,6β-H),4.35(d,J=7.5Hz,anomeric H) (199)"			"199/"	"化学合成品"						"bileaciPage159.html"
"BA0160"	5.00		"6α-HYDROXY-3α-O-(β-D-GLUCOPYRANURONOSYL)-5β-CHOLAN-24-OIC ACID"	"HYODEOXYCHOLIC ACID 3-GLUCURONIDE"	"HDCA 3-GLUCURONIDE"		"C30H48O10"	30.00	48.00	10.00	0.00	0.00	0.00	568		"                       ＼／＼                             (REF:199)"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／"	"          H  O   H �ﾗ"	"             |     H OH"	"      GlcUpβ1"					"199/"	"244-246ﾟC(FROM MeOH-EtOAc)(199)"						"199/"		"cm-1 3387, 1619, 1043 (199)"	"1H-NMR(CD3OD)  0.66(s,18-Me),0.93(s,19-Me),0.94(d,J=6.0Hz,21-Me),3.71(brm,3β-H),4.00(brm,6β-H),4.45(d,J=7.5Hz,anomeric H)"			"199/"	"化学合成品"						"bileaciPage160.html"
"BA0161"	5.00		"6β-HYDROXY-3α-O-(β-D-GLUCOPYRANURONOSYL)-5β-CHOLAN-24-OIC ACID"	"MURIDEOXYCHOLIC ACID 3-GLUCURONIDE"	"MDCA 3-GLUCURONIDE"		"C30H48O10"	30.00	48.00	10.00	0.00	0.00	0.00	568		"                       ＼／＼                             (REF:199)"	"                         �ﾓH �ｵ"	"                   ／＼�ﾇ＼  COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／�ﾅ"	"           �ｶ  �ｶ  �ｶ    H"	"           �ﾕ�ﾊ／�ﾚ／"	"          H  O   H �ﾗ"	"             |    HO H"	"      GlcUpβ1"					"199/"	"251-252ﾟC(FROM MeOH-EtOAc)(199)"						"199/"		"cm-1 3404, 1625, 1028 (199)"	"1H-NMR(CDCl3) 0.69(s,18-Me),0.95(d,J=6.5Hz,21-Me),1.10(s,19-Me), 3.72(m,6α-H),3.77(brm,3β-H),4.44(d,J=8.0Hz,anomeric H)(199)"			"199/"	"化学合成品"						"bileaciPage161.html"
"BA0162"	5.00		"3α,7β-DIHYDROXY-24-NOR-5β-CHOLAN-23-NITRILE"				"C23H37O2"	23.00	37.00	2.00	0.00	0.00	0.00	345		"                                                    (REF:200)"		"              ＼／＼"	"                �ﾓH CN"	"          ／＼�ﾇ＼"	"          �ｵ�ｶ�ｽ�ｺ"	"    ／＼�ﾇ＼／�ﾅ"	"    �ｵ�ｶ  �ｶ    H"	"  �ﾕ�ﾊ／�ﾚ／�ﾗ"	" H  OH  H  HO H"					"200/"	"228-229ﾟC(200)"						"200/"		"2247cm-1 (200)"	"1H-NMR(CDCl3): 0.67(s,18-Me), 0.92(s,19-Me), 1.14(d,J=6.7Hz,21-Me), 2.29(m,22-CH2), 3.54(m,2H,3β-H and 7α-H) (200)"			"200/"							"bileaciPage162.html"
"BA0163"	5.00		"3α,7α,12α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-NITRILE"				"C23H37O3N"	23.00	37.00	3.00	1.00	0.00	0.00	375		"                                                    (REF:200)"		"          H HO＼／＼"	"          �ﾒ�ﾄ  �ﾓH CN"	"          ／＼�ﾇ＼"	"          �ｵ�ｶ�ｽ�ｺ"	"    ／＼�ﾇ＼／�ﾅ"	"    �ｵ�ｶ  �ｶ    H"	"  �ﾕ�ﾊ／�ﾚ／�ﾗ"	" H  OH  H   H OH"					"200/"	"161-165ﾟC(200)"						"200/"		"2250cm-1 (200)"	"1H-NMR(CDCl3): 0.69(s,18-Me), 0.88(s,19-Me), 1.22(d,J=5.3Hz,21-Me), 3.45(m,3β-H), 3.83(bs,7β-H), 3.93(bs,12β-H)(200)"			"200/"							"bileaciPage163.html"
"BA0164"	5.00		"3α,7β-DIHYDROXY-24-NOR-5β-CHOLAN-23-AMINE"	"NORURSODEOXYCHOLANYLAMINE"			"C23H41O2N"	23.00	41.00	2.00	1.00	0.00	0.00	363		"                                                    (REF:200)"		"              ＼／＼"	"                �ﾓH NH2"	"          ／＼�ﾇ＼"	"          �ｵ�ｶ�ｽ�ｺ"	"    ／＼�ﾇ＼／�ﾅ"	"    �ｵ�ｶ  �ｶ    H"	"  �ﾕ�ﾊ／�ﾚ／�ﾗ"	" H  OH  H  HO H"					"200/"	"139-141ﾟC(200)"					"12μM(pH=12 at 25ﾟC) (200)"	"200/"		"1654cm-1 (200)"	"1H-NMR[(CD3)2SO]: 0.61(s,18-Me), 0.87(d,J=11.31Hz,19-Me and 21-Me), 2.49(m,22-CH2), 3.30(b,23-NH2)(200)"			"200/"							"bileaciPage164.html"
"BA0165"	5.00		"3α,7α,12α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-AMINE"	"NORCHOLANYLAMINE"			"C23H41O3N"	23.00	41.00	3.00	1.00	0.00	0.00	379		"                                                    (REF:200)"		"          H HO＼／＼"	"          �ﾒ�ﾄ  �ﾓH NH2"	"          ／＼�ﾇ＼"	"          �ｵ�ｶ�ｽ�ｺ"	"    ／＼�ﾇ＼／�ﾅ"	"    �ｵ�ｶ  �ｶ    H"	"  �ﾕ�ﾊ／�ﾚ／�ﾗ"	" H  OH  H   H OH"					"200/"	"124-127ﾟC(200)"					"3000μM(pH=12 at 25ﾟC) (200)"	"200/"		"1654cm-1 (200)"	"1H-NMR[(CD3)2SO]: 0.59(s,18-Me), 0.81(s,19-Me), 0.93(t,21-Me) (200)"			"200/"							"bileaciPage165.html"
"BA0166"	5.00		"N-(3α,7β-DIHYDROXY-24-NOR-5β-CHOLANYL)SUCCINAMIC ACID"	"SUCCINYLNORURSODEOXYCHOLANYLAMIDE"			"C27H45O5N"	27.00	45.00	5.00	1.00	0.00	0.00	463		"                                                    (REF:200)"		"              ＼／＼"	"                �ﾓH NHCOCH2CH2COOH"	"          ／＼�ﾇ＼"	"          �ｵ�ｶ�ｽ�ｺ"	"    ／＼�ﾇ＼／�ﾅ"	"    �ｵ�ｶ  �ｶ    H"	"  �ﾕ�ﾊ／�ﾚ／�ﾗ"	" H  OH  H  HO H"					"200/"	"103-105ﾟC(200)"					"172μM(pH=1.0 at 25ﾟC)(200), pKa=4.52(in Me2SO at 25ﾟC)(200), CMC=6-7mM(at 25ﾟC)(200)"	"200/"		"cm-1 1725, 1652, 1560 (200)"	"1H-NMR[(CD3)2SO]: 0.61(s,18-Me), 0.89(d,J=6.7Hz,19-Me and 21-Me), 2.32(m,25-CH2 and 26-CH2), 7.75(t,23-NH)(200)"			"200/"					"THE AMIDE BOND IS REVERSED FROM ITS NORMAL CONFIGURATION.(200)"	"200/"	"bileaciPage166.html"
"BA0167"	5.00		"N-(3α,7α12α-TRIHYDROXY-24-NOR-5β-CHOLANY)-SUCCINAMIC ACID"	"SUCCINYLNORCHOLANYLAMIDE"			"C27H45O5N"	27.00	45.00	5.00	1.00	0.00	0.00	463		"                                                    (REF:200)"		"          H HO＼／＼"	"          �ﾒ�ﾄ  �ﾓH NHCOCH2CH2COOH"	"          ／＼�ﾇ＼"	"          �ｵ�ｶ�ｽ�ｺ"	"    ／＼�ﾇ＼／�ﾅ"	"    �ｵ�ｶ  �ｶ    H"	"  �ﾕ�ﾊ／�ﾚ／�ﾗ"	" H  OH  H   H OH"					"200/"	"178-180ﾟC(200)"					"260μM(pH=1.0 at 25ﾟC)(200), pKa=4.62(in Me2SO at 25ﾟC)(200),CMC=10-11mM(at 25ﾟC)(200)"	"200/"		"1656cm-1 (200)"	"1H-NMR[(CD3)2SO]: 0.59(s,18-Me), 0.81(s,19-Me), 0.95(d,J=6.7Hz,21-Me), 2.34(m,25-CH2 and 26-CH2), 7.74(t,23-NH)(200)"			"200/"					"THE AMIDE BOND IS REVERSED FROM ITS NORMAL CONFIGURATION.(200)"		"bileaciPage167.html"
"BA0168"	5.00		"7α-HYDROXY-3α-O-(β-D-GLUCOPYRANOSYL)-5β-CHOLAN-24-OIC ACID"	"CHENODEOXYCHOLIC ACID 3-GLUCOSIDE"	"CDCA 3-GLUCOSIDE"		"C30H50O9"	30.00	50.00	9.00	0.00	0.00	0.00	554		"                             ＼／＼                    (REF:201)"	"                               �ﾓH �ｵ"	"                         ／＼�ﾇ＼  COOH"	"                         �ｵ�ｶ�ｽ�ｺ"	"                   ／＼�ﾇ＼／�ﾅ"	"          CH2OH    �ｵ�ｶ  �ｶ    H"	"           ＼   H�ﾕ�ﾊ／�ﾚ／�ﾗ"	"         HO�ｽ＼_O  O   H   H OH"	"         HO�ｶ�ｼ  �ｫ"	"           �ｪ�ｬ�ｼ"	"               OH"				"201/"	"146-148ﾟC(201)"						"201/"		"3388, 1716, 1074, 1044cm-1 (201)"	"1H-NMR(CDCl3):0.67(18-Me), 0.92(19-Me), 0.95(d,J=6.5Hz,21-Me), 3.56(3β-H),3.83(7β-H), 4.40(d,J=7.5Hz,C'1-H)(201)"			"201/"							"bileaciPage168.html"
"BA0169"	5.00		"12α-HYDROXY-3α-O-(β-D-GLUCOPYRANOSYL)-5β-CHOLAN-24-OIC ACID"	"DEOXYCHOLIC ACID 3-GLUCOSIDE"	"DCA 3-GLUCOSIDE"		"C30H50O9"	30.00	50.00	9.00	0.00	0.00	0.00	554		"                         H HO＼／＼                    (REF:201)"	"                         �ﾒ�ﾄ  �ﾓH �ｵ"	"                         ／＼�ﾇ＼  COOH"	"                         �ｵ�ｶ�ｽ�ｺ"	"                   ／＼�ﾇ＼／�ﾅ"	"          CH2OH    �ｵ�ｶ  �ｶ    H"	"           ＼   H�ﾕ�ﾊ／�ﾚ／"	"         HO�ｽ＼_O  O   H"	"         HO�ｶ�ｼ  �ｫ"	"           �ｪ�ｬ�ｼ"	"               OH"				"201/"	"192-194ﾟC(201)"						"201/"		"3406, 1709, 1076, 1037cm-1 (201)"	"1H-NMR(CDCl3):0.61(18-Me), 0.83(19-Me), 0.91(d,J=6.5Hz,21-Me), 3.61(3β-H),3.87(12β-H), 4.31(d,J=7.5Hz,C'1-H)(201)"			"201/"							"bileaciPage169.html"
"BA0170"	5.00		"7α,12α-DIHYDROXY-3α-O-(β-D-GLUCOPYRANOSYL)-5β-CHOLAN-24-OIC ACID"	"CHOLIC ACID 3-GLUCOSIDE"	"CA 3-GLUCOSIDE"		"C30H50O10"	30.00	50.00	10.00	0.00	0.00	0.00	570		"                         H HO＼／＼                    (REF:201)"	"                         �ﾒ�ﾄ  �ﾓH �ｵ"	"                         ／＼�ﾇ＼  COOH"	"                         �ｵ�ｶ�ｽ�ｺ"	"                   ／＼�ﾇ＼／�ﾅ"	"          CH2OH    �ｵ�ｶ  �ｶ    H"	"           ＼   H�ﾕ�ﾊ／�ﾚ／�ﾗ"	"         HO�ｽ＼_O  O   H   H OH"	"         HO�ｶ�ｼ  �ｫ"	"           �ｪ�ｬ�ｼ"	"               OH"				"201/"	"164-166ﾟC(201)"						"201/"		"3396, 1703, 1075, 1036cm-1 (201)"	"1H-NMR(CDCl3):0.70(18-Me), 0.91(19-Me), 1.00(d,J=6.5Hz,21-Me), 3.55(3β-H),3.84(7β-H), 3.96(12β-H), 4.39(d,J=7.5Hz,C'1-H)(201)"			"201/"							"bileaciPage170.html"
"BA0171"	5.00		"3α-O-(β-D-GLUCOPYRANOSYL)-5β-CHOLAN-24-OIC ACID"	"LITHOCHOLIC ACID 3-GLUCOSIDE"	"LCA 3-GLUCOSIDE"		"C30H50O8"	30.00	50.00	8.00	0.00	0.00	0.00	538		"                             ＼／＼                    (REF:201)"	"                               �ﾓH �ｵ"	"                         ／＼�ﾇ＼  COOH"	"                         �ｵ�ｶ�ｽ�ｺ"	"                   ／＼�ﾇ＼／�ﾅ"	"          CH2OH    �ｵ�ｶ  �ｶ    H"	"           ＼   H�ﾕ�ﾊ／�ﾚ／"	"         HO�ｽ＼_O  O   H"	"         HO�ｶ�ｼ  �ｫ"	"           �ｪ�ｬ�ｼ"	"               OH"				"201/"	"251-255ﾟC(201)"						"201/"		"3424, 1652, 1558, 1033cm-1 (201)"	"1H-NMR(CDCl3):0.65(18-Me), 0.93(19-Me), 0.93(d,J=5.0Hz,21-Me), 4.42(d,J=7.5Hz,C'1-H)(201)"			"201/"							"bileaciPage171.html"
"BA0172"	5.00		"7β-HYDROXY-3α-O-(β-D-GLUCOPYRANOSYL)-5β-CHOLAN-24-OIC ACID"	"URSODEOXYCHOLIC ACID 3-GLUCOSIDE"	"UDCA 3-GLUCOSIDE"		"C30H50O9"	30.00	50.00	9.00	0.00	0.00	0.00	554		"                             ＼／＼                    (REF:201)"	"                               �ﾓH �ｵ"	"                         ／＼�ﾇ＼  COOH"	"                         �ｵ�ｶ�ｽ�ｺ"	"                   ／＼�ﾇ＼／�ﾅ"	"          CH2OH    �ｵ�ｶ  �ｶ    H"	"           ＼   H�ﾕ�ﾊ／�ﾚ／�ﾗ"	"         HO�ｽ＼_O  O   H  HO H"	"         HO�ｶ�ｼ  �ｫ"	"           �ｪ�ｬ�ｼ"	"               OH"				"201/"	"214-216ﾟC(201)"						"201/"		"3387, 1711, 1078, 1023cm-1 (201)"	"1H-NMR(CD3OD):0.70(18-Me), 0.96(19-Me), 0.96(d,J=7.0Hz,21-Me), 3.50(3β-H),3.71(7α-H), 4.40(d,J=8.0Hz,C'1-H)(201)"			"201/"							"bileaciPage172.html"
"BA0173"	5.00		"(22E)-3α,7α,12α-TRIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"	"Δ22-CHOLIC ACID"	"Δ22-CA"		"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                                                       (REF:202)"		"             H HO＼／�ｹ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H  OH  H   H OH"					"202/"	"181-183ﾟC (Me ESTER)(202)"						"202/"		"Me ESTER  3400cm-1(-OH), 1730cm-1(-COOMe), 1650cm-1(Δ22) (202)"	"1H-NMR(PYRIDINE-d5)  Me ESTER : 0.78(s,18-Me), 0.97(s,19-Me), 1.28(d,J=6Hz,21-Me), 3.65(s,COOMe), 3.60(m,3β-H), 3.98(m,7β-H), 4.09(m,12β-H), 5.82(d,J=15.3Hz,23-H), 6.95(dd,J=15.3 and 7.2Hz,22H)(202)"""	"Me-TMS m/z(RELATIVE INTENSITY) : 636(M+,4%), 621(M-15,7%), 546(M-90,14%),  456(M-2x90,39%), 366(M-3x90,32%), 253(M-SIDE CHAIN-3x90,100%)(202)"		"202/"							"bileaciPage173.html"
"BA0174"	5.00		"(22E)-3α,12α-DIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"	"Δ22-DEOXYCHOLIC ACID"	"Δ22-DCA"		"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                       (REF:202)"		"             H HO＼／�ｹ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H  OH  H"					"202/"	"98-100ﾟC (Me ESTER)(202)"						"202/"		"Me ESTER  3400cm-1(-OH), 1720cm-1(-COOMe), 1640cm-1(Δ22) (202)"	"1H-NMR(PYRIDINE-d5) Me ESTER :0.73(s,18-Me), 0.94(s,19-Me), 1.23(d,J=6Hz,21-Me), 3.65(s,COOMe), 3.80(m,3β-H), 4.07(m,12β-H), 5.85(d,J=15.3Hz,23-H), 6.98(dd,J=15.3 and 7.2Hz,22-H)(202)"""	"Me-TMS m/z(RELATIVE INTENSITY) : 548(M+,13%), 533(M-15,19%), 458(M-90,8%), 368(M-2x90,11%),255(M-SIDE CHAIN-2x90,100%)(202)"		"202/"							"bileaciPage174.html"
"BA0175"	5.00		"(22E)-3α,7α-DIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"	"Δ22-CHENODEOXYCHOLIC ACID"	"Δ22-CDCA"		"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                       (REF:202)"		"                 ＼／�ｹ"	"                   �ﾓH �ｵ"	"             ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H  OH  H   H OH"					"202/"									"Me ESTER  3400cm-1(-OH), 1730cm-1(-COOMe), 1650cm-1(Δ22) (202)"	"1H-NMR(PYRIDINE-d5) Me ESTER: 0.68(s,18-Me), 0.95(s,19-Me), 1.03(d,J=6Hz,21-Me), 3.65(s,COOMe), 3.60(m,3β-H), 3.93(m,7β-H), 5.82(d,J=15.3Hz,23-H), 6.89(dd,J=15.3 and 7.2Hz,22-H)(202)"""	"Me-TMS m/z(RELATIVE INTENSITY) : 458(M-90,4%), 368(M-2x90,100%), 353(M-2x90-15,15%), 255(M-SIDE CHAIN-2x90,32%)(202)"		"202/"							"bileaciPage175.html"
"BA0176"	5.00		"(22E)-3α,7β-DIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"	"Δ22-URSODEOXYCHOLIC ACID"	"Δ22-UDCA"		"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                       (REF:202)"		"                 ＼／�ｹ"	"                   �ﾓH �ｵ"	"             ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H  OH  H  HO H"					"202/"	"229-230ﾟC(Me ESTER)(202)"						"202/"		"Me ESTER  3400cm-1(-OH), 1730cm-1(-COOMe), 1650cm-1(Δ22) (202)"	"1H-NMR(PYRIDINE-d5) Me ESTER: 0.69(s,18-Me), 0.95(s,19-Me), 1.06(d,J=6Hz,21-Me), 3.65(s,COOMe), 3.75(m,3β-H and 7α-H), 5.85(d,J=15.3Hz,23-H), 6.95(dd,J=15.3 and 7.2Hz,22-H)(202)"""	"Me-TMS m/z(RELATIVE INTENSITY) : 548(M,13%), 533(M-15,19%), 458(M-90,8%), 368(M-2x90,11%), 255(M-SIDE CHAIN-2x90,100%)(202)"""		"202/"	"UDCAを静注あるいは経口投与により,ラットの血しょう,胆汁,腸内および肝臓中に存在することを初めて同定,確認した。(203)"	"(203)"					"bileaciPage176.html"
"BA0177"	5.00		"3β-AZIDO-7α,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H39O4N3"	24.00	39.00	4.00	3.00	0.00	0.00	433		"                                                       (REF:204)"		"             H HO＼／�ｹ"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   N3  H   H   H OH"					"204/"	"203-205ﾟC(204)"						"204/"	"λMeOH/MAX : 286nm(ε=52),223nm(ε=265) (204)"	"2105cm-1(C-N3), 1720cm-1(C=O) (204)"	"1H-NMR(DMSO-d6/CDCl3=3:1): 0.60(s,18-Me), 0.88(s,19-Me), 0.92(d,J=5Hz,21-Me), 2.10(m,23-CH2), 3.60(s,b,7β-H), 3.76(s,b,12β-H), 3.85(s,b,3α-H)(204)"""	"Me-TMS m/z(RELATIVE INTENSITY) : 405(M-N2), 397(M-2xH2O), 390(M-HN3), 372(M-HN3-H2O), 354(M-HN3-2xH2O)(204)"		"204/"							"bileaciPage177.html"
"BA0178"	5.00		"3β-AZIDO-12-OXO-7α-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H37O4N3"	24.00	37.00	4.00	3.00	0.00	0.00	431		"                                                       (REF:204)"		"               O ＼／�ｹ"	"               �ｾ  �ﾓH �ｵ"	"             ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"   N3  H   H   H OH"					"204/"	"125-130ﾟC(204)"						"204/"	"λMeOH/MAX : 285nm(ε=167),221nm(ε=321) (204)"	"2100cm-1(C-N3), 1700cm-1(C=O) (204)"	"1H-NMR(CDCl3) : 0.82(s,21-Me), 1.00(s,18-Me and 19-Me), 2.27(m,23-CH2), 3.90(m,b,3α-H and 7β-H)(204)"	"m/z : 431(M+), 413(M-H2O), 330(M-SIDE CHAIN), 312(M-SIDE CHAIN-H2O), 290(BASE PEAK)(204)"		"204/"							"bileaciPage178.html"
"BA0179"	5.00		"11ε-AZIDO-12-OXO-3α,7α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H37O5N3"	24.00	37.00	5.00	3.00	0.00	0.00	447		"                                                       (REF:204)"		"               O ＼／＼"	"          N3   �ｾ  �ﾓH �ｵ"	"           �ﾜ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ    H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H  OH  H   H OH"					"204/"	"135-138ﾟC (DECOMPOSITION)(204)"						"204/"	"λMeOH/MAX : 288nm(ε=1237),226nm(ε=1134) (204)"	"2105cm-1(C-N3), 1710cm-1(C=O) (204)"	"1H-NMR(DMSO-d6/CDCl3=3:1): 0.80(d,J=5Hz,21-Me), 1.00(s,19-Me), 1.08(s,18-Me), 2.13(m,23-CH2), 3.30(m,3β-H), 3.69(m,7β-H), 4.23(m,11-CH)(204)"""	"m/z : 447(M+), 419(M-N2), 404(M-HN3), 401(M-N2-H2O), 386(M-HN3-H2O), 368(M-HN3-2xH2O), 318(M-N2-SIDE CHAIN), 300(M-N2-H2O-SIDE CHAIN)(204)"		"204/"							"bileaciPage179.html"
"BA0180"	5.00		"7,7-AZI-3α,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H38O4N2"	24.00	38.00	4.00	2.00	0.00	0.00	418		"                                                       (REF:204)"		"             H HO＼／＼"	"             �ﾒ�ﾄ  �ﾓH �ｵ"	"             ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ�ｽ  H"	"     �ﾕ�ﾊ／�ﾚ�ｬ  N"	"    H  OH  H   N�ｷ"					"204/"	"135-140ﾟC (DECOMPOSITION)(204)"						"204/"	"λMeOH/MAX nm(ε): 367(52), 350(57), 260(146), 232(239) (204)"	"1710cm-1(C=O), 1570cm-1(C-N2) (204)"	"1H-NMR(DMSO-d6):0.55(s,18-Me), 0.95(s,b,19-Me and 21-Me), 2.10(m,23-CH2), 3.30(m,b,3β-H), 3.73(m,12β-H)(204)"	"m/z : 372(M-N2-H2O), 354(M-N2-2xH2O), 271(M-N2-H2O-SIDE CHAIN), 253(M-N2-2xH2O-SIDE CHAIN,BASE PEAK)(204)"		"204/"							"bileaciPage180.html"
"BA0181"	5.00		"7,7-AZI-3α-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H38O3N2"	24.00	38.00	3.00	2.00	0.00	0.00	402		"                                                       (REF:205)"		"                 ＼／＼"	"                   �ﾓH �ｵ"	"             ／＼�ﾇ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ﾇ＼／�ﾅ"	"       �ｵ�ｶ  �ｶ�ｽ  H"	"     �ﾕ�ﾊ／�ﾚ�ｬ  N"	"    H  OH  H   N�ｷ"					"205/"	"145ﾟC (DECOMPOSITION)(205)"						"205/"	"λMeOH/MAX nm(ε): 207(383), 352(89), 368(80) (205)"		"1H-NMR(CD3OD) : 0.63(s,18-Me), 0.92(d,J=7Hz,21-Me), 1.04(s,19-Me), 3.50(m,3β-H) (205)"	"m/z : 374(M-N2), 356(M-N2-H2O), 255(M-N2-H2O-SIDE CHAIN)(205)"		"205/"							"bileaciPage181.html"
"BA0182"	5.00		"5α-CHOLANE-3α,7α,12α,24-TETROL"	"5α-PETROMYZONOL"			"C24H42O4"	24.00	42.00	4.00	0.00	0.00	0.00	394			"              HO �ﾅ／＼／＼                      (REF:001)"	"               �ﾂ ｜       OH"	"             ／�ｪ／＼"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"						"001/"	"224-226 AND 240-241 001)"		"[α]25/D=+27.5 (001)"				"001/"		"(001)"	"(001)"	"(001)"		"001/"	"ヤツメウナギ(PETROMYZON MARINUS)胆汁(001) オーストラリア産肺魚(NEOCERATODUS FORSTERI)胆汁(002) アフリカ産肺魚(PROTOPTERUS AETHIOPICUS)胆汁(002)"	"001/002/"					"bileaciPage182.html"
"BA0183"	5.00		"26,27-DINOR-5β-CHOLESTANE-3α,7α,12α,24,25-PENTOL"				"C25H44O5"	25.00	44.00	5.00	0.00	0.00	0.00	424		"                        OH"	"                        ｜  OH               (REF:003/004)"	"              HO �ﾅ／＼／＼／"	"               �ﾂ ｜"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼�ｬ＼／�ﾅ"	"    HO    H      OH"					"003/004/"	"188(004)"						"004/"		"(004)"		"TMS誘導体で測定(003)"		"003/004/"	"胆汁うっ滞症患者胆汁(003)"	"003/"					"bileaciPage183.html"
"BA0184"	5.00		"5α-CHOLESTANE-3α,7α,26-TRIOL"	"3-EPI-16-DEOXYMYXINOL"			"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420			"                        ｜                 (REF:005)"	"                 �ﾅ／＼／＼／＼"	"                  ｜      ｜   OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"005/"	"187-188 005)"						"005/"		"(005)"	"(005)"			"005/"	"ヌタウナギ(HEPTATRETUS BURGERI)胆汁(005)"	"005/"					"bileaciPage184.html"
"BA0185"	5.00		"5α-CHOLESTANE-3α,7α,16α,26-TETROL"	"3-EPIMYXINOL"			"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                           (REF:005)"	"                 �ﾅ／＼／＼／＼"	"                  ｜   OH ｜   OH"	"             ／＼�ｫ＼�ﾄ"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"005/"	"178(005)"						"005/"		"(005)"	"(005)"			"005/"	"ヌタウナギ(HEPATRETUS BURGERI)胆汁(005)"	"005/"					"bileaciPage185.html"
"BA0186"	5.00		"5β-CHOLESTANE-3α,6β,7α,25,26-PENTOL"	"α-TRICHECHOL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                 �ﾅ／＼／＼／＼                          (REF:006/007)"	"                  ｜       �･  OH"	"             ／＼�ｫ＼        OH"	"            ｜ �ｶ�ｽ�ｺ"	"       ／�ｪ／＼／"	"      ｜  ｜  ｜"	"     �ﾄ＼�ｬ＼／�ﾅ"	"   HO      H｜   OH"	"             OH"					"006/007/"	"126-129(007)"						"007"		"(007)"	"(006/007)"	"(006/007)"		"006/007/"	"西インド諸島マナティー(TROCHECHUS MANATUS LATIROSTRIS)胆汁(006)"	"006/"					"bileaciPage186.html"
"BA0187"	5.00		"5β-CHOLESTANE-2β,3α,7α,12α,26-PENTOL"	"ARAPAIMOL-A"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                                           (REF:008)"	"              HO �ﾅ／＼／＼／＼"	"             �ﾃ   ｜      ｜   OH"	"             ／＼�ｫ＼"	"   HO       ｜  ｜ �ｺ"	"     ＼／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼�ｬ＼／�ﾅ"	"   HO      H     OH"					"008/"	"216-220(008)"		"[α]25/D=+33.9±2 (008)"				"008/"		"(008)"	"(008)"	"(008)"		"008/"	"淡水魚アラパイマ(ARAPAIMA GIGAS)胆汁(008) 西ナイジェリア産アカガエル科のカエル(CARDIOGLOSSA LEUCOMYSTAX)胆汁((009)   西ナイジェリア産アオガエル科のカエル(HYPEROLIUS FUSCIVENTRIS BURTONI, HYPEROLOUS GUTTULATUS"	"008/009/"					"bileaciPage187.html"
"BA0188"	5.00		"5β-CHOLESTANE-2β,3α,7α,12α,26,27-HEXOL"	"ARAPAIMOL-B"			"C27H48O6"	27.00	48.00	6.00	0.00	0.00	0.00	468			"                                            (REF:063)"	"              HO �ﾅ／＼／＼／＼"	"             �ﾃ   ｜      ｜   OH"	"             ／＼�ｫ＼      ＼"	"   HO       ｜  ｜ �ｺ        OH"	"     ＼／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼�ｬ＼／�ﾅ"	"   HO      H     OH"					"063/"	"228-230(008)"		"[α]25/D=+29.6±2 (008)"				"008/"		"(008)"	"(008)"	"(008)"		"008/"	"淡水魚アラパイマ(ARAPAIMA GIGAS)胆汁(008)"	"008/"					"bileaciPage188.html"
"BA0189"	5.00		"5α-CHOLESTANE-3α,7α,12α,25,26,27-HEXOL"	"5α-DERMOPHOL"			"C27H48O6"	27.00	48.00	6.00	0.00	0.00	0.00	468			"                                            (REF:010/011)"	"              HO �ﾅ／＼／＼／＼"	"             �ﾃ   ｜       �ﾉ  OH"	"             ／＼�ｫ＼      ＼OH"	"            ｜  ｜ �ｺ        OH"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼�ﾋ＼／�ﾅ"	"   HO      H     OH"					"010/011/"	"262-263(011)"						"011/"		"(010/011)"	"(011)"	"誘導体として測定(010/011)"		"010/011/"	"イモリ(DIEMYCTYLUS PYRRHOGASTER)胆汁(010) コンゴーイール(AMPHIUMA MEANS)胆汁(010) オウサンショウウオ(MEGALOBACTRACHUS JAPONICUS)胆汁(010)"	"010/"					"bileaciPage189.html"
"BA0190"	5.00		"5β-CHOLESTANE-3α,7α,12α,25,26,27-HEXOL"	"5β-DERMOPHOL"			"C27H48O6"	27.00	48.00	6.00	0.00	0.00	0.00	468			"                                             (REF:010)"	"              HO �ﾅ／＼／＼／＼"	"             �ﾃ   ｜       �ﾉ  OH"	"             ／＼�ｫ＼      ＼OH"	"            ｜  ｜ �ｺ        OH"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾉ／�ﾅ"	"   HO      H     OH"					"010/"	"166-169(010)"						"010/"		"(010)"	"(010)"	"誘導体として測定(010)"		"010/"	"アシナシイモリ(DERMOPHIS MEXICANUS)胆汁(010)  ヒキガエル(BUFO B. FORMOSUS)胆汁(010)"	"010/"					"bileaciPage190.html"
"BA0191"	5.00		"5α-CHOLESTANE-3α,7α,12α,26-TETROL"	"27-DEOXY-5α-CYPRINOL"			"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                              (REF:012/013)"	"              HO �ﾅ／＼／＼／＼"	"             �ﾃ   ｜      ｜   OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"012/013/"	"232(012/013)"		"[α]23/D=+39ﾟ(C=0.2,ETHANOL) (012)"				"012/013/"		"(013)"				"013/"	"コイ(CYPRINUS CARPIO)胆汁(012), 日本産ヒキガエル(BUFO B.FORMOSUS)胆汁(009/ 014), ヨーロッパ産ヒキガエル(BUFO B. VULGARIS)胆汁(009)，アカガエル科のカエル (ARTHROLEPTIS, HYLARANA ALBOLABRIS, DICROGLOSSIS OCCIPTALIS, PTYCHADENAAEQUIPLICATA, PTYCHADENA MASCA"	"012/009/014/002/015/016/"					"bileaciPage191.html"
"BA0192"	5.00		"5α-CHOLESTANE-3β,7α,12α,26,27-PENTOL"	"LATIMEROL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                                            (REF:017)"	"              HO �ﾅ／＼／＼／＼"	"             �ﾃ   ｜      ｜   OH"	"             ／＼�ｫ＼      ＼"	"            ｜  ｜ �ｺ        OH"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     ／＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"017/"	"235-236(017)"		"[α]25/D=+33±2ﾟ(C=1.1,ETHANOL)(017)"				"017/"		"(017)"		"TMS誘導体として測定(018)    (018)"		"017/018/"	"シーラカンス(LATIMERIA CHALUMAE)胆汁(017/002/018)"	"017/002/018/"					"bileaciPage192.html"
"BA0193"	5.00		"5α-CHOLESTANE-3β,7α,16α,26-TETROL"	"MYXINOL"			"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                              (REF:019/020/021)"	"                 �ﾅ／＼／＼／＼"	"                  ｜   OH ｜   OH"	"             ／＼�ｫ＼�ﾄ"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     ／＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"019/020/021/"	"204-206(005/019)"		"[α]/D=-15±2 (C=1.2,ETHANOL) (019)"				"005/019/"		"(019/005)"	"(020/021/005)"	"(020/021)"		"019/005/020/021/"	"大西洋産メクラウナギ(EPTATRETUS STOUTII)胆汁(019)  カリフォルニヤ産メクラウナギ(MYXINE GLUTINOSA)胆汁(019)"	"019/005/"					"bileaciPage193.html"
"BA0194"	5.00		"5α-CHOLESTANE-3β,7α,26-TRIOL"	"16-DEOXYMYXINOL"			"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420			"                                              (REF:022/023/024)"	"                 �ﾅ／＼／＼／＼"	"                  ｜      ｜   OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     ／＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"022/023/024/"	"218-219(022) OR 206-207(024)"		"[α]/D=+13±3 (C=0.92,ETHANOL) (022)"				"022/024/"		"(022)"	"(023/005)"	"(023/024)"		"022/023/005/024/"	"大西洋産メクラウナギ(EPTATRUS STOUTII)胆汁(022) カリフォルニヤ産メクラウナギ(MYXINE GLUTINOSA )胆汁(022) ヌタウナギ(HEPTATRETUS BURGERI)胆汁(005)"	"022/005/"					"bileaciPage194.html"
"BA0195"	5.00		"5α-CHOLESTANE-3β,7α,12α,25,26-PENTOL"	"3-EPI-5α-BUFOL"			"C27H48O4"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                                              (REF:018)"	"              HO �ﾅ／＼／＼／＼"	"               �ﾂ ｜       �ﾉ  OH"	"             ／＼�ｫ＼        OH"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     ／＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"018/"	"253(018)"						"018/"		"(018)"	"(018)"	"TMS誘導体として測定 (018)"		"018/"	"シーラカンス(LATIMERIA CHALUMNAE)胆汁(018)"	"018/"					"bileaciPage195.html"
"BA0196"	5.00		"5α-CHOLESTANE-3α,7α,12α,24-TETROL"	"26-DEOXY-5α-CHIMAEROL"			"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436		"                         OH"	"                         �ｵ                     (REF:025)"	"              HO �ﾅ／＼／＼／"	"               �ﾂ ｜       �ｵ"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"025/"	"NOT REPORTED(025)"						"025/"		"(025)"		"TMS誘導体として測定(025)"		"025/"	"ウサギ胆汁(025)，オーストラリヤ産肺魚(NEOCERATODUS FORSTERI)胆汁(002) コイ科のサカナ(BARBUS TRACHYPTERUS)胆汁(015)， コイ科のサカナ(VARICORHINUS UPEMBENSIS, LABEO CF.CLARIENSIS)胆汁(015), ヒト胆汁(026)，CEREBROTENDIOUS XANTHOMATOSIS患者胆汁(027)"	"002/015/025/026/027/"					"bileaciPage196.html"
"BA0197"	5.00		"5β-CHOLESTANE-3α,7α,12α,26-TETROL"	"27-DEOXY-5β-CYPRINOL"			"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                                 (REF:028/029)"	"              HO �ﾅ／＼／＼／＼"	"               �ﾂ ｜       �ｵ  OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾉ／�ﾅ"	"   HO      H     OH"					"028/029/"	"200-201(028/029)"		"[α]23/D=+36.1±1ﾟ(25R体),+25±2ﾟ(25S体)(029)"				"028/029/"				"DMES誘導体として測定(031/032)"		"031/032/"	"カエル１９種(XENOPUS MULLERI, BUFO B. FORMOSUS, BUFO B. VULGARIS, BUFO MACULATUS,BUFO MARINUS,BUFO REGULARIS,ARTHROLEPTIS,CARDIOGLOSSA LEUCOMYSTAX,DICROGLOSSUS OCCIPITAILIS,PTYCHADENA AEQUIPLICATA,PTYCHADENA LONGIROSTRIS,PTYCHADENA MACCARTHYENSIS,PTY"	"009/030/031/026/032/"					"bileaciPage197.html"
"BA0198"	5.00		"3α,7α,12α-TRIHYDROXY-27-NOR-5α-CHOLESTAN-24-ONE"				"C26H44O4"	26.00	44.00	4.00	0.00	0.00	0.00	420		"                        O"	"                        ‖                         (REF:033/034)"	"              HO �ﾅ／＼／＼／"	"               �ﾂ ｜"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"033/034/"	"NOT REPORTED(034)"						"034/"		"(033)"		"TMS誘導体として測定(033)"		"033/"	"ウシガエル(RANA CATESBEIANA)胆汁(033)"	"033/"					"bileaciPage198.html"
"BA0199"	5.00		"3α,7α,12α-TRIHYDROXY-27-NOR-5β-CHOLESTAN-24-ONE"				"C26H44O4"	26.00	44.00	4.00	0.00	0.00	0.00	420		"                        O"	"                        ‖                         (REF:033/034)"	"              HO �ﾅ／＼／＼／"	"               �ﾂ ｜"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾉ／�ﾅ"	"   HO      H     OH"					"033/034/"	"NOT REPORTED(034)"						"034/"		"(033)"		"TMS誘導体として測定(033)"		"033/"	"ウシガエル(RANA CATESBEIANA)胆汁(033)，ヒト胆汁(026)"	"026/033/"					"bileaciPage199.html"
"BA0200"	5.00		"5β-CHOLANE-3α,7α,12α,24-TETROL"	"5β-PETROMYZONOL"			"C24H42O4"	24.00	42.00	4.00	0.00	0.00	0.00	394			"                                                 (REF:035)"	"              HO �ﾅ／＼／＼"	"               �ﾂ ｜       OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾉ／�ﾅ"	"   HO      H     OH"					"035/"	"234.5-235.5(035)"						"035/"		"(035)"	"(035)"			"035/"	"アフリカ産肺魚( PROTOPTERUS AETHIOPICUS ) 胆汁(002)，ヒト 胆汁(026)"	"002/026/"					"bileaciPage200.html"
"BA0201"	5.00		"3α,7α,12α-TRIHYDROXY-26,27-DINOR-5β-CHOLESTANE-24-ONE"				"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                        O"	"                        ‖                        (REF:003/036)"	"              HO �ﾅ／＼／＼"	"               �ﾂ ｜"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾉ／�ﾅ"	"   HO      H     OH"					"003/036/"	"166-168(036)"						"036/"				"TMS誘導体として測定(003)"		"003/"	"ある胆汁うっ滞症患者  胆汁(003)"	"003/"					"bileaciPage201.html"
"BA0202"	5.00		"5α-CHOLESTANE-3α,7α,12α,25,26-PENTOL"	"5α-BUFOL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                                                (REF:037)"	"              HO �ﾅ／＼／＼／＼"	"               �ﾂ ｜       �ﾉ  OH"	"             ／＼�ｫ＼        OH"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"037/"	"241( 037)"						"037/"		"(037)"				"037/"	"イモリ(DIEMYCTYLUS PHYRRHOGASTER)胆汁(037)，コンゴーイール(AMPHIUMA MEANS) 胆汁(010), アカガエル科のカエル(HYLARANA ALBOLABRIS, PTYCHADENA MASCARENI- ENSIS, PTYCHADENA TAENIOSCELIS, RANA GALAMAMENSIS)胆汁(009)シーラカンス(LATIMERIA CHALUMNAE)胆汁(002),"	"037/010/009/002/030/"					"bileaciPage202.html"
"BA0203"	5.00		"5β-CHOLESTANE-3α,7α,12α,25,26-PENTOL"	"5β-BUFOL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                                                (REF:038/039)"	"              HO �ﾅ／＼／＼／＼"	"               �ﾂ ｜       �ﾉ  OH"	"             ／＼�ｫ＼        OH"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾉ／�ﾅ"	"   HO      H     OH"					"038/039/"	"178.5(038/039)"		"[α]30/D=+38 (038)"				"038/039/"		"(038/039)"	"(035)"	"(040/050)"		"035/038/039/040/050/"	"ニホンヒキガエル(BUFO B.FORMOSUS)胆汁(038/009/010/035), ヌマガエル(RANA LIMNOCHARIS)胆汁(040),各種カエル(DISCOGLOSSUS PICTUS, BUFO B.VULGARIS,     BUFO MACULATUS, BUFO MARINUS, BUFO REGULARIS, ARTHROLETIS POECILONOTUS,DICROGLOSSUS OCCIPITALIS, PTYCHAD"	"038/009/010/035/040/025/030/051/052/026/053/027/032/054/055/056/"					"bileaciPage203.html"
"BA0204"	5.00		"27-NOR-5β-CHOLESTANE-3α,7α,12α,24,26-PENTOL"	"5β-RANOL"			"C26H46O5"	26.00	46.00	5.00	0.00	0.00	0.00	438		"                         OH"	"                         �ﾁ                        (REF:041/042/043)"	"              HO �ﾅ／＼／＼／＼"	"               �ﾂ ｜           OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾉ／�ﾅ           （C24位の絶対配置はRと決定(042/043)）"	"   HO      H     OH"					"041/042/043/"	"189 (041) OR 195.5-196.5 (042) OR 192 (034)"		"[α]/D=+30ﾟ(C=1.02,METHANOL)(042)"				"034/041/042/"		"(041/042)"	"(041/042)"			"041/042/"	"ウシガエル(RANA CATESBEIANA)胆汁(041/042/034) スズガエル科のカエル(DISCOGLOSSUS PICTUS)胆汁(009) アカガエル科のカエル(ARTHROLEPITIS POECILONOTUS, AUBRIA SUBSIGILLATA,   PTYCHADENA AEQUIPLICATA ,RANA PIPIENS)胆汁(009)       アマガエル(HYLA ARBOREA JA"	"041/042/009/040/030/"					"bileaciPage204.html"
"BA0205"	5.00		"27-NOR-5α-CHOLESTANE-3α,7α,12α,24,26-PENTOL"	"5α-RANOL"			"C26H46O5"	26.00	46.00	5.00	0.00	0.00	0.00	438		"                         OH"	"                         �ﾁ                        (REF:044/045)"	"              HO �ﾅ／＼／＼／＼"	"               �ﾂ ｜           OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ       （C-24位の絶対配置は5β-RANOLと同じRと考えられる）"	"   HO      H     OH"					"044/045/"	"GELATINOUS MATERIAL(TETRA-Ac=154-157(044))155(034)"		"[α]/D=+21 (ETHANOL)(044)"				"034/044/"		"TETRA-ACETATE(044)"	"TETRA-ACETATE(045)"	"(045)"		"044/045/"	"ヨーロッパアカガエル(RANA TEMPRORARIA)胆汁(044/009) ウシガエル(RANA CATESBEIANA)胆汁(034) チョウセンアカガエル(RANA AMURENSIS COREANA)胆汁(030)ツシマアカガエル(RANA AMURENSIS TSUSHIMENSIS)胆汁(030)   ヤマアカガエル(RANA TEMPORARIA DYBOWSKII)胆汁(03"	"044/009/034/030/"					"bileaciPage205.html"
"BA0206"	5.00		"5α-CHOLESTANE-3α,7α,12α,24,26-PENTOL"	"5α-CHIMAEROL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452		"                         OH"	"                                                 (REF:029)"	"              HO �ﾅ／＼／＼／＼"	"               �ﾂ ｜      ｜   OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"029/"	"234-235 (029)"		"[α]24/D=+33.5±1 (C=1.1,ETHANOL)(029)"				"029/"		"(029)"				"029/"	"コイ科の類縁のサカナ(CATOSTOMUS COMMERSONI)胆汁(029) オーストラリア産肺魚(NEOCERATODUS FORSTERI)胆汁(002) 多鰭類のサカナ(POLYPTERUS SENEGALALUS)胆汁(015)ザイール河（アフリカ）産サカナ(DISTICHODUS LUSUSSO)胆汁(015)  コイ科のサカナ(LABEO CF CLARIENSI"	"029/022/015/"					"bileaciPage206.html"
"BA0207"	5.00		"5β-CHOLESTANE-3α,7α,12α,24,26-PENTOL"	"5β-CHIMAEROL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452		"                        OH"	"                        ｜                         (REF:046/047)"	"              HO ＼／＼／＼／＼"	"               �ﾂ ｜      ｜   OH"	"             ／＼�ｫ＼"	"            ｜  ｜ �ｺ"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾉ／�ﾅ"	"   HO      H     OH"					"046/047/"	"180-182 (046)"		"[α]/D=+41.5 (C=1.2,ETHANOL)(046)"				"046/"		"(047)"	"(001)"			"001/047/"	"ギンザメ(CHIMAERA MONSTROSA)胆汁 (046) ホシザメ(MUSTELUS MANAZO)胆汁(048) アカエイ(DASYBATUS AKAJEI)胆汁(049)健常人及び胆汁うっ滞症患者尿(032) ヒト胆汁(026)"	"046/048/049/032/026/"					"bileaciPage207.html"
"BA0208"	5.00		"5α-CHOLESTANE-3α,7α,12α,26,27-PENTOL"	"5α-CYPRINOL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                                                 (REF:013/057/058)"	"              HO �ﾅ／＼／＼／＼"	"               �ﾂ ｜      ｜   OH"	"             ／＼�ｫ＼      ＼"	"            ｜  ｜ �ｺ        OH"	"       ／�ｪ／＼／�ｼ"	"      ｜  ｜  ｜"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"					"13/57/58/"	"242(013/057) OR 242-244(058)"		"[α]23/D=+29±2(C=1.7,ETHANOL)(058)"				"013/057/058/"		"(057/058)"	"(057/060/001)"	"(040)"		"057/058/001/060/040/"	"コイ(CYPRINUS CARPIO)胆汁(013/057/058),ハス(OPSARIICHTHYS UNCIROSRIS)胆汁  (059),カマツカ(PSEUDOGOBIO ESOCINUS)胆汁(059),ワタカ(ISHIKAUIA STEENACKERI)胆汁(059),ニゴイ(HEMIBARBUS BARBUS)胆汁(059),オイカワ(ZACCO TYPUS)胆汁(059)ヒガイ(SARCOCHEILICHTHYS VARI"	"013/057/058/059/017/002/018/061/062/015/040/034/009/"	"西ナイジェリア産アカガエル科のカエル(RANA GALAMENSIS)胆汁(009), ニホンアカガエル(RANA JAPONICA JAPONICA)胆汁(030),タゴガエル(RANA TAGOI)胆汁(030),  アカガエル科のカエル(RANA ERYTHREA)胆汁(030)"	"009/030/"			"bileaciPage208.html"
"ST0002"	5.00		"5β-CHOLESTANE-3α,7α,26-TRIOL"				"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420		"                 �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH"	"                   �ｵ      �ｵ                               (063)"	"             �ｱ�ｲ�ｫ�ｲ"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"   HO      H     OH"							"063/"	"25R体 155-157ﾟC, 25S体  138-140ﾟC(063)"		"25R体 [α]25/D +15.9ﾟ, 25S体 [α]25/D +8.8ﾟ (063)"				"063/"			"1H-NMR(CDCl3) 18-CH3=66.0, 19-CH3=90.0, 21-CH3=91.0, 27-CH3=92.5 (in Hz) (063)"	"546,531,456,441,366,351,255,73(BASE PEAK) (TMS DERIV.)(063)"		"063/"	"ﾋﾄ胆汁(026)"	"(026)"					
"ST0003"	5.00		"5β-CHOLESTANE-3α,7α,25-TRIOL"				"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420		"                 �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                   �ｵ      �ﾉ                        合成 (064)"	"             �ｱ�ｲ�ｫ�ｲ        OH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"   HO      H     OH"							"064/"	"181-183ﾟC(064)"						"064/"		"cm-1 3480,2925,2860,1465,1378,1160,1150,1070 AND 980 (064)"		"621,546,531,456,441,366,351,255,253,131(BASE PEAK) (TMS DERIV.)(064)"		"064/"	"ﾋﾄ胆汁(026)"	"(026)"					
"ST0004"	5.00		"5β-CHOLESTANE-3α,7α,24-TRIOL"				"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420		"                          OH"	"                          �ﾂ                 合成 (063)"	"                  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                    �ｵ      �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"063/"	"24R体 125-127ﾟC, 24S体 78-79ﾟC(063)"		"24R体 [α]25/D +25.8ﾟ, 24S体 [α]25/D +4ﾟ 063)"				"063/"			"1H-NMR 18-CH3 19-CH3 21-CH3 26,27-CH3 24R体 66.0 91.0 91.0 91.5 24S体 65.0 90.0 88.5 92.5(IN Hz)"	"546,531,503,456,441,413,366,351,323,255,145(BASE PEAK),73(TMS DERIV.)(063)"		"063/"	"ﾋﾄ胆汁(026)"	"(026)"					
"ST0005"	5.00		"5β-CHOLESTANE-3α,7α,24,26-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436		"                          OH"	"                          �ﾂ                   合成 (065)"	"                  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH"	"                    �ｵ      �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"065/"	"NONCRYSTALLINE MATERIAL(065)"						"065/"		"cm-1 (CHCl3) 3350              (065)"	"1H-NMR   18-CH3=0.70, 19-CH3=0.96, 21-CH3=1.00, 27-CH3=1.23(065)"	"681,632,591,542,501,452,411,343,321(BASE PEAK),294,281,253,233,213(TMS DERIV.) (065)"		"065/"	"ﾋﾄ胆汁(065)"	"(065)"					
"ST0006"	5.00		"5β-CHOLESTANE-3α,7α,25,26-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                              合成 (066)"	"                  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH"	"                    �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"066/"	"200-202ﾟC(066)"						"066/"				"724(M+),621,531,441,364,351,343,255,253,219(BASE PEAK) (TMS DERIV.)(006/065/066)"		"006/065/066/"	"ﾋﾄ胆汁(065),ﾏﾅﾃｨｰ(Trichechus manatus latirostris)胆汁 (006)"	"(006/065)"					
"ST0007"	5.00		"5β-CHOLESTANE-3α,7α,26,27-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                               合成 (065)"	"                  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH"	"                    �ｵ      �ｲ�ｰOH"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"065/"	"136.5-138ﾟC(065)"						"065/"		"cm-1  3300  (065)"	"IH-NMR  18-CH3=0.70, 19-CH3=0.95, 21-CH3=0.93, 3β-H=3.75, 7β-H=3.97,26- AND 27-CH2=4.02 (065)"	"544,529,454,364,343,281,255(BASE PEAK),253 (TMS DERIV.) (065)"		"065/"	"ﾋﾄ胆汁(065)"	"(065)"					
"BA0209"	5.00		"5β-CHOLESTANE-3α,6β,7β,25,26-PENTOL"	"β-TRICHECHOL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH                 (006)"	"                    �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ｲ"	"    OH      H �ｵ  OH"	"              OH"					"006/"											"709,632,619,542,529,452,439,363,349,341,285,219,195(BASE PEAK)(TMS DERIV.) (006)"		"006/"	"ﾏﾅﾃｨｰ(Trichechus manatus latirostris)胆汁(006)，ﾗｯﾄ胆汁(089)"	"(006/089)"					"bileaciPage209.html"
"ST0008"	5.00		"5β-CHOLESTANE-3α,6α,7β,25,26-PENTOL"	"ω-TRICHECHOL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH                 (006)"	"                    �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ｲ"	"    OH      H �ﾂ  OH"	"              OH"					"006/"											"709,632,619,542,529,452,439,363,285,253,219,195(BASE PEAK)(TMS DERIV.)(006)"		"006/"	"ﾏﾅﾃｨｰ(Trichechus manatus latirostris)胆汁(006)"	"(006)"					
"ST0009"	5.00		"5β-CHOLESTANE-3α,6β,7α,26-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH                  (006)"	"                    �ｵ      �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H �ｵ  OH"	"              OH"					"006/"											"634,544,529,489,454,441,285,253,195(BASE PEAK)  (TMS DERIV.)(006)"		"006/"	"ﾏﾅﾃｨｰ(Trichechus manatus latirostris)胆汁(006)"	"(006)"					
"ST0010"	5.00		"3α,12α,25-TRIHYDROXY-5β-CHOLESTAN-7-ONE"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434			"                                               合成 (027)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ｸ"	"    OH      H     O"					"027/"	"188-189ﾟC(027)"						"027/"		"cm-1(KBr)  3350,1695(027)"	"IH-NMR(PYRIDINE-d5) 18-CH3=0.77, 19-CH3=1.02, 21-CH3=1.20, 26,27-CH3=1.39, 3β-H=3.75, 12β-H=4.24(027)"	"560,470,380,359,341,269,251,131(BASE PEAK)  (TMS DERIV.)(027)"		"027/"	"脳腱黄色腫症(CEREBROTENDINOUS XANTHOMATOSIS)患者胆汁及び糞(027)"	"(027)"					
"ST0011"	5.00		"5β-CHOLESTANE-3α,7α,12α,24,25,26-HEXOL"				"C27H48O6"	27.00	48.00	6.00	0.00	0.00	0.00	468		"                          OH"	"                          �ｵ                   合成 (067)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH"	"                �ﾂ  �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"067/"	"24R体 204-206ﾟC, 24S体 208-209ﾟC(067)"						"067/"			"IH-NMR   18-CH3   19-CH3   21-CH3   27-CH3   3β,7β,12β,24-H 26-H2  24R体 0.80 0.98 1.231.53 3.40-4.50 4.00 24S体 0.77 0.95 1.20 1.45 3.40-4.50 3.92 (067)"	"797,681,617,591,527,501,437,411,347,343,321,253,219(BASE PEAK)(TMS DERIV.)(067)"		"067/"	"ﾋﾄ尿(067)，ﾋﾄ血清(055)，肝臓病患者尿(054)"	"(054/055/067)"					
"BA0210"	5.00		"3α,7α,12α,19-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"	"19-HYDROXYCHOLIC ACID"	"19-OH-CA"		"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                          (REF:   )"	"              H HO＼／＼"	"              �ﾒ�ﾄ  �ﾓH �ｵ"	"        HO    ／＼�ｫ＼  COOH"	"          ＼�ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H  OH  H   H OH"							"275-277ﾟC(FROM AcOEt/MeOH)(206)"		"[α]20/D=+40.4ﾟ(C=0.95,MeOH)(206)"				"206/"		"(NUJOL) 3450, 2650, 1700cm-1(206)"	"1H-NMR(PYRIDINE-d6) 0.84(s,18-Me), 1.24(d,21-Me), 3.93,4.28(d,19-Me), 3.89(m,3β-H), 4.16(brs,7β-H), 4.27(brs,12β-H)(206)"	"Me-DMES  M/Z  753(M-29),561(M-104-117),470,457(M-2x104-117),367,353(M-3x104-117),251(206)"		"206/"	"ヒト健常新生児（２〜９日）の尿中(0.1-1.5μg/ml)  全胆汁酸の1.5-7%(206)"	"206/"					"bileaciPage210.html"
"BA0211"	5.00		"3α,7α,12α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-CHLORIDE"				"C23H39O6Cl"	23.00	39.00	3.00	0.00	0.00	0.00	398		"                                                          (REF:   )"	"              H HO＼／＼"	"              �ﾒ�ﾄ  �ﾓH �ｵ"	"              ／＼�ｫ＼  Cl"	"            �ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H  OH  H   H OH"							"182ﾟC(209)"						"209/"			"1H-NMR(CDCl3) 0.73(s,18-Me), 0.90(s,19-Me), 1.04(d,J=5Hz,21-Me), 3.84(s,3β-H), 3.99(s,12β-H)"	"(EI) M/Z  362(M-2xH2O),344(M-3xH2O),271(M-2xH2O-SIDE CHAIN),253(M-3xH2O-SIDE CHAIN)  (DCI) M/Z  416(M+NH4+),363(M+NH4-H2O-Cl),345(M+NH4+-2H2O-Cl)(209)"		"209/"							"bileaciPage211.html"
"BA0212"	5.00		"SODIUM 3α,7α,12α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-SULFONATE"	"NORCHOLANSULFONATE"			"C23H39O6Na"	23.00	39.00	6.00	0.00	0.00	1.00	466		"                                                          (REF:   )"	"              H HO＼／＼"	"              �ﾒ�ﾄ  �ﾓH �ｵ"	"              ／＼�ｫ＼  SO3-Na+"	"            �ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H  OH  H   H OH"							">280ﾟC(209)"						"209/"			"1H-NMR(CD3OD)  0.73(s,18-Me), 0.92(s,19-Me), 1.04(d,J=7Hz,21-Me), 2.73/2.91(m,b,23-CH2), 3.36(m,b,3β-H), 3.79(s,7β-H), 3.95(s,12β-H)(209)"	"(ESI) M/Z= 443.1(209)"		"209/"							"bileaciPage212.html"
"ST0012"	5.00		"5α-CHOLESTANE-3α,7α,12α,25-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                             合成 (027)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾊ�ｱ�ﾅ"	"    OH      H     OH"					"027/"	"NONCRYSTALLINE MATERIAL(027)"						"027/"			"IH-NMR(PYRIDINE-d5) 18-CH3=0.81, 19-CH3=0.89, 21-CH3=1.23, 26,27-CH3=1.36, 7β-H=4.05, 3β,12β-H=4.16 (027)"	"343,253 (TMS DERIV.)(027)"		"027/"	"脳腱黄色腫症(CEREBROTENDINOUS XANTHOMATOSIS)患者尿及び糞(027)"	"(027)"					
"ST0013"	5.00		"5β-CHOLESTANE-3α,7α,12α,22,25-PENTOL"				"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452		"                      OH"	"                     ｜                        合成 (068)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"068/"	"""22R体 253-255ﾟC, 22S体 237-239ﾟC(068)"		"22R体 [α]/D +32ﾟ,  22S体 [α]/D +16ﾟ (068)"				"068/"			"IH-NMR 18-CH3 19-CH3 21-CH3 26,27-CH3 22R体  0.84 1.00 1.40 1.44 22S体 0.86 1.00 1.39 1.40(068)"	"653,563,473,453,433,383,363,343,293,261,253,171(BASE PEAK),131,81,73 (TMS DERIV.) (068)"		"068/"	"脳腱黄色腫症(CEREBROTENDINOUS XANTHOMATOSIS)患者胆汁及び尿(22R体のみ)(068)"	"(068)"					
"ST0014"	5.00		"27-NOR-5β-CHOLEST-25-ENE-3α,7α,12α,24-TETROL"				"C26H44O4"	26.00	44.00	4.00	0.00	0.00	0.00	420		"                          OH"	"                          �ｵ                 合成 (026)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｷ"	"                �ﾂ  �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"026/"	"195-197ﾟC                            (026)"						"026/"		"cm-1 (KBr)  3450(OH)  1636,883(-CH=CH2)(026)"	"IH-NMR(PYRIDINE-d5)18-H3=0.83, 19-H3=1.00, 21-H3=1.24, 3β-H=3.78, 7β-H=4.09, 12β-H=4.26, 24-H=4.35, 25-H=6.15, 26-H2=5.35, 5.55    (026)"""	"708,618,528,481,438,349,343,294,281,253(BASE PEAK),157,129 (TMS DERIV.)(026)"		"026/"	"ﾋﾄ胆汁(026)"	"(026)"					
"ST0015"	5.00		"5β-CHOLANE-3α,7α,23,24-TETROL"				"C24H42O4"	24.00	42.00	4.00	0.00	0.00	0.00	394			"                                               合成 (026)"	"                  �ｲ�ｱ�ｲ�ｱ�ｯOH"	"                    �ｵ  �ｲ"	"              �ｱ�ｲ�ｫ�ｲ    OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"026/"	"224.5-226.5ﾟC (026)"						"026/"		"cm-1 (KBr)  3350(OH)(026)"	"IH-NMR(PYRIDINE-d5)   18-H3=0.74, 19-H3=0.96, 21-H3=1.11, 3β,7β,23β-H =3.4-4.5, 24-H2=3.90(026)"	"579,489,399,309(BASE PEAK),283,267,255,199(TMS DERIV.)(026)"		"026/"	"ﾋﾄ胆汁(026)"	"(026)"					
"ST0016"	5.00		"5β-CHOLESTANE-3α,7α,12α,23-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                                合成 (069)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ  �ｵ  �ｵ"	"              �ｱ�ｲ�ｫ�ｲ  OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"069/"	"23R体 232-233ﾟC, 23S体 189-191ﾟC(069)"		"23R体 [α]/D +52ﾟ, 23S体 [α]/D +41ﾟ　(069)"				"069/"		"cm-1 (KBr)  23S体 3400(OH),1080,1040,980,950,920  23R体 3340(OH),1080,1030,980,950,918 (069)"	"IH-NMR(PYRIDINE-d5) 18-H3  26,27-H  19-H3  21-H3　 3β-H  7β,23-H  12β-H  23R体 0.89 1.00　1.03  1.01　1.39  3.70  4.10 4.32 23S体0.88  0.95　0.98 1.00 1.38 3.70 4.10 4.32 (069)"	"724,667,634,544,454,364,253(BASE PEAK),159 (TMS DERIV) (069/070)"		"069/070/"	"脳腱黄色腫症患者糞便(027/070)，胆汁(027/071)，尿(027)"	"(027/070/071)"					
"ST0017"	5.00		"5β-CHOLESTANE-3α,7α,12α,24-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436		"                          OH"	"                          �ｵ                 合成 (072/073)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ      �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"072/073/"	"24R体 185-185.5ﾟC, 24S体 186-186.5ﾟC(073)"		"24R体 [α]25/D +39ﾟ, 24S体 [α]24/D +24ﾟ (073)"				"073/"		"cm-1  3500 073)"		"m/e=681,634,591,544,501,454,411,364,343,321,253,145(BASE PEAK),55 (TMS DERIV.) (025)"		"025/073/"	"ｳｻｷﾞ胆汁(025)，ﾋﾄ胆汁(026)，脳腱黄色腫症患者糞便(027/070)，胆汁(027/071)，尿(027)"	"(025/026/027/070/071)"					
"ST0018"	5.00		"27-NOR-5β-CHOLESTANE-3α,7α,12α,24-TETROL"	"26-DEOXY-5β-RANOL"			"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422		"                          OH"	"                         ｜                合成 (034)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"034/"	"24R体 196ﾟC, 24S体 184ﾟC(034)"		"24R体 [α]/D +36ﾟ, 24S体 [α]/D +27ﾟ (034)"				"034/"			"IHNMR (PYRIDINE-d5)18-H3 19-H3 26-H3 21-H3  3β,7β,12β,24-H  24R体 0.79 0.99 1.15 1.27 3.5-4.424S体 0.84 1.01 1.17 1.28 3.5-4.4      (043)"""	"m/e= 530,515,501,440,433,425,411,351,343,335,321,281,253,131(BASE PEAK)(TMS DERV.) (043)"		"043/"	"ｳｼｶﾞｴﾙ(Rana catesbeiana)胆汁(034)，ﾆﾎﾝｱｶｶﾞｴﾙ(Rana japonica japonica)胆汁 (030)，各種ｶｴﾙ(Discoglossus pictus, Xenopus mulleri, Arthroleptis poecilo- notus？, Cardioglossa leucomystax, Aubria subsigillata, Dicroglossus occipitalis, Ptychadena aequiplicat"	"(009/030/034)"					
"ST0019"	5.00		"27-NOR-5α-CHOLESTANE-3α,7α,12α,24-TETROL"	"26-DEOXY-5α-RANOL"			"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422		"                          OH"	"                         ｜               合成 (034)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾊ�ｱ�ﾅ"	"    OH      H     OH"					"034/"	"3,7,24-TRIACETATE   24R体 162ﾟC, 24S体 81ﾟC(034)"		"3,7,24-TRIACETATE   24R体 +2ﾟ, 24S体 +15ﾟ (034)"				"034/"							"ｳｼｶﾞｴﾙ(Rana catesbeiana)胆汁(034)，ｱｶｶﾞｴﾙ科ｶｴﾙ(Rana amurensis coreana, Rana amurensis tsushimensis, Rana temporaria dybowskii, Rana temporaria    coreana,  Rana temporaria tsushimensis, Rana japonica japonica, Rana tagoi)胆汁(030)，各種ｶｴﾙ(Ptychadena"	"(009/030/034)"					
"ST0020"	5.00		"5β-CHOLESTANE-3α,7α,12α-TRIOL"				"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420			"                                           合成 (074)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ      �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"074/"	"186-187.5ﾟC(074)"		"+30.4ﾟ       (080)"				"074/080/"				"m/e= 546,456,366(BASE PEAK),253  (TMS DERIV.)(075)"		"075/"	"脳腱黄色腫症(CEREBROTENDINOUS XANTHOMATOSIS)患者胆汁(075)，尿(027)"	"027/075/"					
"ST0021"	5.00		"5β-CHOLEST-25-ENE-3α,7α,12α-TRIOL"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418			"                                          合成 (039)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｷ"	"                �ﾂ  �ｵ      �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"039/"	"164ﾟC(039)"						"039/"		"cm-1 (NUJOL)  3660(OH),1650,883(CH2=C・ ) (039)"				"039/"	"脳腱黄色腫症(CEREBROTENDINOUS XANTHOMATOSIS)患者胆汁(075)"	"075/"					
"ST0022"	5.00		"27-NOR-5β-CHOLESTANE-3α,7α,12α,24,25,26-HEXOL"				"C26H46O6"	26.00	46.00	6.00	0.00	0.00	0.00	454		"                          OH"	"                          �ｵ                 合成 (026)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH"	"                �ﾂ  �ｵ      �ｵ"	"              �ｱ�ｲ�ｫ�ｲ      OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"026/"	"174-175ﾟC(026)"						"026/"		"cm-1 (KBr) 3350(OH) (026)"	"IH-NMR 18-H3=0.80, 19-H3=0.99, 21-H3=1.32, 3β,7β,12β,24,25,26-H=3.50-4.40 (026)"	"m/e= 769,681,591,501,411,343,321(BASE PEAK),281,253,204,191,156,129,116 (TMS DERIV.) (026/081)"""		"026/081/"	"ﾋﾄ胆汁(026)，ﾋﾄ尿(067/081)，肝疾患患者尿(054)，ﾋﾄ血清(055)"	"026/054/055/067/081/"					
"ST0023"	5.00		"5β-CHOLESTANE-3α,7α,12α,25-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436			"                                           合成 (076)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"076/"	"188-189ﾟC (076), 189.5-191ﾟC (077)"		"+36.8ﾟ         (080)"				"076/077/080/"			"(080)"	"m/e= 724,709,634,619,544,529,454,439,364,349,131(BASE PEAK)(TMS DERIV.)(077)"		"077/080/"	"脳腱黄色腫症(CEREBROTENDINOUS XANTHOMATOSIS)患者糞便(027/070/077)，胆汁 (027/071/075)，尿(027/078)，ﾋﾄ胆汁(026)，ｳｻｷﾞ胆汁(025)，ｱﾘｹﾞｰﾀｰ(Alligator  mississippiensis)胆汁(016)"	"016/025/026/027/070/071/075/077/078/"					
"ST0024"	5.00		"5β-CHOLESTANE-3α,7α,12α,23,25-PENTOL"				"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                                           合成 (079)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ  �ｵ  �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ  OH    OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"079/"	"23R体NON-CRYSTALLINE MATERIAL, 23S体209-210ﾟC(079)"		"23S体 [α]25/D +49ﾟ         (079)"				"079/"		"cm-1(CHCl3) 3340(OH),1075,1020,990,920,894 (079/080)"	"IH-NMR(PYRIDINE-d5)        18-H3=0.82, 19-H3=0.96, 21-H3=1.38, 26,27-H3=1.44,1.50, 3β,7β,12β,23-H=3.40-4.60(079/080)"	"m/e =722,667,632,577,550,542,487,460,452,397,370,362,344,307,281,   253,199,143,131(BASE PEAK)(TMS DERIV.)(079/080)"		"079/080/"	"脳腱黄色腫症(CEREBROTENDINOUS XANTHOMATOSIS)患者糞便(027/070/077)，胆汁 (027/071)，尿(027/078)"	"027/070/071/077/078/"					
"ST0025"	5.00		"5β-CHOLESTANE-3α,7α,12α,24,25-PENTOL"				"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452		"                          OH"	"                          �ｵ               合成 (039/080)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ      �ﾉ"	"              �ｱ�ｲ�ｫ�ｲ        OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"039/080/"	"24R体 212-214ﾟC, 24S体 203-205ﾟC (080)"		"24R体 +44.8ﾟ  24S体 +28.7ﾟ (080)"				"080/"		"cm-1(KBr) 3420(OH)    (080)"	"IH-NMR(CD3OD) 18-H3=72.4 Hz, 19-H3=92.2, 21-H3=103.6, 26,27-H3=114.4,116.8,(080)"	"m/e =  812,797,722,707,681,632,617,591,543,527,501,453,437,411,363, 347,343,321,281,253,147,143,131(BASE PEAK)(TMS DERIV.)  (051/080)"		"051/080/"	"脳腱黄色腫症(CEREBROTENDINOUS XANTHOMATOSIS)患者糞便(027/070/077/080)，胆汁(027/071)，尿(027/078)，ﾋﾄ胆汁(026)，ﾋﾄ尿(051/067)，肝疾患患者尿(054)，ﾋﾄ血清(055)"	"026/027/051/054/055/070/071/077/078/080/"					
"ST0026"	5.00		"5β-CHOLESTANE-3α,7α,12α,24,26,27-HEXOL"	"SCYMNOL"			"C27H48O6"	27.00	48.00	6.00	0.00	0.00	0.00	468		"                          OH"	"                          �ｵ                 合成 (047)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH"	"                �ﾂ  �ｵ      �ｲ�ｰOH"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"047/"	"120-123ﾟC(047)"		"+34ﾟ                             (047)"				"047/"		"cm-1(KBr) 3400(OH)047)"				"047/"	"軟骨魚類（ｻﾒ,ｴｲ）胆汁(047/048/049)"	"047/048/049/"					
"ST0027"	5.00		"27-NOR-5β-CHOLESTANE-3α,7α,12α,24,25-PENTOL"				"C26H46O5"	26.00	46.00	5.00	0.00	0.00	0.00	438		"                          OH"	"                          �ｵ               合成 (051/053)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ"	"                �ﾂ  �ｵ      �ｵ"	"              �ｱ�ｲ�ｫ�ｲ     OH"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"051/053/"	"230ﾟC (051),194-200ﾟC (053)"						"051/053/"		"""cm-1(KBr) 3400(OH) (051), cm-1(NUJOL) 3440(OH) (053)"	"IH-NMR(PYRIDINE-d5)   18-H3=0.82, 19-H3=1.00, 21-H3=1.26, 26-H3=1.52,  3β,7β,12β,24,25-H=3.55-4.40(051)"	"m/e= 798,708,693,681,618,603,591,528,513,501,438,411,371,348,343,321(BASE PEAK),281,253,219,129,117 (TMS DERIV.)(051/053/082)"""	"CD(053)"	"051/053/082/"	"ﾋﾄ尿(051/052/067/082)，ﾋﾄ血清(055)，脳腱黄色腫症(CEREBROTENDINOUS XANTHO-  MATOSIS)患者尿(027)，ﾋﾄ胆汁(026)，肝疾患患者血清(056)，肝疾患患者尿(054)， ｼﾄｽﾃﾛｰﾙ血症と黄色腫を有する患者の尿及び糞便(053)，胆汁うっ滞患者尿(031),完全肝外胆汁うっ滞症患者尿(032)"	"026/027/031/032/051/052/053/054/055/056/067/082/089/"					
"ST0028"	5.00		"24-NOR-5β-CHOLESTANE-3α,7α,12α,25-TETROL"				"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422			"                        �ｶ�ｽOH            合成 (083)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ"	"                �ﾂ  �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"083/"	"124-126ﾟC(083)"						"083/"		"cm-1(KBr) 3400(OH)(083)"	"IH-NMR(CDCl3) 18-H3=0.65, 19-H3=0.85, 21-H3=0.95, 26,27-H3=1.16 (083)"	"m/e= 620,565,530,440,384,294,253,131(BASE PEAK) (TMS DERIV.) (003/025/083)"		"003/025/083/"	"胆汁うっ滞患者胆汁(003)，ｳｻｷﾞ胆汁(025)，ﾋﾄ胆汁(026)"	"003/025/026/"					
"ST0029"	5.00		"5-β-CHOLESTANE-3α,7α,12α,26,27-PENTOL"	"5β-CYPRINOL"			"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452			"                                             合成 (084/085)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ�ｱ�ｯOH"	"                �ﾂ  �ｵ    �ｶ"	"              �ｱ�ｲ�ｫ�ｲ      �ｲ"	"              �ｵ�ｶ�ｽ�ｺ        OH"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"084/085/"	"173-174ﾟC (084), 175-177ﾟC(085)"		"+35.5ﾟ    (085)"				"085/"		"cm-1(NUJOL) 3400 (084)"	"IH-NMR(d7-DMF)   18-H3=41.0 cps, 19-H3=52.5(086)"			"084/086/"	"ｱﾅｺﾞ(Conger myriaster)胆汁(087),ﾁｮｳｻﾞﾒ類胆汁(085),ﾄﾉｻﾏｶﾞｴﾙ(Rana nigromacul-ata)胆汁(088),ﾀﾞﾙﾏｶﾞｴﾙ(Rana brevipoda)胆汁(040),ｱﾌﾘｶﾂﾒｶﾞｴﾙ(Xenopus laevis) 胆汁(009/040),各種ｶｴﾙ(Discoglossus pictus, Xenopus laevis,Xenopus mulleri,Arthroleptis poecilonotus?, Pt"	"(009/015/026/030/031/032/040/051/085/087/088)"					
"ST0030"	5.00		"26,27-DINOR-5β-CHOLESTANE-3α,7α,12α,24-TETROL"	"26-DEOXY-26-NOR-5-RANOL"			"C25H44O4"	25.00	44.00	4.00	0.00	0.00	0.00	408		"                          OH"	"                          �ｵ                合成 (090)"	"              HO  �ｲ�ｱ�ｲ�ｱ�ｲ"	"                �ﾂ  �ｵ"	"              �ｱ�ｲ�ｫ�ｲ"	"              �ｵ�ｶ�ｽ�ｺ"	"        �ｱ�ｲ�ｫ�ｲ�ｱ"	"        �ｵ  �ｵ  �ｵ"	"      �ﾄ�ｲ�ｱ�ﾉ�ｱ�ﾅ"	"    OH      H     OH"					"090/"	"24R体 179-180ﾟC, 24S体 192-193ﾟC(090)"		"24R体 +40ﾟ, 24S体 +33ﾟ (090)"				"090/"		"""cm-1(KBr) 3340(OH), 1080,1030,980,950,918   (090)"	"IH-NMR(PYRIDINE-d5) 18-H3=0.83, 19-H3=1.02, 21-H3=1.25, 25-H3=1.35, 3β,7β,12β,24H=3.70-4.35(090)"	"m/z=  696,606,516,426,343,337,253 (TMS DERIV.)(090)"		"090/"	"ｶｴﾙ(Arthroleptis poecilonotus?, Aubria subsigillata,Dicroglossus occipitalis, Rana pipiens)胆汁(009)"	"009/"					
"BA0213"	5.00		"3α,7α,12α,24-TETRAHYDROXY-24-METHYL-5β-CHOLESTAN-26-OIC ACID"				"C28H48O6"	28.00	48.00	6.00	0.00	0.00	0.00	480		"                               OH  O       合成               (REF:091)"	"                             �ｫ  �ｷ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"091/"	"METHYL ESTER 144ﾟC(091)"						"091/"				"METHYL ESTER-TMS ETHER:767(9%),692(4%),602(31%),512(25%),422(14%),343(22%),281(11%),253(17%),203(100%) (092)"		"092/"	"ヒキガエル(BUFO VULGARIS FORMOSUS)胆汁(092)"	"092/"					"bileaciPage213.html"
"BA0214"	5.00		"3α,7α,12α-TRIHYDROXY-24-METHYL-5β-CHOLESTANOIC ACID"				"C28H48O5"	28.00	48.00	5.00	0.00	0.00	0.00	464		"                                 O      合成                 (REF:091)"	"                             �ｵ  �ｾ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"091/"	"192ﾟC(091)"						"091/"				"METHYL ESTER-TMS ETHER : 679(4%),604(4%),514(25%),499(4%),424(56%),409(8%),343(40%),317(15%),281(24%),253(100%) (033)"		"033/"	"ウシガエル(RANA CATESBEIANA)胆汁(033)"	"033/"					"bileaciPage214.html"
"BA0215"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLEST-22-ENE-24-CARBOXYLIC ACID"				"C28H46O5"	28.00	46.00	5.00	0.00	0.00	0.00	462		"                          O�ｹ／OH                           (REF:093)"	"                             �ｵ"	"                 HO  ＼／�ｸ／＼／"	"                 �ﾃ    �ｵ    �ｶ"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"093/"	"160ﾟC(094)"						"094/"				"METHYL ESTER-TMS ETHER:692(6%),602(29%),512(23%),422(28%),343(22%),315(7%),253(100%) (092)"		"092/"	"ヒキガエル(BUFO VULGARIS FORMOSUS)胆汁(092/093/094)"	"092/093/094/"					"bileaciPage215.html"
"BA0216"	5.00		"3α,7α,12α-TRIHYDROXY-5α-CHOLEST-22-ENE-24-CARBOXYLIC ACID"				"C28H46O5"	28.00	46.00	5.00	0.00	0.00	0.00	462		"                          O�ｹ／OH                 （REF:092)"	"                             �ｵ"	"                 HO  ＼／�ｸ／＼／"	"                 �ﾃ    �ｵ    �ｶ"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾊ／�ﾅ"	"       HO     H      OH"					"092/"											"METHYL ESTER-TMS ETHER:692(10%),602(49%),512(27%),422(7%),343(49%),315(37%),253(100%) (092)"		"092/"	"ヒキガエル(BUFO VULGARIS FORMOSUS)胆汁(092)"	"092/"					"bileaciPage216.html"
"BA0217"	5.00		"2β,3α,7α,12α-TETRAHYDROXY-5β-CHOLESTAN-26-OIC ACID"	"ARAPAIMIC ACID"			"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                                O                      （REF:008)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"       HO        �ｵ�ｶ�ｽ�ｺ"	"         ＼／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"008/"	"244-248ﾟC(008)"						"008/"			"1H-NMR(CDCl3) 0.775(C-18),1.03(C-19),1.17(d,J=5.5Hz,C-21),1.29(d,J=6.5Hz,    C-27),4.0-4.4(C-2α),3.5-3.9(C-3β),4.08(m,C-7β),4.20(m,C-12β)(008)"""	"TETRAACETATE-METHYL ESTER: 648(M+),528,468,431,408,371,311,251 (008)"		"008/"	"ARAPAIMA GIGAS 胆汁(008)"	"008/"					"bileaciPage219.html"
"BA0218"	5.00		"3α,7α,12α,22-TETRAHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                         OH     O                      （REF:095/096/098)"	"                         �ｯ    �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"095/095/098/"	"ラクトン体 220ﾟC(095)"						"095/"		"ラクトン体 (NUJOL) 3300,1710cm-1 (096)"	"ﾗｸﾄﾝ体(CDCl3) 0.68(s,19-H3), 0.87(s,18-H3),1.11(d,J=6.5Hz,21-H3), 1.30(d,J= 6.5Hz,27-H3), 2.40(ddq,J=11.5,6.2 & 6.8Hz,25-H), 4.42(dd,J=11.7 & 3.2Hz, 22-H)(095)ｸﾄﾝ体(PYRIDINE-d5) 0.81(18-H3), 1.0(19-H3), 1.25(21-H3), 1.27(27-H3),〜3.73(3β-H),4.10(メチルエステル(PYRIDINE-d5) 0.90(18-H3), 1.03(19-H3), 1.40(21-H3), 1.22(27-H3), 〜3.72(3β-H), 4.11(7β-H),4.35(12β-H),〜4.00(22-H)(097)"	"メチルエステル-TMS-エーテル: M/E=383,293,253,217,185,127 (097) ラクトン体-TMS エーテル: M/E=574,559,484,469,394,343,281,253,113 (097)"		"095/096/097/"	"スッポン (AMYDA JAPONICA)胆汁(095/096),CHELONIA MYDAS 胆汁(097)  ヒト(ZELLWEGER'S SYNDROME 患者)尿(098)"	"095/096/097/098/"			"スッポンなどカメ目に見出されたものの側鎖の絶対配置は(22S,25R)と決定(095) ヒト(ZELLWEGER SYNDROME患者)から見出されたものは 22R体 (098)"		"bileaciPage217.html"
"BA0219"	5.00		"3α,7α,12α,24-TETRAHYDROXY-5α-CHOLESTAN-26-OIC ACID"				"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                            OH   O      合成                  (REF:033)"	"                             �ｯ �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾊ／�ﾅ"	"       HO     H      OH"					"033/"									"(KBr)   3340(OH),  1710(COOH)  (033)"		"メチルエステル-TMS-エーテル: 753, 588, 498, 343, 253 (033)"		"033/"	"ウシガエル (RANA CATESBEIANA)胆汁(033)"	"033/"					"bileaciPage218.html"
"BA0220"	5.00		"3α,7α,12α,23-TETRAHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                                O                        (REF:098)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ  �ｯ�ｶ    OH"	"                 ／＼�ｫ＼  OH"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"098/"											"ラクトン体-TMS-エーテル: 574,559,484,469,394,379,343,253 (098)"		"098/"	"ヒト (ZELLWEGER'S SYNDROME 患者)尿(098/099)"	"098/099/"					"bileaciPage220.html"
"BA0221"	5.00		"3β,7α,12α-TRIHYDROXY-5α-CHOLESTAN-26-OIC ACID"				"C27H46O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                                O       合成                  (REF:018)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ﾊ／�ﾅ"	"       HO     H      OH"					"018/"	"228-229ﾟC(018)"						"018/"		"(KBr)  3400(OH), 1730(COOH)  (018)"	"(PYRIDINE-d5) 0.80(s,18-H3),0.90(s,19-H3),1.23(d,J=6Hz,21-H3),1.32(d,J=6Hz, 27-H3),3.80(m,3α-H),4.09(m,7β-H),4.23(m,12β-H)  (018)"""	"メチルエステル-TMS エーテル: 693,618,514,483,411,357,303,253 (018)"		"018/"	"シーラカンス(LATIMERIA CHALUMNAE)胆汁(018)"	"018/"					"bileaciPage221.html"
"BA0222"	5.00		"1β,3α,7α,12α-TETRAHYDROXY-5β-CHOLESTANOIC ACID"				"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                                O                        (REF:100)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"           HO    ／＼�ｫ＼"	"           �ｶ    �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"100/"											"メチルエステル-TMS エーテル: 588,498,408,341,251,217 (100)"		"100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(100) ヒト (ZELLWEGER'S SYNDROME 患者)尿(099/104/125)"	"100/099/104/125/"					"bileaciPage222.html"
"BA0223"	5.00		"3α,7β,12α-TRIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                                O       合成                  (REF:100)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／＼"	"       HO     H      OH"					"100/"	"90-92ﾟC(100)"						"100/"		"(KBr) 3400, 1720 (100)"	"(PYRIDINE-d5)メチルエステル:0.82(s,18-H3),1.00(s,19-H3),1.13(d,J=6Hz,21-H3),1.17(d,J=6Hz, 27-H3),3.78(m,3β-H AND 7α-H),4.16(m,12β-H),3.57(s,COOCH3) (100)"""	"メチルエステル-TMS エーテル: 665,590,500,433,410,343,281,253,243 (100)"		"100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(100)"	"100/"					"bileaciPage223.html"
"BA0224"	5.00		"7β,12α-DIHYDROXY-3-OXO-5β-CHOLESTAN-26-OIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                O                        (REF:100)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ｴ＼／�ﾉ／＼"	"        O     H      OH"					"100/"											"メチルエステル-TMS エーテル: 591,516,426,269,251 (100)"		"100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(100)"	"100/"					"bileaciPage224.html"
"BA0225"	5.00		"7α,12α-DIHYDROXY-3-OXO-5β-CHOLESTAN-26-OIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                O       合成                  (REF:100)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ｴ＼／�ﾉ／�ﾅ"	"        O     H      OH"					"100/"	"メチルエステル168-170ﾟC(100)"						"100/"		"(KBr)  3400, 1735, 1700(100)"	"(PYRIDINE-d5) メチルエステル:0.80(s,18-H3),0.97(s,19-H3),1.11(d,J=6Hz,21-H3 AND 27-H3),3.50(s,COOCH3),3.99(m,7β-H),4.15(m,12β-H)  (100)"""			"100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(016/100)"	"016/100/"					"bileaciPage225.html"
"BA0226"	5.00		"7α,12α-DIHYDROXY-3-OXO-5α-CHOLESTAN-26-OIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                O                        (REF:016)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ｴ＼／�ﾊ／�ﾅ"	"        O     H      OH"					"016/"														"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(016)"	"016/"					"bileaciPage226.html"
"BA0227"	5.00		"3α,12α-DIHYDROXY-7-OXO-5β-CHOLESTAN-26-OIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                O      合成                    (REF:100)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ｹ"	"       HO     H      O"					"100/"										"(PYRIDINE-d5)メチルエステル:0.75(s,18-H3),1.13(d,J=6Hz,21-H3),1.15(d,J=6Hz,27-H3),1.17(s,19-H3),3.57(COOCH3),3.72(m,3β-H),4.12(m,12β-H)  (100)"""			"100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(016/100)"	"016/100/"					"bileaciPage227.html"
"BA0228"	5.00		"3β-HYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                O                        (REF:101)"	"                               �ｳ"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ﾉ／"	"       HO     H"					"101/"														"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)糞(101) ヒト (ZELLWEGER'S SYNDROME 患者)血清(103)"	"101/103/"					"bileaciPage228.html"
"BA0229"	5.00		"3α-HYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                O       合成                 (REF:102/111)"	"                               �ｳ"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／"	"       HO     H"					"102/111/"	"169ﾟC(102),25L体(111),25D体(112)169-170ﾟC, 155-157ﾟC(112),メチルエステル:100-105ﾟC(111), 25L体 112-113ﾟC(112),25D体 108-109ﾟC(112)169-170ﾟC, 155-157ﾟC(112),"		"25L体 +43ﾟ  25D体 +26ﾟ (112)"				"102/112/111/"		"(KBr) 3400, 1710  (102)"		"メチルエステル-TMS エーテル:504,489,414,399,383,257,230,215 (101)"		"101/102/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)糞(101) ヒト (ZELLWEGER'S SYNDROME 患者)血清(103)"	"101/103/"					"bileaciPage229.html"
"BA0230"	5.00		"3β,12α-DIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                O                          (REF:101)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ﾉ／"	"       HO     H"					"101/"														"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)糞(101)"	"101/"					"bileaciPage230.html"
"BA0231"	5.00		"3α,12α-DIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                O      合成                 (REF:100/112)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／"	"       HO     H"					"100/112/"	"144-146ﾟC(100),25L体(112),25D体(112))144-146ﾟC(100), 25L体 177-179ﾟC(112), 25D体 130, 174-175ﾟC (112)"		"25L体 +63ﾟ, 25D体 +47ﾟ (112)"				"100/112/"		"(KBr) 3400, 1700 (100)"	"(PYRIDINE-d5): 0.73(s,18-H3),0.95(s,19-H3),1.16(d,J=6Hz,21-H3),1.31(d,J=6Hz,27-H3), 3.80(m,3β-H), 4.22(m,12β-H)  (100)"""			"100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(016/100), 糞(101)"	"016/100/101/"					"bileaciPage231.html"
"BA0232"	5.00		"3β,7β-DIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                O                      (REF:101)"	"                               �ｳ"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ﾉ／＼"	"       HO     H      OH"					"101/"														"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)糞(101)"	"101/"					"bileaciPage232.html"
"BA0233"	5.00		"3α,7β-DIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                O       合成                  (REF:100)"	"                               �ｳ"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／＼"	"       HO     H      OH"					"100/"									"(KBr)  3400, 1700 (100)"	"(PYRIDINE-d5): 0.70(s,18-H3), 0.97(s,19-H3), 0.97(d,J=6Hz,21-H3), 1.26(d,J=6Hz,27-H3), 3.70(m,3β-H,7α-H) (100)"			"100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(100), 糞(101)"	"100/101/"					"bileaciPage233.html"
"BA0234"	5.00		"3α,7α-DIHYDROXY-5β-CHOLEST-24-EN-26-OIC ACID"				"C27H44O4"	27.00	44.00	4.00	0.00	0.00	0.00	432		"                                O       合成                (REF:105/150)"	"                               �ｳ"	"                     ＼／＼／�ｹ／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"105/150/"	"214ﾟC (105)"						"105/"		"(KBr)  3400, 1680,1640 (105)"		"メチルエステル-TMS-エーテル:590,575,559,500,410,395,345,283,255 (106)"		"106/"	"オウトカゲ(VARANUS MONITOR)胆汁(106)"	"106/"					"bileaciPage234.html"
"BA0235"	5.00		"3α,7α-DIHYDROXY-5β-CHOLEST-23-EN-26-OIC ACID"				"C27H44O4"	27.00	44.00	4.00	0.00	0.00	0.00	432		"                                O                      (REF:106)"	"                               �ｳ"	"                     ＼／＼�ｴ＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"106/"											"メチルエステル-TMS-エーテル:590,575,500,463,410,373,345,283,255 (106)"		"106/"	"オウトカゲ(VARANUS MONITOR)胆汁(106)"	"106/"					"bileaciPage235.html"
"BA0236"	5.00		"3α,12α,22-TRIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                         OH     O                      (REF:097)"	"                         �ｯ    �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／"	"       HO     H"					"097/"										"メチルエステル(PYRIDINE-d5): 0.83(s,18-H3),0.99(s,19-H3),1.38(d,J=6.5Hz,21-  H3),1.22(d,J=7Hz,27-H3),〜3.90(m,3β-H),4.30(m,12β-H),〜4.01(m,22-H)    ラクトン体(pyridine-d5): 0.73(s,18-H3),0.97(s,19-H3),1.22(d,J=6.5Hz,21-H3)1.29(d,J=7Hz,27-H3),4.20(m,12"	"メチルエステル-TMS-エーテル:665,385,345,295,255,217,185,127 (097) ラクトン体-TMS-エーテル:576,471,396,345,283,255 (097)"		"097/"	"スッポン (CHELONIA MYDAS)胆汁(097)"	"097/"					"bileaciPage236.html"
"BA0237"	5.00		"3α,7α,24-TRIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                             OH O       合成               (REF:106/065)"	"                             �ｯ�ｳ"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"106/065/"									"メチルエステル(CHCl3): 3300,1710 (065)"	"メチルエステル(PYRIDINE-d5):0.70(s,18-H3),0.95(s,19-H3),0.98(d,J=6Hz,21-H3),1.43(d,J=6Hz,27-H3),3.60(COOCH3),3.50-4.10(m,3β-H,24-H),3.95(m,7β-H)    (065)"""	"メチルエステル-TMS-エーテル:500,485,410,395,343,323,296,281,255,253,243,189 (065)"		"065/"	"オウトカゲ (VARANUS MONITOR)胆汁(106) ヒト(ZELLWEGER'S SYNDROME患者)血清(122/123/125)"	"106/122/123/125/"					"bileaciPage237.html"
"BA0238"	5.00		"3β,7α,12α-TRIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                                O                      (REF:101)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ｱ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"101/"														"アリゲーター(ALLIGATOR MISSISSIPPIENSIS) 糞(101)"	"101/"					"bileaciPage238.html"
"BA0239"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLEST-24-EN-26-OIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                O       合成                (REF:107/150)"	"                               �ｳ"	"                 HO  ＼／＼／�ｹ／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"107/150/"	"24E体  205-206ﾟC(107)"						"107/"		"(KBr) 1645,1682,3400  (107)"	"(PYRIDINE-d5) 24E体  0.78(s,18-H3),0.97(s,19-H3),1.19(d,J=6Hz,21-H3),1.80(s,27-H3),3.65(m,3βｰH),4.05(m,7β-H),4.20(m,12β-H),7.13(t,J=6Hz,24-H)      24Z体は 24-Hのみ 5.85(t,6Hz),  残りは全部 24E体と同じ  (107)"""	"メチルエステル-TMS エーテル (106):678,663,588,573,551,498,461,408,371,433, 431,281,343,341,253,251"		"107/106/"	"オウトカゲ (VARANUS MONITOR)胆汁(106) ヒト 胆汁(108)"	"106/108/"					"bileaciPage239.html"
"BA0240"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLEST-23-EN-26-OIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                O                  (REF:109/110)"	"                               �ｳ"	"                 HO  ＼／＼�ｴ＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"109/110/"	"176-179ﾟC(109)"		"[α]12/D = +29.13 (C=1.16,ethanol) (109)"				"109/"				"メチルエステル-TMS エーテル(092):663,588,498,461,408,371,343,301,281,253 メチルエステル-TMS エーテル(106):678,663,588,573,551,498,461,431,408,371,   343,341,281,253,251"		"092/106/"	"ヒキガエル (BUFO VULGARIS JAPONICUS)胆汁(109)  ヒキガエル (BUFO VULGARIS FORMOSUS)胆汁(092) オウトカゲ (VARANUS MONITOR)胆汁(106)"	"092/109/106/"					"bileaciPage240.html"
"BA0241"	5.00		"3α,7α-DIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O6"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                O       合成            (REF:105/112/116)"	"                               �ｳ"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"105/112/116/"	"25D型  175-176ﾟC  25L型 非結晶性(112)"		"25D型 +5ﾟ  25L型 +18ﾟ  (112)"				"112/"		"3400,1700  (105)"		"メチルエステル:448,430,412,397,273,264,255,245,228,213,201 (116)"		"105/116/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(016/100/116), 糞(101) ヒト(ZELLWEGER'S SYNDROME 患者)胆汁(103/123), 尿(103/119/121),     血清(120/122/123/125), 血漿(126)ヒト(幼児性 REFSUM 病患者)血漿(126) トビ(MILVUS LINEATUS LINEATUS)胆汁(129)"	"016/100/116/103/123/119/121/120/122/125/126/129/141/"					"bileaciPage241.html"
"BA0242"	5.00		"3α,7α,12α,24-TETRAHYDROXY-5β-CHOLESTAN-26-OIC ACID"	"VARANIC ACID"			"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                             OH O       合成                  (REF:107)"	"                             �ｯ�ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO     H      OH"					"107/"	"24S,25R体:170-171ﾟC, 24S,25S体:173-175ﾟC,24R,25R体:219-220ﾟC, 24R,25S体:149-150ﾟC(107)"		"+23.5ﾟ  +26.7ﾟ  +61.7ﾟ  +44.6ﾟ  (107)"				"107/"		"24S,25R体 / 24S,25S体 / 24R,215R体 / 24R,25S体 : 1715 / 1715 / 1715 / 1715 : 3390 / 3390 / 3390 / 3390  (107)"	"24S,25R/24S,25R/24R,25R/,24R,25S:0.83/0.82/0.81/0.81(S,18-H3),1.00/1.00/0.98/0.98/(S,19-H3),1.24/1.25/1.25/1.25(d,21-H3),1.24/1.25/1.25/1.25(d,27-H3),3.70/3.70/3.70/3.70(m,3β-H),4.10/4.09/4.07/4.08(M,7β-H),4.27/4.25/4.25/4.25(M,12β-H),4.35/4.29/4.30/4"	"メチルエステル-TMS deriv.:753,588,498,408,343,321,281,253 (033)"		"033/107/"	"オウトカゲ(VARANUS NILOTICUS)胆汁(130) オウトカゲ(VARANUS MONITOR)胆汁(106) スズガエル(BOMBINA ORIENTALIS)胆汁(040/131)ウシガエル(RANA CATESBEIANA)胆汁(033) ヒキガエル(BUFO VU"	"130/106/040/031/033/092/103/122/125/099/119/121/123/126/"					"bileaciPage242.html"
"BA0243"	5.00		"3α,7α,12α,26-TETRAHYDROXY-5α-CHOLESTAN-27-OIC ACID"				"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                                O       合成                  (REF:033)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼      ＼"	"                 �ｵ�ｶ�ｽ�ｺ        OH"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾊ／�ﾅ"	"       HO     H      OH"					"033/"	"238-240ﾟC(033)"						"033/"		"(KBr) 3300,1710  (033)"""	"(PYRIDINE-d5) 0.80(s,18-H3),0.90(s,19-H3),1.19(d,J=6Hz,21-H3),4.09(m,3β-H),4.16-4.36(m,7β-H,12β-H,26-H2) (033)"	"メチルエステル-TMS エーテル:753,678,588,498,343,281,253 (033)"		"033/"	"ウシガエル (RANA CATESBEIANA)胆汁(033)"	"033/"					"bileaciPage243.html"
"BA0244"	5.00		"3α,7α,12α,26-TETRAHYDROXY-5β-CHOLESTAN-27-OIC ACID"				"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                                O      合成                   (REF:030)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼      ＼"	"                 �ｵ�ｶ�ｽ�ｺ        OH"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅOH"	"       HO     H"					"030/"	"268-269ﾟC(030)"						"030/"		"νKBr/max:1720,2940,3400cm-1(030)"	"(PYRIDINE-d5) 0.81(s,18-H3),1.01(s,19-H3),1.21(d,J=6Hz,21-H3),3.76(m,3β-H),4.16(m,7β-H),4.28(m,12β-H),4.30(m,26-H2) (030)"	"メチルエステル-TMS deriv.:753,678,588,498,391,343,281,253 (030)"		"030/"	"プランシーアカガエル (RANA PLANCYI)胆汁(030)ウシガエル(RANA CATESBEIANA)胆汁(033) ヒト(ZELLWEGER'S SYNDROME 患者)尿(099), 血漿(126)ヒト(幼児性 REFSUM 病患者) 血漿(126)       ヒト胆汁(108)    アリゲーター (ALLIGATOR MISSISSIPPIENSIS)胆汁(100)"	"030/033/099/126/108/100/"					"bileaciPage244.html"
"BA0245"	5.00		"3α,7α,12α-TRIHYDROXY-5α-CHOLESTAN-26-OIC ACID"				"C27H46O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                                O      合成                    (REF:127)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾊ／�ﾅ"	"       HO     H      OH"					"127/"	"225-226ﾟC(127),  227-229ﾟC(128)"		"[α]25/D= +41.7ﾟ(127)"				"127/128/"		"3278,1710,1194,1123,1083,1035,1009, 957, 930, 888, 859, 838 (127)"		"メチルエステル-TMS deriv.:665,590,575,500,485,410,395,343,303,281,253 (033)"		"127/033/"	"イグアナ(IGUANA IGUANA)胆汁(128) チョウセンヤマアカガエル(RANA TEMPORARIA COREANA)胆汁(030) ツシマヤマアカガエル(RANA TEMPORARIA TSUSHIMENSIS)胆汁(030)ウシガエル(RANA CATESBEIANA)胆汁(033)ツチガエル(RANA RUGOSA)胆汁(040)"	"128/030/033/040/016/100/"					"bileaciPage245.html"
"BA0246"	5.00		"3α,6α,7α,12α-TETRAHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                                O       合成                    (REF:115)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�･／�ﾅOH"	"       HO     H  �ﾛOH"					"115/"	"260-262ﾟC(115)"						"115/"			"(PYRIDINE-d5) 0.81(s,18-H3),1.04(s,19-H3),1.22(d,J=6Hz,21-H3),1.34(d,J=7Hz,27-H3),3.68-3.84(m,3β-H),4.22-4.31(m,6β-H,7β-H,12β-H) (115)"""	"メチルエステル-TMS エーテル:588,498,409,341,251 (115)"		"115/"	"ヒト(ZELLWEGER'S SYNDROME 患者)尿(099/104),血清(122)"	"099/104/122/"					"bileaciPage246.html"
"BA0247"	5.00		"3β-HYDROXYCHOLEST-5-EN-26-OIC ACID"				"C27H44O3"	27.00	44.00	3.00	0.00	0.00	0.00	416		"                                O                            (REF:103)"	"                               �ｳ                             合成(111)"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／"	"       HO"					"103/111/"	"メチルエステル97-100ﾟC(111)"						"111/"				"メチルエステル-TMS エーテル:502,446,412,373,291,255,129 (103/111/144)"		"103/111/144/"	"ヒト(ZELLWEGER'S SYNDROME 患者)血清,胆汁(103) ヒト血液(144) ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE 欠損症患者)血漿(145)"	"103/144/145/"					"bileaciPage247.html"
"BA0248"	5.00		"3α,7α,12α,25-TETRAHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O6"	27.00	46.00	6.00	0.00	0.00	0.00	466		"                                O     合成                       (REF:113)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ＼  OH"	"                 ／＼�ｫ＼        OH"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO      H     OH"					"113/"											"メチルエステル-TMS エーテル:753,709,678,619,588,529,498,439,391,367,343,253,226,199  113)"		"113/"	"ヒト(高度腸閉塞新生児)胃内容物(113), ZELLWEGER'S SYNDROME患者胆汁(103),尿(102),血漿(126)"	"113/103/102/126"					"bileaciPage248.html"
"BA0249"	5.00		"3α,7α,12α-TRIHYDROXY-27a,27b-DIHOMO-5β-CHOLESTANE-26,27b-DIOIC ACID"				"C29H47O7"	29.00	47.00	7.00	0.00	0.00	0.00	507		"                                    O       合成                (REF:114)"	"                                   �ｳ"	"                 HO  ＼／＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ        OH"	"                 ／＼�ｫ＼    �ｴ＼"	"                 �ｵ�ｶ�ｽ�ｺ   O    OH"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO      H     OH"					"114/"										"(CDCl3)メチルエステルｰアセタート:0.72(s,18-H3),0.92(s,19-H3),0.79(d,J=6.5Hz,21-H3),4.60(tt,J=31Hz,3β-H),4.92(q,J=9.5Hz,7β-H),5.10(t,J=6Hz,12β-H),  2.14,2.10,2.06(s,CH3COx3),3.675(s,COOCH3x2),2.29,2.35(CH2COOCH3), 2.40(CH2CHCOOCH3)  (114)"""	"ジメチルエステル-アセタート(114):542,482,313,253 ジメチルエステル-TMS エーテル(114):752,737,662,572,482,343,253"		"114/"	"ヒト(ZELLWEGER'S SYNDROME 患者)血清(103/122), 胆汁(103), 尿(103/099/123/125 ), 血漿(126) ヒト(幼児性 REFSUM病患者)血漿(126)"	"103/122/099/123/125/126/"					"bileaciPage249.html"
"BA0250"	5.00		"3α,7α,12α-TRIHYDROXY-5α-CHOLEST-23-EN-26-OIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                O       合成                  (REF:092)"	"                               �ｳ"	"                 HO  ＼／＼�ｴ＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼�ﾋ�ｲ／�ﾅ"	"       HO      H     OH"					"092/"											"メチルエステル-TMS エーテル:678,588,498,461,408,371,343,301,281,253(092)"		"092/"	"ヒキガエル(BUFO VULGARIS FORMOSUS)胆汁(092)"	"092/"					"bileaciPage250.html"
"BA0251"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLESTAN-26-OIC ACID"				"C27H46O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                                O     合成              (REF:132/133/112)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾉ／�ﾅ"	"       HO      H     OH"					"132/133/112/"	"25D型,25L型(132/133/112)25D型 :180-182ﾟC(133),183-184ﾟC(112),25L型 :195-196ﾟC(132),195-196ﾟC(133),199-201ﾟC (112)"		"25D型/25L型：+28ﾟ/+44ﾟ  +27ﾟ/+43ﾟ(112/133)"				"112/133/"				"メチルエステル-TMS deriv.:680,665,590,500,410,343,303,281,253 (092)"	"25D型 :180-182ﾟC(133),183-184ﾟC(112), 25L型 :195-196ﾟC(132),195-196ﾟC(133),199-201ﾟC (112)"	"092/133/112/132/"	"ウシガエル(RANA CATESBEIANA)胆汁(134/135/033) アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁(136/016/100) ワニ:(CAIMAN CROCODILUS)胆汁(136), (CROCODYLUS NILOTICUS)胆汁(136/137),(CAIMAN SCLEROPS)胆汁(138),(CAIMAN LATIROSTRIS)胆汁(138),(GAVIALIS    GA (XENOPUS MULLERI)胆汁(009), (BUFO BUFO VULGARIS)胆汁(009),  (BUFO MACULATUS)胆汁(009), (BUFO MARINUS)胆汁(009), (BUFO REGULARIS)胆汁(009), (AUBRIA SUBSIGILLATA)胆汁(009), (DICROGLOSSUS OCCIPITALIS)胆汁(009),"	"134/135/033/136/016/100/137/138/139/140/129/040/009/030/106/092/142/108/143/117/118/122/123/125/103/099/104/119/121/120/126/124/113/"					"bileaciPage251.html"
"BA0252"	5.00		"7α-HYDROXY-3-OXO-4-CHOLESTENOIC ACID"				"C27H42O4"	27.00	42.00	4.00	0.00	0.00	0.00	430		"                                O                            (REF:144)"	"                               �ｳ"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ｴ＼�ｷ＼／�ﾅ"	"        O            OH"					"144/"											"メチルエステル-TMS-エーテル:516,501,426,411,395,394,269,224,209,174,162(144)"		"144/"	"ヒト血液 (144)"	"144/"					"bileaciPage252.html"
"BA0253"	5.00		"5-CHOLESTENE-3β,7α,12α,24-TETROL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                             OH                             (REF:145)"	"                             �ｯ"	"                 HO  ＼／＼／＼／"	"                 �ﾃ    �ｵ    �ｶ"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"145/"											"TMS エーテル:632,542,499,452,409,341,319,251,145,129 (145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)胆汁, 尿 (145)"	"145/"					"bileaciPage253.html"
"BA0254"	5.00		"5-CHOLESTENE-3β,7α,12α,25-TETROL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                         (REF:145)"		"                 HO  ＼／＼／＼／"	"                 �ﾃ    �ｵ    �ｶ＼"	"                 ／＼�ｫ＼        OH"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"145/"											"TMS エーテル:632,542,452,411,341,251,131 (145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)胆汁, 尿 (145)"	"145/"					"bileaciPage254.html"
"BA0255"	5.00		"3β,7α-DIHYDROXY-5-CHOLESTENOIC ACID"				"C27H44O4"	27.00	44.00	4.00	0.00	0.00	0.00	432		"                                O                        (REF:144)"	"                               �ｳ"	"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"144/"											"メチルエステル-TMS エーテル:575,500,485 (144)"		"144/"	"ヒト血液  (144) ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)血漿 (145)"	"144/145/"					"bileaciPage255.html"
"BA0256"	5.00		"5-CHOLESTENE-3β,7α,12α,26-TETROL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                          (REF:145)"		"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"145/"											"TMS エーテル:632,542,452,341,251,103(145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)胆汁, 尿 (145)"	"145/"					"bileaciPage256.html"
"BA0257"	5.00		"5-CHOLESTENE-3β,7α,26-TRIOL"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                                          (REF:145)"		"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ    OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"145/"											"TMS エーテル:634,544,454,253,233,208,129,103 (145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)胆汁, 尿 (145)"	"145/"					"bileaciPage257.html"
"BA0258"	5.00		"27-NOR-5-CHOLESTENE-3β,7α,12α,24,25-PENTOL"				"C26H44O5"	26.00	44.00	5.00	0.00	0.00	0.00	436		"                             OH                           (REF:145)"	"                             �ｵ"	"                 HO  ＼／＼／＼／"	"                 �ﾃ    �ｵ    �ｶ"	"                 ／＼�ｫ＼      OH"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"145/"											"TMS エーテル:706,589,499,409,341,319,251,209,129,117 (145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)胆汁, 尿 (145)"	"145/"					"bileaciPage258.html"
"BA0259"	5.00		"5-CHOLESTENE-3β,7α,12α,24,25-PENTOL"				"C27H46O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                             OH                           (REF:145)"	"                             �ｵ"	"                 HO  ＼／＼／＼／"	"                 �ﾃ    �ｵ    �ｶ＼"	"                 ／＼�ｫ＼        OH"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"145/"											"TMS-エーテル:720,630,540,131 (145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)胆汁, 尿 (145)"	"145/"					"bileaciPage259.html"
"BA0260"	5.00		"5-CHOLESTENE-3β,7α,25,26-TETROL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                          (REF:145)"		"                     ＼／＼／＼／＼"	"                       �ｵ    �ｶ＼  OH"	"                 ／＼�ｫ＼        OH"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"145/"											"TMS エーテル:722,632,619,529,439,349,343,253,219,129,103(145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)胆汁, 尿 (145)"	"145/"					"bileaciPage260.html"
"BA0261"	5.00		"5-CHOLESTENE-3β,7α,12α,25,26-PENTOL"				"C27H44O5"	27.00	46.00	5.00	0.00	0.00	0.00	450		"                                                          (REF:145)"		"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ    �ｶ＼  OH"	"                 ／＼�ｫ＼        OH"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"       HO            OH"					"145/"											"TMS エーテル:720,707,630,617,540,527,437,347,341,251,219(145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)胆汁, 尿 (145)"	"145/"					"bileaciPage261.html"
"BA0262"	5.00		"3β,7α,12α-TRIHYDROXY-5-CHOLESTENOIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                O                         (REF:145)"	"                               �ｳ"	"                 HO  ＼／＼／＼／＼"	"                 �ﾃ    �ｵ      �ｵ  OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         ／＼／�ｸ／�ﾅ"	"      HO             OH"					"145/"											"メチルエステル-TMS-エーテル: 678,588,341,251,209,129 (145)"		"145/"	"ヒト(3β-HYDROXY-△5-C27-STEROID DEHYDROGENASE欠損症患者)血漿 (145)"	"145/"					"bileaciPage262.html"
"BA0263"	5.00		"3α,7α,22-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"22-HIDROXYCHENODEOXYCHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                         OH O       合成                      (REF:146)"	"                         �ｯ�ｳ"	"                     ＼／�ｲ／＼"	"                       �ｵ      OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�･／�ﾅ"	"      HO       H     OH"					"146/147/"	"22R体141-142ﾟC(146) 22S体251-252ﾟC(147) 247-250ﾟC(146)"		"22R体 +1.0ﾟ(146) 22S体 -10ﾟ(147) +2.4ﾟ(146)"				"146/147/"		"3400cm-1, 1720cm-1 (146,147)"	"1H-NMR 22R体/22S体 0.69/0.74(s,18-H3) 0.97/0.96(s,19-H3) 1.17/1.16(d,J=6Hz   21-H3) 3.4-4.4/3.4-4.4(m,3β,7β,22-H)(146)   13C-NMR  22R体/22S体:43.1/42.0(C-20) 12.8/12.4(C-21) 71.2/70.9(C-22) 36.5/  41.5(C-23) (146)"""	"メチルエステル-TMS-エーテル:623,548,533,458,443,368,353,344,295,284,269,255,254,247,227,213 (146)"		"146/147/"	"22S体 イサキ(PARAPRISTIPOMA TRILINEATUM)胆汁 (147) ザイール河魚  POLYPTERUS SENEGALUS胆汁 (015) MORMYRUS CABALLUS胆汁 (015)   CHRYSICHTHYS SP.胆汁 (015) MALAPTERURUS ELECTRICUS胆汁 (015)  SCHILKE MYSTUS胆汁 (015)"	"147/015/"			"かってHAEMULCHOLIC ACIDと呼ばれた(147)"		"bileaciPage263.html"
"BA0264"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"				"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                            O      合成                      (REF:148)"	"                           �ｳ"	"                 HO  ＼／�ｹ／＼"	"                   �ﾂ  �ｵ      OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�･／�ﾅ"	"      HO       H     OH"					"148/"	"22E型 メチルエステル 181-183ﾟC(148)"						"148/"		"22E型 メチルエステル:1650,1730,3400 (148)"	"22E型 メチルエステル    0.78(s,18-H3), 0.97(s,19-H3), 1.28(d,J=6Hz 21-H3), 3.65(s,COOCH3), 3.60(m,3β-H), 3.98(m,7β-H), 4.09(m,12β-H), 5.82(d,J=15.3Hz,23-H), 6.95(dd,J=15.3Hz AND 7.2Hz,22-H) (148)"""	"22E型 メチルエステル-TMS エーテル: 636, 621, 546, 531, 456, 441, 366, 351, 433, 343, 253, 243 (148,100)"		"148/100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁 (100)"	"100/"					"bileaciPage264.html"
"BA0265"	5.00		"3α,7α-DIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                            O      合成                        (REF:148)"	"                           �ｳ"	"                     ＼／�ｹ／＼"	"                       �ｵ      OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�･／�ﾅ"	"      HO       H     OH"					"148/"	"22E型メチルエステル非結晶性(148)"						"148/"		"22E型 メチルエステル:1650,1730,3400 (148)"	"22E型 メチルエステル   0.68(s,18-H3) 0.95(s,19-H3) 1.03(d,J=6Hz 21-H3) 3.65(s,COOCH3) 3.60(m,3β-H) 3.93(m,7β-H) 5.82(d,J=15.3Hz,23-H) 6.89(dd,  J=15.3Hz 7.2Hz,22-H) (148)"""	"22E型 メチルエステル-TMS-エーテル: 458,443,368,353,255,243 (100,148)"		"100/148/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁 (100)"	"100/"					"bileaciPage265.html"
"BA0266"	5.00		"3α,7α,12α-TRIHYDROXY-5α-CHOL-22-EN-24-OIC ACID"				"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                            O                              (REF:100)"	"                           �ｳ"	"                 HO  ＼／�ｹ／＼"	"                   �ﾂ  �ｵ      OH"	"                 ／＼�ｫ＼"	"                 �ｵ�ｶ�ｽ�ｺ"	"           ／�ｪ／＼／"	"           �ｵ  �ｵ  �ｵ"	"         �ﾄ＼／�ﾊ／�ﾅ"	"      HO       H     OH"					"100/"											"メチルエステル-TMS-エーテル:456,366,343,259,253,243 (100)"		"100/"	"アリゲーター(ALLIGATOR MISSISSIPPIENSIS)胆汁 (100)"	"100/"					"bileaciPage266.html"
"BA0267"	5.00		"5α-CHOLESTANE-3α,7α,12α,23,25-PENTOL"				"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452		"                                                           (REF:149)"	"                    HO  ＼／＼／＼／"	"                      �ﾂ  �ｵ  �ｯ�ｶ＼"	"                    ／＼�ｫ＼ OH     OH"	"                    �ｵ�ｶ�ｽ�ｺ"	"              ／�ｪ／＼／"	"              �ｵ  �ｵ  �ｵ"	"            �ﾄ＼／�ﾊ／�ﾅ"	"          HO      H     OH"						"149/"	"238-239ﾟC(149)"						"149/"			"23S体 1H-NMR(149) 0.72(18-H3)/0.80(19-H3)/1.04(21-H3)/1.23,1.27(26-H3,27-H3)/3.97(3β-H)/(7β-H)/3.94(12β-H)/4.01(23-H)   13C-NMR(149)C1 33.2/C2 29.6/C3 67.3/C4 36.6/C5 32.8/C6 37.8/C7 68.8/C8 41.2/C9 40.6/C10 37.0/C11 29.4/C12 74.0/C13 47.7/C14 43.4/C1"	"23S体 メチルエステル-TMS-エーテル: 667,632,577,542,487,452,433,397,362,343,307,281,253,243,131 (149)"		"149/"	"ヒト(CEREBROTEUDINOUS XANTHOMATOSIS患者)尿 (149)"	"149/"					"bileaciPage267.html"
"BA0268"	5.00		"5α-CHOLESTANE-3α,7α,26,27-TETROL"	"12-DEOXY-5α-CYPRINOL"			"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436		"                                                         (REF:040)"	"                      ＼／＼／＼／＼"	"                        �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼      ＼"	"                  �ｵ�ｶ�ｽ�ｺ        OH"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾊ／�ﾅ"	"        HO      H     OH"						"040/"														"合成品(040)"	"040/"					"bileaciPage268.html"
"BA0269"	5.00		"5α-CHOLEST-25-ENE-3α,7α,12α,26-TETROL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                         (REF:011)"	"                  HO  ＼／＼／＼／＼OH"	"                    �ﾂ  �ｵ      �ｾ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾊ／�ﾅ"	"        HO      H     OH"						"011/"	"221 - 224ﾟC(011)"						"011/"		"3340, 890 (011)"	"0,81(3H,s, 18-CH3), 0.91(3H,s, 19-CH3), 1.20(3H,d, J=6Hz,21-CH3), 4.09(1H,m, 3β-H), 4.24(2H,m, 7β-H,12β-H), 4.35(2H,s, 26-CH2-OH),  4.94,5.41(2H,s, 27=CH2) (011)"			"011/"	"合成品(011)"	"011/"					"bileaciPage269.html"
"BA0270"	5.00		"5α-CHOLEST-25-ENE-3α,7α,12α-TRIOL"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                                         (REF:037)"	"                  HO  ＼／＼／＼�ｴ"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾊ／�ﾅ"	"        HO      H     OH"						"037/"	"215ﾟC(037)"						"037/"							"合成品(037)"	"037/"					"bileaciPage270.html"
"BA0271"	5.00		"5α-CHOLESTANE-3α,7α,25-TRIOL"				"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420		"                                                         (REF:151)"	"                      ＼／＼／＼／"	"                        �ｵ      �ﾉ"	"                  ／＼�ｫ＼        OH"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾊ／�ﾅ"	"        HO      H     OH"						"151/"	"197-198ﾟC(151)"						"151/"		"3333, 1230, 1158, 1095, 1078, 1063, 1034, 1020, 1005, 957, 904 (151)"		"402, 384, 369, 366, 351, 289, 273, 271, 264, 255, 253, 249, 246, 231(151)"		"151/"	"合成品(151)"	"151/"					"bileaciPage271.html"
"BA0272"	5.00		"5β-CHOLESTANE-3α,7α,12α,22,26-PENTOL"				"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452		"                          OH                              (REF:098)"	"                          �ｯ"	"                  HO  ＼／＼／＼／＼"	"                    �ﾂ  �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"098/"	"22S体 137-139ﾟC, 22R体結晶せず(098)"						"098/"		"3400 (098)"	"0.92(3H,s, 18-CH3), 1.04(3H,s, 19-CH3), 1.15(3H,d, J=6Hz,27-CH3), 1.45(3H,d, J=6Hz, 21-CH3), 3.65-4.43(6H,m, 3β-H,7β-H,12β-H,22-H,26-CH2) (098)"""	"AS TMS ETHER  453, 363, 343, 261, 253, 171, 129, 103 (098)"		"098/"	"合成品(098)"	"098/"					"bileaciPage272.html"
"BA0273"	5.00		"5β-CHOLESTANE-3α,7α,12α,23,26-PENTOL"				"C27H48O5"	27.00	48.00	5.00	0.00	0.00	0.00	452		"                                                          (REF:098)"		"                  HO  ＼／＼／＼／＼"	"                    �ﾂ  �ｵ  �ｯ  �ｵ  OH"	"                  ／＼�ｫ＼  OH"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"098/"	"23R体 非結晶性, 22S体 213-215ﾟC(098)"						"098/"		"3400 (098)"	"23R体/23S体  087/0.88(3H,s, 18-CH3), 1.01/1.02(3H,s, 19-CH3), 1.15/1.24(3H,d, J=6Hz,27-CH3), 1.36/1.43(3H,d, J=6Hz,21-CH3),    3.69-4.36/3.70-4.35(6H, 3β-H,7β-H,12β-H,23-H,26-CH2)(098)"""	"AS TMS ETHER  542, 452, 363, 343, 253, 247, 157 (098)"		"098/"	"合成品(098)"	"098/"					"bileaciPage273.html"
"BA0274"	5.00		"5β-CHOLESTANE-3α,7α,12α,22-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436		"                          OH                              (REF:069)"	"                          �ｯ"	"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"069/"	"22R体 127-128.5ﾟC, 22S体 203-204ﾟC(069)"		"22R体 +34ﾟ,  22S体  +20ﾟ (069)"				"069/"		"3400, 1080, 1040, 1020, 980, 950, 915 (069)"	"22R体/22S体  087/0.92(3H,s, 18-CH3), 1.02/1.04(3H,s, 19-CH3), 1.46/1.46(3H,d, J=6Hz,21-CH3),0.86,0.89/0.89(6H,d, J=6Hz,26-CH3,27-CH3),   3.70/3.66(1H,m,3β-H),4.08/4.06(1H,m,7β-H), 4.28/4.30(1H,m, 12β-H),  3.94/3.93(1H,m, 22-H) (069)"""	"AS TMS ETHER 724, 653, 634, 563, 544, 473, 454, 383, 364, 293, 253, 173 (069)"		"069/"	"合成品(069)"	"069/"					"bileaciPage274.html"
"BA0275"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLESTAN-23-ONE"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                          (REF:069)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ  �ｾ  �ｵ"	"                  ／＼�ｫ＼  O"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"069/"	"173 - 174ﾟC(069)"						"069/"		"3400, 1710, 1080, 1040, 980, 950, 915 (069)"				"069/"	"合成品(069)"	"069/"					"bileaciPage275.html"
"BA0276"	5.00		"5β-CHOLEST-25-ENE-3α,7α,12α,23-TETROL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                          (REF:152)"		"                  HO  ＼／＼／＼�ｷ"	"                    �ﾂ  �ｵ  �ｯ  �ｵ"	"                  ／＼�ｫ＼  OH"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"152/"	"23R体 非結晶性,  23S体 194.5 - 195ﾟC(152)"		"23R体 +40.3ﾟ,  23S体 +44.2ﾟ(152)"				"152/"		"3400, 890 (152)"	"23R体/23S体  087/0.88(3H,s, 18-CH3), 1.01/1.01(3H,s, 19-CH3), 1.37/1.41(3H,d, J=6Hz,21-CH3),1.83/1.89(3H,s, 27-CH3),3.5-4.4/3.5-4.4(4H,m,3β-H,7β-H, 12β-H,23-H),  4.98/4.98(2H,s, 26-CH2)(152)"""	"AS TMS ETHER  667, 577, 487, 397, 307, 343, 253 (152)"		"152/"	"合成品(152)"	"152/"					"bileaciPage276.html"
"BA0277"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLESTAN-24-ONE"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                              O                           (REF:072)"	"                              �ｾ"	"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"072/"	"141 - 142ﾟC (072)"						"072/"							"合成品(072)"	"072/"					"bileaciPage277.html"
"BA0278"	5.00		"5β-CHOLEST-25-ENE-3α,7α,12α,24-TETROL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                              OH                          (REF:067)"	"                              �ｯ"	"                  HO  ＼／＼／＼�ｷ"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"067/"	"24R体 168.5-170ﾟC, 24S体 190-190.5ﾟC(067)"						"067/"			"24R体/24S体  0.84/0.83(3H,s, 18-CH3), 1.01/1.01(3H,s, 19-CH3), 1.26/1.26(3H,d, J=6Hz,21-CH3),1.88/1.88(3H,s, 27-CH3),  3.4-4.5/3.4-4.5(4H,m, 3β-H,7β-H,12β-H,24-H),4.98,5.20/4.94,5.18(2H,s, 26-CH2)(067)"""			"067/"	"合成品(067)"	"067/"					"bileaciPage278.html"
"BA0279"	5.00		"5β-CHOLESTANE-3α,7β,12α,25-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436		"                                                          (REF:027)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾔ"	"        HO      H     OH"					"027/"	"160 - 161.5ﾟC (027)"						"027/"		"3350 (027)"	"0.82(3H,s, 18-CH3), 0.99(3H,s, 19-CH3), 1.20(3H,d, J=6Hz,21-CH3), 1.34(6H, sx2, 26- AND 27-CH3),3.72(2H,m, 3β-H,7α-H), 4.13(1H,m,12β-H)   (027)"""			"027/"	"合成品(027)"	"027/"					"bileaciPage279.html"
"BA0280"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLESTAN-26-AL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                  O                      (REF:153/154)"	"                                  �ｾ"	"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"153/154/"	"結晶として単離されていない(153/154)"						"153/154/"		"3400, 1710 (153)"		"434, 416, 402, 398, 384, 380, 365, 289, 271, 253, 227, 211   AS TMS ETHER   545, 470, 455, 380, 365, 343, 253, 226, 211 (154)"		"153/154/"	"合成品(153/154)"	"153/154/"					"bileaciPage280.html"
"BA0281"	5.00		"7α,12α,26-TRIHYDROXY-5β-CHOLESTAN-3-ONE"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                         (REF:154)"		"                  HO  ＼／＼／＼／＼"	"                    �ﾂ  �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾉ／�ﾅ"	"         O      H     OH"					"154/"											"AS TMS ETHER   650, 635, 560, 545, 470, 455, 347, 269, 251 (154)"		"154/"	"合成品(154)"	"154/"					"bileaciPage281.html"
"BA0282"	5.00		"7α,12α-DIHYDROXY-3-OXO-5β-CHOLESTAN-26-AL"				"C27H44O4"	27.00	44.00	4.00	0.00	0.00	0.00	432		"                                  O                      (REF:154)"	"                                  �ｾ"	"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾉ／�ﾅ"	"         O      H     OH"					"154/"											"AS TMS ETHER   432, 414, 399, 396, 381, 287, 273, 269, 251 (154)"		"154/"	"合成品(154)"	"154/"					"bileaciPage282.html"
"BA0283"	5.00		"5β-CHOLESTANE-3β,7α,25-TRIOL"				"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420		"                                                         (REF:155)"		"                      ＼／＼／＼／"	"                        �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾕ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"155/"	"157 - 160ﾟC(155)"						"155/"				" 402, 387, 384, 369, 366, 351, 289, 273, 271, 255, 253 (155)"		"155/"	"合成品(155)"	"155/"					"bileaciPage283.html"
"BA0284"	5.00		"5β-CHOLESTANE-3β,7α,12α,25-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436		"                                                         (REF:155)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾕ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"155/"	"半結晶体"										"436, 418, 400, 382, 364, 271, 253 (155)"		"155/"	"合成品(155)"	"155/"					"bileaciPage284.html"
"BA0285"	5.00		"7α,12α,25-TRIHYDROXY-5β-CHOLESTAN-3-ONE"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                         (REF:156)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾉ／�ﾅ"	"         O      H     OH"					"156/"	"198 - 199.5ﾟC(156)"						"156/"		"3426, 1701, 1148, 1095, 1078, 1040, 979, 937 (156)"				"156/"	"合成品(156)"	"156/"					"bileaciPage285.html"
"BA0286"	5.00		"7α,12α,25-TRIHYDROXYCHOLEST-4-EN-3-ONE"				"C27H44O4"	27.00	44.00	4.00	0.00	0.00	0.00	432		"                                                         (REF:156)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼�ｷ＼／�ﾅ"	"         O            OH"					"156/"	"222 - 223ﾟC(156)"						"156/"	"λ243nm ε= 14.834 (156)"	"3367, 1672, 1639, 1230, 1190, 1160, 1086, 1047, 1007, 954, 919, 862 (156)"		"432, 414, 396, 378, 376, 358, 315, 267, 261, 124 (156)"		"156/"	"合成品(156)"	"156/"					"bileaciPage286.html"
"BA0287"	5.00		"7α,25-DIHYDROXY-5β-CHOLESTAN-3-ONE"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                                         (REF:156)"		"                      ＼／＼／＼／"	"                        �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾉ／�ﾅ"	"         O      H     OH"					"156/"	"180 - 181ﾟC(156)"						"156/"		"3484, 3412, 1709, 1098, 1077, 1037, 1007, 980 (156)"	" 0.71(3H,s, 18-CH3), 0.97(3H,d, 21-CH3), 1.01(3H,s, 19-CH3),  1.23(6H,s, 26- & 27-CH3), 3.98(1H,m, 7β-H) (156)"			"156/"	"合成品(156)"	"156/"					"bileaciPage287.html"
"BA0288"	5.00		"7α,25-DIHYDROXYCHOLEST-4-EN-3-ONE"				"C27H44O3"	27.00	44.00	3.00	0.00	0.00	0.00	416		"                                                         (REF:156)"		"                      ＼／＼／＼／"	"                        �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼�ｷ＼／�ﾅ"	"         O            OH"					"156/"	"205 - 206ﾟC(156)"						"156/"	"λ243nm ε= 16.470 (156)"	"3333, 1661, 1618, 1234, 1193, 1156, 1149, 1044, 1030, 952, 940, 913 (156)"	"0.71(3H,s, 18-CH3), 0.93(3H,d, 21-CH3), 1.19(9H,s, 19-CH3,26- & 27-CH3),   3.9 (1H,m, 7β-H), 5.75(1H, 4-H) (156)"	"416, 398, 380, 342, 269, 267, 124 (156)"		"156/"	"合成品(156)"	"156/"					"bileaciPage288.html"
"BA0289"	5.00		"5β-CHOLEST-25-ENE-3α,7α,12α,26-TETROL"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                         (REF:010)"		"                  HO  ＼／＼／＼／＼"	"                    �ﾂ  �ｵ      �ｾ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"010/"	"結晶として単離されていない(010)"						"010/"							"合成品(010)"	"010/"					"bileaciPage289.html"
"BA0290"	5.00		"5β-CHOLESTANE-3α,7α-DIOL"				"C27H48O2"	27.00	48.00	2.00	0.00	0.00	0.00	404		"                                                         (REF:157)"		"                      ＼／＼／＼／"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"157/"	"84 - 86ﾟC(157)"		"+14.1ﾟ (157)"				"157/"							"合成品(157)"	"157/"					"bileaciPage290.html"
"BA0291"	5.00		"5β-CHOLESTAN-3α-OL"				"C27H48O1"	27.00	48.00	1.00	0.00	0.00	0.00	388		"                                                         (REF:157)"		"                      ＼／＼／＼／"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／"	"        HO      H"					"157/"	"116 - 118ﾟC(157)"		"+30.7ﾟ (157)"				"157/"							"合成品(157)"	"157/"					"bileaciPage291.html"
"BA0292"	5.00		"5β-CHOLESTANE-3α,12α-DIOL"				"C27H48O2"	27.00	48.00	2.00	0.00	0.00	0.00	404		"                                                         (REF:157)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／"	"        HO      H"					"157/"	"108 - 110ﾟC(157)"		"+45.0ﾟ (157)"				"157/"							"合成品(157)"	"157/"					"bileaciPage292.html"
"BA0293"	5.00		"7α-HYDROXY-5β-CHOLESTAN-3-ONE"				"C27H46O2"	27.00	46.00	2.00	0.00	0.00	0.00	402		"                                                         (REF:158)"		"                      ＼／＼／＼／"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾉ／�ﾅ"	"         O      H     OH"					"158/"	"120 - 121ﾟC(158)"						"158/"							"合成品(158)"	"158/"					"bileaciPage293.html"
"BA0294"	5.00		"7α,12α-DIHYDROXY-5β-CHOLESTAN-3-ONE"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                                         (REF:159)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾉ／�ﾅ"	"         O      H     OH"					"159/"	"209 - 210ﾟC(159)"		"+42.6ﾟ(159)"				"159/"							"合成品(159)"	"159/"					"bileaciPage294.html"
"BA0295"	5.00		"7α,12α-DIHYDROXYCHOLEST-4-EN-3-ONE"				"C27H44O3"	27.00	44.00	3.00	0.00	0.00	0.00	416		"                                                         (REF:159)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼�ｷ＼／�ﾅ"	"         O            OH"					"159/"	"228 - 229ﾟC(159)"		"+85.0ﾟ(159)"				"159/"	"λ243nm ε= 16.800 (159)"					"159/"	"合成品(159)"	"159/"					"bileaciPage295.html"
"BA0296"	5.00		"5β-CHOLEST-24-ENE-3α,7α-DIOL"				"C27H46O2"	27.00	46.00	2.00	0.00	0.00	0.00	402		"                                                         (REF:063/160)"		"                      ＼／＼／�ｹ／"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"063/160/"	"DIACETATE 67 - 69ﾟC(063/160)"						"063/160/"		"826 (063/160)"				"063/160/"	"合成品(063/060)"	"063/060/"					"bileaciPage296.html"
"BA0297"	5.00		"5β-CHOLEST-25-ENE-3α,7α-DIOL"				"C27H46O2"	27.00	46.00	2.00	0.00	0.00	0.00	402		"                                                         (REF:063/160)"		"                      ＼／＼／＼�ｴ"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"063/160/"	"DIACETATE 69 - 72ﾟC(063/160)"						"063/160/"		"890 (063/160)"				"063/160/"	"合成品(063/060)"	"063/060/"					"bileaciPage297.html"
"BA0298"	5.00		"5β-CHOLESTANE-3α,7α,24,25-TETROL"				"C27H48O4"	27.00	48.00	4.00	0.00	0.00	0.00	436		"                              OH                         (REF:160)"	"                              �ｯ"	"                      ＼／＼／＼／"	"                        �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"160/"	"24R体 201 - 203ﾟC, 24S体 203 - 204ﾟC(160)"		"24R体 +17.8ﾟ,  24S体 +3.0ﾟ (160)"				"160/"		"24S体  3290, 1455, 1365, 1155, 1118, 1104, 1067, 1036, 990, 967, 902, 890  24R体  3385, 1460, 1442, 1371, 1164, 1155, 1122, 1106, 1067, 1054, 1023, 992, 970, 906, 890 (160)"	"24R体/24S体 68/66(3H,s, 18-CH3), 91/91(3H,s, 19-CH3),  94/94.5(3H,d,J=7Hz,21-CH3), 123,126/123,126(6H,s,  26,27-CH3) (160)"	"AS TMS ETHER   709, 634, 593, 529, 503, 413, 323, 283, 255, 131 (160)"		"160/"	"合成品(160)"	"160/"					"bileaciPage298.html"
"BA0299"	5.00		"5β-CHOLESTANE-3α,24,25-TRIOL"				"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420		"                              OH                         (REF:160)"	"                              �ｯ"	"                      ＼／＼／＼／"	"                        �ｵ    �ｶ�ｼOH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／"	"        HO      H"					"160/"	"24R体 148 - 150ﾟC, 24S体 162 - 164ﾟC(160)"		"24R体 +40.0ﾟ,  24S体 +17.3ﾟ(160)"				"160/"		"24R体  3300, 1455, 1445, 1370, 1140, 1075, 1028, 980, 956, 945, 936, 918,    898     24S体  3320, 1457, 1445, 1372, 1150, 1033, 960, 920 (160)"	"24R体/24S体 65/64(3H,s, 18-CH3), 92/92(3H,s, 19-CH3),  92/94(3H,d,J=7Hz,21-CH3), 114,118/117,122(6H,sx2, 26,27-CH3) (160)"	"AS TMS ETHER  636, 621, 531, 505, 456, 441, 415, 351, 345, 325, 257, 255,   215, 131 (160)"		"160/"	"合成品(160)"	"160/"					"bileaciPage299.html"
"BA0300"	5.00		"5β-CHOLEST-24-EN-3α-OL"				"C27H46O1"	27.00	46.00	1.00	0.00	0.00	0.00	386		"                                                         (REF:160)"		"                      ＼／＼／�ｹ／"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／"	"        HO      H"					"160/"	"非結晶性(160)"						"160/"		"ACETATE  1736, 1660, 1460, 1445, 1375, 1360, 1245, 1025, 825 (160)"				"160/"	"合成品(160)"	"160/"					"bileaciPage300.html"
"BA0301"	5.00		"5β-CHOLEST-25-EN-3α-OL"				"C27H46O1"	27.00	46.00	1.00	0.00	0.00	0.00	386		"                                                         (REF:160)"		"                      ＼／＼／＼�ｷ"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／"	"        HO      H"					"160/"	"非結晶性(160)"						"160/"		"ACETATE  1728, 1650, 1465, 1450, 1370, 1350, 1255, 1025, 950, 930, 890 (160)"				"160/"	"合成品(160)"	"160/"					"bileaciPage301.html"
"BA0302"	5.00		"5β-CHOLESTANE-3α,26-DIOL"				"C27H48O2"	27.00	48.00	2.00	0.00	0.00	0.00	404		"                                                         (REF:161)"		"                      ＼／＼／＼／＼"	"                        �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／"	"        HO      H"					"161/"	"150 - 155ﾟC(161)"						"161/"		"3300 (160)"				"160/"	"合成品(160)"	"160/"					"bileaciPage302.html"
"BA0303"	5.00		"3α-HYDROXY-5β-CHOLESTAN-26-AL"				"C27H46O2"	27.00	46.00	2.00	0.00	0.00	0.00	402		"                                  O                      (REF:161)"	"                                  �ｾ"	"                      ＼／＼／＼／"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          ／＼／�ﾉ／"	"        HO      H"					"161/"	"非結晶性(161)"						"161/"		"3400, 1720 (161)"				"161/"	"合成品(161)"	"161/"					"bileaciPage303.html"
"BA0304"	5.00		"7α-HYDROXYCHOLEST-4-EN-3-ONE"				"C27H44O2"	27.00	44.00	2.00	0.00	0.00	0.00	400		"                                                         (REF:162)"		"                      ＼／＼／＼／"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼�ｷ＼／�ﾅ"	"         O            OH"					"162/"	"183 - 184ﾟC(162)"		"+67ﾟ (162)"				"162/"	"λ242.5nm ε= 16.100 (162)"					"162/"	"合成品(162)"	"162/"					"bileaciPage304.html"
"BA0305"	5.00		"12α-HYDROXYCHOLEST-4-EN-3-ONE"				"C27H44O2"	27.00	44.00	2.00	0.00	0.00	0.00	400		"                                                         (REF:163)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼�ｷ＼／"	"         O"					"163/"	"142 - 143ﾟC(163)"		"+86ﾟ (163)"				"163/"	"λ241nm ε= 17.500 (163)"					"163/"	"合成品(163)"	"163/"					"bileaciPage305.html"
"BA0306"	5.00		"12α-HYDROXY-5β-CHOLESTAN-3-ONE"				"C27H46O2"	27.00	46.00	2.00	0.00	0.00	0.00	402		"                                                         (REF:163)"		"                  HO  ＼／＼／＼／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾉ／"	"         O      H"					"163/"	"122ﾟC(163)"		"+51ﾟ (163)"				"163/"							"合成品(163)"	"163/"					"bileaciPage306.html"
"BA0307"	5.00		"7β-HYDROXYCHOLEST-4-EN-3-ONE"				"C27H44O2"	27.00	44.00	2.00	0.00	0.00	0.00	400		"                                                         (REF:162)"		"                      ＼／＼／＼／"	"                        �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼�ｷ＼／＼"	"         O            OH"					"162/"	"182 - 183ﾟC(162)"		"+62ﾟ (162)"				"162/"							"合成品(162)"	"162/"					"bileaciPage307.html"
"BA0308"	5.00		"5β-CHOLEST-24-ENE-3α,7α,12α-TRIOL"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                                         (REF:039)"		"                  HO  ＼／＼／�ｹ／"	"                    �ﾂ  �ｵ      �ｵ"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO      H     OH"					"039/"	"171ﾟC(039)"						"039/"		"3650, 1645 (039)"				"039/"	"合成品(039)"	"039/"					"bileaciPage308.html"
"BA0309"	5.00		"3α,6α,7α,12α-TETRAHYDROXY-5β-CHOLEST-24-EN-26-OIC ACID"				"C27H44O6"	27.00	44.00	6.00	0.00	0.00	0.00	464		"                                  O                      (REF:115)"	"                                  �ｾ"	"                  HO  ＼／＼／�ｹ／＼"	"                    �ﾂ  �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾉ／�ﾅ"	"        HO     H  �ﾂ  OH"	"                  OH"				"115/"	"非結晶(115)"						"115/"			" 0.80(3H,s, 18-CH3), 1.04(3H,s, 19-CH3), 1.24(3H,d,J=6Hz,21-CH3), 1.90(3H,s, 27-CH3), 3.68-3.82(1H,m, 3β-H), 4.20-4.30(3H,m, 6β-H,7β-H,12β-H), 6.94(1H,t, J=9Hz,24-H)(115)"			"115/"	"合成品(115)"	"115/"					"bileaciPage309.html"
"BA0310"	5.00		"3α,7α-DIHYDROXY-12-OXO-5α-CHOLESTAN-26-OIC ACID"				"C27H44O5"	27.00	44.00	5.00	0.00	0.00	0.00	448		"                                  O                      (REF:127)"	"                                  �ｾ"	"                    O ＼／＼／＼／＼"	"                    �ｾ  �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾊ／�ﾅ"	"        HO      H     OH"					"127/"	"メチルエステル・ジアセタート 138 - 139ﾟC(127)"		"メチルエステル・ジアセタート +60ﾟ (127)"				"127/"		"メチルエステル・ジアセタート     1727, 1700, 1243, 1089, 1030, 1022, 963, 936, 873, 849 (127)"		"349, 289 (12-ケトステロイドに特徴的なフラグメント) (127)"		"127/"	"合成品(127)"	"127/"					"bileaciPage310.html"
"BA0311"	5.00		"3α,7α-DIHYDROXY-5α-CHOLESTAN-26-OIC ACID"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                  O                 (REF:127/164/165)"	"                                  �ｾ"	"                      ＼／＼／＼／＼"	"                        �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾊ／�ﾅ"	"        HO      H     OH"					"127/164/165/"	"248 - 250ﾟC(127/164)"		"0ﾟ (164)"				"127/164/"		"3389, 3305, 1706, 1302, 1262, 1234, 1209, 1090, 1069, 1042, 1033, 1000,    961,  888 (127)"		"メチルエステル 448, 430, 412, 399, 273, 255, 249, 231, 213 (127)"		"127/"	"合成品(127/164/165)"	"127/164/165/"					
"BA0312"	5.00		"3β,7α-DIHYDROXY-5α-CHOLESTAN-26-OIC ACID"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                  O                     (REF:164)"	"                                  �ｾ"	"                      ＼／＼／＼／＼"	"                        �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾕ＼／�ﾊ／�ﾅ"	"        HO      H     OH"					"164/"	"251 - 253ﾟC(164)"						"164/"		"3400, 3252, 1712, 1229, 1155, 1087, 1033, 1028, 943 (164)"				"164/"	"合成品(164)"	"164/"					
"BA0313"	5.00		"7α-HYDROXY-5α-CHOLESTAN-26-OIC ACID"				"C27H44O4"	27.00	44.00	4.00	0.00	0.00	0.00	432		"                                  O                     (REF:164)"	"                                  �ｾ"	"                      ＼／＼／＼／＼"	"                        �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾊ／�ﾅ"	"         O      H     OH"					"164/"	"7-アセタート 211 - 213ﾟC(164)"						"164/"		"7-アセタート    1731, 1695, 1250, 1157, 1022, 938 (164)"				"164/"	"合成品(164)"	"164/"					
"BA0314"	5.00		"3,7,12-TRIOXO-25-HOMO-5α-CHOLAN-25-OIC ACID"				"C25H36O5"	25.00	36.00	5.00	0.00	0.00	0.00	416		"                                                        (REF:058)"	"                                  OH"	"                    O ＼／＼／＼／"	"                    �ｾ  �ｵ      �ｾ"	"                  ／＼�ｫ＼      O"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾊ／�ｹ"	"         O      H     O"					"058/"	"206 - 211ﾟC(058)"						"058/"							"合成品(058)"	"058/"					
"BA0315"	5.00		"3α,7α-DIHYDROXY-25-HOMO-5α-CHOLAN-25-OIC ACID"				"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                                                        (REF:151)"	"                                  OH"	"                      ＼／＼／＼／"	"                        �ｵ      �ｾ"	"                  ／＼�ｫ＼      O"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ﾄ＼／�ﾊ／�ﾅ"	"        HO      H     OH"					"151/"	"メチルエステル  122ﾟC(151)"						"151/"		"メチルエステル       3367, 1748, 1270, 1239, 1209, 1169, 1034, 1005, 961, 887 (151)"		"メチルエステル TMS エーテル 564, 549, 474, 459, 384, 369, 345, 225, 243, 228, 213 (151)"		"151"	"合成品(151)"	"151/"					
"BA0316"	5.00		"3,7-DIOXO-25-HOMO-5α-CHOLAN-25-OIC ACID"				"C25H38O4"	25.00	38.00	4.00	0.00	0.00	0.00	402		"                                                        (REF:151)"	"                                  OH"	"                      ＼／＼／＼／"	"                        �ｵ      �ｾ"	"                  ／＼�ｫ＼      O"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾊ／�ｹ"	"         O      H     O"					"151/"	"メチルエステル  188 - 189ﾟC(151)"						"151/"							"合成品(151)"	"151/"					
"BA0317"	5.00		"3,7-DIOXO-5α-CHOLESTAN-26-OIC ACID"				"C27H42O4"	27.00	42.00	4.00	0.00	0.00	0.00	430		"                                  O                     (REF:165)"	"                                  �ｾ"	"                      ＼／＼／＼／＼"	"                        �ｵ      �ｵ  OH"	"                  ／＼�ｫ＼"	"                  �ｵ�ｶ�ｽ�ｺ"	"            ／＼�ｫ＼／"	"            �ｵ  �ｵ  �ｵ"	"          �ｴ＼／�ﾊ／�ｹ"	"         O      H     O"					"165/"	"メチルエステル  124 - 125ﾟC(165)"						"165/"		"メチルエステル      2940, 2860, 1739, 1723, 1708, 1164 (165)"	"メチルエステル 0.67(3H,s, 18-CH3), 0.90(3H,d,J=6Hz,21-CH3), 1.14(3H,d, J=7Hz,27-CH3), 1.25(3H,s, 19-CH3), 1.80-2.60(8H,m, 2-CH2,4-CH2,6-CH2,25CH), 3.67(3H,s, CH3 ESTER) (165)"	"メチルエステル 444, 426, 412, 384, 287, 269, 260, 247, 246, 245 (165)"		"165"	"合成品(165)"	"165/"					
"BA0318"	5.00		"5α-CHOLESTANE-3α,7α,12α-TRIOL"				"C27H48O3"	27.00	48.00	3.00	0.00	0.00	0.00	420		"                                                          (REF:166)"	"                    HO ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾊ／�ﾅ"	"         HO      H     OH"						"166/"	"251ﾟC(166)"						"166/"							"化学合成品(166)"	"166/"					
"BA0319"	5.00		"7α,12α-DIHYDROXY-5α-CHOLESTAN-3-ONE"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                                          (REF:166)"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ｴ＼／�ﾊ／�ﾅ"	"          O      H     OH"						"166/"	"190-192ﾟC(166)"						"166/"							"化学合成品(166)"	"166/"					
"BA0320"	5.00		"3α,12α-DIHYDROXY-5β-CHOLESTAN-7-ONE"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                                          (REF:167)"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾊ／�ｹ"	"         HO      H     O"						"167/"	"140ﾟC(167)"						"167/"			"(CDCl3)  0.68(s,CH3-18),0.86(d,J=6Hz,CH3-26/27),0.96(d,J=6Hz,CH3-21), 1.17(s,CH3-19),3.54(m,b,CH-3),4.02(m,b,CH-12) (167)"			"167/"	"化学合成品(167)"	"167/"					
"BA0321"	5.00		"CHOLEST-4-ENE-3α,7α,12α-TRIOL"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                                          (REF:166)"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼�ｷ＼／�ﾅ"	"         HO            OH"						"166/"	"208-210ﾟC(166)"						"166/"							"化学合成品(166)"	"166/"					
"BA0322"	5.00		"24-NOR-5β-CHOLESTANE-3α,7α,12α,23,25-PENTOL"				"C26H46O5"	26.00	46.00	5.00	0.00	0.00	0.00	438		"                                 OH                      (REF:083)"	"                               �ｫ"	"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ  �ｶ"	"                   ／＼�ｫ＼  OH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"083/"	"172-175ﾟC(083)"						"083/"		"(KBr DISC) 3390cm-1 (083)"	"CDCl3+DMSO(d6) 0.68(s,3H,18-CH3),0.84(s,3H,18-CH3),0.99(d,J=6Hz,3H,21-CH3), 1.04(s,3H,26-CH3),1.08(s,3H,27-CH3)(083)"	"AS TMS DERIVATIVE M/E 667,618,577,529,487,439,397,349,307 (083)"		"083/"	"化学合成品(083)"	"083/"					
"BA0323"	5.00		"24-NOR-5β-CHOLESTANE-3α,7α,12α,23-TETROL"				"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422		"                                                         (REF:168)"	"                               �ｵ"	"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ  �ｶ"	"                   ／＼�ｫ＼  OH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"168/"	"23(S) 115-118ﾟC, 23R 246-247ﾟC(168)"		"23S +26.67ﾟ, 23R 43.34ﾟ (168)"				"168/"							"化学合成品(168)"	"168/"					
"BA0324"	5.00		"24-NOR-5β-CHOLESTANE-3α,7α,12α,26-TETROL"				"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422		"                                                         (REF:168)"	"                               �ｵ  OH"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／＼／�ﾅ"	"         HO            OH"					"168/"	"25S 178-181ﾟC, 25R  59-61ﾟC(168)"		"25S +29.0ﾟ, 25R +40.0ﾟ (168)"				"168/"							"化学合成品(168)"	"168/"					
"BA0325"	5.00		"(22R)-24-NOR-5β-CHOLESTANE-3α,7α,22,25-TETROL"				"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422		"                         HO      OH                      (REF:147)"	"                         �ﾃ    �ﾇ"	"                       ＼／＼／＼"	"                       �ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"147/"	"193ﾟC(147)"						"147/"							"化学合成品(147)"	"147/"					
"BA0326"	5.00		"24-NOR-5β-CHOLESTANE-3α,7α,23,25-TETROL"				"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422		"                                 OH                        (REF:169)"	"                               �ﾇ"	"                       ＼／＼／＼"	"                       �ｶ  �ｶ"	"                   ／＼�ｫ＼  OH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"169/"	"189.5-190.5ﾟC(23β),182.5-183ﾟC(23α)(169)"		"+30ﾟ(23β), -9ﾟ(23α) (169)"				"169/"		"(KBr DISC) cm-1 (23β)3420,2930,1460,1370,1070,993,972,893,850 (23α)3400,2930,1458,1370,1070,992,970,891,848 (169)"		"M/E AS TMS DERIVATIVES (23β)579,530,489,440,399,384,309,253,243,131 (23α)579,489,440,399,384,309,253,243,131 (169)"		"169/"	"化学合成品(169)"	"169/"					
"BA0327"	5.00		"24-NOR-5β-CHOLESTANE-3α,7α,25,26-TETROL"				"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422		"                                 OH                        (REF:169)"	"                               �ﾇ  OH"	"                       ＼／＼／＼／"	"                       �ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"169/"	"182.5-183ﾟC(169)"						"169/"		"(KBr DISC) cm-1 3400,2930,2865,1456,1380,1073,975 (169)"		"AS TMS DERIVATIVE M/E 710,607,517,427,350,337,255,253,243,219,173 (169)"		"169/"	"化学合成品(169)"	"169/"					
"BA0328"	5.00		"24-NOR-5β-CHOLESTANE-3α,7α,12α-TRIOL"				"C26H46O3"	26.00	46.00	3.00	0.00	0.00	0.00	406		"                                                           (REF:083/168)"	"                               �ｵ"	"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"083/168/"	"182-184ﾟC(168/083)"		"+31.23 (168)"				"168/083/"		"KBr DISC cm-1 3370,1360-1380(THREE PEAKS) (083)"	"CDCl3  0.64(s,3H,18-CH3), 0.84(s,3H,19-CH3), 0.96(d,J=6Hz,3H,21-CH3), 0.84(d,J=6Hz,3H,26-CH3), 0.92(d,J=6Hz,3H,27-CH3) (083)"	"AS TMS DERIVATIVE  M/E 622,546,532,461,456,442,433,371,352,343,281 (083)"		"083/"	"化学合成品(083/168)"	"083/168/"					
"BA0329"	5.00		"24-NOR-5β-CHOLEST-23-ENE-3α,7α,12α-TRIOL"				"C26H44O3"	26.00	44.00	3.00	0.00	0.00	0.00	404		"                                                           (REF:083/168)"	"                               �ｵ"	"                   HO  ＼／＼�ｷ＼"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"083/168/"	"190-191ﾟC(083)"						"083/"		"KBr DISC cm-1 3375,1365-1395 (083)"	"CDCl3  0.68(s,3H,18-CH3), 0.88(s,3H,19-CH3), 0.94(d,J=6Hz,3H,21-CH3), 1.60(s,3H,26-CH3), 1.68(s,3H,27-CH3) (083)"	"TMS DERIVATIVE  M/E 564,530,481,474,461,440,391,384,371,350,344,301,294, 254,253,211 (083)"		"083/"	"化学合成品(083/168)"	"083/168/"					
"BA0330"	5.00		"24-NOR-5β-CHOLEST-25-ENE-3α,7α,12α-TRIOL"				"C26H44O3"	26.00	44.00	3.00	0.00	0.00	0.00	404		"                                                           (REF:083/168)"	"                               �ｵ"	"                   HO  ＼／＼／�ｹ"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"083/168/"	"166-169ﾟC(083)"						"083/"		"KBr DISC cm-1 3375,883 (083)"		"AS TMS DERIVATIVE  M/E 620,530,461,440,391,371,350,301,281,211 (083)"		"083/"	"化学合成品(083/168)"	"083/168/"					
"BA0331"	5.00		"24-NOR-5β-CHOLESTANE-3α,7β,25-TRIOL"				"C27H46O3"	27.00	46.00	3.00	0.00	0.00	0.00	418		"                                 OH                        (REF:108)"	"                               �ﾇ"	"                       ＼／＼／＼"	"                       �ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"					"108/"	"154-155ﾟC(108)"						"108/"			"PYRIDINE-d5  0.74(s,3H,18-CH3),0.98(s,3H,19-CH3),1.05(d,J=6Hz,3H,21-CH3), 1.43(s,6H,26-CH3,27-CH3),3.60-4.00(m,2H,3β-H,7α-H) (108)"			"108/"	"化学合成品(108)"	"108/"					
"BA0332"	5.00		"27-NOR-5β-CHOLESTANE-3α,7α,12α,26-TETROL"				"C26H46O4"	26.00	46.00	4.00	0.00	0.00	0.00	422		"                                                          (REF:028)"		"                   HO  ＼／＼／＼／＼"	"                     �ﾂ�ｶ            OH"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"028/"	"202ﾟC(028)"						"028/"							"化学合成品(028)"	"028/"					
"BA0333"	5.00		"3α,7α,12α-TRIHYDROXY-27-NOR-5β-CHOLESTAN-25-ONE"				"C26H44O4"	26.00	44.00	4.00	0.00	0.00	0.00	420		"                                                          (REF:038)"		"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｾ"	"                   ／＼�ｫ＼      O"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"038/"	"162ﾟC(038)"						"038/"					"C 73.89, H 10.40(CALCD C 74.24, H 10.54) (038)"	"038/"	"化学合成品(038)"	"038/"			"C73.89 H101.40(CALCD C74.24 H10.54)"		
"BA0334"	5.00		"27-NOR-5β-CHOLESTANE-3α,7α,12α-TRIOL"				"C26H46O3"	26.00	46.00	3.00	0.00	0.00	0.00	406		"                                                          (REF:170)"		"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"170/"	"187.5-189ﾟC(170)"						"170/"							"化学合成品(170)"	"170/"					
"BA0335"	5.00		"27-NOR-5β-CHOLEST-24-ENE-3α,7α,12α-TRIOL"				"C26H44O3"	26.00	44.00	3.00	0.00	0.00	0.00	404		"                                                          (REF:051)"		"                   HO  ＼／＼／�ｸ／"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"051/"	"182ﾟC(051)"						"051/"		"KBr DISC cm-1  3400 (051)"	"PYRIDINE-d5 0.81(3H,s,18-CH3),0.99(3H,s,19-CH3),1.21(3H,d,J=6Hz,21-CH3), 1.62(3H,m,26-CH3),3.45-4.40(3H,m,3β-H,7β-H,and 12β-H),  5.46(2H,m,-CH=CH-) (051)"			"051/"	"化学合成品(051)"	"051/"					
"BA0336"	5.00		"26,27-DINOR-5α-CHOLESTANE-3α,7α,12α,24-TETROL"				"C25H44O4"	25.00	44.00	4.00	0.00	0.00	0.00	408		"                               OH                         (REF:009)"	"                               �ｵ"	"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾊ／�ﾅ"	"         HO      H     OH"					"009/"														"RANA PIPIENS(009)"	"009/"					
"BA0337"	5.00		"26,27-DINOR-5β-CHOLESTANE-3α,7α,12α,25-TETROL"				"C25H44O4"	25.00	44.00	4.00	0.00	0.00	0.00	408		"                                                          (REF:028)"	"                                   OH"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"028/"	"202ﾟC(028)"						"028/"							"化学合成品 (028)"	"028/"					
"BA0338"	5.00		"26,27-DINOR-5β-CHOLESTANE-3α,7α,12α-TRIOL"				"C25H44O3"	25.00	44.00	3.00	0.00	0.00	0.00	392		"                                                          (REF:036)"		"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"036/"	"185-186ﾟC(036)"						"036/"							"化学合成品 (036)"	"036/"					
"BA0339"	5.00		"3α,7α,12α-TRIHYDROXY-5α-CHOLAN-24-AL"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                               O                          (REF:033)"	"                               �ｾ"	"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ        H"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾊ／�ﾅ"	"         HO      H     OH"					"033/"									"CHCl3 AS TRIACETATE cm-1 2720,1725,1735,1250,1050 (033)"				"033/"	"化学合成品 (033)"	"033/"					
"BA0340"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLAN-24-AL"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                               O                 (REF:004/092/167)"	"                               �ｾ"	"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ        H"	"                   ／＼�ｫ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ｫ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"004/092/167/"	"150ﾟC(004)"						"004/"		"cm-1 2820,2720,1725 (004)"	"PYRIDINE-d5 (AS TRIACETATE) 0.67(3H,s,18-CH3),0.83(3H,s,19-CH3), 0.84(3H,d,J=6Hz,21-CH3),1.97(6H,s,2x-OCOCH3),2.03(3H,s,-OCOCH3), 4.70(1H,m,3β-H),5.05(1H,m,7β-H),5.23(1H,m,12β-H),  9.83(1H,t,J=3Hz,-CHO) (107)"			"004/107/"	"化学合成品 (004/092/167)"	"004/092/167/"					
"BA0341"	5.00		"5β-CHOLANE-3α,6α,24-TRIOL"				"C24H42O3"	24.00	42.00	3.00	0.00	0.00	0.00	378		"                                                  (REF:171)"	"                       ＼／＼／＼"	"                       �ｶ        OH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO     H  �ﾂ"	"                   OH"					"171/"	"150-155ﾟC(171)"						"171/"			"CD3OD  0.69(3H,s,18-CH3),0.93(3H,s,19-CH3),0.95(3H,d,J=6.6Hz,21-CH3), 3.50(3H,m,3β-H and 24-H2),4.00(1H,m,6β-H) (171)"			"171/"	"化学合成品 (171)"	"171/"					
"BA0342"	5.00		"5β-CHOLANE-3α,7α,12α-TRIOL"				"C24H42O3"	24.00	42.00	3.00	0.00	0.00	0.00	378		"                                                  (REF:036)"	"                   HO  ＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"						"036/"	"186-188ﾟC(036)"						"036/"							"化学合成品 (036)"	"036/"					
"BA0343"	5.00		"5β-CHOLANE-3α,7α,24-TRIOL"				"C24H42O3"	24.00	42.00	3.00	0.00	0.00	0.00	378		"                                                  (REF:172)"	"                       ＼／＼／＼"	"                       �ｶ        OH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"						"172/"	"99-100ﾟC(172)"						"172/"			"CD3OD  0.69(3H,s,18-CH3),0.93(3H,s,19-CH3),0.97(3H,d,J=6.6Hz,21-CH3), 3.38(1H,m,3β-H),3.51(2H,m,24-CH2OH),3.79(1H,m,7β-H) (172)"			"172/"	"化学合成品 (172)"	"172/"					
"BA0344"	5.00		"5β-CHOLANE-3α,7β,24-TRIOL"				"C24H42O3"	24.00	42.00	3.00	0.00	0.00	0.00	378		"                                                  (REF:172)"	"                       ＼／＼／＼"	"                       �ｶ        OH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"						"172/"	"163-164ﾟC(172)"						"172/"		"KBr DISC cm-1 3400 (172)"	"CD3OD  0.71(3H,s,18-CH3),0.96(3H,s,19-CH3),0.97(3H,d,J=6.6Hz,21-CH3), 3.50(4H,m,3β-H,7α-H and 24-CH2OH) (172)"			"172/"	"化学合成品 (172)"	"172/"					
"BA0345"	5.00		"5β-CHOLANE-3α,12α,24-TRIOL"				"C24H42O3"	24.00	42.00	3.00	0.00	0.00	0.00	378		"                                                  (REF:171/173)"	"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ        OH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"						"171/173/"	"118-120ﾟC(171)"						"171/"			"CD3OD  0.71(3H,s,18-CH3),0.93(3H,s,19-CH3),1.01(3H,d,J=6.4Hz,21-CH3), 3.51(3H,m,3β-H and 24-CH2OH),3.96(1H,m,12β-H) (171)"			"171/"	"化学合成品 (171/173)"	"171/173/"					
"BA0346"	5.00		"3α,7α-DIHYDROXY-5β-CHOLAN-24-AL"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376		"                               O                   (REF:105)"	"                               �ｾ"	"                       ＼／＼／＼"	"                       �ｶ        H"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"105/"									"cm-1 2720,1720 (105)"				"105/"	"化学合成品 (105)"	"105/"					
"BA0347"	5.00		"24-NOR-5β-CHOLANE-3α,7α,12α,22,23-PENTOL"				"C23H40O5"	23.00	40.00	5.00	0.00	0.00	0.00	396		"                             OH                       (REF:010)"	"                           ／  OH"	"                   HO  ＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"010/"	"202ﾟC(010)"						"010/"		"3400,1075,1020,990,920,894 (010)"				"010/"	"化学合成品 (010)"	"010/"					
"BA0348"	5.00		"3α,7α,12α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-AL"				"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                      (REF:152/174)"	"                               O"	"                   HO  ＼／＼�ｷ"	"                     �ﾂ�ｶ  �ｶ"	"                   ／＼�ﾇ＼  H"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"152/174/"	"80-85ﾟC (AS TRIACETATE)(174)"						"174/"		"cm-1 3400,1740 (152)"	"PYRIDINE-d5 0.81(3H,s,18-CH3),1.00(3H,s,19-CH3),1.23(3H,d,J=6Hz,21-CH3),3.70(1H,m,3β-H),4.09(1H,m,7β-H),4.19(1H,m,12β-H), 9.83(1H,t,J=3Hz,23-CHO) (152)"	"M/E 504,460,444,401,400,384,340,324,313,280,253 (174)"		"152/174/"	"化学合成品 (152/174)"	"152/174/"					
"BA0349"	5.00		"24-NOR-5β-CHOLANE-3α,7α,12α,23-TETROL"				"C23H40O4"	23.00	40.00	4.00	0.00	0.00	0.00	380		"                                                      (REF:171)"	"                               OH"	"                   HO  ＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"171/"	"215-220ﾟC (171)"						"171/"			"CD3OD  0.72(3H,s,18-CH3),0.92(3H,s,19-CH3),1.02(3H,d,J=6.6Hz,21-CH3), 3.36(1H,m,3β-H),3.55 and 3.63(2H,m,23-H),3.79(1H,m,7β-H), 3.95(1H,m,12β-H) (171)"			"171/"	"化学合成品 (171)"	"171/"					
"BA0350"	5.00		"24-NOR-5β-CHOLANE-3α,7α,22,23-TETROL"				"C23H40O4"	23.00	40.00	4.00	0.00	0.00	0.00	380		"                           OH                         (REF:146)"	"                         �ｶ    OH"	"                       ＼／＼／"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"146/"	"22S 138.5-140ﾟC, 22R 229-230ﾟC (146)"		"22S +8.2ﾟ, 22R +0.7ﾟ (146)"				"146/"		"3400cm-1 (KBr DISC)(146)"	"PYRIDINE-d5 22S:0.71(3H,s,18-CH3),0.97(3H,s,19-CH3),1.24(3H,d,J=6Hz,21-CH3) 3.4-4.4(5H,m,CH-OH's)22R:0.77(3H,s,18-CH3),0.97(3H,s,19-CH3),1.21(3H,d,J=6Hz,21-CH3)  3.4-4.4(5H,m,CH-OH's) (146)"	"AS TMS DERIVATIVE 565,475,385,345,295,255 (146)"		"146/"	"化学合成品 (146)"	"146/"					
"BA0351"	5.00		"24-NOR-5β-CHOLANE-3α,7β,22,23-TETROL"				"C23H40O4"	23.00	40.00	4.00	0.00	0.00	0.00	380		"                           OH                         (REF:148)"	"                         �ｶ    OH"	"                       ＼／＼／"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"					"148/"	"208-210ﾟC (148)"						"148/"		"3400cm-1 (148)"	"PYRIDINE-d5 0.71(3H,s,18-CH3),0.95(3H,s,19-CH3),1.15(3H,s,J=6Hz,21-CH3), 3.4-4.3(5H,m,3β-,7α-,22-,23-H) (148)"			"148/"	"化学合成品 (148)"	"148/"					
"BA0352"	5.00		"24-NOR-5β-CHOLANE-3α,12α,22,23-TETROL"				"C23H40O4"	23.00	40.00	4.00	0.00	0.00	0.00	380		"                           OH                         (REF:146)"	"                         �ｶ    OH"	"                   HO  ＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"					"146/"	"120-122ﾟC (146)"						"146/"		"3400cm-1 (146)"	"PYRIDINE-d5 0.78(3H,s,18-CH3),0.93(3H,s,19-CH3),1.34(3H,d,J=6Hz,21-CH3), 3.4-4.3(5H,m,3β-,12β-,22- AND 23-H) (146)"			"146/"	"化学合成品 (146)"	"146/"					
"BA0353"	5.00		"24-NOR-5β-CHOLANE-3α,6α,23-TRIOL"				"C23H40O3"	23.00	40.00	3.00	0.00	0.00	0.00	364		"                               OH                     (REF:171)"	"                       ＼／＼／"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H �ﾂ"	"                   OH"					"171/"	"212-215ﾟC (171)"						"171/"			"CD3OD  0.70(3H,s,18-CH3),0.93(3H,s,19-CH3),0.96(3H,d,J=6.6Hz,21-CH3),3.51(2H,m,3β-H,23-H),3.61(2H,m,23-H),4.00(1H,m,6β-H) (171)"			"171/"	"化学合成品 (171)"	"171/"					
"BA0354"	5.00		"24-NOR-5β-CHOLANE-3α,7α,12α-TRIOL"				"C23H40O3"	23.00	40.00	3.00	0.00	0.00	0.00	364		"                                                      (REF:175)"	"                   HO  ＼／＼"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"						"175/"	"200-202ﾟC (175)"						"175/"							"化学合成品 (175)"	"175/"					
"BA0355"	5.00		"24-NOR-5β-CHOLANE-3α,7α,23-TRIOL"				"C23H40O3"	23.00	40.00	3.00	0.00	0.00	0.00	364		"                               OH                     (REF:171)"	"                       ＼／＼／"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"						"171/"	"247-249ﾟC (171)"						"171/"			"CD3OD 0.70(3H,s,18-CH3),0.93(3H,s,19-CH3),0.96(3H,J=6.6Hz,21-CH3), 3.35(1H,m,3β-H),3.54 AND 3.61(EACH 1H,m,λ3-H),3.79(1H,m,7β-H)(171)"			"171/"	"化学合成品 (171)"	"171/"					
"BA0356"	5.00		"24-NOR-5β-CHOLANE-3α,7β,23-TRIOL"				"C23H40O3"	23.00	40.00	3.00	0.00	0.00	0.00	364		"                               OH                     (REF:171)"	"                       ＼／＼／"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"						"171/"	"179-181ﾟC (171)"						"171/"			"CD3OD  0.72(3H,s,18-CH3),0.96(3H,s,19-CH3),0.96(3H,d,J=6.6Hz,21-CH3),3.48(2H,m,3β-H AND 7α-H),3.54 AND 3.61(EACH 1H,m,23-H) (171)"			"171/"	"化学合成品 (171)"	"171/"					
"BA0357"	5.00		"24-NOR-5β-CHOLANE-3α,12α,23-TRIOL"				"C23H40O3"	23.00	40.00	3.00	0.00	0.00	0.00	364		"                               OH                     (REF:171)"	"                   HO  ＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"						"171/"	"210-212ﾟC (171)"						"171/"			"CD3OD  0.72(3H,s,18-CH3),0.93(3H,s,19-CH3),1.01(3H,d,J=6.6Hz,21-CH3), 3.54(2H,m,3β-H AND 23-H),3.61(1H,m,23-H),3.96(1H,m,12β-H) (171)"			"171/"	"化学合成品 (171)"	"171/"					
"BA0358"	5.00		"24-NOR-5β-CHOL-22-ENE-3α,7α,12α-TRIOL"				"C23H38O3"	23.00	38.00	3.00	0.00	0.00	0.00	362		"                                                      (REF:068/176)"	"                   HO  ＼／�ｹ"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"						"068/176/"	"183-184ﾟC (068)"						"068/"		"cm-1 3400,1660,910,890,1075,1020,990,920,894 (068)"	"0.85(3H,s,18-CH3),1.00(3H,s,19-CH3),1.33(3H,d,J=6Hz,21-CH3), 3.68-4.30(3H,m,3β-H,7β-H,12β-H),4.75-6.00(3H,m,CH=CH2) (068)"			"068/"	"化学合成品 (068/176)"	"068/176/"					
"BA0359"	5.00		"24-NOR-5β-CHOL-22-ENE-3α,6α-DIOL"				"C23H38O2"	23.00	38.00	2.00	0.00	0.00	0.00	346		"                                                      (REF:176)"	"                       ＼／�ｹ"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H �ﾂ"	"                   OH"					"176/"	"151-153ﾟC (AS 3α-FORMATE) (176)"						"176/"							"化学合成品 (176)"	"176/"					
"BA0360"	5.00		"24-NOR-5β-CHOL-22-ENE-3α,7α-DIOL"				"C23H38O2"	23.00	38.00	2.00	0.00	0.00	0.00	346		"                                                      (REF:146/176)"	"                       ＼／�ｹ"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"						"146/176/"	"129.5-130ﾟC (146)"						"146/"		"KBr DISC  3400,991,908 (146)"	"PYRIDINE-d5  0.72(3H,s,18-CH3),0.97(3H,s,19-CH3),1.06(3H,d,J=6Hz,21-CH3), 3.4-4.4(2H,m,3β-H AND 7β-H),4.9(2H,m,23-H2),5.73(1H,m,22-H)(146)"	"AS TMS DERIVATIVE  M/E 400,385,345,310,295,255 (146)"		"146/"	"化学合成品 (146/176)"	"146/176/"					
"BA0361"	5.00		"24-NOR-5β-CHOL-22-ENE-3α,7β-DIOL"				"C23H38O2"	23.00	38.00	2.00	0.00	0.00	0.00	346		"                                                      (REF:176)"	"                       ＼／�ｹ"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"						"176/"	"122-124ﾟC (AS 3α-FORMATE) (176)"						"176/"							"化学合成品 (176)"	"176/"					
"BA0362"	5.00		"24-NOR-5β-CHOL-22-ENE-3α,12α-DIOL"				"C23H38O2"	23.00	38.00	2.00	0.00	0.00	0.00	346		"                                                      (REF:176)"	"                   HO  ＼／�ｹ"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"						"176/"	"97-99ﾟC (AS 3α-FORMATE) (176)"						"176/"							"化学合成品 (176)"	"176/"					
"BA0363"	5.00		"3α-HYDROXY-24-NOR-5β-CHOLAN-23-AL"				"C23H38O2"	23.00	38.00	2.00	0.00	0.00	0.00	346		"                                                      (REF:177/178)"	"                               O"	"                       ＼／＼�ｷ"	"                       �ｶ    �ｵ"	"                   ／＼�ﾇ＼  H"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"					"177/178/"	"145ﾟC (178)"		"+13ﾟ (178)"				"178/"			"CDCl3,(AS 3α-ACETATE) 0.70(s,18-H3),0.94(s,19-H3),1.00(d,21-H3),2.05(s,Ac) 2.0-2.5(m,22-H2),4.73(m,3β-H),9.76(m,23-H) (177)"	"AS 3α-ACETATE  M/E 388,373,370,355,344,328,313,284,230,215 (177)"		"177/"	"化学合成品 (177/178)"	"177/178/"					
"BA0364"	5.00		"3α,7α,12α-TRIHYDROXY-23,24-DINOR-5β-CHOLAN-22-AL"				"C22H36O4"	22.00	36.00	4.00	0.00	0.00	0.00	364		"                           O                          (REF:068)"	"                           �ｾ"	"                   HO  ＼／＼"	"                     �ﾂ�ｶ    H"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"068/"									"KBr DISC cm-1  3400,1720,1075,1020,990,920,894 (068)"	"PYRIDINE-d5  0.78(s,3H,18-CH3),1.00(s,3H,19-CH3),1.28(d,3H,21-CH3),3.68-4.09(m,3H,3β-H,7β-H,12β-H),9.64(d,1H,CHO) (068)"			"068/"	"化学合成品 (068)"	"068/"					
"BA0365"	5.00		"3α,7α-DIHYDROXY-23,24-DINOR-5β-CHOLAN-22-AL"				"C22H36O3"	22.00	36.00	3.00	0.00	0.00	0.00	348		"                           O                          (REF:146)"	"                           �ｾ"	"                       ＼／＼"	"                       �ｶ    H"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"146/"	"82.5-83.5ﾟC (146)"						"146/"		"cm-1 3400, 1720 (146)"	"PYRIDINE-d5  0.68(3H,s,18-CH3),0.96(3H,s,19-CH3),1.08(3H,d,J=6Hz,21-CH3), 3.4-4.4(2H,m,3β-H,7β-H),9.73(1H,d,J=3Hz,-CHO) (146)"	"AS TMS DERIVATIVE M/E 492,402,312,292,255 (146)"		"146/"	"化学合成品 (146)"	"146/"					
"BA0366"	5.00		"3α,7β-DIHYDROXY-23,24-DINOR-5β-CHOLAN-22-AL"				"C22H36O3"	22.00	36.00	3.00	0.00	0.00	0.00	348		"                           O                          (REF:148)"	"                           �ｾ"	"                       ＼／＼"	"                       �ｶ    H"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"					"148/"									"cm-1 3400, 1720 (148)"	"PYRIDINE-d5  0.78(3H,s,18-CH3),0.95(3H,s,19-CH3),1.09(3H,d,J=6Hz,21-CH3), 3.80(2H,m,3β- AND 7α-H),9.53(1H,d,J=3Hz,22-H) (148)"			"148/"	"化学合成品 (148)"	"148/"					
"BA0367"	5.00		"3α,12α-DIHYDROXY-23,24-DINOR-5β-CHOLAN-22-AL"				"C22H36O3"	22.00	36.00	3.00	0.00	0.00	0.00	348		"                           O                           (REF:148)"	"                           �ｾ"	"                   HO  ＼／＼"	"                     �ﾂ�ｶ    H"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"					"148/"									"cm-1 3400, 1720 (148)"	"PYRIDINE-d5  0.73(3H,s,18-CH3),0.94(3H,s,19-CH3),1.23(3H,d,J=6Hz,21-CH3), 3.80(1H,m,3β-H),4.07(1H,m,12β-H),9.53(1H,d,J=3Hz,22-H)(148)"""			"148/"	"化学合成品 (148)"	"148/"					
"BA0368"	5.00		"5β-CHOLANE-3α,24-DIOL"				"C24H42O2"	24.00	42.00	2.00	0.00	0.00	0.00	362		"                                                      (REF:171/173)"		"                       ＼／＼／＼"	"                       �ｶ        OH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"					"171/173/"	"177-178ﾟC (171)"						"171/"			"CD3OD  0.69(3H,s,18-CH3),0.94(3H,s,19-CH3),0.96(3H,d,J=6.2Hz,21-CH3),   3.51(3H,m,3β-H AND 24-CH2OH) (171)"			"171/"	"化学合成品 (171/173)"	"171/173/"					
"BA0369"	5.00		"3α,7α,12α,24-TETRAHYDROXY-24-ETHYL-5β-CHOLESTAN-26-OIC ACID"				"C29H50O6"	29.00	50.00	6.00	0.00	0.00	0.00	494		"                             ＼                         (REF:179)"	"                               �ｵ  COOH"	"                   HO  ＼／＼／�ﾉ／"	"                     �ﾂ�ｶ    HO  �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"179/"	"198.5-199ﾟC (179)"						"179/"							"化学合成品 (179)"	"179/"					
"BA0370"	5.00		"3α,7α,12α-TRIHYDROXY-24-ETHYL-5β-CHOLESTAN-26-OIC ACID"				"C27H50O5"	27.00	50.00	5.00	0.00	0.00	0.00	454		"                             ＼                         (REF:179)"	"                               �ｵ  COOH"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"179/"	"209-210ﾟC (179)"						"179/"							"化学合成品 (179)"	"179/"					
"BA0371"	5.00		"3α,7α,12α-TRIHYDROXY-24-CARBOXYMETHYL-5β-CHOLESTAN-26-OIC ACID"				"C29H48O7"	29.00	48.00	7.00	0.00	0.00	0.00	508		"                         HOOC                             (REF:111)"	"                             ＼"	"                             �ｶ    COOH"	"                   HO  ＼／＼／＼／"	"                   �ﾃ  �ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"				"111/"											"AS METHYL ESTER-ACETATE  M/E 571,560,542,482,313,253 (111)"		"111/"	"化学合成品 (111)"	"111/"					
"BA0372"	5.00		"3α,7α,12α-TRIHYDROXY-24-ETHYL-5β-CHOLESTANE-26,27-DIOIC ACID"				"C29H48O7"	29.00	48.00	7.00	0.00	0.00	0.00	508		"                             ＼                         (REF:111)"	"                               �ｵ  COOH"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼      COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"111/"											"AS METHYL ESTER-ACETATE  M/E 662,619,603,602,571,542,482,313,253 (111)"		"111/"	"化学合成品 (111)"	"111/"					
"BA0373"	5.00		"3α,7α-DIHYDROXY-24-ETHYL-5β-CHOLESTAN-26-OIC ACID"				"C29H50O4"	29.00	50.00	4.00	0.00	0.00	0.00	462		"                             ＼                         (REF:180)"	"                               �ｵ  COOH"	"                       ＼／＼／＼／"	"                       �ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"180/"											"AS METHYL ESTER-TMS  M/E 435,411,255 (180)"		"180/"	"FECES IN SITOSTEROL-FED MONKEY(180)"	"180/"					
"BA0374"	5.00		"3α-HYDROXY-24-ETHYL-5β-CHOLESTAN-26-OIC ACID"				"C29H50O3"	29.00	50.00	3.00	0.00	0.00	0.00	446		"                             ＼                         (REF:180)"	"                               �ｵ  COOH"	"                       ＼／＼／＼／"	"                       �ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"					"180/"											"AS METHYL ESTER-TMS  M/E 460,435,429,411,257 (180)"		"180/"	"FECES IN SITOSTEROL FED MONKEY(180)"	"180/"					
"BA0375"	5.00		"3β-HYDROXY-24-ETHYLCHOLEST-5-EN-26-OIC ACID"				"C29H48O3"	29.00	48.00	3.00	0.00	0.00	0.00	444		"                             ＼                         (REF:180)"	"                               �ｵ  COOH"	"                       ＼／＼／＼／"	"                       �ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           ／＼／�ｸ／"	"         HO"					"180/"											"AS METHYL ESTER-TMS  M/E 381,357,255 (180)"		"180/"	"FECES IN SITOSTEROL FED MONKEY(180)"	"180/"					
"BA0376"	5.00		"3α,7α,12α-TRIHYDROXY-24-METHYL-5β-CHOLEST-23-EN-26-OIC ACID"				"C28H46O5"	28.00	46.00	5.00	0.00	0.00	0.00	462		"                                                        (REF:091)"	"                               �ｵ  COOH"	"                   HO  ＼／＼�ｷ＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"091/"	"182ﾟC (091)"						"091/"							"化学合成品 (091)"	"091/"					
"BA0377"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLESTANE-24-CARBOXYLIC ACID"				"C28H48O5"	28.00	48.00	5.00	0.00	0.00	0.00	464		"                               COOH                      (REF:093)"	"                               �ｵ"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"093/"	"200ﾟC (093)"						"093/"							"化学合成品 (093)"	"093/"					
"BA0378"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLESTANE-26-CARBOXYLIC ACID"				"C28H48O5"	28.00	48.00	5.00	0.00	0.00	0.00	464		"                                                       (REF:133)"		"                   HO  ＼／＼／＼／＼"	"                     �ﾂ�ｶ        �ｵ  COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"133/"	"205-207ﾟC(25-D), 173-176ﾟC(25-L) (133)"		"+37ﾟ(25-D), +29ﾟ(25-L) (133)"				"133/"							"化学合成品 (133)"	"133/"					
"BA0379"	5.00		"3α,7α,12α,26-TETRAHYDROXY-5β-CHOLEST-23-EN-27-OIC ACID"				"C27H44O6"	27.00	44.00	6.00	0.00	0.00	0.00	464		"                                                       (REF:181)"	"                                   COOH"	"                   HO  ＼／＼�ｷ＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼      ＼"	"                   �ｵ�ｶ�ｽ�ｺ        OH"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"181/"											"METHYL ESTER-TMS M/E 766,751,736,676,586,551,522,496,461,431,406,393,371, 355,281,253,185,103 (181)"		"181/"	"化学合成品 (181)"	"181/"					
"BA0380"	5.00		"3α,7α,12α-TRIHYDROXY-5α-CHOLESTANE-26,27-DIOIC ACID"				"C27H44O7"	27.00	44.00	7.00	0.00	0.00	0.00	480		"                                                       (REF:011/033)"	"                                   COOH"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼      COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾊ／�ﾅ"	"         HO      H     OH"					"011/033/"									"CHCl3 (AS METHYL ESTER-ACETATE) 1710cm-1 (033)"	"PYRIDINE-d5 (AS METHYL ESTER ACETATE) 0.70(s,3H,18-CH3),0.74(s,3H,19-CH3), 0.89(d,J=6Hz,3H,21-CH3),1.93,1.99,2.02(s,3Hx3,3-,7- AND 12-OCOCH3),   3.68(s,6H,26- AND 27-COOCH3),5.14(m,λH,3β- AND 7β-H),  5.26(m,1H,12β-H) (033)"			"033/"	"化学合成品 (011/033)"	"011/033/"					
"BA0381"	5.00		"3α,7α,12α-TRIHYDROXY-5β-CHOLESTANE-26,27-DIOIC ACID"				"C27H44O7"	27.00	44.00	7.00	0.00	0.00	0.00	480		"                                                       (REF:010/030)"	"                                   COOH"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼      COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"010/030/"	"154ﾟC-156ﾟC (AS DIETHYL ESTER) (030)"						"030/"		"KBr DISC (AS DIETHYL ESTER) cm-1 1740, 3440 (030)"	"PYRIDINE-d5 (AS DIETHYL ESTER) 0.80(s,3H,18-CH3),1.00(s,3H,19-CH3), 1.14(t,J=7Hz,6H,26- AND 27- COOCH2CH3), 1.20(d,J=6Hz,3H,21-CH3),3.70(m,1H,3β-H),4.07(m,1H,7β-H),  4.18(q,J=7Hz,4H,26- AND 27-COOCH2CH3),4.22(m,1H,12β-H)(030)"			"030/"	"化学合成品 (010/030)"	"010/030/"					
"BA0382"	5.00		"3α,7α-DIHYDROXY-5β-CHOLESTANE-26,27-DIOIC ACID"				"C27H44O6"	27.00	44.00	6.00	0.00	0.00	0.00	464		"                                                       (REF:065)"	"                                   COOH"	"                       ＼／＼／＼／"	"                       �ｶ        �ｵ"	"                   ／＼�ﾇ＼      COOH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"065/"									"CHCl3 (AS DIETHYL ESTER) cm-1 1720, 3400 (065)"	"PYRIDINE-d5 (AS DIETHYL ESTER) 0.69(3H,s,18-CH3),0.95(3H,d,J=6Hz,21-CH3),  0.97(3H,s,19-CH3),1.17(6H,t,J=6Hz,2xOCH2CH3),3.67(1H,m,3β-H),  3.95(1H,m,7β-H),4.17(4H,q,J=6Hz,2xOCH2CH3) (065)"			"065/"	"化学合成品 (065)"	"065/"					
"BA0383"	5.00		"3α,7β-DIHYDROXY-5β-CHOLEST-24-EN-26-OIC ACID"				"C27H44O4"	27.00	44.00	4.00	0.00	0.00	0.00	432		"                                                       (REF:100)"	"                                   COOH"	"                       ＼／＼／�ｹ／"	"                       �ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"					"100/"									"KBr DISC cm-1 3400, 1680, 1640 (100)"	"PYRIDINE-d5  0.70(3H,s,18-CH3),0.96(3H,s,19-CH3),1.01(3H,d,J=6Hz,21-CH3), 2.05(3H,s,27-CH3),3.70(λH,m,3β-AND 7α-H), 7.02(1H,t,J=6Hz,24-H) (100)"			"100/"	"化学合成品 (100)"	"100/"					
"BA0384"	5.00		"3α,12α-DIHYDROXY-5β-CHOLEST-24-EN-26-OIC ACID"				"C27H44O4"	27.00	44.00	4.00	0.00	0.00	0.00	432		"                                                          (REF:100/150)"	"                                   COOH"	"                   HO  ＼／＼／�ｹ／"	"                     �ﾂ�ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"					"100/150/"									"KBr DISC cm-1 3500, 1680, 1640 (100)"	"PYRIDINE-d5  0.73(3H,s,18-CH3),0.93(3H,s,19-CH3),1.18(3H,d,J=6Hz,21-CH3), 2.03(3H,s,27-CH3),3.75(1H,m,3β-H),4.11(1H,m,12β-H), 7.03(1H,t,J=6Hz,24-H) (100)"	"AS METHYL ESTER  M/E 446,428,413,410,395,319,301,299,289,283,281,273,  271,255,253 (150)"		"100/150/"	"化学合成品 (100/150)"	"100/150/"					
"BA0385"	5.00		"3α,7α-DIHYDROXY-24-METHYL-27-NOR-5β-CHOLESTAN-26-OIC ACID"				"C27H46O4"	27.00	46.00	4.00	0.00	0.00	0.00	434		"                                                       (REF:182)"	"                               �ｵ  COOH"	"                       ＼／＼／＼／"	"                       �ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"182/"	"179-181ﾟC(24R), 197-199ﾟC(24S) (182)"		"+18.5ﾟ(24R), +8.7(24S) (182)"				"182/"		"cm-1 3610, 3440, 1725, 1455, 1430, 1375, 1160, 1070, 970, 890 (182)"		"METHYL ESTER  M/E 448, 430, 412, 397, 381, 359, 273, 255, 246, 228, 213 (182)"		"182/"	"化学合成品 (182)"	"182/"					
"BA0386"	5.00		"3α-HYDROXY-5β-CHOLEST-24-EN-26-OIC ACID"				"C27H44O3"	27.00	44.00	3.00	0.00	0.00	0.00	416		"                                                       (REF:102/150)"	"                                   COOH"	"                       ＼／＼／�ｹ／"	"                       �ｶ        �ｵ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"					"102/150/"	"188.5ﾟC (102)"						"102/"	"(AS METHYL ESTER) λmax  219nm(24E), λmax  212nm(24Z)(150)"	"KBr cm-1 1680, 1640 (102)"""		"AS METHYL ESTER  M/E  412, 397, 303, 285, 283, 273, 257, 255 (150)"		"150/"	"化学合成品 (102/150)"	"102/150/"					
"BA0387"	5.00		"3α,7α,12α,24-TETRAHYDROXY-27-NOR-5β-CHOLESTAN-26-OIC ACID"				"C26H44O6"	26.00	44.00	6.00	0.00	0.00	0.00	452		"                               OH                      (REF:042)"	"                               �ｯ  COOH"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"042/"	"AS METHYL ESTER 183.5-184.5ﾟC(24S),162.5-163.5ﾟC(24R) (042)"		"AS METHYL ESTER +35ﾟ(24S), +30ﾟ(24R) (042)"				"042/"		"KBr AS METHYL ESTER  cm-1 3350, 1710 (042)"	"PYRIDINE-d5 AS METHYL ESTER      24S : 0.76(s,3H,18-CH3),0.95(s,3H,19-CH3),1.17(d,J=6Hz,3H,21-CH3), 3.45(s,3H,-COOCH3),3.58(m,1H,3β-H),3.94(m,1H,7β-H),4.08(m,1H,12β-H),4.20(m,1H,24-H) (042)"			"042/"	"化学合成品 (042)"	"042/"					
"BA0388"	5.00		"3α,7α,12α-TRIHYDROXY-27-NOR-5β-CHOLESTAN-26-OIC ACID"				"C26H44O6"	26.00	44.00	5.00	0.00	0.00	0.00	436		"                                                       (REF:133/183/184)"	"                                   COOH"	"                   HO  ＼／＼／＼／"	"                     �ﾂ�ｶ"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"					"133/183/184/"	"195ﾟC (133)"		"+34ﾟ(ETHANOL)) (133)"				"133/"							"化学合成品 (133/183/184)"	"133/183/184/"					
"BA0389"	5.00		"3α,7α,12α,23-TETRAHYDROXY-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H42O6"	25.00	42.00	6.00	0.00	0.00	0.00	438		"                                                       (REF:079/185)"		"                   HO  ＼／＼／＼"	"                     �ﾂ�ｶ    �ｯ  COOH"	"                   ／＼�ﾇ＼  OH"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／＼／�ﾅ"	"         HO            OH"					"079/185/"	"188-189ﾟC(23R), 238.5-240ﾟC(23S) (185)"						"185/"		"KBr AS METHYL ESTER cm-1 23S: 3400,1740, 23R: 3400,1749 (185)"	"PYRIDINE-d5 23R:0.84(3H,s,18-CH3),0.98(3H,s,19-CH3),1.33(3H,d,J=6Hz,21-CH3) 3.64(1H,m,3β-H),4.01(1H,m,7β-H),4.21(1H,m,12β-H), 4.61(1H,m,23-H) (185)"			"185/"	"化学合成品 (079/185)"	"079/185/"					
"BA0390"	5.00		"3α,6β,7α-TRIHYDROXY-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H42O5"	25.00	42.00	5.00	0.00	0.00	0.00	422		"                                                       (REF:007)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H �ｵ  OH"	"                   OH"					"007/"	"240-241.5ﾟC (007)"						"007/"		"KBr cm-1 3400,1700 (007)"	"PYRIDINE-d5  0.76(s,3H,18-CH3),0.99(d,J=6.6Hz,3H,21-CH3),1.44(s,3H,19-CH3), 3.80(m,1H,3β-H),4.21(m,2H,6α- AND 7β-H) (007)"			"007/"	"化学合成品 (007)"	"007/"					
"BA0391"	5.00		"3α,7α,12α-TRIHYDROXY-26,27-DINOR-5α-CHOLESTAN-25-OIC ACID"				"C25H42O5"	25.00	42.00	5.00	0.00	0.00	0.00	422		"                                                       (REF:013)"	"                   HO  ＼／＼／＼"	"                   �ﾃ  �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾊ／�ﾅ"	"         HO      H     OH"						"013/"	"198-200ﾟC (013)"						"013/"							"化学合成品 (013)"	"013/"					
"BA0392"	5.00		"3α,7α,12α-TRIHYDROXY-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H42O5"	25.00	42.00	5.00	0.00	0.00	0.00	422		"                                                       (REF:076/133/186)"	"                   HO  ＼／＼／＼"	"                   �ﾃ  �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"						"076/133/186/"	"215-216ﾟC (133), 215-215.5ﾟC (186)"						"133/186/"							"化学合成品 (076/133/186)"	"076/133/186/"					
"BA0393"	5.00		"3α,7β,12α-TRIHYDROXY-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H42O5"	25.00	42.00	5.00	0.00	0.00	0.00	422		"                                                       (REF:187)"	"                   HO  ＼／＼／＼"	"                   �ﾃ  �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"						"187/"	"185.5-186ﾟC (187)"						"187/"			"PYRIDINE-d5 0.85(3H,s,18-CH3),1.01(3H,s,19-CH3),1.20(3H,d,J=6Hz,21-CH3),  3.70-4.00(2H,m,3β- AND 7α-H),4.23(1H,m,12β-H) (187)"			"187/"	"化学合成品 (187)"	"187/"					
"BA0394"	5.00		"3α,12α-DIHYDROXY-7-OXO-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H40O5"	25.00	40.00	5.00	0.00	0.00	0.00	420		"                                                       (REF:187)"	"                   HO  ＼／＼／＼"	"                   �ﾃ  �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ｹ"	"         HO      H     O"						"187/"	"213-214ﾟC (187)"						"187/"			"PYRIDINE-d5 0.75(3H,s,18-CH3),1.15(3H,d,J=6Hz,21-CH3),1.20(3H,s,19-CH3),  3.80(1H,m,3β-H),4.20(1H,m,12β-H) (187)"			"187/"	"化学合成品 (187)"	"187/"					
"BA0395"	5.00		"3α,7β-DIHYDROXY-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                                                       (REF:187)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"						"187/"	"174-175ﾟC (187)"						"187/"				"AS METHYL ESTER-TMS DERIVATIVE  M/E 564,549,474,459,384,369,345,255 (187)"		"187/"	"化学合成品 (187)"	"187/"					
"BA0396"	5.00		"3α,7β-DIHYDROXY-26,27-DINOR-5β-CHOLEST-11-EN-25-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                                                       (REF:187)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   �ｴ＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／＼"	"         HO      H     OH"						"187/"										"PYRIDINE-d5 (AS METHYL ESTER-ACETATE) 0.72(3H,s,18-CH3),0.85(3H,s,19-CH3),0.96(3H,d,J=6Hz,21-CH3),2.02(6H,s,3α- AND 7β-OCOCH3),3.62(3H,s,-COOCH3),  4.6-5.0(2H,m,3β- AND 7α-H) (187)"			"187/"	"化学合成品 (187)"	"187/"					
"BA0397"	5.00		"3α-HYDROXY-7-OXO-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                                                       (REF:188)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ｹ"	"         HO      H     O"						"188/"	"185-186ﾟC (188)"						"188/"			"PYRIDINE-d5 0.62(3H,s,18-CH3),0.97(3H,s,19-CH3),1.14(3H,d,J=6Hz,21-CH3), 3.81(1H,m,3β-H) (188)"			"188/"	"化学合成品 (187)"	"187/"					
"BA0398"	5.00		"3α-HYDROXY-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H42O3"	25.00	42.00	3.00	0.00	0.00	0.00	390		"                                                       (REF:188)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／"	"         HO      H"						"188/"	"129-130ﾟC (188)"						"188/"			"PYRIDINE-d5 0.65(3H,s,18-CH3),0.96(3H,s,19-CH3),0.97(3H,d,J=6Hz,21-CH3), 3.98(1H,m,3β-H) (188)"			"188/"	"化学合成品 (188)"	"188/"					
"BA0399"	5.00		"3α-HYDROXY-26,27-DINOR-5β-CHOLEST-6-EN-25-OIC ACID"				"C25H40O3"	25.00	40.00	3.00	0.00	0.00	0.00	388		"                                                       (REF:007)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ�ｷ"	"         HO      H"						"007/"	"138.5-139.5ﾟC (007)"						"007/"		"KBr DISC cm-1 3300, 1700 (007)"	"PYRIDINE-d5 0.64(3H,s,18-CH3),0.92(3H,s,19-CH3),0.98(3H,d,J=6.6Hz,21-CH3), 5.50(1H,d,J=10.6Hz,6-H),5.65(1H,ddd,J1=10.1Hz,J2=4.6Hz,J3=2.6Hz,7-H) (007)"			"007/"	"化学合成品 (007)"	"007/"					
"BA0400"	5.00		"7α-HYDROXY-3-OXO-26,27-DINOR-5-CHOLESTAN-25-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                                                       (REF:151)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ｴ＼／�ﾊ／�ﾅ"	"          O      H     OH"						"151/"	"189-191ﾟC (AS METHYL ESTER) (151)"						"151/"		"AS NUJOL MULLS(METHYL ESTER) cm-1 3533,1745,1709,1278,1231,1197,1162,1077,1039,1020,1005,963,952,892 cm-1 (151)"		"AS METHYL ESTER-TMS DERIVATIVE M/E 490,475,400,385,369,367,334,330,319, 271,244 (151)"		"151/"	"化学合成品 (151)"	"151/"					
"BA0401"	5.00		"7α-HYDROXY-3-OXO-26,27-DINORCHOLEST-4-EN-25-OIC ACID"				"C25H38O4"	25.00	38.00	4.00	0.00	0.00	0.00	402		"                                                       (REF:156)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ｴ＼�ｷ＼／�ﾅ"	"          O            OH"						"156/"	"211-212ﾟC (156)"						"156/"	"λmax 243nm (156)"	"cm-1 3508,3154,1724,1666,1310,1282,1265,1237,1186,1117,1066,1041,1006,945(156)"	"0.71(s,18-H),0.93(d,21-H),1.18(s,18-H),3.95(m,7β-H),5.78(4-H) (156)"	"M/E 402,384,374,369,366,346,269,261,249,227,124 (156)"		"156/"	"化学合成品 (156)"	"156/"					
"BA0402"	5.00		"7α-HYDROXY-3-OXO-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H40O4"	25.00	40.00	4.00	0.00	0.00	0.00	404		"                                                       (REF:151/156)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ｴ＼／�ﾉ／�ﾅ"	"          O      H     OH"						"151/156/"	"131-132ﾟC (156)"						"156/"		"cm-1 3597,1745,1718,1191,1162,1119,1071,985,975 (156)"		"AS METHYL ESTER-TMS DERIVATIVE  M/E 490,475,400,385,369,367,271,229 (156)"		"156/"	"化学合成品 (151/156)"	"151/156/"					
"BA0403"	5.00		"3α,7α-DIHYDROXY-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H42O4"	25.00	42.00	4.00	0.00	0.00	0.00	406		"                                                       (REF:064)"	"                       ＼／＼／＼"	"                       �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ﾄ＼／�ﾉ／�ﾅ"	"         HO      H     OH"						"064/"	"210-212ﾟC (064)"						"064/"		"cm-1 2935,2865,1692,1365,1265,1068,965 (064)"		"AS METHYL ESTER  M/E 406,388,370,355,301,255,228,201 (064)"		"064/"	"化学合成品 (064)"	"064/"					
"BA0404"	5.00		"3β,7α,12α-TRIHYDROXY-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H42O5"	25.00	42.00	5.00	0.00	0.00	0.00	422		"                                                       (REF:189)"	"                   HO  ＼／＼／＼"	"                   �ﾃ  �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           ／＼／�ﾉ／�ﾅ"	"         HO      H     OH"						"189/"	"196-198ﾟC (189)"		"+33ﾟ (189)"				"189/"			"DMSO  0.59(3H,s,18-CH3),0.83(3H,s,19-CH3),0.93(3H,d,J=6.3Hz,21-CH3), 3.61(1H,q,J=3.0Hz,7β-H),3.78(2H,m,3α-H,12β-H) (189)"			"189/"	"化学合成品 (189)"	"189/"					
"BA0405"	5.00		"7α,12α-DIHYDROXY-3-OXO-26,27-DINOR-5β-CHOLESTAN-25-OIC ACID"				"C25H40O5"	25.00	40.00	5.00	0.00	0.00	0.00	420		"                                                       (REF:189)"	"                   HO  ＼／＼／＼"	"                   �ﾃ  �ｶ        COOH"	"                   ／＼�ﾇ＼"	"                   �ｵ�ｶ�ｽ�ｺ"	"             ／＼�ﾇ＼／"	"             �ｵ�ｶ  �ｶ"	"           �ｴ＼／�ﾉ／�ﾅ"	"          O      H     OH"						"189/"	"105-107ﾟC (189)"		"+43ﾟ (METHANOL) (189)"				"189/"			"DMSO  0.63(3H,s,18-CH3),0.92(3H,s,19-CH3),0.93(3H,d,J=6.3Hz,21-CH3), 3.68(1H,q,J=3.0Hz,7β-H),3.82(1H,t,J=2.8Hz,12β-H) (189)"			"189/"	"化学合成品 (189)"	"189/"					
"BA0406"	5.00		"13-HYDROXY-9,10-DIMETHOXY-11-OCTADECENOIC ACID"				"C20H38O5"	20.00	38.00	5.00	0.00	0.00	0.00	358		"           OH    CH3O  OCH3                                   (REF:090)"	"           |        |  |"	"CH3-(CH2)4-CH-CH=CH-CH-CH-(CH2)7-COOH"												"090/"									"METHYL ESTER(CS2)(090): TRANS OLEFIN(973-970cm-1), OH(3600 AND 3440cm-1)"	"1H-NMR(METHYL ESTER;CDCl3,300MHz)(090): C9(3.15-3.19ppm), C10(3.58-3.62ppm)C11(5.55-5.58ppm), C12(5.71ppm), C13(4.15ppm), C9OCH3(3.27-3.29ppm),C10OCH3(3.40-3.41ppm), J11-12=15.7Hz(TRANS UNSATURATION)"	"GC-EI-MS(METHYL,TMS)(090):m/e=201[CHOCH3(CH2)7COOCH3](基準ﾋﾟｰｸ), 243[M-201] 173[SMTO=CH(CH2)4CH3]"	"ORD分析(090)"	"090/"	"13-ヒドロペルオキシリノール酸のメタノール中での酸分解物(090)"	"090/"					
"BA0407"	5.00		"13-HYDROXY-9,12-DIMETHOXY-10-OCTADECENOIC ACID"				"C20H38O5"	20.00	38.00	5.00	0.00	0.00	0.00	358		"           OH OCH3     OCH3                                   (REF:090)"	"           |  |        |"	"CH3-(CH2)4-CH-CH-CH=CH-CH-(CH2)7-COOH"												"090/"									"METHYL ESTER(CS2)(090): TRANS OLEFIN(975cm-1), OH(3570 AND 3460cm-1)"	"1H-NMR(METHYL ESTER;CDCl3,300MHz)(090): C9(3.54-3.55ppm), C10(5.49-5.56ppm)C11(5.40-5.58ppm),C12(3.35-3.52ppm),C13(3.46-3.71ppm),C12OCH3(3.28-3.31ppm)C9OCH3(3.25-3.27ppm), J10-11=15.7Hz(TRANS UNSATURATION)"	"GC-EI-MS(METHYL,TMS)(090):m/e=173[SMTO=CH(CH2)4CH3](基準ﾋﾟｰｸ),  240[M-173-OCH3]"	"ORD分析(090)"	"090/"	"13-ヒドロペルオキシリノール酸のメタノール中での酸分解物(090)"	"090/"					
"BA0408"	5.00		"12,13-DIHYDROXY-11-METHOXY-9-OCTADECENOIC ACID"				"C19H36O5"	19.00	36.00	5.00	0.00	0.00	0.00	344		"           OH OH OCH3                                       (REF:090)"	"           |  |  |"	"CH3-(CH2)4-CH-CH-CH-CH=CH-(CH2)7-COOH"												"090/"									"METHYL ESTER(CS2)(090): CIS OLEFIN(750cm-1), OH(3550 AND 3490cm-1)"	"1H-NMR(METHYL ESTER;CDCl3,300MHz)(090):C9(5.74ppm),C10(5.37ppm),C11(4.11ppm),C12(3.62ppm),C13(3.45ppm),C11OCH3(3.27ppm),C12OH(2.39ppm),C13OH(2.70ppm), J9-10=11.2Hz(CIS UNSATURATION)"	"GC-EI-MS(METHYL,TMS)(090):m/e=227[CHOCH3CH=CH(CH2)7COOCH3], 300[227+TMS], 275[M-227], 185[275-HOTMS], 173[SMTO=CH(CH2)4CH3]"		"090/"	"13-ヒドロペルオキシリノール酸のメタノール中での酸分解物(090)"	"090/"					
"BA0409"	5.00		"9-HYDROXY-10-OXO-12-OCTADECENOIC ACID"				"C18H32O4"	18.00	32.00	4.00	0.00	0.00	0.00	312		"                     O OH                                  (REF:086)"	"                     ‖|"	"CH3-(CH2)4-CH=CH-CH2-C-CH-(CH2)7-COOH"												"086/"								"λEtOH/max=226nm(ε=2900±400), λEtOH/max=277nm(ε=1300±200)  (086)"		"1H-NMR(086): C9(4.21ppm), C11(3.22ppm), C12,13(5.54ppm), C14(2.00ppm)"			"086/"	"リノール酸のトウモロコシ胚芽抽出液による酸化物(086)．9-ヒドロペルオキシリノール酸からトウモロコシのヒドロペルオキシドイソメラー ゼの作用で生成(086)．生成機構(012/086/094/095)"	"086/012/094/095/"					
"BA0410"	5.00		"9-HYDROXY-12-OXO-10-OCTADECENOIC ACID"				"C18H32O4"	18.00	32.00	4.00	0.00	0.00	0.00	312		"           O       OH                                  (REF:086)"	"           ‖      |"	"CH3-(CH2)5-C-CH=CH-CH-(CH2)7-COOH"												"086/"								"λEtOH/max=226nm(ε=9900±1100), λEtOH/max=275nm(ε=260±30)  (086)"	"TRANS UNSATURATION(973cm-1), CONJUGATED C=O(1617cm-1), OH(3460,1070cm-1) (086)"	"1H-NMR(086): C9(4.29ppm), C11(6.28ppm), C10(6.80ppm), C13(2.56ppm)"			"086/"	"13-ヒドロペルオキシリノール酸からトウモロコシのヒドロペルオキシドイソメラーゼの作用で生成(086)．生成機構(050/086/094/095)"	"086/050/094/095/"					
"BA0411"	5.00		"9-HYDROXY-13-OXO-10-OCTADECENOIC ACID"				"C18H32O4"	18.00	32.00	4.00	0.00	0.00	0.00	312		"           O           OH                                  (REF:038/087)"	"           ‖          |"	"CH3-(CH2)4-C-CH2-CH=CH-CH-(CH2)7-COOH"												"038/087/"									"METYL ESTER: ISOLATED TRANS OLEFIN(970cm-1), KETO CARBONYL(1717cm-1), OH(3460cm-1)(038/092)"	"1H-NMR(METHYL ESTER, TRANS ENE)(038): C9(4.08ppm), C10(5.56ppm),C11(5.7ppm)C12(3.11ppm), C2,14(2.33ppm)"	"GC-EI-MS(METHYL,TMS)(038/087/092): m/e=398[M], 383[M-CH3], 367[M-OCH3],     327[M-(CH2)4CH3], 259[SMTO=CH-(CH2)7COOCH3], 241[M-(CH2)7COOCH3],          99[CH3(CH2)4CO] GC-EI-MS(METHYL,水添,TMS)(087)"""		"038/087/092/"	"リノール酸ヒドロペルオキシドのFe(III)-CYSTEINE存在下での分解物［二重結合は トランス配置］(038/087)．13-ヒドロペルオキシリノール酸の酸分解物(089)．レシチンの苦味成分(092) 生成機構(095)"	"087/089/092/095/"					
"BA0412"	5.00		"13-HYDROXY-9-OXO-11-OCTADECENOIC ACID"				"C18H32O4"	18.00	32.00	4.00	0.00	0.00	0.00	312		"           OH           O                                  (REF:038/087)"	"           |            ‖"	"CH3-(CH2)4-CH-CH=CH-CH2-C-(CH2)7-COOH"												"038/087/"									"METYL ESTER(CS2):ISOLATED TRANS OLEFIN(970cm-1), KETO CARBONYL(1717cm-1), OH(3460cm-1) (038/092)"	"1H-NMR(METHYL ESTER, TRANS ENE)(038):C2,8(2.33ppm),C10(3.11ppm),C11(5.7ppm)C12(5.56ppm), C13(4.08ppm)"	"GC-EI-MS(METHYL,TMS)(038/087/092): m/e=398[M], 383[M-CH3], 367[M-OCH3],     327[M-(CH2)4CH3], 241[M-(CH2)7COOCH3], 199[CH2CO(CH2)7COOCH3],     185[CO(CH2)7COOCH3], 173[SMTO=CH-(CH2)4CH3]GC-EI-MS(METHYL,水添,TMS)(087)"""		"038/087/092/"	"リノール酸ヒドロペルオキシドのFe(III)-CYSTEINE存在下での分解物［二重結合は トランス配置］(038/087). 13-ヒドロペルオキシリノール酸の酸分解物(089)．レシチンの苦味成分(092)  生成機構(095)"	"038/087/089/092/095/"					
"BA0413"	5.00		"13-HYDROXY-10-OXO-11-OCTADECENOIC ACID"				"C18H32O4"	18.00	32.00	4.00	0.00	0.00	0.00	312		"           OH       O                                         (REF:086)"	"           |        ‖"	"CH3-(CH2)4-CH-CH=CH-C-(CH2)8-COOH"												"086/"								"λEtOH/max=226nm(ε=9900±1100), λEtOH/max=275nm(ε260±30)  (086)"	"TRANS UNSATURATION(973cm-1), CONJUGATED C=O(1617cm-1),  OH(3460,1070cm-1) (086)"	"1H-NMR(086):C9(2.56ppm), C11(6.28ppm), C12(6.80ppm), C13(4.29ppm)"	"GC-EI-MS(METHYL,水添)(086): m/e=328[M], 257[M-(CH2)4CH3], 225[257-CH3OH],   199[CO(CH2)8COOCH3], 167[199-CH3OH](基準ﾋﾟｰｸ), 157[(CH2)7COOCH3 OR         CH3(CH2)4CH(OH)-(CH2)2CO]"""		"086/"	"リノール酸のトウモロコシ胚芽抽出液による酸化物(086)．9-ヒドロペルオキシリノール酸からトウモロコシのヒドロペルオキシドイソメラー ゼの作用で生成(086)．生成機構(050/086/094/095))"	"086/050/094/095/"					
"BA0414"	5.00		"13-HYDROXY-12-OXO-9-OCTADECENOIC ACID"				"C18H32O4"	18.00	32.00	4.00	0.00	0.00	0.00	312		"           OH O                                                (REF:086)"	"           |  ‖"	"CH3-(CH2)4-CH-C-CH2-CH=CH-(CH2)7-COOH"												"086/"								"λEtOH/max=226nm(ε=2900±400), λEtOH/max=277nm(ε=1300±200)  (086)"		"1H-NMR(086): C8(2.00ppm), C9,10(5.54ppm), C11(3.22ppm), C13(4.21ppm)"			"086/"	"13-ヒドロペルオキシリノール酸からトウモロコシのヒドロペルオキシドイソメラーゼの作用で生成(086)．生成機構(012/050/086/094/095))"	"086/012/050/094/095/"					
"BA0415"	5.00		"METHYL 9,12-DIHYDROXY-13-OXO-10-OCTADECENOATE"				"C19H34O5"	19.00	34.00	5.00	0.00	0.00	0.00	342		"           O OH       OH                                     (REF:075/076)"	"           ‖|        |"	"CH3-(CH2)4-C-CH-CH=CH-CH-(CH2)7-COOCH3"												"075/076/"											"GC-EI-MS(TMS)(075):m/e=486[M],471[M-CH3],455[M-OCH3],386[M-C(O)(CH2)4CH3-H]  259[SMTO=CH-(CH2)7COOCH3]"		"075/"	"13-ヒドロペルオキシリノール酸メチルのラジカル分解物(075/076)．"	"075/076/"					
"BA0416"	5.00		"METHYL 10,13-DIHYDROXY-9-OXO-11-OCTADECENOATE"				"C19H34O5"	19.00	34.00	5.00	0.00	0.00	0.00	342		"           OH       OH O                                    (REF:075/076)"	"           |        |  ‖"	"CH3-(CH2)4-CH-CH=CH-CH-C-(CH2)7-COOCH3"												"075/076/"											"GC-EI-MS(TMS)(075):m/e=486[M],471[M-CH3],455[M-OCH3],300[M-C(O)(CH2)7CH3-H]   173[SMTO=CH-(CH2)4CH3]"		"075/"	"13-ヒドロペルオキシリノール酸メチルのラジカル分解物(075/076)．"	"075/076/"					
"BA0417"	5.00		"(METHYL) 9-OXO-10,12-OCTADECADIENOIC ACID (OCTADECADIENOATE)"				"C18H30O3"	18.00	30.00	3.00	0.00	0.00	0.00	294		"                       O                                (REF:038/078/075)"	"                       ‖"	"CH3-(CH2)4-CH=CH-CH=CH-C-(CH2)7-COOH"												"038/078/075/"	"33-34  (091)"						"091/"	"λMeOH/max=277-278nm(ε=20300),λmax=267nm(CYCLOHEXANE)(038/078/075/091/092)"	"TRANS,TRANS UNSATURATIONS(STRONG ABSORPTION AT 1000-990cm-1), TRANS,CISUNSATURATIONS(960-955cm-1), UNSATURATED KETONE(1695-1600cm-1) (038/078/075/092/089)"	"1H-NMR(038/092): C8(2.54ppm), C10,12,13(6.06-6.21ppm), C11(7.02-7.51ppm), C14(2.20-2.23ppm)"	"GC-EI-MS(METHYL,TMS)(075/092/037/089):m/e=308[M],277[M-OCH3],237[M-(CH2)4CH 3],185[C(O)(CH2)6COOCH3],166[CH3(CH2)4-CH=CH-CH=CH-C(OH)=CH2;MACLAFFERTY転 位] 151[M-(CH2)7COOCH3]GC-EI-MS(TMS)(038):m/e=366[M],341[M-CH3],295[[M-(CH2)4CH3],276[M-HOTMS],166,151"		"038/078/075/091/092/089/037/084/"	"リノール酸ヒドロペルオキシドのFe(III)-CYSTEINE存在下での分解物［TRANS,TRANSまたはTRANS,CIS］(038)．リノール酸メチルヒドロペルオキシドのDI-t-BUTYL DIPEROXYOXALATEまたはCo(II)存在下での分解物(077)．リノール酸ヒドロペルオキシドの大豆リポキシゲナ−ゼ"	"038/077/078/089/075/037/092/091/094/043/"	"リノール酸モノヒドロペルオキシドより若干低い毒性を示す(064/066)"	"064/066/"			
"BA0418"	5.00		"(METHYL) 13-OXO-9,11-OCTADECADIENOIC ACID (OCTADECADIENOATE)"				"C18H30O3"	18.00	30.00	3.00	0.00	0.00	0.00	294		"           O                                         (REF:038/039/078/075)"	"           ‖"	"CH3-(CH2)4-C-CH=CH-CH=CH-(CH2)7-COOH"												"038/039/078/075/"								"λMeOH/max=277-278nm(ε=20300)(038/078/075), λEtOH/max=278nm(039),λmax=267nm(CYCLOHEXANE)(092), DNP HYDRAZONE:λCHCl3/max=388,304,265nm(096)"	"TRANS,TRANS UNSATURATIONS(STRONG ABSORPTION AT 1000-990cm-1),  CIS,TRANS UNSATURATIONS(960-955cm-1),UNSATURATED KETONE(1695-1600cm-1)(038/078/075/092)"	"1H-NMR(038/092):C8(2.20-2.23ppm), C9,10,12(6.06-6.21ppm), C11(7.02-7.51ppm) C14(2.54ppm)"	"GC-EI-MS(METHYL,TMS)(039/092/037/089): m/e=308[M], 277[M-OCH3], 252[M-CH2=C  H-CH2CH3], 237[M-(CH2)4CH3], 209[M-C(O)(CH2)4CH3], 151[M-(CH2)7COOCH3],  GC-EI-MS(TMS)(038):m/e=366[M], 341[M-CH3], 295[M-(CH2)4CH3], 276[M-HOTMS],166[M-(CH2)6C(=O)OTMS];REARRAN"		"038/078/075/039/092/096/037/089/084/"	"リノール酸ヒドロペルオキシドのFe(III)-CYSTEINE存在下での分解物［TRANS,TRANSまたはCIS,TRANS］(038)．リノール酸メチルヒドロペルオキシドのDI-t-BUTYL DIPEROXYOXALATEまたはCo(II)存在下での分解物(077)．   リノール酸ヒドロペルオキシドの大豆リポキシゲナーゼ"	"038/077/078/089/039/073/096/075/037/092/"	"リノール酸モノヒドロペルオキシドより若干低い毒性を示す(064/066)"	"064/066/"			
"BA0419"	5.00		"METHYL 9-BUTYLPEROXY-10,12-OCTADECADIENOATE"				"C23H42O4"	23.00	42.00	4.00	0.00	0.00	0.00	382		"                       OOC(CH3)3                                (REF:076)"	"                       |"	"CH3-(CH2)4-CH=CH-CH=CH-CH-(CH2)7-COOCH3"												"076/"								"λETHER/max=234nm(076)"	"ESTER CARBONYL(1740cm-1),  TRANS,TRANS DIENE(991cm-1)(076)"	"1H-NMR(076): C10-C13(5.5-6.1ppm), C9(4.1ppm), C14(2.1ppm)"	"GC-EI-MS(PALLADIUM-CHARCOAL触媒で水添)(076)"		"076/"	"13-ヒドロペルオキシリノール酸メチルのDI-TERT-BUTYL PEROXYOXALATE存在下での 分解物(076)"	"076/"					
"BA0420"	5.00		"METHYL 13-BUTYLPEROXY-9,11-OCTADECADIENOATE"				"C23H42O4"	23.00	42.00	4.00	0.00	0.00	0.00	382		"           OOC(CH3)3                                            (REF:076)"	"           |"	"CH3-(CH2)4-CH-CH=CH-CH=CH-(CH2)7-COOCH3"												"076/"								"λETHER/max=234nm(076)"	"ESTER CARBONYL(1740cm-1),  TRANS,TRANS DIENE(991cm-1)(076)"	"1H-NMR(076): C9-C12(5.5-6.1ppm), C13(4.1ppm), C8(2.1ppm)"	"GC-EI-MS(PALLADIUM-CHARCOAL触媒で水添)(076)"		"076/"	"13-ヒドロペルオキシリノール酸メチルのDI-TERT-BUTYL PEROXYOXALATE存在下での 分解物(076)"	"076/"					
"BA0421"	5.00		"SODIUM 3α,12α-DIHYDROXY-7-OXO-24-NOR-5β-CHOLAN-23-SULFONATE"				"C23H37O6Na"	23.00	37.00	6.00	0.00	0.00	1.00	464		"                                                          (REF:   )"	"              H HO＼／＼"	"              �ﾒ�ﾄ  �ﾓH �ｵ"	"              ／＼�ｫ＼  SO3-Na+"	"            �ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／�ｹ"	"     H  OH  H     O"							"258ﾟC(209)"						"209/"			"1H-NMR(CD3OD)    0.74(s,18-Me), 1.06(d,J=7Hz,21-Me), 1.22(s,19-Me), 2.56(t,J=11Hz,8-CH), 2.71/2.90(m,b,23-CH2), 2.98(dd,7/14Hz,6ax-CH), 3.54(m,b,3β-H), 4.00(m,12β-H)(209)"	"(ESI) M/Z= 441.1(209)"		"209/"							
"BA0422"	5.00		"3-OXO-4-CHOLEN-24-OIC ACID"				"C24H36O3"	24.00	36.00	3.00	0.00	0.00	0.00	372		"                                                          (REF:   )"	"                  ＼／＼"	"                    �ﾓH �ｵ"	"              ／＼�ｫ＼  COOH"	"            �ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ｴ＼�ｷ＼／"	"     O"							"131-132ﾟC(Me ESTER)(210)"						"210/"		"(Me ESTER) (NUJOL)1740, 1680, 1620cm-1(210)"	"1H-NMR(CDCl3,Me ESTER)   0.70(s,18-Me), 1.18(s,19-Me), 3.63(s,COOMe), 5.69(s,4-CH)"			"210/"							
"BA0423"	5.00		"6-(O-CARBOXYMETHYLOXYIMINO)-3α-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C26H41O6N"	26.00	41.00	6.00	1.00	0.00	0.00	463		"                                                          (REF:   )"	"                  ＼／＼"	"                    �ﾓH �ｵ"	"              ／＼�ｫ＼  COOH"	"            �ｶ  �ｶ�ｽ�ｺ"	"        ／＼�ｫ＼／�ﾅ"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／"	"     H  OH  H �ｾ"	"              NOCH2COOH"								"[α]15/D=-29.1ﾟ(Me ESTER)(211)"				"211/"			"1H-NMR(CDCl3,Me ESTER)   0.65(s,18-Me), 0.83(s,19-Me), 0.92(d,J=5Hz,21-Me), 3.65(m,3β-H), 3.68(s,COOMe), 4.54(s,NOCH2COOH)(211)"			"211/"							
"BA0424"	5.00		"(3α,7α,12α-TRIHYDROXY-5β-CHOLAN-24-OYL)-5'-AMINO-2'-NITRO-BENZOIC ACID"				"C31H47O6N"	31.00	47.00	6.00	1.00	0.00	0.00	529		"                                                          (REF:   )"	"              H HO＼／＼           COOH"	"              �ﾒ�ﾄ  �ﾓH �ｵ   �ｴ＼／"	"              ／＼�ｫ＼  CONH-�ｵ�ｳ"	"            �ｶ  �ｶ�ｽ�ｺ       �ｸ／＼"	"        ／＼�ｫ＼／�ﾅ               NO2"	"        �ｵ�ｶ  �ｶ    H"	"      �ﾕ�ﾊ／�ﾚ／�ﾗ"	"     H  OH  H   H OH"							"161-164ﾟC(212)"						"212/"		"cm-1 3327(OH), 1703(COOH), 1697(CONH), 1550,1517(NO2)(212)"	"1H-NMR(DMSO-d6)   0.60(s,18-Me), 0.81(s,19-Me), 0.99(d,J=5.6Hz,21-Me), 3.18(s,NH), 3.35(m,3β-H), 4.15(d,7β-H), 4.35(bs,12β-H), 7.95(m,AROMATIC), 10.56(s,COOH)(212)"			"212/"	"化学合成品（２１２）"	"212/"			"抱合胆汁酸加水分解酵素の分光学的測定の為の基質のとし合成された｡(212)"	"212/"	
"BA0425"	5.00		"7α,12α-DIHYDROXY-3β-(2-HYDROXYETHOXY)-5β-CHOLAN-24-OIC ACID"				"C26H44O6"	26.00	44.00	6.00	0.00	0.00	0.00	452		"                                                          (REF:   )"	"                 H HO＼／＼"	"                 �ﾒ�ﾄ  �ﾓH �ｵ"	"                 ／＼�ｫ＼  COOH"	"               �ｶ  �ｶ�ｽ�ｺ"	"           ／＼�ｫ＼／�ﾅ"	"           �ｵ�ｶ  �ｶ    H"	"         �ﾕ�ﾊ／�ﾚ／�ﾗ"	"HOCH2CH2O  H   H   H OH"							"190-192ﾟC,159-164ﾟC(Me ESTER)(213)"						"213/"			"1H-NMR(DMSO-d6)   0.60(s,3H), 0.82(s,3H), 0.90-2.45(m,24H), 0.93(d,J=4.0Hz,3H), 3.31(m,2H), 3.48(m,3H), 3.62(m,1H), 3.78(m,1H), 4.00(d,J=2.7Hz,1H), 4.08(d,J=2.7Hz,1H), 4.45(t,1H), 11.90(s,1H)(213)"			"213/"							
"BA0426"	5.00		"7α,12α-DIHYDROXY-3α-(2-HYDROXYETHOXY)-5β-CHOLAN-24-OIC ACID"				"C26H44O6"	26.00	44.00	6.00	0.00	0.00	0.00	452		"                                                          (REF:   )"	"                 H HO＼／＼"	"                 �ﾒ�ﾄ  �ﾓH �ｵ"	"                 ／＼�ｫ＼  COOH"	"               �ｶ  �ｶ�ｽ�ｺ"	"           ／＼�ｫ＼／�ﾅ"	"           �ｵ�ｶ  �ｶ    H"	"         �ﾕ�ﾊ／�ﾚ／�ﾗ"	"        H  �ﾂ  H   H OH"	"  HOCH2CH2O"						"183-185ﾟC,104-106ﾟC(Me ESTER)(213)"						"213/"			"1H-NMR(DMSO-d6)   0.60(s,3H), 0.83(s,3H), 0.90-2.30(m,24H), 0.92(d,J=4.0Hz,3H), 3.05(m,1H), 3.3-3.5(m,4H), 3.62(m,1H), 3.79(m,1H), 4.01(d,J=2.7Hz,1H), 4.10(d,J=2.7Hz,1H), 4.50(m,1H), 11.91(s,1H)(213)"			"213/"							
"BA0427"	5.00		"N-[(3α,5β,7β)-3,7-DIHYDROXY-24-OXOCHOLAN-24-YL]-L-PROLINE"				"C29H47O5N"	29.00	47.00	5.00	1.00	0.00	0.00	489		"                                                          (REF:   )"	"                     ＼／＼"	"                       �ﾓH �ｵ"	"                 ／＼�ｫ＼  C=O"	"               �ｶ  �ｶ�ｽ�ｺ  |"	"           ／＼�ｫ＼／�ﾅ    N    COOH"	"           �ｵ�ｶ  �ｶ    H ／  ＼�ﾑ"	"         �ﾕ�ﾊ／�ﾚ／�ﾗ  �ｶ�ｽ�ｽ�ｺ�ﾅ"	"        H  OH  H  HO H           H"							"133-137ﾟC(214)"		"[α]20/=-23.7ﾟ(CHCl3)(214)"			"113μM(WATER)(214)"	"214/"		"(NUJOL) 3360, 1719, 1623cm-1(214)"	"1H-NMR(CDCl3)  0.67(s,3H), 0.94(s,3H), 1.0(d,3H), 0.8-2.4(COMPLEX PATTERN,28H), 3.0(m,2H), 3.6(m,2H), 4.57(t,1H), 5.0(b,2H)(214)"		"CMC:15mM,   PKa:3.9 (214)"	"214/"					"New Bile Acids Amidated with Cyclic Amino Acids(214)"	"214/"	
"BA0428"	5.00		"N-[(3α,5β,7β)-3,7-DIHYDROXY-24-OXOCHOLAN-24-YL]-D-PROLINE"				"C29H47O5N"	29.00	47.00	5.00	1.00	0.00	0.00	489		"                                                          (REF:   )"	"                     ＼／＼"	"                       �ﾓH �ｵ"	"                 ／＼�ｫ＼  C=O"	"               �ｶ  �ｶ�ｽ�ｺ  |"	"           ／＼�ｫ＼／�ﾅ    N    H"	"           �ｵ�ｶ  �ｶ    H ／  ＼�ﾑ"	"         �ﾕ�ﾊ／�ﾚ／�ﾗ  �ｶ�ｽ�ｽ�ｺ�ﾅ"	"        H  OH  H  HO H           COOH"							"140-144ﾟC(214)"		"[α]20/=+76.5ﾟ(MeOH)(214)"			"59μM(WATER)(214)"	"214/"		"(NUJOL) 3360, 1719, 1625cm-1(214)"	"1H-NMR(CDCl3)  0.67(s,3H), 0.94(s,3H), 1.0(d,3H), 0.8-2.4(COMPLEX PATTERN,28H), 3.0(m,2H), 3.6(m,4H), 4.35(t,1H), 4.4(b,2H)(214)"		"CMC: 7mM,   PKa:3.9 (214)"	"214/"					"New Bile Acids Amidated with Cyclic Amino Acids(214)"	"214/"	
"BA0429"	5.00		"N-[(3α,5β,7β)-3,7-DIHYDROXY-24-OXOCHOLAN-24-YL]-4-TRANS-HYDROXY-L-PROLINE"				"C29H47O6N"	29.00	47.00	6.00	1.00	0.00	0.00	505		"                                                          (REF:   )"	"                     ＼／＼"	"                       �ﾓH �ｵ"	"                 ／＼�ｫ＼  C=O"	"               �ｶ  �ｶ�ｽ�ｺ  |"	"           ／＼�ｫ＼／�ﾅ    N    COOH"	"           �ｵ�ｶ  �ｶ    H ／  ＼�ﾑ"	"         �ﾕ�ﾊ／�ﾚ／�ﾗ  �ｶ�ｽ�ｽ�ｺ�ﾅ"	"        H  OH  H  HO H   �ﾗ      H"	"                         H OH"						"98-100ﾟC(214)"		"[α]20/=+16.2ﾟ(MeOH)(214)"			"250μM(WATER)(214)"	"214/"		"(NUJOL) 3360, 1719, 1625cm-1(214)"	"1H-NMR(CDCl3)  0.67(s,3H), 0.94(s,3H), 1.0(d,3H), 0.8-2.4(COMPLEX PATTERN,28H), 3.0(m,2H), 3.6(m,4H), 4.57(dd,1H), 5.0(b,2H)(214)"		"CMC:10mM,   PKa:3.1 (214)"	"214/"					"New Bile Acids Amidated with Cyclic Amino Acids(214)"	"214/"	
"BA0430"	5.00		"12β-HYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376		"             HO  �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (001)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"       �ｲ�ｱ�ﾊ�ｱ"	"           H"							"001/"	"128〜129.5ﾟC(001)"						"001/"		"1700(C=0),3420,1000(OH) (001)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3)(001), 13C-NMR(CDCl3)(002) 18-Me 0.71 (s),19-Me 0.79(s),21-Me 1.00(d),COOMe 3.63(s), C1 38.5,C2 22.0,C3 26.2,C4  28.8,C5 46.9,C6 28.8,C7 32.1,C8 34.1,C9 53.4,C10 36.0,C11 29.4,C12 79.4,C13 47.7,C14 54.4,C15 23.4,C16 2"	"METHYL ESTER DERIVATIVE  m/z 372,357,257(BASE PEAK),233,215 (001)"		"001/"	"ﾋﾄふん便(003)"	"003/"					
"BA0431"	5.00		"1β,3α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"            HO   �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (004)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾊ�ｱ"	"   HO      H"							"004/"	"274〜278ﾟC(004)"						"004/"		"3300,3200,1680 (004)"	"1H-NMR(PYRIDINE-d5)(004),18-Me 0.62(s),19-Me 1.28(s)"	"METHYL ESTER-TRIMETHYLSILYL ESTER DERIVATIVE (Me-TMS) m/z 535,460,370,318, 255,217(BASE PEAK) (004)"		"004/"	"ﾋﾄ胆汁(005)"	"005/"					
"BA0432"	5.00		"2β,3α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (006)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"    HO       �ｵ�ｶ�ｽ�ｺ"	"     �ﾒ�ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾊ�ｱ"	"   HO      H"							"006/"	"193〜196ﾟC(006)"						"006/"		"1715(C=0),3364,1001(OH) (006)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.64(s),19-Me 0.96(s),21-Me  0.92(d),COOMe 3.66(s) 13C-NMR(CDCl3) C1 43.27,C2 71.53,C3 76.85,C4 34.18, C5 42.10,C6 26.50,C7 26.41,C8 35.90,C9 42.07,C10 37.23,C11 21.12,C12 40.13, C13 42.76,C14 56.44,C15 24.2"	"METHYL ESTER-TRIMETHYLSILYL ESTER DERIVATIVE (Me-TMS) m/z 550,460,406,371 (BASE PEAK),330 (006)"		"006/"							
"BA0433"	5.00		"3α,4β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (007)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ"	"   HO    �ﾀH"	"         OH"						"007/"	"156〜158ﾟC(007)"						"007/"		"1703(C=0),3456,1019(OH) (007)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.62(s),19-Me 0.94(s),21-Me  0.88(d),COOMe 3.64(s) 13C-NMR(CDCl3) C1 34.6,C2 27.3,C3 76.7,C4 72.7, C5  48.7,C6 20.9,C7 26.0,C8 35.7,C9 42.4,C10 37.0,C11 20.9,C12 40.1,C13 42.7,C14 56.5,C15 24.1,C16 28.1,C17"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 406(M+),388(BASE PEAK),370,264,249, 231,213 (007)"		"007/"	"ﾋﾄ（妊婦）羊水(008)"	"008/"					
"BA0434"	5.00		"3β,4β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (007)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾚ�ｱ"	"   HO    �ﾀH"	"         OH"						"007/"	"189〜191ﾟC(007)"						"007/"		"1708(C=0),3412,1028(OH) (007)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.63(s),19-Me 0.96(s),21-Me  0.88(d),COOMe 3.64(s) 13C-NMR(CDCl3) C1 29.2,C2 25.8,C3 68.4,C4 69.5, C5  44.0,C6 21.1,C7 26.0,C8 35.5,C9 41.6,C10 36.6,C11 20.7,C12 40.1,C13 42.6,C14 56.6,C15 24.1,C16 28.1,C17"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 406(M+),388(BASE PEAK),370,264,249, 231,213 (007)"		"007/"							
"BA0435"	5.00		"3d,7β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (009)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾊ�ｱ�ﾔ"	"   HO      H    OH"							"009/"	"243.5〜245ﾟC(009)"						"009/"		"1677(C=0),3300,1032,1003(OH) (009)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.68(s),19-Me 0.79(s),21-Me  0.93(d),COOMe 3.65(s)(009) 13C-NMR(CDCl3) C1 32.2,C2 29.0,C3 65.9,C4 35.7, C5 36.4,C6 38.4,C7 74.9,C8 43.6,C9 52.8,C10 35.4,C11 20.9,C12 40.0,C13 43.6,C14 55.2,C15 26.8,C16 28.3,C"	"METHYL ESTER DERIVATIVE  m/z 388,373,370(BASE PEAK),355,255,249,246 (009)"		"009/"							
"BA0436"	5.00		"3β,7α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (009)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾊ�ｱ�ﾅ"	"   HO      H     OH"							"009/"	"271〜272ﾟC(009)"						"009/"		"1715(C=0),3550,1042,1024(OH) (009)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.66(s),19-Me 0.80(s),21-Me  0.92(d),COOMe 3.66(s)(009) 13C-NMR(CDCl3) C1 36.8,C2 31.1,C3 70.8,C4 37.5, C5 36.5,C6 36.3,C7 67.5,C8 39.3,C9 45.6,C10 35.3,C11 20.8,C12 39.3,C1342.4,C14 50.2,C15 23.4,C16 27.8,C1"	"METHYL ESTER DERIVATIVE  m/z 406(M+),388(BASE PEAK),373,273,264,249,246 (009)"		"009/"	"ﾋﾄ胆汁(034)"	"034/"					
"BA0437"	5.00		"3β,7β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (009)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾊ�ｱ�ﾔ"	"   HO      H     OH"							"009/"	"245〜246.5ﾟC(009)"						"009/"		"1690(C=0),3400,1034(OH) (009)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.69(s),19-Me 0.83(s),21-Me  0.93(d),COOMe 3.66(s)(009) 13C-NMR(CDCl3) C1 36.8,C2 31.3,C3 70.4,C4 37.7, C5 42.1,C6 38.5,C7 74.6,C8 43.3,C9 52.5,C10 34.8,C11 21.1,C12 39.9,C13 43.3,C14 55.0,C15 26.5,C16 28.1,C"	"METHYL ESTER DERIVATIVE  m/z 406(M+),388(BASE PEAK),373,273,264,255,249,  246 (009)"		"009/"	"ﾋﾄ胆汁(034)"	"034/"					
"BA0438"	5.00		"3α,12β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"            HO   �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (001)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾊ�ｱ"	"   HO      H"							"001/"	"206.5〜207.5ﾟC(001)"						"001/"		"1680(C=0),3400,1050,1028,1013,1000,970 (009)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.73(s),19-Me 0.79(s),21-Me  1.01(d),COOMe 3.65(s)(001) 13C-NMR(CDCl3) C1 32.1,C2 28.8,C3 66.2,C4 35.7, C5 38.9,C6 28.4,C7 32.1,C8 34.1,C9 53.0,C10 35.8,C11 29.4,C12 79.3,C13 47.7,C14 54.4,C15 23.4,C16 23.8,C"	"METHYL ESTER DERIVATIVE  m/z 388,357,273(BASE PEAK),255,249,213 (001)"		"001/002/"	"ﾋﾄふん便(010)"	"010/"					
"BA0439"	5.00		"3β,12α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"            HO   �ｲ�ｱ�ｲ"	"             �ﾅ    �ｵ  �ｵ                               (001)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾊ�ｱ"	"   HO      H"							"001/"	"228.5〜229.5ﾟC(001)"						"001/"		"1715(C=0),3530,1042,1017,982(OH) (001)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.71(s),19-Me 0.82(s),21-Me  0.98(d),COOMe 3.65(s)(001) 13C-NMR(CDCl3) C1 36.7,C2 21.5,C3 70.8,C4 37.9, C5 44.6,C6 28.4,C7 31.2,C8 35.5,C9 47.2,C10 34.9,C11 28.7,C12 72.8,C13 46.2,C14 47.9,C15 23.4,C16 27.1,C"	"METHYL ESTER DERIVATIVE  m/z 388,273(BASE PEAK),255,249,213 (001)"		"001/002/"	"ﾋﾄ尿(011,012,013,014),ﾋﾄふん便(010)"	"010/011/012/013/014/"					
"BA0440"	5.00		"3β,12β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"            HO   �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (001)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾊ�ｱ"	"   HO      H"							"001/"	"223.5〜225.5ﾟC(001)"						"001/"		"1715(C=0),3250,1040,1027,975(OH) (001)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.72(s),19-Me 0.81(s),21-Me  1.01(d),COOMe 3.64(s)(001) 13C-NMR(CDCl3) C1 36.8,C2 31.4,C3 70.7,C4 37.7, C5 44.6,C6 28.4,C7 32.0,C8 34.0,C9 52.9,C10 35.2,C11 29.3,C12 79.1,C13 47.6,C14 54.2,C15 23.4,C16 23.7,C"	"METHYL ESTER DERIVATIVE  m/z 388,273,357,273(BASE PEAK),255,249 (001)"		"001/002/"	"ﾋﾄふん便(010)"	"010/"					
"BA0441"	5.00		"7α,12α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"            HO   �ｲ�ｱ�ｲ"	"             �ﾅ    �ｵ  �ｵ                               (015)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"       �ｲ／�ﾊ�ｱ�ﾅ"	"           H     OH"							"015/"	"225〜227ﾟC(015)"						"015/"		"1719(C=0),3400,1028(OH) (015)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.69(s),19-Me 0.78(s),21-Me  0.98(d),COOMe 3.66(s)(015) 13C-NMR(CDCl3) C1 38.2,C2 22.0,C3 26.6,C4 28.6, C5 39.1,C6 36.8,C7 67.9,C8 39.7,C9 39.7,C10 35.9,C11 28.3,C12 72.8,C13 46.5,C14 42.3,C15 23.0,C16 27.3,C"	"METHYL ESTER DERIVATIVE  m/z 388,370,355,273,255(BASE PEAK) (015)"		"002/015/"							
"BA0442"	5.00		"7α,12β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"            HO   �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (015)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"       �ｲ�ｱ�ﾊ�ｱ�ﾅ"	"          H      OH"							"015/"	"168〜170ﾟC(015)"						"015/"		"1708(C=0),3425,1032,1015(OH) (015)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.72(s),19-Me 0.79(s),21-Me  1.01(d),COOMe 3.66(s)(015) 13C-NMR(CDCl3) C1 38.3,C2 21.9,C3 26.5,C4 28.4, C5 39.1,C6 36.8,C7 67.6,C8 38.2,C9 45.2,C10 36.2,C11 29.5,C12 78.9,C13 47.6,C14 48.7,C15 23.0,C16 23.9,C"	"""METHYL ESTER DERIVATIVE  m/z 388,370,355,273,255(BASE PEAK) (015)"		"002/015/"							
"BA0443"	5.00		"7β,12α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"            HO   �ｲ�ｱ�ｲ"	"             �ﾅ    �ｵ  �ｵ                               (015)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"       �ｲ�ｱ�ﾊ�ｱ�ﾔ"	"          H      OH"							"015/"	"207.5〜208.5ﾟC(015)"						"015/"		"1685(C=0),3300,1028,990(OH) (015)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.71(s),19-Me 0.80(s),21-Me  0.99(d),COOMe 3.66(s)(015) 13C-NMR(CDCl3) C1 38.5,C2 22.0,C3 26.5,C4 28.5, C5 44.0,C6 38.7,C7 74.9,C8 43.6,C9 45.7,C10 35.2,C11 28.6,C12 72.4,C13 47.3,C14 46.0,C15 26.3,C16 27.7,C"	"METHYL ESTER DERIVATIVE  m/z 388,370,355,273,255(BASE PEAK) (015)"		"002/015/"							
"BA0444"	5.00		"7β,12β-DIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392		"            HO   �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (015)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"       �ｲ�ｱ�ﾊ�ｱ�ﾔ"	"          H      OH"							"015/"	"208〜210ﾟC(015)"						"015/"		"1677(C=0),3275,1036,1008,990(OH) (015)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.76(s),19-Me 0.81(s),21-Me  1.00(d),COOMe 3.66(s)(015) 13C-NMR(CDCl3) C1 38.6,C2 21.9,C3 26.4,C4 28.5, C5 44.2,C6 38.7,C7 74.8,C8 42.1,C9 51.6,C10 35.5,C11 29.1,C12 79.4, C1348.5,C14 53.9,C15 26.3,C16 23.7,C"	"METHYL ESTER DERIVATIVE  m/z 388,370,355,273(BASE PEAK),255 (015)"		"002/015/"							
"BA0445"	5.00		"3β,7β-DIHYDROXY-CHOL-5-EN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (016)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ｸ�ｱ�ﾔ"	"   HO            OH"							"016/"	"237ﾟC(016)"						"016/"		"3470,3200(OH),2570,1725,1700(COOH) (016)"	"1H-NMR(PYRIDINE-d5) 18-Me 0.70(s),19-Me 0.95(s) (016)"			"016/"							
"BA0446"	5.00		"1β,3α,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"            HO   �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (004)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO            OH"							"004/"	"266〜270ﾟC(004)"						"004/"		"3380,3280,1705 (004)"	"1H-NMR(PYRIDINE-d5) 18-Me 0.69(s),19-Me 1.30(s) (004)"	"METHYL ESTER-TRIMETHYLSILYL ETHER DERIVATIVE (Me-TMS) m/z 623,548,458,368, 316,253,217(BASE PEAK) (004)"		"004/"	"ﾋﾄ尿(013/017/018/023),ﾋﾄ血液(017/018/023),ﾋﾄ胎便(019)，ﾋﾄ羊水(017)"	"013/017/018/019/023/"					
"BA0447"	5.00		"1β,3α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"           HO    �ｲ�ｱ�ｲ"	"             �ﾅ    �ｵ  �ｵ                               (004)"	"      HO     �ｱ�ｲ�ｫ�ｲ  COOH"	"       �ﾒ    �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ"	"   HO      H"							"004/"	"262〜264ﾟC(004)"						"004/"		"3400,3300,1705 (004)"	"1H-NMR(PYRIDINE-d5) 18-Me 0.75(s),19-Me 1.34(s) (004)"	"METHYL ESTER-TRIMETHYLSILYL ETHER DERIVATIVE (Me-TMS) m/z 623,548,458,368, 316,253,217(BASE PEAK) (004)"		"004/"	"ﾋﾄ尿(011/012/013/014/017/018/020/021/022/023),ﾋﾄ胎便(019), ﾋﾄ血液（017/018/022/023), ﾋﾄ羊水(008/017)"	"008/011/012/013/014/017/018/019/020/021/022/023/"					
"BA0448"	5.00		"2β,3α,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (006)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"    HO       �ｵ�ｶ�ｽ�ｺ"	"     �ﾒ�ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO      H     OH"							"006/"	"132〜134ﾟC(006)"						"006/"		"1700(C=O),3350,1008,975(OH) (006)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.62(s),19-Me 0.91(s),21-Me 0.88(d),COOMe 3.62(s) 13C-NMR C1 43.05,C2 71.27,C3 76.94,C4 37.33,C5 41.51,C6 33.97,C7 68.27,C8 39.41,C9 34.26,C10 37.53,C11 20.95,C12 39.68,C13 42.66,C14 50.36,C15 23.65,C16 28.2"	"METHYL ESTER-TRIMETHYLSILYL ETHER DERIVATIVE (Me-TMS) m/z 548,458,369(BASE PEAK),243 (006)"		"006/"							
"BA0449"	5.00		"2β,3α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"              HO �ｲ�ｱ�ｲ"	"               �ﾂ  �ｵ  �ｵ                               (006)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"    HO       �ｵ�ｶ�ｽ�ｺ"	"     �ﾒ�ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ"	"   HO      H"							"006/"	"234〜235ﾟC(006)"						"006/"		"1723(C=O),3368,1004(OH) (006)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.64(s),19-Me 0.90(s),21-Me 0.93(d),COOMe 3.63(s) 13C-NMR C1 43.60,C2 70.75,C3 76.37,C4 34.50,C5 42.04,C6 26.49,C7 26.16,C8 36.07,C9 35.06,C10 36.06,C11 28.60,C12 73.21,C13 46.61,C14 47.98,C15 23.73,C16 27.5"	"METHYL ESTER-TRIMETHYLSILYL ETHER DERIVATIVE (Me-TMS) m/z 623,548,458,369,  343,253(BASE PEAK) (006)"		"006/"							
"BA0450"	5.00		"3α,4β,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (007)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO    �ﾀH     OH"	"         OH"						"007/"	"131〜133ﾟC(007)"						"007/"		"1707(C=O),3420,1016,975(OH) (007)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.64(s),19-Me 0.92(s),21-Me 0.90(d),COOMe 3.64(s) 13C-NMR C1 34.6,C2 28.1,C3 75.9,C4 75.5,C5 47.9,C6   27.5,C7 68.5,C8 39.2,C9 34.9,C10 37.1,C11 20.7,C12 39.6,C13 42.7,C14 50.5,C15 23.6,C16 28.1,C17 55.9,C18"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 404,386(BASE PEAK),271,127 (007)"		"007/"	"ﾋﾄ胆汁(024/025),ﾋﾄ羊水(008)"	"008/024/025/"					
"BA0451"	5.00		"3β,4β,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (007)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO    �ﾀH     OH"	"         OH"						"007/"	"212〜214ﾟC(007)"						"007/"		"1712(C=O),3372(OH) (007)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.64(s),19-Me 0.94(s),21-Me 0.90(d),COOMe 3.64(s) 13C-NMR C1 29.2,C2 25.9,C3 69.5,C4 71.4,C5 42.9,C6   28.0,C7 68.6,C8 39.3,C9 34.0,C10 36.9,C11 20.9,C12 39.6,C13 42.7,C14 50.4,C15 23.6,C16 28.1,C17 55.8,C18"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 404(BASE PEAK),386,127 (007)"		"007/"							
"BA0452"	5.00		"3α,4β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"           HO    �ｲ�ｱ�ｲ"	"             �ﾅ    �ｵ  �ｵ                               (007)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ"	"   HO    �ﾀH"	"         OH"						"007/"	"151〜152ﾟC(007)"						"007/"		"1706(C=O),3402,1036(OH) (007)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.66(s),19-Me 0.93(s),21-Me 0.94(d),COOMe 3.64(s) 13C-NMR C1 34.6,C2 27.4,C3 76.7,C4 72.5,C5 48.5,C6   20.8,C7 25.8,C8 35.9,C9 35.4,C10 36.4,C11 28.7,C12 73.0,C13 46.5,C14 48.3,C15 23.6,C16 27.4,C17 47.3,C18"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 289(BASE PEAK),271 (007)"		"007/"							
"BA0453"	5.00		"3β,4β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"           HO    �ｲ�ｱ�ｲ"	"             �ﾅ    �ｵ  �ｵ                               (007)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾚ�ｱ"	"   HO    �ﾀH"	"         OH"						"007/"	"202〜203ﾟC(007)"						"007/"		"1705(C=O),3412,1029(OH) (007)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.67(s),19-Me 0.95(s),21-Me 0.94(d),COOMe 3.64(s) 13C-NMR C1 29.1,C2 25.7,C3 68.3,C4 69.5,C5 43.9,C6   20.6,C7 25.7,C8 35.7,C9 34.9,C10 36.1,C11 28.9,C12 73.1,C13 46.4,C14 48.3,C15 23.5,C16 27.4,C17 47.2,C18"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 289(BASE PEAK),271 (007)"		"007/"							
"BA0454"	5.00		"3β,6α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (026)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO      H �ﾂ  OH"	"             OH"						"026/"	"214〜217ﾟC(026)"						"026/"		"1708(C=O),3440,1048(OH) (026)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.69(s),19-Me 0.94(s),21-Me 0.93(d),COOMe 3.66(s) 13C-NMR C1 30.0,C2 27.4,C3 66.0,C4 29.3,C5 42.4,C6   71.8,C7 69.5,C8 38.4,C9 32.0,C10 36.4,C11 20.9,C12 39.4,C13 42.7,C14 50.2,C15 23.4,C16 28.0,C17 55.7,C18"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 422(M+),404,386,371 (026)"		"026/"							
"BA0455"	5.00		"3β,6β,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (026)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO      H �ﾀ  OH"	"             OH"						"026/"	"214〜216ﾟC(026)"						"026/"		"1720(C=O),3420,1038,1020(OH) (026)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.70(s),19-Me 1.12(s),21-Me 0.93(d),COOMe 3.67(s) 13C-NMR C1 30.6,C2 27.7,C3 66.3,C4 33.2,C5 42.8,C6   76.6,C7 73.0,C8 35.2,C9 33.0,C10 35.2,C11 20.8,C12 39.5,C13 42.6,C14 49.8,C15 23.7,C16 28.1,C17 55.8,C18"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 422(M+),404,386,371 (026)"		"026/"							
"BA0456"	5.00		"3β,6α,7β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (026)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾚ�ｱ�ﾔ"	"   HO      H �ﾂ  OH"	"             OH"						"026/"	"129〜131ﾟC(026)"						"026/"		"1710(C=O),3410,1025(OH) (026)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.68(s),19-Me 0.99(s),21-Me 0.92(d),COOMe 3.67(s) 13C-NMR C1 29.9,C2 27.3,C3 65.6,C4 27.8,C5 42.3,C6   73.0,C7 75.6,C8 41.6,C9 38.9,C10 35.8,C11 21.5,C12 40.1,C13 43.8,C14 55.1,C15 26.7,C16 28.5,C17 56.0,C18"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 422(M+),404,386,371,368 (026)"		"026/"							
"BA0457"	5.00		"3β,6β,7β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                 �ｲ�ｱ�ｲ"	"                   �ｵ  �ｵ                               (026)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾚ�ｱ�ﾔ"	"   HO      H �ﾐ  OH"	"             OH"						"026/"	"189〜190ﾟC(026)"						"026/"		"1713(C=O),3425,1038(OH) (026)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.70(s),19-Me 1.13(s),21-Me 0.93(d),COOMe 3.67(s) 13C-NMR C1 30.1,C2 27.4,C3 65.7,C4 32.5,C5 42.4,C6   75.0,C7 73.4,C8 38.5,C9 39.2,C10 34.2,C11 21.0,C12 39.9,C13 43.5,C14 54.9,C15 26.9,C16 28.4,C17 55.6,C18"	"METHYL ESTER DERIVATIVE (Me-TMS) m/z 422(M+),404,386,371 (026)"		"026/"							
"BA0458"	5.00		"3α,6α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                   (REF:027)"	"            HO  ＼／＼"	"              �ﾂ ｜  ｜"	"            ／＼�ﾇ＼  COOH"	"           ｜ �ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／"	"     ｜  ｜  ｜"	"    �ﾄ＼／�ﾚ／"	"  HO      H �ﾂ"	"            OH"					"027/"	"135〜137ﾟC(027)"						"027/"		"1709(C=O), 3401,1037(OH) (027)"	"METHYL ESTER DERIVATIVE(027):1H-NMR(CDCl3):18-Me 0.666(s),19-Me 0.890(s),  21-Me 0.967(d),COOMe 3.663(s);13C-NMR(CDCl3):C1 35.66,C2 30.08,C3 71.53,   C4 29.18,C5 48.53,C6 68.08,C7 34.81,C8 35.10,C9 32.97,C10 35.60,C11 28.62C12 72.95,C13 46.69,C14 47.87,C"	"METYL ESTER DERIVATIVE (027) m/e=404, 368, 289, 217(BASE PEAK), 253"		"027/"	"ﾋﾄふん便  (003)，  ﾋﾄ尿(012/014/021/028)"	"003/012/014/021/028/"					
"BA0459"	5.00		"3α,6β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                   (REF:027)"	"            HO  ＼／＼"	"              �ﾂ ｜  ｜"	"            ／＼�ﾇ＼  COOH"	"           ｜ �ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／"	"     ｜  ｜  ｜"	"    �ﾄ＼／�ﾚ／"	"  HO      H �ﾐ"	"            OH"					"027/"	"137〜139C(027)"						"027/"		"1711=O), 3401,1045(OH) (027)"	"METHYL ESTER DERIVATIVE(027):1H-NMR(CDCl3):18-Me 0.712(s),19-Me 1.099(s),  21-Me 0.976(d),COOMe 3.665(s);13C-NMR(CDCl3):C1 35.76,C2 30.12,C3 71.30,   C4 36.44,C5 48.68,C6 73.13,C7 34.45,C8 30.96,C9 34.06,C10 33.97,C11 28.51 C12 73.13,C13 46.63,C14 48.00,"	"METYL ESTER DERIVATIVE (027) m/e=404, 368, 289, 217(BASE PEAK), 253"		"027/"	"ﾋﾄ尿(011/012/013/014)"	"011/012/013/014/"					
"BA0460"	5.00		"3β,6α,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                   (REF:027)"	"            HO  ＼／＼"	"              �ﾂ ｜  ｜"	"            ／＼�ﾇ＼  COOH"	"           ｜ �ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／"	"     ｜  ｜  ｜"	"    �ﾕ＼／�ﾚ／"	"  HO      H �ﾂ"	"            OH"					"027/"	"135〜137C(027)"						"027/"		"1709=O), 3412,1036, 976(OH) (027)"	"METHYL ESTER DERIVATIVE(027):1H-NMR(CDCl3):18-Me 0.680(s),19-Me 0.929(s),  21-Me 0.973(d),COOMe 3.664(s);13C-NMR(CDCl3):C1 30.08,C2 27.43,C3 66.09,   C4 26.25,C5 43.05,C6 67.85,C7 34.37,C8 34.93,C9 32.33,C10 36.05,C11 28.93 C12 73.04,C13 46.75,C14 48.12,"	"METYL ESTER DERIVATIVE (027) m/e=404, 368, 289, 217(BASE PEAK), 253"		"027/"							
"BA0461"	5.00		"3β,6β,12α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                   (REF:027)"	"            HO  ＼／＼"	"              �ﾂ ｜  ｜"	"            ／＼�ﾇ＼  COOH"	"           ｜ �ｶ�ｽ�ｺ"	"      ／＼�ﾇ＼／"	"     ｜  ｜  ｜"	"    �ﾕ＼／�ﾚ／"	"  HO      H �ﾀ"	"            OH"					"027/"	"1315〜1337C(027)"						"027/"		"1709=O), 3408,1023(OH) (027)"	"METHYL ESTER DERIVATIVE(027):1H-NMR(CDCl3):18-Me 0.686(s),19-Me 1.101(s),  21-Me 0.983(d),COOMe 3.640(s);13C-NMR(CDCl3):C1 29.43,C2 26.50,C3 64.44,   C4 32.24,C5 42.23,C6 71.38,C7 33.42,C8 29.91,C9 32.86,C10 33.48,C11 28.04C12 71.58,C13 45.57,C14 47.05,C"	"METYL ESTER DERIVATIVE (027) m/e=404, 368, 289, 217(BASE PEAK), 253"		"027/"							
"BA0462"	5.00		"3α,7β,12α-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (029)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾊ�ｱ�ﾔ"	"   HO      H   OH"							"029/"	"269〜271ﾟC(029)"						"029/"		"1675(C=O),3500,1025,1000(OH) (029)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.71(s),19-Me 0.79(s),21-Me  0.98(d),COOMe 3.66(s)(029);13C-NMR C1 31.9,C2 28.8,C3 65.7,C4 35.4,C5 36.1,C6   38.2,C7 74.6,C8 43.4,C9 45.1,C10 34.8,C11 28.4,C12 72.1,C13 47.1,C14 47.4,C15 26.2,C16 27.6,C17 45."			"002/029/"							
"BA0463"	5.00		"3α,7α,12β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"             HO  �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (029)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾊ�ｱ�ﾅ"	"   HO      H     OH"							"029/"	"210.5〜212ﾟC(029)"						"029/"		"1700(C=O),3450,1010,995(OH) (029)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.72(s),19-Me 0.79(s),21-Me  1.01(d),COOMe 3.66(s)(029);13C-NMR C1 32.2,C2 28.8,C3 66.2,C4 35.4,C5 31.4,C6 36.4,C7 67.5,C8 38.3,C9 44.8,C10 36.0,C11 29.5,C12 78.9,C13 47.6,C14 48.7,C15 23.0,C16 23.8,C17 57.2,"			"002/029/"							
"BA0464"	5.00		"3α,7β,12β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"             HO  �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (029)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾊ�ｱ�ﾔ"	"   HO      H     OH"							"029/"	"243〜244ﾟC(029)"						"029/"		"1710(C=O),3280,1028,1005(OH) (029)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.74(s),19-Me 0.79(s),21-Me  0.99(d),COOMe 3.65(s)(029);13C-NMR C1 31.5,C2 28.1,C3 64.4,C4 34.8,C5 35.5,C6 38.0,C7 73.4,C8 41.2,C9 50.5,C10 34.5,C11 28.6,C12 78.4,C13 47.6,C14 53.3,C15 25.6,C16 23.0,C17 55.8,"			"002/029/"							
"BA0465"	5.00		"3β,7α,12α-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (029)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾊ�ｱ�ﾅ"	"   HO      H     OH"							"029/"	"236〜238ﾟC(029)"						"029/"		"1705(C=O),3420,1035(OH) (029)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.69(s),19-Me 0.80(s),21-Me  0.98(d),COOMe 3.66(s)(029) 13C-NMR C1 36.6,C2 31.3,C3 71.0,C4 37.7,C5 37.1,C6 36.5,C7 67.7,C8 39.8,C9 39.3,C10 35.1,C11 28.6,C12 72.8,C13 46.5,C14 42.0,C15 23.0,C16 27.3,C17 47.2,"			"002/029/"							
"BA0466"	5.00		"3β,7β,12α-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (029)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾊ�ｱ�ﾔ"	"   HO      H     OH"							"029/"	"252〜254ﾟC(029)"						"029/"		"1680(C=O),3440,1027(OH) (029)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.71(s),19-Me 0.83(s),21-Me  0.98(d),COOMe 3.66(s)(029);13C-NMR C1 36.7,C2 31.3,C3 70.9,C4 37.7,C5 42.1,C6 38.3,C7 74.8,C8 43.5,C9 45.1,C10 34.5,C11 29.0,C12 72.4,C13 47.4,C1447.4,C15 26.2,C16 27.4,C17 46.0,C"			"002/029/"	"ﾋﾄ尿(011)，  ﾋﾄ胆汁(034)"	"011/034/"					
"BA0467"	5.00		"3β,7α,12β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"             HO  �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (029)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾊ�ｱ�ﾅ"	"   HO      H     OH"							"029/"	"242〜243ﾟC(029)"						"029/"		"1675(C=O),3200,1010(OH) (029)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.73(s),19-Me 0.82(s),21-Me 1.01(d),COOMe 3.66(s)(029) 13C-NMR C1 36.6,C2 31.0,C3 70.3,C4 37.3,C5 36.9,C6 36.4,C7 66.8,C8 38.0,C9 44.4,C10 35.2,C11 29.3,C12 78.4,C13 47.3,C1434.5, C11 29.0,C12 72.4,C13 47.4,"			"002/029/"							
"BA0468"	5.00		"3β,7β,12β-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"             HO  �ｲ�ｱ�ｲ"	"             �ﾒ    �ｵ  �ｵ                               (029)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾊ�ｱ�ﾔ"	"   HO      H     OH"							"029/"	"227〜228ﾟC(029)"						"029/"		"1673(C=O),3450,1035,1003(OH) (029)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.76(s),19-Me 0.84(s),21-Me 0.99(d),COOMe 3.66(s)(029);13C-NMR C1 36.4,C2 30.9,C3 70.5,C4 37.1,C5 41.4,C6 37.8,C7 74.3,C8 41.6,C9 50.7,C10 34.4,C11 28.7,C12 78.9,C13 48.1,C1453.3,C15 25.8,C16 23.2,C17 56.1,C"			"002/029/"							
"BA0469"	5.00		"2β,3α,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (006)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"    HO       �ｵ�ｶ�ｽ�ｺ"	"     �ﾒ�ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO      H     OH"							"006/"	"230〜232ﾟC(006)"						"006/"		"1702(C=O),3436,978(OH) (006)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.63(s),19-Me 0.88(s),21-Me 0.93(d),COOMe 3.63(s) 13C-NMR C1 43.14,C2 70.55,C3 76.54,C4 37.26,C5 41.39,C6 33.87,C7 68.33,C8 39.46,C9 27.67,C10 37.16,C11 28.43,C12 72.99,C13 46.44,C14 41.64,C15 23.22,C16 27.6"	"METHYL ESTER-TRIMETHYLSILYL ETHER DERIVATIVE(Me-TMS)  m/z 636,546,456,367  (BASE PEAK),341,243 (006)"		"006/"	"ﾋﾄ羊水(008),ﾋﾄ胃液(030)"	"008/030/"					
"BA0470"	5.00		"3α,4β,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (007)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO    �ﾀH     OH"	"        HO"						"007/"	"150〜152ﾟC(007)"						"007/"		"1703(C=O),3396,1028(OH) (007)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.65(s),19-Me 0.90(s),21-Me 0.95(d),COOMe 3.64(s) 13C-NMR C1 34.6,C2 28.1,C3 76.0,C4 75.3,C5 47.9,C6   27.5,C7 68.5,C8 39.2,C9 28.1,C10 36.8,C11 28.1,C12 73.0,C13 46.4,C14 41.6,C15 23.1,C16 27.5,C17 47.0,C18"	"METHYL ESTER DERIVATIVE  m/z 402,384,287,269(BASE PEAK),242,127 (007)"		"007/"	"ﾋﾄ胆汁(024,025),ﾋﾄ羊水(008)"	"008/024/025/"					
"BA0471"	5.00		"3β,4β,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (007)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾕ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO    �ﾀH     OH"	"        HO"						"007/"	"148〜149ﾟC(007)"						"007/"		"1708(C=O),3385,1023(OH) (007)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.68(s),19-Me 0.93(s),21-Me 0.95(d),COOMe 3.64(s) 13C-NMR C1 29.2,C2 25.6,C3 69.7,C4 71.1,C5 42.7,C6   28.6,C7 68C15 23.2,C16 27.4,C17 47.2,C18 12.5,C19 22.6,C20 35.2,C21 17.3,C22 31.1,   C23 30.9,C24 174.7,"	"METHYL ESTER DERIVATIVE  m/z 420,402,384,287(BASE PEAK),269,260,127 (007)"		"007/"							
"BA0472"	5.00		"3α,6β,7α,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (031)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ�ﾅ"	"   HO    �ﾀH     OH"	"        HO"						"031/"	"154〜157ﾟC(031)"						"031/"		"1703(C=O),3538,1014,986,952(OH)(031)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.72(s),19-Me 1.06(s),21-Me 0.98(d),COOMe 3.67(s) 13C-NMR C1 35.7,C2 29.9,C3 71.4,C4 35.9,C5 47.4,C6   76.0,C7 73.2,C8 35.3,C9 26.6,C10 34.5,C11 27.7,C12 73.2,C13 46.4,C14 41.1,C15 23.3,C16 27.5,C17 47.0,C18"	"METHYL ESTER DERIVATIVE m/z 402,384,366,305,287,269,260,251 (031)"		"031/"	"ﾋﾄ尿(021/032/033)，ﾋﾄ羊水(033)"	"021/032/033/"					
"BA0473"	5.00		"3α,6α,7β,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (031)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ�ﾔ"	"   HO      H �ﾂ  OH"	"             OH"						"031/"	"148〜151ﾟC(031)"						"031/"		"1708(C=O),3421,1040,952(OH)(031)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.70(s),19-Me 0.95(s),21-Me 0.98(d),COOMe 3.67(s) 13C-NMR C1 35.1,C2 30.9,C3 71.1,C4 29.2,C5 47.7,C6   73.1,C7 75.2,C8 41.8,C9 32.1,C10 34.8,C11 27.8,C12 72.4,C13 47.4,C14 47.4,C15 26.2,C16 27.8,C17 45.9,C18"	"METHYL ESTER DERIVATIVE m/z 402,384,366,305,287,269,251 (031)"		"031/"							
"BA0474"	5.00		"3α,6β,7β,12α-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"             HO  �ｲ�ｱ�ｲ"	"             �ﾃ    �ｵ  �ｵ                               (031)"	"             �ｱ�ｲ�ｫ�ｲ  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       �ｱ�ｲ�ｫ�ｲ�ｱ"	"       �ｵ�ｶ  �ｶ"	"     �ﾄ�ｲ�ｱ�ﾚ�ｱ�ﾔ"	"   HO      H �ﾐ  OH"	"             OH"						"031/"	"234〜236ﾟC(031)"						"031/"		"1716(C=O),3366,1001(OH)(031)"	"METHYL ESTER DERIVATIVE 1H-NMR(CDCl3) 18-Me 0.73(s),19-Me 1.09(s),21-Me 0.99(d),COOMe 3.67(s) 13C-NMR C1 34.6,C2 28.8,C3 69.4,C4 34.6,C5 46.6,C6   74.6,C7 72.0,C8 37.6,C9 31.3,C10 32.4,C11 27.7,C12 70.8,C13 46.0,C14 46.1,C15 25.6,C16 26.8,C17 44.5,C18"	"METHYL ESTER DERIVATIVE m/z 420,402,384,305,287,269,251 (031)"		"031/"	"ﾋﾄ尿(033)，ﾋﾄ羊水(033)"	"033/"					
"BA0475"	5.00		"1α,3α,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                         (REF:035)"	"                 ＼／＼"	"                   �ｵ�ｶ"	"        HO   ／＼�ｫ＼  COOH"	"         �ﾂ  �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"						"035/"										"1H-NMR(CDCl3)δMETHYL ESTER DERIVATIVE:0.76(3H,s,18-CH3),0.90(3H,bd,21-CH3), 1.11(3H,s,19-CH3), 2.5〜3.5(brs), 3.30(bd), 3.68(S,Ome), 3.85(bs) (035)"""	"MS,M/Z(%,INT.):408[M+](6),390[M-18](99),372[M-2x18](100),368[M-2x18-4](40), 357[M-2x18-15](14),300(10),289[M-18-SIDE CHAIN 118](11),280[M-118-C16,17]  (10),271[M-2x18-118](9),262[M-18-118-C-16,17](21),244[M-2x18-118-C-16,17](10)  (035)"		"035/"	"ふくろうねずみ（有袋類の） (035)"	"035/"					
"BA0476"	5.00		"3α,12α,15α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                         (REF:036)"	"             HO  ＼／＼"	"               �ﾂ  �ｵ�ｶ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／    �ﾅ"	"       �ｵ  �ｵ  �ｵ      OH"	"     �ﾄ＼／�ﾚ／"	"   HO      H"						"036/"	"322-325ﾟC(decomp.)(036),265-267ﾟC(METHYL ESTER(037"			"[α]25/D +80.6ﾟ  (METHYL ESTER DERIVATIVE)(037)"			"036/037/"		"3400,1710(COOH) (036)"	"1H-NMR(PYRIDINE)δ: 0.81(3H,s,18-CH3), 0.98(3H,s,19-CH3) (036)     METHYL ESTER DERIVATIVE;1H-NMR(PYRIDINE-d5)δ:0.82(3H,s,18-CH3),0.97(3H,s,  19-CH3), 3.61(3H,s,COOCH3), 3.85(1H,m,3β-H), 4.00-4.30(2H,m,12β- AND 15β-H)  (037)"""	"METHYL ESTER DERIVATIVE : MS,M/Z; 404[M-18], 386[M-2x18], 368[M-3x18],271[M-2x18-SIDE CHAIN S.C.](BASE PEAK), 253[M-3x18-S.C.] (037)"		"036/037/"							
"BA0477"	5.00		"(22R)-3α,7α,22-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                     OH                                    (REF:038)"	"                     �ﾂ"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"					"038/"	"141-142ﾟC  (038)"		"[α]/D:+1.0ﾟ (038)"				"038/"		"3400(OH), 1720(COOH)(038)"	"1H-NMR(PYRIDINE-d5)δ: 0.69(3H,s,18-CH3),0.97(3H,s,19-CH3),1.17(3H,d,J=6Hz,21-CH3),3.4〜4.4(3H,m,3β-,7β-,22-CH-OH); 13C-NMR(CD3OD)δ: C-1 36.5,C-2 31.4,C-3 72.9,C-4 40.6,C-5 43.1,C-6 35.9,C-7 69.1,C-8 40.8,C-9 34.0,C-10 36.1,C-11 21.7,C-12 40.8,C-"	"METHYL ESTER DERIVATIVE,Hi-MS,M/Z:M+, 422.3002(CALCD.FOR C25H42O5=422.3030); M-H2O, 404.2945(CALCD.FOR C25H40O4=404.2925); M-2H2O, 386.2729(CALCD.FOR C25H38O3=386.2818) (038)"		"038/"							
"BA0478"	5.00		"(22S)-3α,7α,22-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"HAEMUCHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                     OH                                  (REF:038)"	"                     �ﾁ"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"					"038/"	"247-250ﾟC  (038)"			"[α]/D : +2.4ﾟ (038)"			"038/"		"3400(OH), 1720(COOH) (038)"	"1H-NMR(PYRIDINE-d5)δ: 0.74(3H,s,18-CH3),0.96(3H,s,19-CH3),1.16(3H,d,J=6Hz,21-CH3),3.4〜4.4(3H,m,3β-,7β-,22-CH-OH); 13C-NMR(CD3OD)δ: C-1 36.6,C-2 31.5,C-3 73.0,C-4 40.6,C-5 43.2,C-6 36.0,C-7 69.2,C-8 40.9,C-9 34.1,C-10 36.2,C-11 21.8,C-12 41.2,C-"	"METHYL ESTER DERIVATIVE,Hi-MS,M/Z:M+, 422.3070(CALCD.FOR C25H42O5=422.3030); M-H2O, 404.2944(CALCD.FOR C25H40O4=404.2925); M-2H2O, 386.2858(CALCD.FOR C25H38O3=386.2818) (038)"		"038/"	"魚類 (039/040)"	"039/040/"					
"BA0479"	5.00						"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                         (REF:041)"	"                         OH"	"                 ＼／＼�ﾄ"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"					"041/"	"110-112ﾟC (METHYL ESTER DERIVATIVE) (041)"		"M/D +34ﾟ (METHYL ESTER DERIVATIVE)(041)"	"[α]23/D +8ﾟ (METHYL ESTER DERIVATIVE)(041)"			"041/"				"METHYL ESTER DERIVATIVE, MS,M/Z(%INT.) : 422[M+](7.6),404[M-18](41.6),386  [M-2x18](100),371[M-15-2x18](40.1), 332[M-18-A環](11.3), 315[M-18-C23-C24] (13.0), 297[M-2x18-C23-C24](23.3), 273[M-18-side Chain S.C.](25.0), 264[M-S.C.-C16-17](31.5), 255[M-2x18213][M-15-2x18-S.C.-C16-C17](24.9),201[M-18-A環-S.C.](12.1)(041)"		"041/"	"ヒト尿(042), アザラシ，トド(043)"	"042/043/"					
"BA0480"	5.00		"(23S)-3α,7α,23-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                         (REF:041)"	"                       OH"	"                 ＼／＼�ﾑ"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"					"041/"	"197-199ﾟC (METHYL ESTER DERIVATIVE) (041)"		"M/D +84ﾟ (METHYL ESTER DERIVATIVE)(041)"	"[α]23/D +20ﾟ (METHYL ESTER DERIVATIVE)(041)"			"041/"				"METHYL ESTER DERIVATIVE, MS,M/Z(%INT.):422[M+](10.8),404[M-18](45.0),386[M-2x18](100),371[M-15-2x18](31.2),332[M-18-A環](8.5),315[M-18-C23-C24](12.2),297[M-2x18-C23-C24](21.8), 273[M-18-SIDE CHAIN S.C.](27.7), 264[M-S.C.-C16-C17](33.1),255[M-2x18-S.C.](3)201[M-18-S.C.-A環](9.5) (041)"		"041/"							
"BA0481"	5.00		"(23R)-3α,7α,12α,23-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                         (REF:041)"	"                         OH"	"             HO  ＼／＼�ﾄ"	"               �ﾂ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"					"041/"	"194-196ﾟC (METHYL ESTER DERIVATIVE) (041)"	"M/D +136(METHYL ESTER DERIVATIVE)(041)"	"[α]23/D +31ﾟ (METHYL ESTER DERIVATIVE)(041)"				"041/"							"ヒト尿(011/013/042/044/045), ヒト血清(044), ヒト胎便(046), アザラシ,トド,ヘビ (043)"	"011/013/042/044/045/046/043/"					
"BA0482"	5.00		"(23S)-3α,7α,12α,23-TETRAHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O6"	24.00	40.00	6.00	0.00	0.00	0.00	424		"                                                         (REF:041)"	"                         OH"	"             HO  ＼／＼�ﾄ"	"               �ﾂ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"					"041/"	"195-197ﾟC (METHYL ESTER DERIVATIVE) (041)"		"M/D +180 (METHYL ESTER DERIVATIVE)(041)"	"[α]23/D +41ﾟ (METHYL ESTER DERIVATIVE)(041)"			"041/"													
"BA0483"	5.00		"7-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O3"	24.00	38.00	3.00	0.00	0.00	0.00	374		"                                                         (REF:047)"		"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"       ＼／�ﾚ／�ｹ"	"           H     O"					"047/"	"150-151ﾟC (049)"						"049/"		"1700-1730cm-1 (047)"	"1H-NMR(CDCl3)δ: 0.67(3H,s,18-CH3), 1.19(3H,s,19-CH3) (047) 13C-NMR(CDCl3)(METHYL ESTER DERIVATIVE) δ: C-1 36.4,C-2 21.6,C-3 26.5,C-4 28.1,C-5 47.6,C-6 45.8,C-7 212.2,C-8 49.5,C-9 42.8,C-10 35.8,C-11 20.6,C-12 39.0,C-13 42.8,C-14 49.0,C-15 24.8,C-16 2"	"MS (METHYL ESTER DERIVATIVE) M/Z : 388[M+], 273, 245(BASE PEAK) (047)"		"047/048/"	"ヒト尿(003)"	"003/"					
"BA0484"	5.00		"12-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O3"	24.00	38.00	3.00	0.00	0.00	0.00	374		"                                                         (REF:047)"		"               O ＼／＼"	"               �ｾ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"       ＼／�ﾚ／"	"           H"					"047/"	"184.5-187ﾟC (047)"						"047/"		"1720,1700cm-1 (047)"	"1H-NMR(CDCl3)δ: 1.12(3H,s,18-CH3), 1.07(3H,s,19-CH3) (047) 13C-NMR(CDCl3)(METHYL ESTER DERIVATIVE) δ: C-1 37.5,C-2 21.0,C-3 26.9,C-4 27.4,C-5 43.1,C-6 26.9,C-7 26.2,C-8 35.8,C-9 44.3,C-10 36.2,C-11 38.1,C-12 214.9,C-13 57.5,C-14 58.7,C-15 24.3,C-16 27"	"MS,M/Z : 374[M+], 273, 233(BASE PEAK) (047)"		"047/048/"	"ヒト尿(003)"	"003/"					
"BA0485"	5.00		"3,7-DIOXO-5β-CHOLAN-24-OIC ACID"				"C24H36O4"	24.00	36.00	4.00	0.00	0.00	0.00	388		"                                                            (REF:049)"		"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ｴ＼／�ﾚ／�ｹ"	"    O      H     O"					"049/"	"145ﾟC (049)"						"049/"			"1H-NMR(CDCl3) (METHYL ESTER DERIVATIVE)δ : 0.70(3H,s,18-CH3), 1.29(3H,s,19-CH3), 0.92(3H,d,J=5Hz,21-CH3),3.63(3H,s,COOCH3) (050)   13C-NMR(CDCl3) (METHYL ESTER DERIVATIVE)δ: C-1 35.4,C-2 36.6,C-3 210.7,C-4 42.9,C-5 47.7,C-6 44.9,C-7 209.7,C-8 49.5,C-9 C-18 12.0,C-19 22.3,C-20 35.1,C-21 18.3,C-22 31.0,C-23 31.0,C-24 174.3,C-25 51.3 (048)"			"050/048/"							
"BA0486"	5.00		"7,12-DIOXO-5β-CHOLAN-24-OIC ACID"				"C24H36O4"	24.00	36.00	4.00	0.00	0.00	0.00	388		"                                                         (REF:047)"		"               O ＼／＼"	"               �ｾ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"       ＼／�ﾚ／�ｹ"	"           H     O"					"047/"	"180-182.5ﾟC (047)"						"047/"		"1720-1710,1700cm-1 (047)"	"1H-NMR(CDCl3)δ: 1.05(3H,s,18-CH3), 1.31(3H,s,19-CH3) (047) 13C-NMR(CDCl3) (METHYL ESTER DERIVATIVE)δ: C-1 36.4,C-2 20.4,C-3 26.2,C-4 28.2,C-5 46.7,C-6 45.8,C-7 209.8,C-8 49.0,C-9 45.6,C-10 36.6,C-11 38.4,C-12 212.8,C-13 56.9,C-14 52.0,C-"	"MS M/Z : 388[M+], 370, 287, 247(BASE PEAK)(047)"		"047/048/"							
"BA0487"	5.00		"3,7,12-TRIOXO-5β-CHOLAN-24-OIC ACID"				"C24H34O5"	24.00	34.00	5.00	0.00	0.00	0.00	402		"                                                         (REF:049)"		"               O ＼／＼"	"               �ｾ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ｴ＼／�ﾚ／�ｹ"	"    O      H     O"					"049/"	"237ﾟC (049)"			"[α]20/D +26ﾟ (049)"			"049/"			"1H-NMR(CDCl3)(METHYL ESTER DERIVATIVE)δ: 1.07(3H,s,18-CH3), 1.39(3H,s,19-CH3),0.84(3H,d,J=5Hz,21-CH3),3.63(3H,s,COOCH3),(050)       13C-NMR(CDCl3)(METHYL ESTER DERIVATIVE)δ: C-1 35.2,C-2 36.4,C-3 208.6,C-442.7,C-5 46.7,C-6 44.9,C-7 208.4,C-8 49.0,C-9 4 C-18 11.7,C-19 21.8,C-20 35.4,C-21 18.5,C-22 31.3,C-23 30.4,C-24 174.3,C-25 51.3 (048)"			"050/048/"							
"BA0488"	5.00		"7β-HYDROXY-3-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                         (REF:051)"		"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ｴ＼／�ﾚ／�ﾔ"	"    O      H     OH"					"051/"	"73-75ﾟC (051)"			"[α]/D +67ﾟ (051)"			"051/"			"1H-NMR(DMSO-d6)δ: 0.65(3H,s,18-CH3), 0.89(3H,d,J=6.3Hz,21-CH3), 0.96(3H,s,19-CH3), 3.28(1H,dt,J1=10.6Hz,J2=4.5Hz,7α-H) (051)"			"051/"							
"BA0489"	5.00		"6α,7α-DIHYDROXY-3-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                                                              (REF:051)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ  �ｵ"	"     �ｴ＼／�ﾚ／�ﾅ"	"    O      H �ﾂ  OH"	"             OH"					"051/"	"195-197ﾟC(051)"			"[α]/D +12ﾟ (051)"			"051/"			"1H-NMR(PYRIDINE-d5)δ: 0.64(3H,s,18-CH3), 0.89(3H,d,J=6.3Hz,21-CH3), 0.94(3H,3H,s,19-CH3),3.61(2H,m,6β- AND 7β-H) (051)"			"051/"							
"BA0490"	5.00		"3α-HYDROXY-7,12-DIOXO-5β-CHOLAN-24-OIC ACID"				"C24H36O5"	24.00	36.00	5.00	0.00	0.00	0.00	404		"                                                              (REF:052)"	"               O ＼／＼"	"               �ｾ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ｹ"	"   HO      H     O"						"052/"	"190-191ﾟC (052)"			"[α]/D +32ﾟ (052)"			"052/"			"1H-NMR(DMSO-d6)δ: 0.98(3H,s,18-CH3), 1.24(3H,s,19-CH3), 0.74(3H,d,J=6.3Hz,21-CH3),3.33(1H,sept,J=10.7 AND 4.6Hz, 3β-H)(052) 13C-NMR(CDCl3)(METHYL ESTER DERIVATIVE)δ:C-1 34.1,C-2 29.6,C-3 70.2,C-437.3,C-5 45.2,C-6 45.4,C-7 209.8,C-8 48.9,C-9 45.5,C-1 C-18 11.8,C-19 22.4,C-20 35.5,C-21 18.6,C-22 31.3,C-23 30.5,C-24 174.6 (053)"	"MS (METHYL ESTER TRIFLUOROACETATE DERIVATIVE:Me-TFA)  M/Z :  245[M-114-155](BASE PEAK), 359[M-155], 496[M-18], 400[M-114], 514[M+] (054)"		"052/053/054/"	"ヒト尿(054)"	"054/"					
"BA0491"	5.00		"3β-HYDROXY-7,12-DIOXO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	36.00	5.00	0.00	0.00	0.00	404		"                                                              (REF:052)"	"               O ＼／＼"	"               �ｾ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾕ＼／�ﾚ／�ｹ"	"   HO      H     O"						"052/"	"270-272ﾟC (052)"			"[α]/D +22ﾟ (052)"			"052/"			"1H-NMR(DMSO-d6)δ: 0.98(3H,s,18-CH3), 1.26(3H,s,19-CH3), 0.74(3H,d,J=6.3Hz,21-CH3),3.79(1H,t,J=3.0Hz, 3α-H)(052)"			"052/"							
"BA0492"	5.00		"7α-HYDROXY-3,12-DIOXO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	36.00	5.00	0.00	0.00	0.00	404		"                                                              (REF:052)"	"               O ＼／＼"	"               �ｾ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ｴ＼／�ﾚ／�ﾅ"	"    O      H     OH"						"052/"	"193-195ﾟC (052)"			"[α]/D +73ﾟ (052)"			"052/"			"1H-NMR(DMSO-d6)δ: 1.00(3H,s,18-CH3), 1.05(3H,s,19-CH3), 0.77(3H,d,J=6.3Hz,  21-CH3),3.78(1H,q,J=3.3Hz, 7β-H)(052) 13C-NMR(CDCl3)(METHYL ESTER-ACETATE DERIVATIVE:Me-Ac) δ:C-1 36.3,C-2 36.5,  C-3 211.1,C-4 44.4,C-5 41.9,C-6 31.1,C-7 70.3,C-8 38.6,C C-16 27.3,C-17 46.3,C-18 11.5,C-19 21.3,C-20 35.5,C-21 18.5,C-22 31.0,C-23 30.4,C-24 174.5(053)"			"052/053/"							
"BA0493"	5.00		"7β-HYDROXY-3,12-DIOXO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	36.00	5.00	0.00	0.00	0.00	404		"                                                              (REF:052)"	"               O ＼／＼"	"               �ｾ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ�ｶ  �ｶ"	"     �ｴ＼／�ﾚ／�ﾔ"	"    O      H     OH"						"052/"	"187-189ﾟC (052)"			"[α]/D +90ﾟ (052)"			"052/"			"1H-NMR(DMSO-d6)δ: 1.01(3H,s,18-CH3), 1.05(3H,s,19-CH3), 0.77(3H,d,J=6.3Hz,21-CH3),3.40(1H,dt,J=10.6 AND 4.5Hz, 7α-H)(052)"	"MS(POSITIVE FAB), M/Z(%INT.): 405[(M+H)+](100), 387(98), 369(30), 353(14), 351(17), 341(21), 323(12), 263(12), 219(9), 145(18), 121(23), 105(35) (052)"		"052/"							
"BA0494"	5.00		"12α-HYDROXY-3,7-DIOXO-5β-CHOLAN-24-OIC ACID"				"C24H38O5"	24.00	36.00	5.00	0.00	0.00	0.00	404		"                                                              (REF:052)"	"              HO ＼／＼"	"               �ﾂ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ｴ＼／�ﾚ／�ｹ"	"    O      H     O"						"052/"	"168-170ﾟC (052)"			"[α]/D -9ﾟ (052)"			"052/"			"1H-NMR(DMSO-d6)δ: 0.63(3H,s,18-CH3), 1.22(3H,s,19-CH3), 0.93(3H,d,J=6.3Hz,21-CH3),3.83(1H,t,J=3.2Hz, 12β-H)(052)"			"052/"							
"BA0495"	5.00		"3β,7α-DIHYDROXYCHOL-4-EN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                              (REF:055)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾕ＼�ｷ＼／�ﾅ"	"   HO            OH"						"055/"	"229-231ﾟC(DEC.) (055)"		"[α]23/D +40.8±0.5ﾟC (055)"				"055/"							"鶏(めん)(055),  ヒト胆汁(056)"	"055/056/"					
"BA0496"	5.00		"(22E)-3α,7α-DIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"	"22-DEHYDROCHENODEOXYCHOLIC ACID"			"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                              (REF:057)"	"                 ＼／�ｹ"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"						"057/"	"OIL (METHYL ESTER DERIVATIVE) (057)"						"057/"		"METHYL ESTER DERIVATIVE: 1650(△22), 1730(COOCH3), 3400(OH) (057)"	"1H-NMR(CDCl3) (METHYL ESTER DERIVATIVE)δ: 0.68(3H,s,18-CH3), 0.95(3H,s,19-CH3), 1.03(3H,d,J=6Hz,21-CH3),3.65(3H,s,COOCH3),3.60(1H,m,3β-H),3.93(1H,m,7β-H),5.82(1H,d,J=15.3Hz,23-H),6.89(1H,dd,J=15.3 AND 7.2Hz,22-H)(057)"""	"MS (METHYL ESTER-TRIMETHYLSILYL ETHER DERIVATIVE:Me-TMS) : M/Z(%INT.) :  458[M-90](4), 443[M-15-90](3), 368[M-2x90](100), 353[M-15-2x90](15),  255[M-2x90-SIDE CHAIN S.C.](32), 243[C-3〜C-7](8) (057)"		"057/"							
"BA0497"	5.00		"(22E)-3α,7β-DIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"	"22-DEHYDROURSODEOXYCHOLIC ACID"			"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                              (REF:057)"	"                 ＼／�ｹ"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ﾔ"	"   HO      H     OH"						"057/"	"229-230ﾟC (057)"						"057/"		"METHYL ESTER DERIVATIVE : 1650(△22), 1730(COOCH3), 3400(OH) (057)"	"1H-NMR(CDCl3) (METHYL ESTER DERIVATIVE)δ: 0.69(3H,s,18-CH3), 0.95(3H,s,19-CH3), 1.06(3H,d,J=6Hz,21-CH3), 3.65(3H,s,COOCH3), 3.75(2H,m,3β- AND 7α-H), 5.85(1H,d,J=15.3Hz, 23-H), 6.95(1H,dd,J=15.3 AND 7.2Hz,22-H) (057)"""	"MS (METHYL ESTER-TRIMETHYLSILYL ETHER DERIVATIVE;Me-THS) : M/Z(%INT.) ; 621[M-15](16),458[M-90](100),443[M-15-90](9),368[M-2x90](26),353[M-15-2x90]   (13),345[M-90-SIDE CHAIN S.C.](8),255[M-2x90-S.C.](49),243(C-3〜C-7,](20)"		"057/"							
"BA0498"	5.00		"(22E)-3α,12α-DIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"	"22-DEHYDRODEOXYCHOLIC ACID"			"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390		"                                                              (REF:057)"	"              HO ＼／�ｹ"	"               �ﾂ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／"	"   HO      H"						"057/"	"98-100ﾟC (METHYL ESTER DERIVATIVE)(057)"						"057/"		"METHYL ESTER DERIVATIVE : 1640(△22), 1720(COOCH3), 3400(OH) (057)"	"1H-NMR(CDCl3) (METHYL ESTER DERIVATIVE) δ: 0.73(3H,s,18-CH3), 0.94(3H,s,19-CH3), 1.23(3H,d,J=6Hz,21-CH3),3.65(3H,s,COOCH3), 3.80(1H,m,3β-H), 4.07(1H,m,12β-H), 5.85(1H,d,J=15.3Hz, 23-H), 6.98(1H,dd,J=15.3 AND 7.2Hz,22-H)"""	"MS (METHYL ESTER-TRIMETHYL SILYL ETHER DERIVATIVE ; Me-TMS) M/Z (% INT.) : 548[M+](13),533[M-15](19),458[M-90](8), 368[M-2x90](11), 353[M-15-2x90](7),345[M-90-SIDE CHAIN S.C.](17), 255[M-2x90-S.C.](100) (057)"		"057/"							
"BA0499"	5.00		"(22E)-3α,7α,12α-TRIHYDROXY-5β-CHOL-22-EN-24-OIC ACID"	"22-DEHYDROCHOLIC ACID"			"C24H38O5"	24.00	38.00	5.00	0.00	0.00	0.00	406		"                                                              (REF:057)"	"              HO ＼／�ｹ"	"               �ﾂ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"						"057/"	"181-183ﾟC (METHYL ESTER DERIVATIVE) (057)"						"057/"		"METHYL ESTER DERIVATIVE : 1650(△22), 1730(COOCH3), 3400(OH) (057)"	"1H-NMR(CDCl3)(METHYL ESTER DERIVATIVE) δ: 0.78(3H,s,18-CH3), 0.97(3H,s,19-CH3), 1.28(3H,d,J=6Hz,21-CH3), 3.65(3H,s,COOCH3) 3.60(1H,m,3β-H), 3.98(1H,m,7β-H),4.09(1H,m,12β-H), 5.82(1H,d,J=15.3Hz,23-H),6.95(1H,dd,J=15.3 AND7.2Hz,22-H) (057)"""	"MS (METHYL ESTER TRIMETHYLSILYL ETHER DERIVATIVE:Me-TMS) M/Z(%INT.) : 636  [M+](4),621[M-15](7),546[M-90](14),531[M-15-90](5),456[M-2x90](39),441[M-15-2x90](7),366[M-3x90](32),351[M-15-3x90](20),433[M-90-SIDE CHAIN(S.C.)](4),343[M-2x90-S.C.](24),253[M-3x"		"057/"	"ヒト胆汁(058)"	"058/"					
"BA0500"	5.00		"3-OXOCHOL-4-EN-24-OIC ACID"				"C24H36O3"	24.00	36.00	3.00	0.00	0.00	0.00	372		"                                                              (REF:059)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ｴ＼�ｷ＼／"	"    O"						"059/"	"184-186ﾟC (059)"						"059/"	"UV(METHYL ESTER DERIVATIVE) λmax =240(16500)nm (060)"	"METHYL ESTER DERIVATIVE : 3030, 1745, 1680, 1620cm-1 (060)"	"1H-NMR(CDCl3)δ: 0.72(3H,s,18-CH3), 0.94(3H,d,J=6Hz,21-CH3), 1.19(3H,s,19-CH3), 5.74(1H,s,4-H)(059), 13C-NMR(CDCl3)(METHYL ESTER DERIVATIVE)δ: C-1 35.7,C-2 33.9,C-3 199.4,C-4 123.8,C-5 171.4,C-6 32.9,C-7 32.0,C-8 35.7,C-9 53.7,C-10 38.6,C-11 21.0, C-23 31.0,C-24 174.6,C-25 51.4(060)"	"MS (METHYL ESTER DERIVATIVE) M/Z(%INT.) : 386[M+](17),271(3),263(6),244(5),229(26),124(100) (060)"		"060/059/"	"ヒト糞便(061)"	"061/"					
"BA0501"	5.00		"7α-HYDROXY-3-OXOCHOL-4-EN-24-OIC ACID"				"C24H36O4"	24.00	36.00	4.00	0.00	0.00	0.00	388		"                                                              (REF:009)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ｴ＼�ｷ＼／�ﾅ"	"    O            OH"						"009/"	"227-229ﾟC (009)"						"009/"	"UVλmax (ε) : 242(15900)nm (009)"	"1718(C=O),1630(4-ENE),3500(OH) (009)"	"1H-NMR(CDCl3+20%DMSO-d6)δ: 0.71(3H,s,18-CH3), 0.93(3H,d,J=5.4Hz,21-CH3),  1.19(3H,s,19-CH3), 3.91(1H,m,7β-H),5.70(1H,s,4-H)(009)"""			"009/"	"ヒト尿(062)"	"062/"					
"BA0502"	5.00		"7α,12α-DIHYDROXY-3-OXOCHOL-4-EN-24-OIC ACID"				"C24H36O5"	24.00	36.00	5.00	0.00	0.00	0.00	404		"                                                              (REF:015)"	"             HO  ＼／＼"	"               �ﾂ  �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ｴ＼�ｷ＼／�ﾅ"	"    O            OH"						"015/"	"235-237ﾟC (015)"						"015/"	"UVλmax (ε) : 244(18000)nm (015)"	"1708(C=O), 1620(4-ENE)(015)"	"1H-NMR(CDCl3+20%DMSO-d6)δ: 0.72(3H,s,18-CH3), 0.99(3H,d,J=5.4Hz,21-CH3), 1.17(3H,s,19-CH3), 3.93(2H,m,7β- AND 12β-H),5.72(1H,s,4-H) (015)"""			"015/"	"ヒト尿(062), ヒト胃液(030)"	"030/062/"					
"BA0503"	5.00		"3-OXOCHOLA-4,6-DIEN-24-OIC ACID"				"C24H34O3"	24.00	34.00	3.00	0.00	0.00	0.00	370		"                                                              (REF:009)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ｴ＼�ｷ＼�ｷ"	"    O"						"009/"	"197-198ﾟC (009)"						"009/"	"UVλmax (ε) : 284(30500)nm (009)"	"1710(C=O), 1628, 1608,(4,6-DIENE)(009)"	"1H-NMR(CDCl3)δ: 0.77(3H,s,18-CH3), 0.95(3H,d,J=5.4Hz,21-CH3), 1.11(3H,s,19-CH3), 5.69(1H,s,4-H), 6.12(2H,s,6- AND 7-H) (009)"			"009/"	"ヒト尿(062)"	"062/"					
"BA0504"	5.00		"3β-HYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376		"                                                              (REF:063)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾕ＼／�ﾊ／"	"   HO      H"						"063/"	"208-211ﾟC (063)"			"[α]/D +33.3ﾟ (063)"			"063/"		"1705(C=O)(063)"	"1H-NMR(CDCl3-CH3OH)δ:0.69(3H,s,18-CH3), 0.81(3H,s,19-CH3), 0.95(3H,d,J=6Hz,21-CH3), 3.20〜3.75(1H,m,3α-H)(063)"	"MS M/Z: 376[M+](063)"		"063/"	"ヒト糞便(010), ヒト血清(064)"	"010/064/"					
"BA0505"	5.00		"3α,6α,7α-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"ALLOHYOCHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                              (REF:065)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H �ﾂ  OH"	"             OH"					"065/"	"272-273ﾟC (065)"			"[α]25/D +30ﾟ(065)"			"065/"		"3367, 3257, 1709(COOH), 1163, 1095, 1048, 1010, 962 (065)"		"MS (METHYL ESTER DERIVATIVE) M/Z : 422[M+], 407[M-15], 404[M-18], 389[M-15-18], 386[M-2x18], 373[M-18-31], 371[M-15-2x18], 368[M-3x18],355[M-31-2x18],353[M-15-3x18], 337[M-31-3x18], 289[M-18-115(SIDE CHAIN)], 271[M-2x18-115],253[M-3x18-115] (065)"		"065/"							
"BA0506"	5.00		"3α,6β,7α-TRIHYDROXY-5α-CHOLAN-24-OIC ACID"	"ALLO-α-MURICHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                              (REF:065)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H �ﾐ  OH"	"             OH"					"065/"	"261-262ﾟC (065)"			"[α]25/D  0ﾟ(065)"			"065/"		"3444, 1704(COOH), 1307, 1266, 1166, 1104, 1047, 1000(3α-OH-5α-) (065)"		"MS(METHYL ESTER DERIVATIVE) : M/Z  422[M+], 407[M-15], 404[M-18], 389[M-15-18], 386[M-2x18], 373[M-18-31], 371[M-15-2x18], 368[M-3x18],355[M-31-2x18],353[M-15-3x18], 337[M-31-3x18], 289[M-18-115(SIDE CHAIN)], 271[M-2x18-115],253[M-3x18-115] (065)"		"065/"							
"BA0507"	5.00		"3α,6α,7β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"ALLO-ω-MURICHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                              (REF:065)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾊ／�ﾔ"	"   HO      H �ﾂ  OH"	"             OH"					"065/"	"192-193ﾟC (AS METHYL ESTER DERIVATIVE) (065)"			"[α]25/D +19.9ﾟ (AS METHYL ESTER DERIVATIVE) (065)"			"065/"		"METHYL ESTER DERIVATIVE : 3448, 3279, 1739(COOCH3), 1227, 1170, 1038, 1006 (3α-OH-5α), 965, 896 (065)"		"MS (METHYL ESTER DERIVATIVE) : M/Z 422[M+], 407[M-15], 404[M-18], 389[M-15-18], 386[M-2x18], 373[M-18-31], 371[M-15-2x18], 368[M-3x18],355[M-31-2x18],353[M-15-3x18], 337[M-31-3x18], 289[M-18-115(SIDE CHAIN)], 271[M-2x18x115],253[M-3x18-115] (065)"		"065/"							
"BA0508"	5.00		"3α,6β,7β-TRIHYDROXY-5β-CHOLAN-24-OIC ACID"	"ALLO-β-MURICHOLIC ACID"			"C24H40O5"	24.00	40.00	5.00	0.00	0.00	0.00	408		"                                                              (REF:065)"	"                 ＼／＼"	"                   �ｵ  �ｵ"	"             ／＼�ｫ＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾊ／�ﾔ"	"   HO      H �ﾐ  OH"	"             OH"					"065/"	"253-255ﾟC  (065)"						"065/"		"3425(OH), 3300, 1672(COOH), 1160, 1085, 1036, 1011, 972, 939, 897 (065)"		"MS(METHYL ESTER DERIVATIVE)  : M/Z 422[M+], 407[M-15], 404[M-18], 389[M-15-18], 386[M-2x18], 373[M-18-31], 371[M-15-2x18], 368[M-3x18],355[M-31-2x18],353[M-15-3x18], 337[M-31-3x18], 289[M-18-115(SIDE CHAIN)], 271[M-2x18-115],253[M-3x18-115] (065)"		"065/"							
"BA0509"	5.00		"3α-HYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"24-NORLITHOCHOLIC ACID"			"C23H38O3"	23.00	38.00	3.00	0.00	0.00	0.00	362		"                                                              (REF:066)"	"                 ＼／＼"	"                   �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／"	"   HO      H"						"066/"	"183.5-184.5ﾟC  (066)"						"066/"			"1H-NMR(CDCl3 +10%DMSO-d6)δ:0.71(3H,s,18-CH3),0.93(3H,s,19-CH3),0.99(3H,d, J=6.0Hz,21-CH3),3.53(1H,m,3β-H),(066) 13C-NMR(Cl3CD):METHYL ESTER DERIVATIVE δ : C-1 35.2,C-2 30.4,C-3 71.6,   C-4 36.3,C-5 42.0,C-6 27.1,C-7 26.3,C-8 35.7,C-9 40.3,C-10 34 C-17 56.0,C-18 12.0,C-19 23.3,C-20 33.7,C-21 19.4,C-22 41.4, C-23 174.0,C-24 51.3 (066)"	"MS M/Z(% INT.):362[M+](0.4), 344[M-18](13), 329[M-15-18](5), 302[M-60](1.5), 248[M-SIDE CHAIN-C16〜C17](1.4), 230(4), 215(28), 41(100) (067)"		"066/067/"							
"BA0510"	5.00		"3β-HYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"				"C23H38O3"	23.00	38.00	3.00	0.00	0.00	0.00	362		"                                                              (REF:067)"	"                 ＼／＼"	"                   �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾕ＼／�ﾚ／"	"   HO      H"						"067/"	"178-179ﾟC  (067)"						"067/"			"1H-NMR(METYL ESTER DERIVATIVE)(CDCl3)δ:0.69(3H,s,18-CH3),0.97(3H,s,19-CH3) ,0.97(3H,d,21-CH3),2.40(2H,d,J=10Hz,22-CH2),3.66(3H,s,COOCH3),4.10(1H,bs,  3α-H),(067)13C-NMR(METHYL ESTER DERIVATIVE)(CDCl3)δ : C-1 30.03,C-2 28.35,C-3 67.24, C-4 33.66,C-5 C-10 35.23,C-11 21.17,C-12 40.22,C-13 42.96,C-14 56.75,C-15    24.26,C-16 28.35,C-17 56.29,C-18 12.17,C-19 23.96,C-20 33.88,C-21 19.60,   C-22 41.55,C-23 174.14,CH30- 51.38 (067)"	"MS M/Z(%INT.) : 362[M+](4), 347[M-15](4), 344[M-18](16), 329[M-15-18](18), 248(4), 233(13), 230(2), 215(19),41(100) (067)"		"067/"							
"BA0511"	5.00		"3α,6α-DIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"24-NORHYODEOXYCHOLIC ACID"			"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                              (REF:066)"	"                 ＼／＼"	"                   �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／"	"   HO      H �ﾂ"	"             OH"					"066/"	"218-219.5ﾟC  (066)"						"066/"			"1H-NMR(CDCl3 +10% DMSO-d6)δ: 0.67(3H,s,18-CH3),0.89(3H,s,19-CH3),1.00(3H, d,J=5.8Hz,21-CH3),3.51(1H,m,3β-H),3.97(1H,m,W1/2=24Hz,6β-H)(066)      13C-NMR(CDCl3)METHYL ESTER DERIVATIVE δ ; C-1 35.6,C-2 29.9,C-3 71.3,C-4   29.2,C-5 48.4,C-6 67.8, C-7 3 C-18 12.0,C-19 23.5,C-20 33.7,C-21 19.4,C-22 41.3,C-23 173.9,CH3 51.3 (066)"			"066/"							
"BA0512"	5.00		"3α,7α-DIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"24-NORCHENODEOXYCHOLIC ACID"			"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                              (REF:066)"	"                 ＼／＼"	"                   �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"						"066/"	"204-205ﾟC  (066)"						"066/"			"1H-NMR(CDCl3 +10% DMSO-d6)δ: 0.69(3H,s,18-CH3),0.88(3H,s,19-CH3),0.98(3H, d,J=6.0Hz,21-CH3),3.32(1H,m,3β-H),3.73(1H,bs,7β-H)(066)  13C-NMR(Cl3CD) METHYL ESTER DERIVATIVE δ: C-1 35.2,C-2 30.5,C-3 71.8,C-4 39.4,C-5 41.3,C-6 34.6,C-7 68.3,C-8 39.3,C-C-18 11.7,C-19 22.7,C-20 33.7,C-21 19.4,C-22 41.3,C-23 174.0,  CH3 51.2 (066)"	"MS(Me-TMS)M/Z(%INT.):431[M-90-15](2.7), 415[M-90-31](4.3), 356[M-2x90](100), 341[M-2x90-15](23.9), 325[M-2x90-31](9.3), 255[M-2x90-SIDE CHAIN](12.4) (058)"		"066/058/"	"ヒト胆汁(058)"	"058/"					
"BA0513"	5.00		"3α,7β-DIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"24-NORURSODEOXYCHOLIC ACID"			"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                              (REF:066)"	"                 ＼／＼"	"                   �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ﾔ"	"   HO      H     OH"						"066/"	"248-250ﾟC (066)"						"066/"			"1H-NMR(CDCl3 +10% DMSO-d6)δ: 0.70(3H,s,18-CH3),0.93(3H,s,19-CH3), 0.98(3H,d,J=5.5Hz,21-CH3),3.41(2H,m,3β-AND 7α-H),(066) 13C-NMR(CDCl3)METHYL ESTER DERIVATIVE δ:C-1 34.7,C-2 30.1,C-3 71.0,C-4 37.1,C-6 36.9,C-7 71.0,C-8 43.5,C-9 39.0,C-10 33.9, C-20 33.5,C-21 19.5,C-22 41.3,C-23 173.8,CH3 51.2 (066)"	"MS (METYL ESTER DEIVATIVE),M/Z(%INT):392.2925(calc.392.2926[M+](3)),374[M-18](25),359[M-18-15](16),356[M-2x18](55),341[M-2x18-15](50),302[M-2x18-54](20),283[M-2x18-CH2COOCH3](56),273[M-101(SIDE CHAIN)-18](19),264[M-101-27](27"		"066/"	"ヒト胆汁(058), ヒト尿(045)"	"058/045/"					
"BA0514"	5.00		"3α,12α-DIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"24-NORDEOXYCHOLIC ACID"			"C23H38O4"	23.00	38.00	4.00	0.00	0.00	0.00	378		"                                                              (REF:066)"	"             HO  ＼／＼"	"               �ﾂ  �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／"	"   HO      H"						"066/"	"212-213.5ﾟC  (066)"						"066/"			"1H-NMR(CDCl3 +10% DMSO-d6)δ: 0.69(3H,s,18-CH3),0.89(3H,s,19-CH3),1.03(3H, d,J=3.0Hz,21-CH3),3.50(1H,m,3β-H),3.90(1H,bs,12β-H)(066)              13C-NMR(CDCl3) METHYL ESTER DERIVATIVEδ: C-1 35.1,C-2 30.3,C-3 71.5,C-4 36.3,C-5 41.9,C-6 27.0,C-7 26.0  C-18 12.6,C-19 23.0,C-20 33.5,C-21 18.4,C-22 41.2,C-23 173.9,  CH3 51.3 (066)"			"066/"							
"BA0515"	5.00		"3α,7α,12α-TRIHYDROXY-24-NOR-5β-CHOLAN-23-OIC ACID"	"24-NORCHOLIC ACID"			"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                              (REF:066)"	"             HO  ＼／＼"	"               �ﾂ  �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"						"066/"	"188-190ﾟC(066), 195-200ﾟC  (068)"						"066/068/"		"3550,3350,2650,1710,1385,1370,1225, 945, 915 cm-1(068)"	"1H-NMR(CDCl3 +10% DMSO-d6)δ: 0.70(3H,s,18-CH3), 0.87(3H,s,19-CH3), 1.06 (3H,bs,W1/2=6Hz,21-CH3),3.32(1H,m,3β-H),3.75(1H,bs,7β-H),3.87(1H,bs,     12β-H)(066)13C-NMR(CDCl3)METHYL ESTER DERIVATIVE δ:C-1 35.2,C-2 30.0,C-3 71.6,C-4 39.3,C-5 41 C-11 27.9,C-12 72.8,C-13 46.3,C-14 41.3,C-15 23.1,C-16 27.5,   C-17 46.9, C-18 12.3,C-19 22.3,C-20 33.6,C-21 18.4,C-22 41.2,C-23 174.0,   CH3 51.3 (066)"	"MS (METHYL ESTER-TRIMETHYL SILYL ETHER:Me-TMS) M/Z(%INT.): 609[M-15](3.8), 444[M-2x90](62.5),429[M-2x90-15](16.2),413[M-2x90-31](7.5),354[M-3x90](100),343[M-2x90-SIDE CHAIN(S.C.)](35.8),339[M-3x90-15](27.0),253[M-3x90-S.C.](77.7) (058)"		"066/058/"	"ヒト胆汁(058), ヒト尿(011〜014/020/042/044/045/071), ヒト胃液(030), ヒト胎便(046)"	"058/011/012/013/014/020/042/044/045/071/030/046/"					
"BA0516"	5.00		"12α-HYDROXY-3-OXO-24-NOR-5β-CHOLAN-23-OIC ACID"				"C23H36O4"	23.00	36.00	4.00	0.00	0.00	0.00	376		"                                                              (REF:051)"	"             HO  ＼／＼"	"               �ﾂ  �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ｴ＼／�ﾚ／"	"   HO      H"						"051/"	"216-218ﾟC (051)"			"[α]/D +56ﾟ(051)"			"051/"			"1H-NMR(DMSO-d6)δ: 0.66(3H,s,18-CH3), 0.94(3H,s,19-CH3), 0.97(3H,d,J=6.7Hz, 21-CH3), 3.81(1H,t,J=2.8Hz,12β-H)(051)"			"051/"							
"BA0517"	5.00		"3α,7α,12α-TRIHYDROXY-24-NOR-5α-CHOLAN-23-OIC ACID"	"24-NOR-5α-CHOLIC ACID, ALLONORCHOLIC ACID"			"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                              (REF:068)"	"             HO  ＼／＼"	"               �ﾂ  �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾊ／�ﾅ"	"   HO      H     OH"						"068/"	"248-250ﾟC (068)"			"[α]/D +25.6ﾟ(068)"			"068/"		"3465-3365,2924,1704,1272,1202,1190,1165,1125,1066,1035,958,944,930,892cm-1 (068)"	"1H-NMR(CDCl3) METHYL ESTER δ: 0.72(3H,s,18-CH3), 0.76(3H,s,19-CH3), 1.02 (3H,d,J=4Hz, 21-CH3), 2.75-2.50(3H,m,-OH), 3.66(3H,s,COOCH3), 4.16-3.50    (3H,m,3β,7β-,12β-H) (068)"""	"MS (METHYL ESTER DERIVATIVE) M/Z (%INT.) : 408[M+](10.4),390[M-18](6),372[M-2x18](71), 354[M-3x18](19), 335[M-73](4), 317[M-18-73](11), 299[M-2x18-73](25), 289[M-18-101](14), 271[M-2x18-101](100), 253[M-3x18-101](49), 247(43)"		"068/"	"ヒト胆汁(058/069), ヒト尿(069/071)"	"058/069/071/"					
"BA0518"	5.00		"3β,7α,12α-TRIHYDROXY-24-NOR-5α-CHOLAN-23-OIC ACID"				"C23H38O5"	23.00	38.00	5.00	0.00	0.00	0.00	394		"                                                              (REF:068)"	"             HO  ＼／＼"	"               �ﾂ  �ｵ  COOH"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾕ＼／�ﾊ／�ﾅ"	"   HO      H     OH"						"068/"	"235-237ﾟC (068)"			"[α]/D +27.60ﾟ (068)"			"068/"		"3490-3370,2925,1700,1272,1260,1240,1188,1160,1088,1035,958,944,925,892cm-1 (068)"	"1H-NMR(CDCl3) METHYL ESTER δ: 0.73(3H,s,18-CH3), 0.80(3H,s,19-CH3), 1.02 (3H,d,J=4Hz,21-CH3), 3.66(3H,s,COOCH3), 4.00-3.50(3H,m,3α,7β,12β-H)(068)"""	"MS (METHYL ESTER DERIVATIVE) M/Z (%INT.): 408[M+], 390[M-18](5),372[M-2x18](63), 354[M-3x18](3), 335[M-73](4), 317[M-18-73](13), 299[M-2x18-73](29),  289[M-18-101](22), 271[M-2x18-101](100), 253[M-3x18-101](20), 247(36) (068)"		"068/"							
"BA0519"	5.00		"(20S)-3α-HYDROXY-23,24-BISNOR-5β-CHOLAN-22-OIC ACID"				"C22H36O3"	22.00	36.00	3.00	0.00	0.00	0.00	348		"                     COOH                                     (REF:067)"	"                 �ﾅ／"	"                   �ﾁ"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／"	"   HO      H"						"067/"	"160-162ﾟC (METHYL ESTER DERIVATIVE) (067)"						"067/"				"MS(20eV)(METHYL ESTER DERIVATIVE) M/Z (%INT.): 362[M+](2),344[M-18](70),329[M-15-18](25),312[M-18-CH3OH](3),297[M-15-18-CH3OH](4),290[M- C-1〜C-4ﾌﾗｸﾞﾒﾝﾄ](19),257[M-18-SIDE CHAIN S.C.](10),248[M-S.C.- C-16〜C-17ﾌﾗｸﾞﾒﾝﾄ](9)"		"067/"	"ヒト胎便(070)"	"070/"					
"BA0520"	5.00		"(20S)-3β-HYDROXY-23,24-BISNOR-5β-CHOLAN-22-OIC ACID"				"C22H36O3"	22.00	36.00	3.00	0.00	0.00	0.00	348		"                     COOH                                       (REF:067)"	"                 �ﾅ／"	"                   �ﾁ"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾕ＼／�ﾚ／"	"   HO      H"						"067/"	"120-122ﾟC (METHYL ESTER DERIVATIVE) (067)"						"067/"				"MS(20eV)(METHYL ESTER DERIVATIVE) M/Z (%INT.): 362[M+](20), 347[M-15](21), 344[M-18](95), 329[M-15-18](29), 312[M-18-CH3OH](2), 297[M-15-18-CH3OH](5),290[M-A環の一部](16), 285[M-15-18-COOCH3](6), 257[M-18-SIDE CHAIN S.C.](7),248[M-S.C.-C-16〜C-17ﾌﾗｸﾞﾒﾝﾄ]"		"067/"							
"BA0521"	5.00		"3α,12α-DIHYDROXY-7-OXO-23,24-DINOR-5β-CHOLAN-22-OIC ACID"				"C22H34O5"	22.00	34.00	5.00	0.00	0.00	0.00	378		"                     COOH                                     (REF:071)"	"             HO  ＼／"	"               �ﾂ  �ｵ"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ｹ"	"   HO      H     O"						"071/"	"199-200ﾟC (071)"						"071/"			"1H-NMR(C5H5N-d5)δ:0.78(3H,s,18-CH3),1.06(3H,s,19-CH3),1.15(3H,d,J=6Hz,21-CH3),3.69(1H,m,3β-H),4.13(1H,m,12β-H) (071)"			"071/"	"ヒト尿(071)"	"071/"					
"BA0522"	5.00		"3α,7α-DIHYDROXY-12-OXO-23,24-DINOR-5β-CHOLAN-22-OIC ACID"				"C22H34O3"	22.00	34.00	5.00	0.00	0.00	0.00	378		"                     COOH                                     (REF:071)"	"               O ＼／"	"               �ｾ  �ｵ"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／�ﾅ"	"   HO      H     OH"						"071/"	"262ﾟC (071)"						"071/"			"1H-NMR(C5H5N-d5)δ: 1.04(3H,s,18-CH3), 1.09(3H,s,19-CH3), 1.13(3H,d,J=6Hz, 21-CH3), 3.88(1H,m,3β-H), 4.01(1H,m,7β-H) (071)"			"071/"	"ヒト尿(071)"	"071/"					
"BA0523"	5.00		"3α-HYDROXY-5β-PREGNAN-21-OIC ACID"				"C21H34O3"	21.00	34.00	3.00	0.00	0.00	0.00	334		"                     COOH                                     (REF:067)"	"                   ／"	"                   �ｵ"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾄ＼／�ﾚ／"	"   HO      H"						"067/"	"217-218ﾟC (067)"						"067/"				"MS(20eV)(ETHYL ESTER DERIVATIVE) M/Z(% INT.):  362[M+](2),344[M-18](100), 329[M-15-18](61), 317[M-C2H5O](4), 316[M-C2H5OH](4),298[M-18-C2H5OH](4), 290[M-C-1〜C-4ﾌﾗｸﾞﾒﾝﾄ](12), 283[M-15-18-C2H5OH](5), 256[M-18-SIDE CHAIN (S.C.)-1](9), 248[M-S.C.-C-16〜C"		"067/"							
"BA0524"	5.00		"3β-HYDROXY-5β-PREGNAN-21-OIC ACID"				"C21H34O3"	21.00	34.00	3.00	0.00	0.00	0.00	334		"                     COOH                                     (REF:067)"	"                   ／"	"                   �ｵ"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾕ＼／�ﾚ／"	"   HO      H"						"067/"	"217.5-219ﾟC (067)"						"067/"													
"BA0525"	5.00		"3β-HYDROXYPREGN-5-EN-21-OIC ACID"				"C21H32O3"	21.00	32.00	3.00	0.00	0.00	0.00	332		"                     COOH                                     (REF:070)"	"                   ／"	"                   �ｵ"	"             ／＼�ｫ＼"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／"	"       �ｵ  �ｵ�ｶ"	"     �ﾕ＼／�ｸ／"	"   HO"						"070/"	"110-114ﾟC (METHYL ESTER DERIVATIVE)(070)"						"070/"			"1H-NMR(CDCl3)(METHYL ESTER DERIVATIVE)δ: 0.62(3H,s,18-CH3), 1.02(3H,s,19-CH3), 2.30(2H,bd,20-CH2), 3.50(1H,m,3α-H), 3.66(3H,s,COOCH3), 5.36(1H,bd,J=4Hz,6-H) (070)"""			"070/"	"ヒト胎便(070)"	"070/"					
"BA0526"	5.00		"N-[(3α,5β,7β)-3,7-DIHYDROXY-24-OXOCHOLAN-24-YL]-4-TRANS-METHOXY-L-PROLINE"				"C30H49O6N"	30.00	49.00	6.00	1.00	0.00	0.00	519		"                                                          (REF:   )"	"                     ＼／＼"	"                       �ﾓH �ｵ"	"                 ／＼�ｫ＼  C=O"	"               �ｶ  �ｶ�ｽ�ｺ  |"	"           ／＼�ｫ＼／�ﾅ    N    COOH"	"           �ｵ�ｶ  �ｶ    H ／  ＼�ﾑ"	"         �ﾕ�ﾊ／�ﾚ／�ﾗ  �ｶ�ｽ�ｽ�ｺ�ﾅ"	"        H  OH  H  HO H   �ﾗ      H"	"                         H OMe"						"118-124ﾟC(214)"		"[α]20/=+17.3ﾟ(MeOH)(214)"			"30μM(WATER)(214)"	"214/"		"(NUJOL) 3360, 1719, 1625cm-1(214)"	"1H-NMR(CDCl3)  0.67(s,3H), 0.85(s,3H), 0.9(d,3H), 0.8-2.4(COMPLEX PATTERN,30H), 3.5(s,3H), 3.68(m,1H), 4.0(b,2H), 4.47(t,1H)(214)"		"CMC:29mM,   PKa:3.5 (214)"	"214/"					"New Bile Acids Amidated with Cyclic Amino Acids(214)"	"214/"	
"BA0527"	5.00		"N-[(3α,5β,6α,7α)-3,6,7-TRIHYDROXY-24-OXOCHOLAN-24-YL]-L-PROLINE"				"C29H47O6N"	29.00	47.00	6.00	1.00	0.00	0.00	505		"                                                          (REF:   )"	"                     ＼／＼"	"                       �ﾓH �ｵ"	"                 ／＼�ｫ＼  C=O"	"               �ｶ  �ｶ�ｽ�ｺ  |"	"           ／＼�ｫ＼／�ﾅ    N    COOH"	"           �ｵ�ｶ  �ｶ    H ／  ＼�ﾑ"	"         �ﾕ�ﾊ／�ﾚ／�ﾗ  �ｶ�ｽ�ｽ�ｺ�ﾅ"	"        H  OH  H �ﾗOH H          H"	"                 H OH"						"218-222ﾟC(214)"		"[α]20/=-18.1ﾟ(MeOH)(214)"			"60μM(WATER)(214)"	"214/"		"(NUJOL) 3360, 1715, 1630cm-1(214)"	"1H-NMR(CDCl3)  0.69(s,3H), 0.95(s,3H), 1.03(d,3H), 0.9-2.5(COMPLEX PATTERN,27H), 3.0(m,2H), 3.72(m,6H), 4.6(t,1H), 5.1(b,1H)(214)"		"CMC:30mM,   PKa:3.9 (214)"	"214/"					"New Bile Acids Amidated with Cyclic Amino Acids(214)"	"214/"	
"BA0528"	5.00		"N-[(3α,5β,6α)-3,6-DIHYDROXY-24-OXOCHOLAN-24-YL]-L-PROLINE"				"C29H47O5N"	29.00	47.00	5.00	1.00	0.00	0.00	489		"                                                          (REF:   )"	"                     ＼／＼"	"                       �ﾓH �ｵ"	"                 ／＼�ｫ＼  C=O"	"               �ｶ  �ｶ�ｽ�ｺ  |"	"           ／＼�ｫ＼／�ﾅ    N    COOH"	"           �ｵ�ｶ  �ｶ    H ／  ＼�ﾑ"	"         �ﾕ�ﾊ／�ﾚ／    �ｶ�ｽ�ｽ�ｺ�ﾅ"	"        H  OH  H �ﾗ              H"	"                 H OH"						"203-209ﾟC(214)"		"[α]20/=-13.9ﾟ(MeOH)(214)"			"52μM(WATER)(214)"	"214/"		"(NUJOL) 3360, 1719, 1625cm-1(214)"	"1H-NMR(CDCl3)  0.60(s,3H), 0.85(s,3H), 0.95(d,3H), 1.03(d,3H), 0.8-2.4(COMPLEX PATTERN,29H), 3.3(t,1H), 3.5(m,2H), 3.8(m,2H), 4.1(b,2H)(214)"		"CMC:25mM,   PKa:3.9 (214)"	"214/"					"New Bile Acids Amidated with Cyclic Amino Acids(214)"	"214/"	
"BA0529"	5.00		"2-(R)-[2-[3α-HYDROXY-12α-(2-(S)-METHYL-1-OXOBUTOXY)-5β-ANDROSTAN-17β-YL]ETHYL]TETRAHYDRO-4-(R)-HYDROXY-2H-PYRAN-6-ONE"				"C31H50O6"	31.00	50.00	6.00	0.00	0.00	0.00	518		"                  O                                        (REF:   )"	"                  �ｾ    ◎"	"            ／＼／＼  H�ﾃ       H        O"	"              �ﾕ H  O  �ﾈ        �ﾅ／＼�ｷ"	"                 �ﾒ�ﾄ  �ﾓH       �ﾕ�ｵ�ｶ"	"                 ／＼�ﾇ＼      OH  �ｵ  O"	"                 �ｵ�ｶ�ｽ�ｺ          ＼／"	"           ／＼�ﾇ＼／�ﾅ              �ﾂ"	"           �ｵ�ｶ  �ｶ    H            ◎"	"         �ﾕ�ﾊ／�ﾚ／"	"        H  OH  H"														"1H-NMR(CDCl3)  0.64(s,3H), 0.90(s,3H), 0.91(t,3H,J=7Hz), 1.16(d,3H,J=7Hz), 2.40(m,1H), 2.59(m,1H), 2.72(dd,1H,J1=16Hz,J2=6Hz), 3.55-3.68(m,1H), 4.32-4.39(m,1H), 4.52-4.62(m,1H), 4.94-4.98(m,1H)(215)"	"M/Z (FAB) 525.4(M+Li)(215)"		"215/"			"HMG-CoA REDUCTASE INHIBITOR ON CHOLESTEROL BIOSYNTHESIS IN Hep G2 CELLS IC50-Value : 1.5x10-5M (215/216)"	"215/216/"	"SYNTHESIS AND BIOLOGICAL ACTIVITY OF BILE ACID-DERIVED HMG-CoA REDUCTASE INHIBITORS(215)"	"215/"	
"BA0530"	5.00		"2-(S)-[2-[3α-HYDROXY-12α-(2-(S)-METHYL-1-OXOBUTOXY)-5β-ANDROSTAN-17β-YL]ETHYL]-TETRAHYDRO-4-(S)-HYDROXY-2H-PYRAN-6-ONE"				"C31H50O6"	31.00	50.00	6.00	0.00	0.00	0.00	518		"                  O                                        (REF:   )"	"                  �ｾ    ◎"	"            ／＼／＼  H  �ﾐ     OH       O"	"              �ﾕ H  O  �ﾈ        �ﾅ／＼�ｷ"	"                 �ﾒ�ﾄ  �ｵ        �ﾕ�ｵ�ｶ"	"                 ／＼�ﾇ＼       H  �ｵ  O"	"                 �ｵ�ｶ�ｽ�ｺ          ＼／"	"           ／＼�ﾇ＼／�ﾅ              �ﾐ"	"           �ｵ�ｶ  �ｶ    H            ◎"	"         �ﾕ�ﾊ／�ﾚ／"	"        H  OH  H"														"1H-NMR(CDCl3)  0.64(s,3H), 0.90(s,3H), 0.91(t,3H,J=7Hz), 1.16(d,3H,J=7Hz), 2.40(m,1H), 2.59(m,1H), 2.72(dd,1H,J1=16Hz,J2=6Hz), 3.55-3.68(m,1H), 4.32-4.39(m,1H), 4.52-4.62(m,1H), 4.94-4.98(m,1H)(215)"	"M/Z (FAB) 525.4(M+Li)(215)"		"215/"			"HMG-CoA REDUCTASE INHIBITOR ON CHOLESTEROL BIOSYNTHESIS IN Hep G2 CELLS IC50-Value : 3x10-5M (215/216)"	"215/216/"	"SYNTHESIS AND BIOLOGICAL ACTIVITY OF BILE ACID-DERIVED HMG-CoA REDUCTASE INHIBITORS(215)"	"215/"	
"BA0531"	5.00		"5β-CHOLAN-24-OIC ACID"				"C24H40O2"	24.00	40.00	2.00	0.00	0.00	0.00	360			"                 ＼／＼                        (REF:001)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／�ﾂ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾚ／"	"           H"						"001/"	"164ﾟC (001)"		"[α]/D=+22ﾟ (001)"				"001/"			"1H-NMR(CDCl3)(002),18-CH3=0.67(s),19-CH3=0.93(s),21-CH3=0.93(d),23-CH2=2.2513C-NMR(CD2Cl2)(005),C1=37.9,C2=21.6,C3=27.4,C4=27.8,C5=44.1,C6=27.5,                           C7=26.9,C8=36.2,C9=40.8,C10=35.6,C11=21.1,C12=40.6, C13=43.0,C14=56.9,C15=24.4,C16="	"METHYL ESTER-TRIMETHYLSILYL ETHER DERIVATIVE (Me-TMS)(003) MOL.Wt.(FREE) Me-TMS360  374 359 217 (BASE PEAK)"		"001/002/005/003/"	"ヒト糞便(004)"	"004/"					
"BA0532"	5.00		"5α-CHOLAN-24-OIC ACID"	"ALLOCHOLANIC ACID"			"C24H40O2"	24.00	40.00	2.00	0.00	0.00	0.00	360			"                 ＼／＼                        (REF:006)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／�ﾂ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾊ／"	"           H"						"006/"	"172-173ﾟC, 93ﾟC (Me ESTER)(006)"		"[α]/D=+22.2ﾟ  (006)"				"006/"			"13C-NMR(CDCl3)Me ESTER(007), C1=38.6, C2=22.1, C3=26.7, C4=29.0, C5=46.9,  C6=29.0, C7=32.0, C8=35.4, C9=54.7, C10=36.1, C11=20.7, C12=40.0, C13=42.5,C14=56.5, C15=24.0, C16=28.0, C17=55.8, C18=11.9, C19=12.1, C20=35.2,C21=18.1, C22=30.9, C23=30.9,C24=17"	"MOL.Wt.(FREE) Me-TMS (003) 360,374, 359, 217 (BASE PEAK)"		"007/003/"							
"BA0533"	5.00		"5β-CHOL-3-EN-24-OIC ACID"				"C24H38O2"	24.00	38.00	2.00	0.00	0.00	0.00	358			"                 ＼／＼                        (REF:008)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／�ﾂ"	"      ｜  ｜  ｜ H"	"       �ｸ／�ﾚ／"	"           H"						"008/"	"73.5-74.5 (Me ESTER)    (008)"""		"[α]/D=+18ﾟ  (Me ESTER)(008)"				"008/"			"1H-NMR (CCl4) Me ESTER  5.50(M,OLEFIN) (009)"	"Me ESTER (010/011), 372 (M+,BASE),357 (M-15),215 Me-TMS (003), 372, 357, 215 (BASE)"		"008/009/010/011/003/"	"ヒト糞便(010) 正常者  TRACE ( <0.1μMOL/DAY ) 大腸ガン患者  TRACE - 11.2μMOL/DAY"	"010/"					
"BA0534"	5.00		"3α-HYDROXY-5β-CHOLAN-24-OIC ACID"	"LITHOCHOLIC ACID"	"LCA"		"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ�ｶ�ｽ�ｺ"	"       ／＼�ｫ＼／�ﾂ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H OH   H"							"187-188ﾟC , 129-130ﾟC( Me ESTER )(001)"		"[α]/D=+35ﾟ (001)"			"0.00005mM(WATER SOLUBILITY IN PROTONATED FORM)(012)"	"001/012/"			"1H-NMR (CDCl3) (002), 18-CH3=0.66(s), 19-CH3=0.93(s), 21-CH3=0.93(d), 23-CH2=2.20, 3β-H=3.60 13C-NMR(CD3OD) (005), C1=35.6, C2=30.4, C3=71.8,C4=36.5, C5=42.5, C6=27.5, C7=26.7, C8=36.1, C9=40.6, C10=34.8, C11=21.1,C12=40.5, C13=43.0, C14=56.7, C"	"Me-TMS 462, 447, 372, 357, 257, 215(BASE PEAK)  (003)"		"002/005/003/"	"二次胆汁酸の一つで広く分布（腸内細菌によるケノデオキシコール酸の7α-脱水酸 化反応の代謝物） (013/014) 牛，ウサギ，サル，ブタ，GUINEA PIG，ヒト胆汁中 ヒト糞便中(015)"	"013/014/015/"					
"BA0535"	5.00		"3β-HYDROXY-5β-CHOLAN-24-OIC ACID"	"ISOLITHOCHOLIC ACID"	"iso LCA"		"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    OH H   H"							"177ﾟC(016)"		"[α]/D=+20ﾟ  (016)"			"0.00079mM(WATER SOLUBILITY IN PROTONATED FORM)(012)"	"016/012/"			"13C-NMR (CDCl3) 24-COOMe (060) C1=29.8, C2=27.8, C3=66.7, C4=33.4, C5=36.3, C6=26.5, C7=26.1, C8=35.5, C9=39.6, C10=34.9, C11=20.9, C12=40.2, C13=42.6, C14=56.4, C15=24.0,C16=28.0, C17=55.8, C18=11.9, C19=23.7, C20=35.2, C21=18.1, C22=30.8,   C"	"Me-TMS 462, 447, 405, 372(BASE PEAK), 357, 257, 230, 215 (003)"		"060/003/"	"ウサギ糞便(017)，ヒト糞便(018/019)"	"017/018/019/"					
"BA0536"	5.00		"3α-HYDROXY-5α-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾊ／"	"    H OH   H"							"204-208ﾟC, 160-161ﾟC (Me ESTER)(020)"		"[α]26/D=+26.0ﾟ (DIOXANE)(020)"				"020/"			"13C-NMR (CDCl3) Me ESTER  (007) C1=32.1, C2=28.9, C3=66.3, C4=35.8, C5=39.0, C6=28.5, C7=31.9, C8=35.4, C9=54.2, C10=35.9, C11=20.7, C12=39.9, C13=42.5, C14=56.4, C15=24.0,C16=28.0, C17=55.8, C18=12.0, C19=11.1, C20=35.2, C21=18.2, C22=30.9,"	"Me-TMS (021), 462, 372, 357, 230, 215"		"117/021/"	"ヒト尿(021)，ヒト糞便(019)，ラット糞便(019)"	"021/019/"					
"BA0537"	5.00		"7α-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376			"             ＼／＼"	"               �ﾓH｜"	"         ／�ｪ／＼  COOH"	"        ｜ �ｶ�ｽ�ｺ"	"   ／�ｪ／＼／�ﾅ"	"  ｜  ｜  ｜   H"	"   ＼／�ﾚ／�ﾗ"	"       H   H OH"							"96-98ﾟC, 78-79ﾟC (Me ESTER)(022)"		"[α]22/D=+7ﾟ (CHCl3)(022)"			"0.00020mM(WATER SOLUBILITY IN PROTONATED FORM)(012)"	"022/012/"			"1H-NMR (PRY-d5) Me ESTER (023), 18-CH3=0.65(s), 19-CH3=0.91(s), 7β-H=3.86 (bmr), CO2Me=3.68(S)  13C-NMR (CDCl3) Me ESTER (060), C1=37.4, C2=21.1, C3=27.5, C4=30.2, C5=43.0, C6=35.5, C7=68.1, C8=39.2, C9=32.6, C10=35.0, C11=20.3, C12=39.4, C13=42.3, C14="	"Me-TMS (003), 462, 447, 372(BASE PEAK), 357, 257, 215"		"023/060/003/"							
"BA0538"	5.00		"7β-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376			"                 ＼／＼                     (REF:024)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾚ／�ﾗ"	"           H  OH H"						"024/"	"131-133.5ﾟC, 89-90.5ﾟC (Me ESTER)(024)"		"[α]/D=+56ﾟ(024)"				"024/"		"(KBr, cm-1) 1695(C=0), 3401, 1015(OH), 990  (024)"	"1H-NMR(CDCl3) (024), 18-CH3=0.68(s), 19-CH3=0.93(s), 7α-H=3.58(brm)13C-NMR(CDCl3) Me ESTER (060), C1=37.4, C2=21.0, C3=26.7, C4=28.4, C5=44.0,C6=37.1, C7=71.2, C8=43.6, C9=39.1, C10=34.7, C11=20.9, C12=40.1, C13=43.6,C14=55.7, C15=26.9, C16=27.9,"	"Me-TMS (003), 462, 447, 372, 357, 257, 215, 73(BASE PEAK)"		"024/060/003/"	"ヒト糞便(004)"	"004/"					
"BA0539"	5.00		"12α-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376			"             H OH＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾚ／"	"           H"							"90.5ﾟC, 120-121ﾟC (Me ESTER)(025)"		"[α]12/D=+43.5ﾟ (ACETONE)(025)"				"025/"			"1H-NMR (PYR-d5) (023), 18-CH3=0.71(s), 19-CH3=0.92(s), 12β-H=4.15(brm), COOCH3=3.62(s)  13C-NMR(CDCl3) Me ESTER (060), C1=37.2, C2=21.0, C3=26.7,  C4=27.2, C5=43.5, C6=26.9, C7=26.0, C8=35.8, C9=33.4, C10=34.6, C11=28.5,C12=72.8, C13=46.2, C14=48.0, C"	"Me-TMS (003), 447, 372, 357, 257(BASE PEAK), 229, 215(弱い)"		"023/060/003/"							
"BA0540"	5.00		"12β-HYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O3"	24.00	40.00	3.00	0.00	0.00	0.00	376			"             OH H＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾚ／"	"           H"							"110-116ﾟC(025)"		"[α]12/D=+37.9ﾟ (ACETONE)(025)"				"025/"			"13C-NMR(CDCl3) Me ESTER (060), C1=37.2, C2=21.0, C3=26.8, C4=27.2, C5=43.1,C6=26.9, C7=25.9, C8=34.4, C9=39.1, C10=35.0, C11=29.3, C12=79.1, C13=47.6,C14=54.4, C15=23.4, C16=23.8, C17=57.2, C18=7.7, C19=23.8, C20=32.4, C21=20.7, C22=31.9, C23=30.9, C24=1"			"060/"							
"BA0541"	5.00		"3β-HYDROXY-CHOL-5-EN-24-OIC ACID"				"C24H38O3"	24.00	38.00	3.00	0.00	0.00	0.00	374			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ｸ／"	"   HO  H"							"235-236ﾟC, 145-146ﾟC (Me ESTER)(026)"						"026/"			"1H-NMR(CDCl3) (027), 18-CH3=0.69(S), 19-CH3=1.00(S), COOMe=3.63(S), 3β-OH =1.82"	"Me-TMS (003), 460, 445, 404, 370, 355, 331(BASE PEAK), 255, 129"		"027/003/"	"肝胆道疾患患者の尿中(021/028)"	"021/028/"					
"BA0542"	5.00		"3-OXO-5β-CHOLAN-24-OIC ACID"				"C24H38O3"	24.00	38.00	3.00	0.00	0.00	0.00	374			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ｷ＼／�ﾚ／"	"    O      H"							"138-139ﾟ,116-118ﾟ(Me ESTER),147-148ﾟC(OXIME) (029)"		"[α]28/D=+32.3ﾟ (029)"				"029/"			"13C-NMR(CDCl3) Me ESTER  (030), C1=37.1, C2=36.9, C3=212.9, C4=42.3, C5=44.3, C6=25.7, C7=26.6, C8=35.6, C9=40.9, C10=34.9, C11=21.1, C12=40.1,    C13=42.8, C14=56.5, C15=24.1, C16=28.1, C17=56.0, C18=12.0, C19=22.6, C20=35.2, C21=18.2, C22=31.0, C23="	"Me ESTER (003), 388, 373, 356, 273(BASE PEAK), 255, 231, 213"		"030/003/"	"ヒト糞便(015/018)"	"015/018/"					
"BA0543"	5.00		"3α,6α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"	"HYODEOXYCHOLIC ACID"	"HDCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H OH   H �ﾗ"	"             H OH"						"198-201ﾟC, 120ﾟC (Me ESTER)(031)"		"[α]22/D=+7ﾟ (METHANOL)(031)"			"0.015mM(WATER SOLUBILITY IN PROTONATED FORM)(012)"	"031/012/"		"cm-1  1739(C=0) 3425, 3226, 1155, 1033, 1007, 953, 794 (OH) (031)"	"13C-NMR (CD2Cl2) Me ESTER (005) C1=36.3, C2=29.7, C3=71.8, C4=35.3, C5=48.8, C6=68.1, C7=30.6, C8=35.3, C9=40.2, C10=36.1, C11=21.0, C12=40.2, C13=43.1, C14=56.3, C15=24.5, C16=28.4, C17=56.3, C18=12.1, C19=23.6, C20=35.8, C21=18.3, C22=31.3,"	"Me-TMS  (003), 550, 460, 370(BASE PEAK), 355, 255, 213"		"031/005/003/"	"ブタ胆汁の主成分(032)ラット血漿(033)，肝臓(033)，胆汁(034)，糞便(035)にも存在 ヒト肝胆道疾患患者の尿(021/036/037/038)"	"032/033/034/035/021/036/037/038/"					
"BA0544"	5.00		"3α,6β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H OH   H �ﾗ"	"             OH H"						"209-210ﾟC(039), 214-215ﾟC,114-115ﾟC(Me ESTER)(040)"		"[α]26/D=+37ﾟ (039)"				"039/040/"		"cm-1  1715(C=0), 3410, 3300(OH), 1050, 1028  (040)"	"1H-NMR(CDCl3+30%DMSO-d6), 18-CH3=0.68(s), 21-CH3=0.93(d,J=5.4Hz), 19-CH3=1.11(s), 3β-H=3.57(brm),6α-H=3.74(m) 13C-NMR(CDCl3) Me ESTER, C1=35.8,  C2=30.1,C3=71.2,C4=36.5,C5=48.6,C6=73.1,C7=34.7,C8=30.7,C9=40.7,C10=34.3,C11=20.6,C12=40.0,C13=42.7,C14="	"Me-TMS , 550, 535, 460, 405(BASE PEAK), 370, 355, 255, 213 (003)"		"040/003/"	"ブタ胆のう胆汁中にTRACE (041)，肝胆道疾患患者の尿(037/042)および血漿(043)"	"041/037/042/043/"					
"BA0545"	5.00		"3β,6α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    HO H   H �ﾗ"	"             H OH"						"191-192ﾟC (044), 198-199, 74-75ﾟC (Me ESTER) (040)"						"044/040/"		"cm-1  1702(C=0), 3398(OH), 1040 (040)"	"1H-NMR (CDCl3+30%DMSO-d6) 18-CH3=0.65(s), 21-CH3=0.92(d,J=5.4Hz), 19-CH3= 0.93(s), 6β-H=3.99(brm), 3α-H=4.09(m) 13C-NMR(CDCl3) Me ESTER, C1=30.0, C2=27.5,C3=66.0,C4=26.3,C5=43.0,C6=67.8,C7=34.6,C8=34.6,C9=39.1,C10=36.4,C11=20.6,C12=40.0,C13=42.7,C14="	"Me-TMS  550, 535, 460, 445, 405, 370(BASE PEAK), 255, 213 (003)"		"040/003/"	"ブタ胆汁(045)，ブタ胆石(046)"	"045/046/"					
"BA0546"	5.00		"3β,6β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    HO H   H �ﾗ"	"             OH H"						"250ﾟ(047),258ﾟ(048),260-261,124-125ﾟ(Me EST.)(040)"		"[α]20/D=+21ﾟ (048)"				"047/048/040/"		"cm-1  1710(C=0), 3440, 3400, 1448, 1038, 1018(OH) (040)"	"1H-NMR(CDCl3+30%DMSO-d6) 18-CH3=0.68(s), 21-CH3=0.92(d,J=5.4Hz), 19-CH3= 1.13(s), 6α-H=3.64(m), 3α-H=4.02(m) 13C-NMR(CDCl3) Me ESTER, C1=30.2,C2=27.5,C3=66.1,C4=33.7,C5=43.6,C6=73.2,C7=34.5,C8=30.6,C9=40.1,C10=34.8,C11=C11=20.6,C12=40.0,C13=42.7,C14"			"040/"							
"BA0547"	5.00		"3α,7α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"	"CHENODEOXYCHOLIC ACID"	"CDCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H OH   H   H OH"							"145-146ﾟC(049)"		"[α]20/D=+10.7 (DIOXANE)(049)"			"0.027mM(WATER SOLUBILIRY IN PROTONATED FORM)(012)"	"049/012/"			"1H-NMR(CDCl3) (050), 18-CH3=0.64(s), 19-CH3=0.88(s), 21-CH3=0.94(d), 3β-H =3.38(brm), 7β-H=3.78(m) 13C-NMR(CD3OD) (005), C1=35.8, C2=31.0,C3=71.4, C4=39.7, C5=42.1, C6=35.4, C7=67.8, C8=39.9, C9=33.3, C10=35.5, C11=21.1,C12=39.9, C13=43.0, C14=50.9, C"	"Me-TMS  460, 445, 370(BASE PEAK), 355, 255, 213 (003)"		"050/005/003/"	"哺乳動物に広く分布，一次胆汁酸 (052)，鳥類，哺乳類，最初ガチョウの胆汁中よ り見い出されてこの名がついた (051)"	"052/051/"	"胆石溶解剤"				
"BA0548"	5.00		"3α,7β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"	"URSODEOXYCHOLIC ACID"	"UDCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    H OH   H   OH H"							"201-202ﾟC(053)"		"[α]25/D=+57ﾟ(DIOXANE)(053)"			"0.0009mM(WATER SOLUBILITY IN PROTONATED FORM)(012)"	"053/012/"			"1H-NMR (CDCl3;DMSO-d6) (050), 18-CH3=0.66(s), 19-CH3=0.95(s), 21-CH3=0.92 (d), 3β-H=3.45(brm), 7α-H=3.45(brm) 13C-NMR (CD3OD) (054), C1=36.1, C2= 30.9, C3=71.7, C4=38.4, C5=44.3, C6=37.9, C7=71.9, C8=43.9, C9=40.5, C10=35.0, C11=22.3, C12=41.4, C13=4"	"Me-TMS  535, 460(BASE PEAK), 370, 355, 255, 213 (003)"		"003/050/054/"	"最初にクマ胆汁(055)から発見され，日本人により確認された(056)    哺乳動物の胆汁中にMINOR (057)，ヒト糞便(018)"	"055/056/057/018/"	"胆石溶解剤（クマノイとして昔から服用）"				
"BA0549"	5.00		"3β,7α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    HO H   H   H OH"							"193ﾟC(058),193-195ﾟC,204-206ﾟC,156.5-158.5ﾟC (059)"		"[α]23/D=+8.5ﾟ (ETHANOL)(058)"				"058/059/"		"cm-1 (KBr)   1715(C=0),1071, 1034, 1003, 982(COH) (059)"	"1H-NMR (059) 18-CH3=0.67(s), 19-CH3=0.94(s), 7β-H=3.87(m), 3α-H=4.07(m) 13C-NMR(CDCl3) (060) Me ESTER, C1=29.8,C2=27.7,C3=66.7,C4=36.6,C5=35.9,C6= 35.5,C7=68.5,C8=39.3,C9=32.0,C10=34.2,C11=20.8,C12=39.6,C13=42.6,C14=50.4,C15=23.6,C16=28.0,C17=55.7,C18"	"Me-TMS  460, 445, 370(BASE PEAK), 355, 255, 213 (003)"		"059/060/003/"	"ヒト糞便中(018)，肝胆道疾患患者の尿，血漿中(021/036/043/061)"	"018/021/036/043/061/"					
"BA0550"	5.00		"3β,7β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼                     (REF:059)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／�ﾗ"	"    HO H   H   OH H"						"059/"	"166-168.5ﾟC, 124-125ﾟC(Me ESTER)(059)"						"059/"		"cm-1 (KBr) 1709(C=0), 1031(3β-COH), 1016(7β-COH) (059)"	"1H-NMR (059), 18-CH3=0.71(s), 19-CH3=1.00(s), 7α-H=3.65(brm), 3α-H=4.07 (m)13C-NMR(CDCl3)Me ESTER (060), C1=29.3,C2=27.2,C3=65.7,C4=34.1,C5=36.7,C6=36.5,C7=70.7,C8=43.0,C9=38.2,C10=34.1,C11=21.1,C12=39.8,C13=43.2,C14=55.6,C15=26.5,C16=28.2,C17=54.5,"	"Me-TMS  550, 535, 460, 445, 370(BASE PEAK), 355, 255 (003)"		"059/060/003/"							
"BA0551"	5.00		"3α,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"	"DEOXYCHOLIC ACID"	"DCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"             H HO＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H OH   H"							"168-169ﾟC(062),174-174.5ﾟC,70-108ﾟC(Me ESTER)(063)"		"[α]26/D=+50.6ﾟ (DIOX.)(062)"			"0.028mM(WATER SOLUBILITY IN PROTONATED FORM)(012)"	"063/062/012/"		"cm-1 (kBr) 1724(C=0) 3390, 1036(OH) (063)"	"1H-NMR(CD3OD) (002), 18-CH3=0.70(s), 19-CH3=0.92(s), 21-CH3=1.00(d), 3β-H =3.50(brm), 12β-H=3.95(s), 23-CH2=2.20(m) 13C-NMR(CDCl3) Me ESTER (060), C1=35.1,C2=30.2,C3=71.4,C4=36.2,C5=42.0,C6=27.1,C7=26.0,C8=35.9,C9=33.3,C10=33.9,C11=28.5,C12=72.8,C13=4"	"Me-TMS  550, 535, 370, 345, 255(BASE PEAK), 208 (003)"		"063/002/060/003/"	"ウシ胆中から最初に単離(CHOLEIC ACID)(064) 哺乳動物の胆汁，糞便中に存在(001) 二次胆汁酸でコール酸が腸内細菌で脱7α- 水酸化され生じる(065)"	"064/001/065/"	"CORTISONE やCORTICAL STEROID の合成の出発原料(001)"	"001/"			
"BA0552"	5.00		"3α,12β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"             HO H＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    H OH   H"							"172.5-173.5ﾟC, AMORPH. (Me ESTER)(063)"		"[α]/D=+37.8ﾟ (DIOXANE)(063)"				"063/"		"cm-1 (KBr) 1706(C=0)3546, 3390, 1036, 1015, 1000(OH) (063)"	"13C-NMR(CDCl3) Me ESTER, C1=35.2, C2=30.3, C3=71.1, C4=35.9, C5=41.6, C6=26.9, C7=25.8, C8=34.4, C9=39.3, C10=34.2, C11=29.5, C12=79.1, C13=47.8,C14=54.8, C15=23.5, C16=24.0, C17=57.3, C18=7.8, C19=23.0, C20=32.5,C21=20.7, C22=32.0, C23=31.2, C24=17"	"Me-TMS  535, 460, 370, 345, 255(BASE PEAK), 208 (003)"		"063/060/003/"	"ヒト糞便(004/018)，肝胆道疾患患者の尿(021/037/066)"	"004/018/021/027/066/"					
"BA0553"	5.00		"3β,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"             H HO＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"    HO H   H"							"174.5-176ﾟC, 156.5-158ﾟC (Me ESTER)(063)"		"[α]/D=+39.0 (063)"				"063/"		"cm-1 (KBr) 1730, 1709 (C=0) 3570, 3425, 1031 (OH) (063)"	"13C-NMR(CDCl3) Me ESTER, C1=29.7, C2=27.6, C3=66.9, C4=33.3, C5=36.4, C6=26.5, C7=25.9, C8=35.7, C9=32.7, C10=34.5, C11=28.8, C12=73.0,         ,C13=46.4, C14=48.3, C15=23.5, C16=27.4, C17=47.2, C18=12.6, C19=23.5,C20=35.0, C21=17.2, C22=31.0, C23=3"	"Me-TMS  535, 460, 370, 345, 255(BASE PEAK), 215 (003)"		"063/060/003/"	"ウサギ，ヒトの糞便(018)，ヒト糞便(015)，肝胆道疾患患者の尿(037/042/043/066)，血漿(043)"	"018/015/037/042/043/066/"					
"BA0554"	5.00		"3β,12β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"            HO  H＼／＼             (REF:063)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾚ／"	"   HO  H   H"						"063/"	"204-206ﾟC, 116ﾟC(Me ESTER)(063)"		"[α]/D=+27.0ﾟ (DIOXANE) (063)"				"063/"		"cm-1 1712(C=0)(KBr)3570, 3333, 1028, 1005(OH) (063)"	"13C-NMR (CDCl3) Me ESTER (060) C1=29.5, C2=27.3, C3=66.1, C4=33.0, C5=35.7, C6=26.3, C7=25.5, C8=33.9, C9=38.3, C10=34.5, C11=29.1, C12=78.9, C13=47.5, C14=54.2, C15=23.3,C16=23.6, C17=57.0, C18=7.5, C19=23.3, C20=32.1, C21=20.5, C22=31.8,"	"Me-TMS  (003), 550, 460, 345,255(BASE PEAK)"		"063/060/003/"	"ヒト糞便  (004/018)"						
"BA0555"	5.00		"7α,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"             H HO＼／＼                          (REF:135)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾚ／�ﾗ"	"           H   H OH"						"135/"	"207-208ﾟC, 155-156ﾟC (Me ESTER)(135)"		"[α]21/D=+18ﾟ (DIOXANE) (135)"				"135/"		"cm-1 (KBr)  1724(C=0) 3425, 1024, 984(OH) (024)"	"1H-NMR(CDCl3) Me ESTER (024),18-Me=0.68(s),19-Me=0.89(s), 24-COOMe=3.63(s),7β-H=3.84(m), 12β-H=3.96(m) 13C-NMR(CDCl3) Me ESTER (060), C1=37.5,C2= 21.2,C3=27.7,C4=30.4,C5=43.1,C6=35.4,C7=68.7,C8=39.5,C9=26.3,C10=35.6,C11=28.1,C12=73.1,C13=46.5,C14=41."	"Me-TMS  535, 370, 355, 255(BASE PEAK), 228  (003)"		"024/060/003/"							
"BA0556"	5.00		"7α,12β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"             HO H＼／＼                          (REF:024)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾚ／�ﾗ"	"           H   H OH"						"024/"	"150-152.5ﾟC, 129.5-131ﾟC (Me ESTER)(024)"						"024/"		"cm-1 (KBr)  1701(C=0) 3448, 1018, 1005, 992(OH) (024)"	"1H-NMR(CDCl3+10%Me2SO-d6) (024), 18-CH3=0.72(s), 19-CH3=0.91(s), 12α-H=   3.51(brm),7β-H=3.82(m)  13C-NMR(CDCl3) Me ESTER (060), C1=37.4,C2=21.2,C3=27.5,C4=30.2,C5=42.7,C6=35.1,C7=68.0,C8=37.9,C9=31.9,C10=35.6,C11=29.2,C12=78.8,C13=47.4,C14=48.4,C15=22"	"Me-Oac 430(2.6), 370(63.4), 255(100.0) (RELATIVE INTENSITY)  Me-DMES 578(0.6), 563(2.9), 549(100.0), 370(14.9), 255(26.7)(067)"		"024/060/067/"							
"BA0557"	5.00		"7β,12α-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"             H HO＼／＼                          (REF:024)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾚ／�ﾗ"	"           H   OH H"						"024/"	"174.5-176ﾟC, 131-132ﾟC(Me ESTER)(024)"						"024/"		"cm-1 (KBr)  1689(C=0) 3356, 1026, 1015, 943(OH) (024)"	"1H-NMR(CDCl3+10%Me2SO-d6)(024),18-CH3=0.67(s),19-CH3=0.90(s), 7α-H=3.49   (brm), 12β-H=3.88(m), 13C-NMR(CDCl3) Me ESTER (060), C1=37.2,C2=20.7,C3=26.8,C4=27.8,C5=43.9,C6=36.8,C7=71.1,C8=43.7,C9=31.9,C10=34.1,C11=28.7,C12=72.2,C13=47.1,C14=47.2,C15=26.2"	"Me-Oac 430(0.6), 370(70.3), 255(100.0)  (RELATIVE INTENSITY) Me-DMES 578(0.2), 563(4.0), 549(100.0), 370(34.7), 255(56.4)(067)"		"024/060/067/"							
"BA0558"	5.00		"7β,12β-DIHYDROXY-5β-CHOLAN-24-OIC ACID"				"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"             HO H＼／＼                          (REF:024)"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"       ＼／�ﾚ／�ﾗ"	"           H   OH H"						"024/"	"179-182ﾟC, 131-132ﾟC (Me ESTER)(024)"						"024/"		"cm-1 (KBr)  1642(C=0) 3413, 1026, 1015, 956(OH) (024)"	"1H-NMR(CDCl3+10%Me2SO-d6)  (024), 18-CH3=0.72(s), 19-CH3=0.93(s), 7α-,12α-H=3.41(brm)  13C-NMR(CDCl3) Me ESTER  (060), C1=37.5,C2=21.1,C3=26.9,C4=  28.0,C5=43.8,C6=37.1,C7=71.2,C8=42.3,C9=37.8,C10=34.7,C11=29.0,C12=79.4,C13=48.6,C14=53.9,C15=26.2,C16=2"	"Me-Oac 430(0.8), 370(100.0), 255(99.3)  (RELATIVE INTENSITY) Me-DMES 578(0.2), 563(3.6), 549(100.0), 370(19.8), 255(17.8) (067)"		"024/060/067/"							
"BA0559"	5.00		"3α,7α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"	"ALLO-CHENODEOXYCHOLIC ACID"	"allo-CDCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"                 ＼／＼"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾊ／�ﾗ"	"    H OH   H   H OH"							"245-246ﾟC(068/069), 126.5-127.5ﾟC(Me ESTER) (069)"						"068/069"		"cm-1 1700(C=0) 3400, 1027, 1000(OH)(069)"	"1H-NMR(CDCl3+20%DMSO-d6) (069), 18-CH3=0.64(s), 19-CH3=0.75(s), 21-CH3=0.91(d,J=5.4Hz), 7β-H=3.72(m), 3β-H=3.95(m)   13C-NMR(CDCl3) Me ESTER (007)  C1=32.2,C2=29.1,C3=66.4,C4=35.9,C5=31.8,C6=36.6,C7=68.0,C8=39.8,C9=46.2,C10=36.4,C11=20.7,C12=39.9,C13=4"	"Me ESTER 406(M+), 388(BASE PEAK), 373, 370, 355, 273, 264, 249(069)"		"069/007/"	"肝胆道疾患患者の尿(021/037/066)，血漿(043)"	"021/037/066/043/"					
"BA0560"	5.00		"3α,12α-DIHYDROXY-5α-CHOLAN-24-OIC ACID"	"ALLO-DEOXYCHOLIC ACID"	"allo DCA"		"C24H40O4"	24.00	40.00	4.00	0.00	0.00	0.00	392			"             H HO＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ﾊ／"	"    H OH   H"							"214-215ﾟC, 173-174ﾟC (Me ESTER)(017)"		"[α]/D=+42ﾟ (017)"				"017/"		"cm-1 1690(C=0)  3350, 1060, 1013, 1003, 975, 955(OH) (070)"	"1H-NMR(CDCl3+20%Me2SO-d6) (070), 18-CH3=0.68(s), 19-CH3=0.77(s), 21-CH3=   1.00(d,J=5.4Hz), 3β-,12β-H=3.95(m)  13C-NMR(CDCl3) Me ESTER  (007), C1= 1.9,C2=28.7,C3=66.1,C4=35.7,C5=38.7,C6=28.3,C7=31.4,C8=35.4,C9=46.9,C10=35.4,C11=28.3,C12=72.8,C13=46.2,C"	"Me-TMS  535, 460, 370, 345, 255(BASE PEAK), 208 (003)"		"070/007/003/"	"ウサギ糞便(017)，肝胆道疾患患者の尿(021/037/066)，血漿(043)"	"017/021/037/066/043/"					
"BA0561"	5.00		"3β,7α-DIHYDROXY-CHOL-5-EN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390			"                 ＼／＼                       (REF:071)"	"                   �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ｸ／�ﾗ"	"    OH H       H OH"						"071/"	"206-210ﾟC, 161-163ﾟC(Me ESTER)(071)"		"[α]20/D=-87.4ﾟ (DIOXANE) (071)"				"071/"			"1H-NMR(CDCl3) Me ESTER  (027), 18-CH3=0.68(s), 19-CH3=0.98(s), 24-COOCH3=  3.67(s), 6-H=5.59(d,J=6Hz)"	"Me-TMS  548, 458(BASE PEAK), 353, 253, 233 (003)"		"027/003/"	"ヒト胆汁(072)"	"072/"	"ケノデオキシコール酸生合成の別経路の KEY INTERMEDIATE (073/074)"	"073/074/"	"ALLYL ALCOHOLであり，酸，熱に不安定(027)"	"027/"	
"BA0562"	5.00		"3β,12α-DIHYDROXY-CHOL-5-EN-24-OIC ACID"				"C24H38O4"	24.00	38.00	4.00	0.00	0.00	0.00	390			"             H HO＼／＼"	"             �ﾒ�ﾄ  �ﾓH｜"	"             ／�ｪ／＼  COOH"	"             �ｵ ｜ �ｺ"	"       ／＼�ｫ＼�ﾋ�ｼ"	"      ｜  ｜  ｜ H"	"     �ﾕ�ﾊ／�ｸ／"	"    OH H"							"253-254ﾟC(075)"						"075/"		"cm-1 (NUJOL) 1700(CO)  3435, 3300(OH) (075)"	"1H-NMR (CD3OD) (075), 18-CH3=0.82(s), 19-CH3=0.99(s), 3α-H=3.20-3.66(m),  12β-H=3.99(t,J=3Hz), 6-H=5.30(d,J=4Hz) (075)"	"Me-TMS (RELATIVE INTENSITY)   458(13), 368(23), 253(100) (075)"		"075/"	"肝胆道疾患患者の尿(021/037/066/136)および血漿(043/076/136)"	"021/037/066/136/043/076/"