"LIPID_ID" "CLASSIFICA" "CHEM_NA" "COMMON_NA" "SYMBOL" "GROUP_NA" "MOL_FORMULA" "FORMULA_C" "FORMULA_H" "FORMULA_O" "FORMULA_N" "FORMULA_P" "FORMULA_S" "MOL_WT" "STR_1" "STR_2" "STR_3" "STR_4" "STR_5" "STR_6" "STR_7" "STR_8" "STR_9" "STR_10" "STR_11" "REF_STR" "MELT_PT" "BOIL_PT" "OPT_ROT" "REFRA_IND" "DENSITY" "SOLUBILITY" "REF_PRP" "UV_SPEC" "IR_SPEC" "NMR_SPEC" "MS_SPEC" "NOTE_SPEC" "REF_SPC" "SOURCE" "REF_SOU" "BIOL_ACTIV" "REF_BA" "NOTE" "REF_NOTE" "MA0001" 15.00 "1,3-DIPALMITOYL-2-OLEYLGLYCEROL" "2OLEO-DIPALMITIN" "POP" "C53H100O6" 53.00 100.00 6.00 0.00 0.00 0.00 832.00 " O (REF: )" " ｾ" " CH2-O-C-(CH2)14-CH3" " |" " CH-O-C-(CH2)7-CH=CH-(CH2)7-CH3" " | ｾ" " | O" " CH2-O-C-(CH2)14-CH3" " ｾ" " O" "19.0-35.5ﾟC (001)" "001/" "X線回析(001):SHORT-SPACING およびLONG-SPACING についてのデータ．" "001/" "パーム油（PALM OIL）中に25-30%" "MA0002" 15.00 "1,3-DIBEHENYL-2-OLEOLY GLYCEROL" "2-OLEO-DIBEHENIN" "BOB" "C65H124O6" 65.00 124.00 6.00 0.00 0.00 0.00 1000.00 " O (REF: )" " ｾ" " CH2-O-C-(CH2)20-CH3" " |" " CH-O-C-(CH2)7-CH=CH-(CH2)7-CH3" " | ｾ" " | O" " CH2-O-C-(CH2)20-CH3" " ｾ" " O" "41.5 - 53.3ﾟC (001)" "001/" "X線回析 SHORT-SPACING およびLONG-SPACINGについてのデータ(001)" "001/" "MA0003" 15.00 "1,3-DISTEARYL-2-OLEOYLGLYCEROL" "2-OLEO-DISTEARIN" "SOS" "C57H108O6" 57.00 108.00 6.00 0.00 0.00 0.00 888.00 " O (REF: )" " ｾ" " CH2-O-C-(CH2)16-CH3" " |" " CH-O-C-(CH2)7-CH=CH-(CH2)7-CH3" " | ｾ" " | O" " CH2-O-C-(CH2)16-CH3" " ｾ" " O" "28.0 - 42.6ﾟC (001)" "001/" "X線回析：SHORT-SPACING およびLONG-SPACINGについてのデータ(001)" "001/" "シア脂（SHEU BUTTER）中に40-45%．" "MA0004" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C51:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C49-diΔ(β-unit)+C22:0(α-unit)" "C71H138O3" 71.00 138.00 3.00 0.00 0.00 0.00 1038.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=41,x=19" "004/" "[M]+(molecular ion),[M-15]+(loss of -CH3),[M-90]+(loss of trimethylsilanol),[A]+(TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+(loss of trimethylsilanol from [A]+),[B]+(TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+(loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrogenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium diernhoferi(MD-1)(004/005)" "004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0005" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C52:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C50-diΔ(β-unit)+C22:0(α-unit)" "C72H140O3" 72.00 140.00 3.00 0.00 0.00 0.00 1052.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=42,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (004/005) M.parafortuitum(19686)(001/004/005) M.diernhoferi(MD-1)(001/004/005) M.phlei(005) M.rhodesiae(RHO-1)(001/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0006" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C53:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C51-diΔ(β-unit)+C22:0(α-unit)" "C73H142O3" 73.00 142.00 3.00 0.00 0.00 0.00 1066.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=43,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (004/005) M.parafortuitum(19686)(001/004/005) M.diernhoferi(MD-1)(004/005) M.phlei(004) M.rhodesiae(RHO-1)(001/004/005) M.aurum (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0007" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C54:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C52-diΔ(β-unit)+C22:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=44,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (001/004/005) Mycobacterium parafortuitum(19686)(001/004/005) Mycobacterium diernhoferi(MD-1)(001/004/005) Mycobacterium phlei (005) Mycobacterium rhodesiae(RHO-1)(001/004/005) M.aurum (004/005) M.Kansasii (001)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.dirnhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0008" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C55:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C53-diΔ(β-unit)+C22:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=45,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (004/005) M.parafortuitum(19686)(001/004/005) M.diernhoferi(MD-1) (004/005) M.phlei (001/004/005) M.rhodesiae(RHO-1)(001/004/005) M.aurum (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0009" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C56:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C54-diΔ(β-unit)+C22:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=46,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (001/004/005) M.parafortuitum(19686)(001/004/005) M.diernhoferi(MD-1) (001/004/005) M.phlei (001/004/005) M.rhodesiae(RHO-1)(001/004/005) M.duvalii (004) M.gilvum (001) M.aurum (004/005) M.kansasii (001/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.dirnhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0010" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C57:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C55-diΔ(β-unit)+C22:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=47,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (004/005) M.parafortuitum(19686)(001/004/005) M.diernhoferi(MD-1) (004) M.phlei (001/004/005) M.rhodesiae(RHO-1) (001/005) M.aurum (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0011" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C58:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C56-diΔ(β-unit)+C22:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=48,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium parafortuitum(19686)(001/004/005) M.diernhoferi(MD-1) (004) M.phlei (001/004/005) M.rhodesiae(RHO-1) (001/004/005) M.vaccae (001/004/005) M.agri (001) M.gilvum (001/004) M.aurum (004/005) M.thermoresistibile (001) M.pulveris (004) M.kansasii (001/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0012" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C59:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C57-diΔ(β-unit)+C22:0(α-unit)" "C79H154O3" 79.00 154.00 3.00 0.00 0.00 0.00 1150.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=49,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (001/004/005) Mycobacterium agri(90012) (001) M.aurum (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0013" 15.00 "2-EICOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C60:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C58-diΔ(β-unit)+C22:0(α-unit)" "C80H156O3" 80.00 156.00 3.00 0.00 0.00 0.00 1164.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=50,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (005) M.aurum(Au-1) (005) M.thermoresistibile (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0014" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C50:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C48-diΔ(β-unit)+C24:0(α-unit)" "C72H140O3" 72.00 140.00 3.00 0.00 0.00 0.00 1052.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=40,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae (004/005) M.rhodesiae (001/005) M.marinum (005) M.gordonae (005) M.phlei (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0015" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C51:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C49-diΔ(β-unit)+C24:0(α-unit)" "C73H142O3" 73.00 142.00 3.00 0.00 0.00 0.00 1066.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=41,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (004/005) M.aurum(Au-1) (005) M.rhodesiae(RHO-1)(001/004/005) M.gordonae (005) M.marinum (005) M.phlei (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0016" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C52:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C50-diΔ(β-unit)+C24:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=42,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (004/005) M.rhodesiae(RHO-1) (001/004/005) M.phlei (005) M.marinum (005) M.gordonae (005) M.aurum (004/005) M.kansasii (lab.) (001/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) C74,76,78の diΔ(HPLC,MSによる) (016) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡" "001/004/005/008/010/011/014/016/017/" "MA0017" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C53:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C51-diΔ(β-unit)+C24:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=43,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (004/005) M.rhodesiae(RHO-1) (001/004/005) M.phlei (001/004/005) M.marinum (005) M.gordonae (005) M.aurum (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.dirnhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0018" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C54:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C52-diΔ(β-unit)+C24:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=44,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (001/004/005) M.rhodesiae(RHO-1) (001/004/005) M.phlei (001/004/005) M.marinum (004/005) M.gordonae (004) M.duvalii (004) M.gilvum (001) M.aurum (004/005) M.diernhoferi (001/005) M.kansasii (001/005) M.bovis (001) M.tuberculosis (001) M.ulcerans (004)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0019" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C55:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C53-diΔ(β-unit)+C24:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=45,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (004/005) M.rhodesiae(RHO-1) (001/005) M.phlei (001/005) M.marinum (005) M.gordonae (005) M.aurum (005) M.parafortuitum (001)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0020" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C56:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C54-diΔ(β-unit)+C24:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=46,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium vaccae(VA-1) (001/004/005) M.rhodesiae(RHO-1) (001/004/005) M.phlei (001/004/005) M.marinum (005) M.gordonae (004/005) M.agri(001/004/005) M.gilvum (001/004) M.pulveris (004) M.thermoresistible (001/004/005) M.aurum (004/005) M.parafortuitum (001) M.intracellulare (001) M.kansasii (001/005) M.bovis (001) M.tuberculosis (001)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0021" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C57:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C55-diΔ(β-unit)+C24:0(α-unit)" "C79H154O3" 79.00 154.00 3.00 0.00 0.00 0.00 1150.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=47,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium agri (005) M.thermoresistibile (005) M.intracellulare (005) M.kansasii(lab.) (005) M.marinum (005) M.aurum (005) M.phlei (001/004/005) M.gordonae (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0022" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C58:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C56-diΔ(β-unit)+C24:0(α-unit)" "C80H156O3" 80.00 156.00 3.00 0.00 0.00 0.00 1164.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=48,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium agri (001/004/005) M.aurum (005) M.thermoresistibile (001/004/005) M.phlei (004) M.intracellulare (001/004/005) M.kansasii(lab.) (001/004) M.marinum (005) M.gordonae (005) M.gilvum (001) M.avium (004/005) M.bovis (001) M.tuberculosis (001)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0023" 15.00 "2-DOCOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C60:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C58-diΔ(β-unit)+C24:0(α-unit)" "C82H160O3" 82.00 160.00 3.00 0.00 0.00 0.00 1192.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=50,x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium agri (001/004/005) Mycobacterium thermoresistibile (001/004/005) Mycobacterium intracellulare (001/005) Mycobacterium kansasii (lab.) (001/005) Mycobacterium marinum (005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0024" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C50:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C48-diΔ(β-unit)+C26:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=40,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis BCG (004/005) M.tuberculosis (005)" "004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0025" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C51:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C49-diΔ(β-unit)+C26:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=41,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis (004/005)" "004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0026" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C52:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C50-diΔ(β-unit)+C26:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=42,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis (001/004/005) M.tuberculosis H37Rv (001/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) C76, 78, 79, 80, 81, 82 の diΔ が存在(016) α-unit が C24:0,C26:0で, l=17,18,19, m=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0027" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C53:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C51-diΔ(β-unit)+C26:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=43,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis BCG (004/005) M.tuberculosis H37Rv (005)" "004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0028" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C54:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C52-diΔ(β-unit)+C26:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=44,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis BCG (001/004/005) M.tuberculosis H37Rv (001/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0029" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C55:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C53-diΔ(β-unit)+C26:0(α-unit)" "C79H154O3" 79.00 154.00 3.00 0.00 0.00 0.00 1150.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=45,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis BCG (004/005) M.tuberculosis H37Rv (005)" "004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0030" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C56:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C54-diΔ(β-unit)+C26:0(α-unit)" "C80H156O3" 80.00 156.00 3.00 0.00 0.00 0.00 1164.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=46,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis BCG (001/004/005) M.tuberculosis H37Rv (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0031" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C57:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C55-diΔ(β-unit)+C26:0(α-unit)" "C81H158O3" 81.00 158.00 3.00 0.00 0.00 0.00 1178.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=47,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester reslting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis (004/005) M.tuberculosis H37Rv (005)" "004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0032" 15.00 "2-TETRACOSANOYL3-HYDROXY-DICYCLOPROPANOYL-C58:0 ACID" "DICYCLOPROPANOYL-α-MYCOLIC ACID" "C56-diΔ(β-unit)+C26:0(α-unit)" "C82H160O3" 82.00 160.00 3.00 0.00 0.00 0.00 1192.00 " (REF:004)" " CH2 CH2 OH COOH" " ／＼ ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH−CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=48,x=23" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium bovis (001/004/005) M.tuberculosis H37Rv (001/005) M.simiae (004)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) C84(α-unit C26:0) も存在(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡" "001/004/005/008/010/011/014/016/017/" "MA0033" 15.00 "2-EICOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C49:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C47:1(monoΔ)(β-unit)+C22:0(α-unit)" "C69H134O3" 69.00 134.00 3.00 0.00 0.00 0.00 1010.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=40,x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium diernhoferi (005)" "005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014) ･M.fortuifum,'M.peregvium',M.smegumatisに α-mycol(TLC) (006) ･M.smegumatisにα'(TLC) (006)" "001/004/005/008/010/011/014/016/017/006/" "MA0034" 15.00 "2-EICOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C51:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C49:1(monoΔ)(β-unit)+C22:0(α-unit)" "C71H138O3" 71.00 138.00 3.00 0.00 0.00 0.00 1038.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=42, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium diernhoferi (004/005)" "004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0035" 15.00 "2-EICOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C53:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C51:1(monoΔ)(β-unit)+C22:0(α-unit)" "C73H142O3" 73.00 142.00 3.00 0.00 0.00 0.00 1066.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=44, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium diernhoferi (004/005) M.parafortuitum (001/004/005) M.phlei (005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0036" 15.00 "2-EICOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C55:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C53:1(monoΔ)(β-unit)+C22:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=46, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium diernhoferi (004/005) M.parafortuitum (001/004/005) M.phlei (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0037" 15.00 "2-EICOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C57:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C55:1(monoΔ)(β-unit)+C22:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=48, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester reulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)s" "004/001/005/" "Mycobacterium parafortuitum (001/004/005) M.phlei (001/004/005) M.rhodesiae (001/005) M.diernhoferi (004)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0038" 15.00 "2-EICOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C59:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C57:1(monoΔ)(β-unit)+C22:0(α-unit)" "C79H154O3" 79.00 154.00 3.00 0.00 0.00 0.00 1150.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=50, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0039" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C51:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C49:1(monoΔ)(β-unit)+C24:0(α-unit)" "C73H142O3" 73.00 142.00 3.00 0.00 0.00 0.00 1066.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=42, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0040" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C53:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C51:1(monoΔ)(β-unit)+C24:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=44, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0041" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOCYCLOPROPANOYL-C55:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C53:1(monoΔ)(β-unit)+C24:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=46, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium parafortuitum (001) M.phlei (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0042" 15.00 "α-DOCOSANOYLβ-HYDROXY-MONOCYCLOPROPANOYL-C57:1 ACID" "MONOENOIC,MONOCYCLOPROPANOYL-α-MYCOLIC ACID" "C55:1(monoΔ)(β-unit)+C24:0(α-unit)" "C79H154O3" 79.00 154.00 3.00 0.00 0.00 0.00 1150.00 " (REF:004)" " CH2 OH COOH" " ／＼ | |" " CH3(CH2)lCH−CH(CH2)mCH=CH(CH2)nCH−CH(CH2)xCH3" " l+m+n=48, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (001/005)" "001/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0043" 15.00 "2-EICOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C51:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C49:1(monoΔ)(β-unit)+C22:0(α-unit)" "C72H140O3" 72.00 140.00 3.00 0.00 0.00 0.00 1052.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=42, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium parafortuitum (001/004/005) M.phlei (005) M.rhodesiae (001/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0044" 15.00 "2-EICOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C53:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL-MONOENOIC-α-MYCOLIC ACID" "CH3-C51:1(monoΔ)(β-unit)+C22:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=44, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium parafortuitum (001/004/005) M.phlei (005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0045" 15.00 "2-EICOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C55:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C53:1(monoΔ)(β-unit)+C22:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=46, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium parafortuitum (001/004/005) M.phlei (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0046" 15.00 "2-EICOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C57:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C55:1(monoΔ)(β-unit)+C22:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=48, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium parafortuitum (001/005) M.phlei (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0047" 15.00 "2-EICOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C59:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C57:1(monoΔ)(β-unit)+C22:0(α-unit)" "C80H156O3" 80.00 156.00 3.00 0.00 0.00 0.00 1164.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=50, x=19" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (004)" "004/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0048" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C49:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C47:1(monoΔ)(β-unit)+C24:0(α-unit)" "C72H140O3" 72.00 140.00 3.00 0.00 0.00 0.00 1052.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=40, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (004) M.rhodesiae (001/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0049" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C51:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C49:1(monoΔ)(β-unit)+C24:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=42, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0050" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C53:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C51:1(monoΔ)(β-unit)+C24:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=44, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0051" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C55:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C53:1(monoΔ)(β-unit)+C24:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=46, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium parafortuitum (001) M.phlei (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0052" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOMETHYL-MONOCYCLOPROPANOYL-C57:1 ACID" "MONOMETHYL,MONOCYCLOPROPANOYL,MONOENOIC-α-MYCOLIC ACID" "CH3-C55:1(monoΔ)(β-unit)+C24:0(α-unit)" "C80H156O3" 80.00 156.00 3.00 0.00 0.00 0.00 1164.00 " (REF:004)" " CH2 CH3 OH COOH" " ／＼ | | |" " CH3(CH2)lCH−CH(CH2)m-1CH=CHCH(CH2)nCH−CH(CH2)xCH3" " l+m+n=48, x=21" "004/" "[M]+ (molecular ion),[M-15]+ (loss of -CH3),[M-90]+ (loss of trimethylsilanol),[A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+),[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage),[B-29]+ (loss of CHO from [B]+),(AgNO3-TLC,ﾒﾀﾉﾘｼｽ,ﾄﾘﾒﾁﾙｼﾘﾙ化および Hydrigenation後にGC-MSを行う)(004/001/005)" "004/001/005/" "Mycobacterium phlei (004)" "004/" "･Mycobacterium tuberculosisには, diΔのミコール酸が存在する(011) α-unitが C24:0,C26:0 で, l=17,18,19, M=10, n=15,17,19,21 のミコール酸が存在する(diΔ)(016) α-unit C26:0 で C84のもの(005) ･M.microti には α-unitが C26:0で l+m+n=42,44,46,48,50,52のもの(008) ･M.kansaii には C80H156O3がある(017) ･M.diernhoferi には α-unit C22:0で C70(001), C71(004)のものが存在する｡ ･M.phlei には C72,74,76,77,78,79,80のdieneとして報告(014)｡ C70,72,74,76,77,78,80のdieneとして報告(010)｡ いずれも培養温度が高くなると C-lengthの長いものが増加する(010/014)" "001/004/005/008/010/011/014/016/017/" "MA0053" 15.00 "2-DODECANOYL3-HYDROXY-OCTANOIC ACID" "(CORYNOMYCOLIC ACID) SATURATED-α-MYCOLIC ACID" "C20H40O3" 20.00 40.00 3.00 0.00 0.00 0.00 328.00 " (REF:027)" " CH3(CH2)4-CH-CH-COOH" " | |" " OH(CH2)11" " |" " CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0054" 15.00 "2-DODECANOYL3-HYDROXY-DECANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C20H44O3" 22.00 44.00 3.00 0.00 0.00 0.00 356.00 " (REF:027)" " CH3(CH2)6-CH-CH-COOH" " | |" " OH(CH2)11" " |" " CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0055" 15.00 "2-DODECANOYL3-HYDROXY-TETRADECANOIC ACID" "SATURATED (or CORYNOMYCOLIC ACID)" "C26H52O3" 26.00 52.00 3.00 0.00 0.00 0.00 412.00 " (REF:027)" " OH COOH" " | |" " CH3(CH2)10CH-CH(CH2)11CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0056" 15.00 "2-DODECANOYL3-HYDROXY-HEXADECANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C28H56O3" 28.00 56.00 3.00 0.00 0.00 0.00 440.00 " (REF:027)" " OH COOH" " | |" " CH3(CH2)12CH-CH(CH3)11CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0057" 15.00 "2-TETRADECANOYL3-HYDROXY-DECANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C24H48O3" 24.00 48.00 3.00 0.00 0.00 0.00 384.00 " (REF:027)" " CH3(CH2)6CH−CH-COOH" " | |" " OH (CH2)13" " |" " CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0058" 15.00 "2-TETRADECANOYL3-HYDROXY-DODECANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C26H52O3" 26.00 52.00 3.00 0.00 0.00 0.00 412.00 " (REF:027)" " CH3(CH2)8CH−CH-COOH" " | |" " OH (CH2)13" " |" " CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0059" 15.00 "2-TETRADECANOYL3-HYDROXY-TETRADECANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C28H56O3" 28.00 56.00 3.00 0.00 0.00 0.00 440.00 " (REF:027)" " CH3(CH2)10CH−CH-COOH" " | |" " OH (CH2)13" " |" " CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0060" 15.00 "2-TETRADECANOYL3-HYDROXY-HEXADECANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C30H60O3" 30.00 60.00 3.00 0.00 0.00 0.00 468.00 " (REF:027)" " CH3(CH2)12CH−CH-COOH" " | |" " OH (CH2)13" " |" " CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0061" 15.00 "2-TETRADECANOYL3-HYDROXY-OCTADECANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C32H64O3" 32.00 64.00 3.00 0.00 0.00 0.00 496.00 " (REF:027)" " CH3(CH2)14CH−CH-COOH" " | |" " OH (CH2)13" " |" " CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0062" 15.00 "2-DODECANOYL3-HYDROXY-TETRADECANOIC ACID(C14:1)(OR C16:1, C18:1)" "MONOENOIC-α-MYCOLIC ACID" "C26H49O3" 26.00 49.00 3.00 0.00 0.00 0.00 409.00 " (REF:027)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CH(CH2)11CH3" " x+y=8, 10, 12" " ※「分子式：C=26-32,H=49-62 」" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0063" 15.00 "2-TETRADECANOYL3-HYDROXY-DODECENOIC ACID(C12:1)(OR C14:1, 16:1, 18:1)" "MONOENOIC-α-MYCOLIC ACID" "C26H52O3" 26.00 49.00 3.00 0.00 0.00 0.00 409.00 " (REF:027)" " CH3(CH2)xCH=CH(CH2)yCH−CH-COOH" " | |" " OH (CH2)13" " |" " x+y=6, 8, 10, 12 CH3" " ※「分子式：C=26-32,H=49-62 」" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0064" 15.00 "2-TETRADECANOYL3-HYDROXY-C18:2 ACID-OCTADIENOIC ACID" "DIENOIC-α-MYCOLIC ACID" "C32H60O3" 32.00 60.00 3.00 0.00 0.00 0.00 492.00 " (REF:027)" " CH3-(CH2)xCH=CH(CH2)yCH=CH(CH2)2CH−CH-COOH" " | |" " OH (CH3)13" " |" " x+y=10 CH3" "027/" "A:[CH3-(CH2)m-CH-O-TMS] B:[-CH(-O-TMS)-CH(CO-O-CH3)-(CH2)n-CH3] (m=4to14, n=11or13)" "[M]+ ,[M-15]+ (M-CH3),[M-90]+ (M-TRIMETHYLSILANOL),[C2-C3 Cleavage]による[A]+,[C3-C4 Cleavage]による[B]+, (after methanolysis and trimethylsilylation)(027)" "027/" "Corynebacterium ulcerans の菌体成分として存在(027)" "027/" "1) Corynebacterium diphtheriae には,次のようなミコール酸が存在する(026) C30,32 のミコール酸が約 70%, 他に C24, 26, 28, 34 のものがある。 また奇数炭素数のものが約 3%存在｡ 飽和の他に monoene の存在も示唆｡ 2) ヒトの leprosy lesion, 患者の血液中から分離した ""diphtheroids"" groupの細胞膜にはC24-36 で double bond 0-4 のも のが 20種くらい存在する｡ Main が C34,36 で約 70% ｡ 奇数炭素数のものが 5% くらいまで存在する｡ (026) Corynebacterium xerusis には, C24-36 で偶数炭素数のものが多く存在する｡ 結核の治療薬 イソニコケン酸ヒドラジン共存によるミコール酸の影響についても報告｡ (019)" "026/019/" "MA0065" 15.00 "2-HEXADECANOYL3-HYDROXY-C44:1 ACID(OR C46:1, C48:1, C50:1)" "MONOENOIC" "C42H118O3" 42.00 118.00 3.00 0.00 0.00 0.00 670.00 " (REF:024)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CH(CH2)15CH3" " x+y=38, 40, 42, 44 ※「分子式:C=42-48,H=118-130」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0066" 15.00 "2-OCTADECANOYL3-HYDROXY-C42:1 ACID(OR C44:1, C46:1, C50:1, C52:1 ACID)" "MONOENOIC" "C60H118O3" 60.00 118.00 3.00 0.00 0.00 0.00 886.00 " (REF:024)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CH(CH2)17CH3" " x+y=36, 38, 40, 42, 44, 46 ※「分子式:C=60-70,H=118-138」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0067" 15.00 "2-EICOSANOYL3-HYDROXY-C44:1 ACID(OR C46:1, C48:1, C50:1, C52:1)" "MONOENOIC" "C64H126O3" 64.00 126.00 3.00 0.00 0.00 0.00 942.00 " (REF:024)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CH(CH2)19CH3" " x+y=38, 40, 42, 44, 46 ※「分子式:C=64-72,H=126-142」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0068" 15.00 "2-HEXADECANOYL3-HYDROXY-C46:2 ACID(OR C48:2, C50:2, C52:2, C54:2)" "MONOENOIC" "C62H120O3" 62.00 120.00 3.00 0.00 0.00 0.00 912.00 " (REF:024)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH-CH(CH2)15CH3" " x+y+z=38, 40, 42, 44, 46 ※「分子式:C=62-70,H=120-136」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0069" 15.00 "2-OCTADECANOYL3-HYDROXY-C44:2 ACID(OR C46:2, C48:2, C50:2, C52:2, C54:2)" "DIENOIC" "C62H120O3" 62.00 120.00 3.00 0.00 0.00 0.00 912.00 " (REF:024)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH-CH(CH2)17CH3" " x+y+z=36, 38, 40, 42, 44, 46 ※「分子式:C=62-72,H=120-140」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0070" 15.00 "2-EICOSANOYL3-HYDROXY-C44:2 ACID(OR C46:2, C48:2, C50:2, C52:2, C54:2)" "DIENOIC" "C64H124O3" 64.00 124.00 3.00 0.00 0.00 0.00 940.00 " (REF:024)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH-CH(CH2)19CH3" " x+y+z=36, 38, 40, 42, 44, 46 ※「分子式:C=64-74,H=124-144」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0071" 15.00 "2-OCTADECCENOYL3-HYDROXY-C46:1 ACID(OR C48:1, C50:1, C52:1, C54:1)" "DIENOIC" "C64H124O3" 64.00 124.00 3.00 0.00 0.00 0.00 940.00 " (REF:024)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CHC15H28CH3" " x+y=40, 42, 44, 46, 48 ※「分子式:C=64-72,H=124-140」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0072" 15.00 "2-OCTADECENOYL3-HYDROXY-C44:1 ACID(OR C46:1, C48:1, C50:1, C52:1, C54:1)" "DIENOIC" "C64H124O3" 64.00 124.00 3.00 0.00 0.00 0.00 940.00 " (REF:024)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CHC17H32CH3" " x+y=38, 40, 42, 44, 46, 48 ※「分子式:C=64-72,H=124-140」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0073" 15.00 "2-HEXADECANOYL3-HYDROXY-C48:3 ACID(OR C50:3, C52:3, C54:3)" "TRIENOIC" "C64H122O3" 64.00 122.00 3.00 0.00 0.00 0.00 938.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-6CH-CH(CH2)15CH3" " n=44, 46, 48, 50 ※「分子式:C=64-70,H=122-134」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0074" 15.00 "2-OCTADECANOYL3-HYDROXY-C46:3 ACID(OR C48:3, C50:3, C52:3, C54:3, C56:3)" "TRIENOIC" "C64H122O3" 64.00 122.00 3.00 0.00 0.00 0.00 938.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-6CH-CH(CH2)17CH3" " n=42, 44, 46, 48, 50, 52 ※「分子式:C=64-74,H=122-142」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0075" 15.00 "2-EICOSANOYL3-HYDROXY-C46:3 ACID(OR C48:3, C50:3, C52:3, C54:3)" "TRIENOIC" "C66H126O3" 66.00 126.00 3.00 0.00 0.00 0.00 966.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-6CH-CH(CH2)19CH3" " n=42, 44, 46, 48, 50, ※「分子式:C=66-74,H=126-142」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0076" 15.00 "2-COTADECENOYL3-HYDROXY-C48:2 ACID(OR C50:2, C52:2, C54:2)" "TRIENOIC" "C66H126O3" 66.00 126.00 3.00 0.00 0.00 0.00 966.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-4CH-CHC17H32CH3" " n=44, 46, 48, 50 ※「分子式:C=66-72,H=126-138」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0077" 15.00 "2-EICOSENOYL3-HYDROXY-C46:2 ACID(OR C48:2, C50:2, C52:2, C54:2)" "TRIENOIC" "C66H126O3" 66.00 126.00 3.00 0.00 0.00 0.00 966.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-4CH-CHC19H36CH3" " n=42, 44, 46, 48, 50 ※「分子式:C=66-74,H=126-142」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0078" 15.00 "2-HEXADECANOYL3-HYDROXY-C50:4 ACID(OR C52:4)" "TETRAENOIC" "C66H124O3" 66.00 124.00 3.00 0.00 0.00 0.00 964.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-8CH-CH(CH2)15CH3" " n=46, 48 ※「分子式:C=66 or 68,H=124 or 128」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0079" 15.00 "2-OCTADECANOYL3-HYDROXY-C48:4 ACID(OR C50:4, C52:4, C54:4, C56:4, C58:4)" "TETRAENOIC" "C66H124O3" 66.00 124.00 3.00 0.00 0.00 0.00 964.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-8CH-CH(CH2)17CH3" " n=44, 46, 48, 50, 52, 54 ※「分子式:C=66-76,H=124-144」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0080" 15.00 "2-EICOSANOYL3-HYDROXY-C48:4 ACID(OR C50:4, C52:4, C54:4, C56:4)" "TETRAENOIC" "C68H128O3" 68.00 128.00 3.00 0.00 0.00 0.00 992.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-8CH-CH(CH2)19CH3" " n=44, 46, 48, 50, 52 ※「分子式:C=68-76」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0081" 15.00 "2-OCTADECENOYL3-HYDROXY-C48:3 ACID(OR C50:3, C52:3, C54:3, C56:3)" "TETRAENOIC" "C66H124O3" 66.00 124.00 3.00 0.00 0.00 0.00 964.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-6CH-CHC17H32CH3" " n=44, 46, 48, 50, 52 ※「分子式:C=66-74,H=124-140」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0082" 15.00 "2-EICOSENOYL3-HYDROXY-C48:3 ACID(OR C50:3, C52:3, C54:3, C56:3)" "TETRAENOIC" "C68H128O3" 68.00 128.00 3.00 0.00 0.00 0.00 992.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-6CH-CHC19H36CH3" " n=44, 46, 48, 50, 52 ※「分子式:C=68-76,H=128-144」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0083" 15.00 "2-OCTADECANOYL3-HYDROXY-C52:5 ACID(OR C54:5, C56:5)" "PENTANOIC" "C70H130O3" 70.00 130.00 3.00 0.00 0.00 0.00 1018.00 " (REF:024)" " OH COOH" " | |" " CH3C2nH2n-10CH-CH(CH2)17CH3" " n=48, 50, 52 ※「分子式:C=70-74,H=130-138」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0084" 15.00 "2-EICOSANOYL3-HYDROXY-C50:5 ACID(OR C52:5, C54:5, C56:5)" "PENTAENOIC" "C70H130O3" 70.00 130.00 3.00 0.00 0.00 0.00 1018.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-10CH-CH(CH2)19CH3" " n=46, 48, 50, 52 ※「分子式:C=70-76,H=130-142」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0085" 15.00 "2-OCTADECENOYL3-HYDROXY-C52:4 ACID(OR C54:4, C56:4)" "PENTAENOIC" "C70H130O3" 70.00 130.00 3.00 0.00 0.00 0.00 1018.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-8CH-CHC17H32CH3" " n=48, 50, 52 ※「分子式:C=70-76,H=130-138」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0086" 15.00 "2-EICOSENOYL3-HYDROXY-C50:4 ACID(OR C52:4, C54:4, C56:4)" "PENTAENOIC" "C70H130O3" 70.00 130.00 3.00 0.00 0.00 0.00 1018.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-8CH-CHC19H36CH3" " n=46, 48, 50, 52 ※「分子式:C=70-76,H=130-142」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0087" 15.00 "2-OCTADECANOYL3-HYDROXY-C52:6 ACID(OR C54:6, C56:6, C58:6)" "HEXAENOIC" "C70H128O3" 70.00 128.00 3.00 0.00 0.00 0.00 1016.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-12CH-CH(CH2)17CH3" " n=48, 50, 52, 54 ※「分子式:C=70-76,H=128-140」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0088" 15.00 "2-EICOSANOYL3-HYDROXY-C54:6 ACID(OR C56:6, C58:6)" "HEXAENOIC" "C74H136O3" 74.00 136.00 3.00 0.00 0.00 0.00 1072.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-12CH-CH(CH2)19CH3" " n=50, 52, 54 ※「分子式:C=74-78,H=136-144」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0089" 15.00 "2-OCTADECENOYL3-HYDROXY-C52:5 ACID(OR C54:5, C56:5)" "HEXAENOIC" "C70H128O3" 70.00 128.00 3.00 0.00 0.00 0.00 1016.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-10CH-CHC17H32CH3" " n=48, 50, 52 ※「分子式:C=70-74,H=128-136」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0090" 15.00 "2-EICOSENOYL3-HYDROXY-C54:5 ACID(OR C56:5)" "HEXAENOIC" "C74H136O3" 74.00 136.00 3.00 0.00 0.00 0.00 1072.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-10CH-CHC19H36CH3" " n=50, 52, ※「分子式:C=74 OR 76,H=136 OR 140」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0091" 15.00 "2-EICOSANOYL3-HYDROXY-C52:7 ACID(OR C54:7, C56:7, C58:7)" "HEPAENOIC" "C72H130O3" 72.00 130.00 3.00 0.00 0.00 0.00 1042.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-14CH-CH(CH2)19CH3" " n=48, 50, 52, 54 ※「分子式:C=72-78,H=130-142」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0092" 15.00 "2-OCTADECENOYL3-HYDROXY-C54:6 ACID(OR C56:6, C58:6)" "HEPAENOIC" "C72H130O3" 72.00 130.00 3.00 0.00 0.00 0.00 1042.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-12CH-CHC17H32CH3" " n=50, 52, 54 ※「分子式:C=72-76,H=130-138」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0093" 15.00 "2-EICOSENOYL3-HYDROXY-C52:6 ACID(OR C54:6, C56:6, C58:6)" "HEPAENOIC" "C72H130O3" 72.00 130.00 3.00 0.00 0.00 0.00 1042.00 " (REF:024)" " OH COOH" " | |" " CH3CnH2n-12CH-CHC19H36CH3" " n=48, 50, 52, 54 ※「分子式:C=72-78,H=130-142」" "024/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+), (After Methylation and trimethylsilylation) (024)" "024/" "Gordona aurantiaca の菌体成分(024)" "024/" "･Gordona aurantiaca に C60-C78 double bond 2-7コ AgNO3-TLC 上スポット 2コ→lower monoene, diene, triene, tetraene, C62-C74 α-unit C16:0, 18:0, 20:0 diene, triene, tetraene の他に pentaenoic, hexaenoic(heptaenoic)C64-C78 C2 には C18:1 or C20:1｡ これらはマイコバクテリアやノカルテイアとは異なる｡ (024) ･Gordona bronchialis のミコール酸 (α-unit C18:0) C58:0, C58:1 ,60:1, 62:1, C58:2, 60:2, 62:2, 64:2, C60:3, 62:3, 64:3, 66:3, C62:4, 64:4, 66:4, 68:4, C64:5, 66:5, 68:5 (022)" "024/022/" "MA0094" 15.00 "2-DODECANOYL3-HYDROXY-C38:0 ACID(ORC40:0)" "SATURATED-α-MYCOLIC ACID" "C50H100O3" 50.00 100.00 3.00 0.00 0.00 0.00 748.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)11CH3" " x=34, 36 ※「分子式:C=50 OR 52,H=100 OR 104」" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(021)" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0095" 15.00 "2-TETRADECANOYL3-HYDROXY-C34:0 ACID (OR C36:0, C38:0, C40:0, C42:0, C44:0, C46:0)" "SATURATED-α-MYCOLIC ACID" "C48H96O3" 48.00 96.00 3.00 0.00 0.00 0.00 720.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)13CH3" " x=30, 32, 34, 36, 38, 40, 42 ※「分子式:C=48-60,H=96-120」" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(021)" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0096" 15.00 "2-HEXADECANOYL3-HYDROXY-C38:0 (OR C40:0) ACID" "SATURATED-α-MYCOLIC ACID" "C54H108O3" 54.00 108.00 3.00 0.00 0.00 0.00 804.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)15CH3" " x=34, OR 36, ※「分子式:C=54 OR 56,H=108 OR 112」" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(021)" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0097" 15.00 "2-TETRADECANOYL3-HYDROXY-C34:1 ACID(OR C34 MONOENOIC ACID)(OR C36:1, C38:1, C40:1, C42:1, C44:1, C46:1)" "MONOENOIC-α-MYCOLIC ACID" "C48H94O3" 48.00 94.00 3.00 0.00 0.00 0.00 718.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CH(CH2)13CH3" " x+y=28, 30, 32, 34, 36, 38, 40 ※「分子式:C=48-60,H=94-118」" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(021)" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0098" 15.00 "2-TETRADECENOYL3-HYDROXY-C36:0 ACID(OR C38:0, C40:0)" "MONOENOIC-α-MYCOLIC ACID" "C50H98O3" 50.00 98.00 3.00 0.00 0.00 0.00 746.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)yCH=CH(CH2)zCH3" " x=32, 34, 36 ※「分子式:C=50-54,H=98-106」" " y+z=11" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0099" 15.00 "2-TETRADECANOYL3-HYDROXY-C34:2 ACID (OR C36:2, C38:2, C40:2, C42:2, C44:2, C46:2)" "DIENOIC-α-MYCOLIC ACID" "C48H92O3" 48.00 92.00 3.00 0.00 0.00 0.00 716.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH-CH(CH2)13CH3" " x+y+z=26, 28, 30, 32, 34, 36, 38 ※「分子式:C=48-60,H=92-116」" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0100" 15.00 "2-TETRADECENOYL3-HYDROXY-C36:1 ACID (OR C38:1, C40:1)" "DIENOIC-α-MYCOLIC ACID" "C50H96O3" 50.00 96.00 3.00 0.00 0.00 0.00 744.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CH(CH2)mCH=CH(CH2)nCH3" " x+y=30, 32, 34 ※「分子式:C=50-54,H=96-104」" " m+n=11" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0101" 15.00 "2-TETRADECANOYL3-HYDROXY-C36:3 ACID (OR C38:3, C40:3, C42:3, C44:3, C46:3, C48:3)" "TRIENOIC-α-MYCOLIC ACID" "C50H94O3" 50.00 94.00 3.00 0.00 0.00 0.00 742.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH=CH(CH2)mCH-CH(CH2)13CH3" " x+y+z+m=26, 28, 30, 32, 34, 36, 38 ※「分子式:C=50-62,H=94-118」" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025r" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0102" 15.00 "2-DOCOSANOYL3-HYDROXY-C38:3 ACID (OR C40:3, C42:3)" "TRIENOIC-α-MYCOLIC ACID" "C50H94O3" 50.00 94.00 3.00 0.00 0.00 0.00 742.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH=CH(CH2)mCH-CH(CH2)11CH3" " x+y+z+m=28, 30, 32 ※「分子式:C=50-54,H=94-102」" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0103" 15.00 "2-TETRADECENOYL3-HYDROXY-C42:2 ACID" "TRIENOIC-α-MYCOLIC ACID" "C56H106O3" 56.00 106.00 3.00 0.00 0.00 0.00 826.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH-CH(CH2)mCH=CH(CH2)nCH3" " x+y+z= 34" " m+n=11" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0104" 15.00 "2-TETRADECANOYL3-HYDROXY-C38:4 ACID (OR C40:4, C42:4, C44:4)" "TETRAENOIC-α-MYCOLIC ACID" "C52H96O3" 52.00 96.00 3.00 0.00 0.00 0.00 768.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)13CH3" " x+y+z+m+n=26, 28, 30, 32 ※「分子式:C=52-64,H=96-106」" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0105" 15.00 "2-TETRADECENOYL3-HYDROXY-C38:3 ACID (OR C40:3, C42:3, C44:3)" "TETRAENOIC ACID" "C52H96O3" 52.00 96.00 3.00 0.00 0.00 0.00 768.00 " (REF:020)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)zCH=CH(CH2)mCH-CH(CH2)nCH=CH(CH2)pCH3" " x+y+z+m=28, 30, 32, 34 ※「分子式:C=52-58,H=96-108」" " n+p=11" "020/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia asteroidesの菌体成分 (020,022)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0106" 15.00 "2-OCTANOYL3-HYDROXY-TETRACOSANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C32H64O3" 32.00 64.00 3.00 0.00 0.00 0.00 496.00 " (REF:023)" " OH COOH" " | |" " CH3(CH2)20CH-CH(CH2)7CH3" "023/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia erythropolisの菌体成分 (023)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0107" 15.00 "2-NONANOYL3-HYDROXY-TETRACOSANOIC ACID" "SATURATED-α-MYCOLIC ACID" "C33H66O3" 33.00 66.00 3.00 0.00 0.00 0.00 510.00 " (REF:023)" " OH COOH" " | |" " CH3(CH2)20CH-CH(CH2)8CH3" "023/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia erythropolisの菌体成分 (023)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0108" 15.00 "2-DECANOYL3-HYDROXY-DOCOSANOIC ACID (OR C23:0, C24:0, C25:0, C26:0)" "SATURATED" "C32H64O3" 32.00 64.00 3.00 0.00 0.00 0.00 496.00 " (REF:023)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)9CH3" " x=18, 19, 20, 21, 22 ※「分子式:C=32-36,H=64-72」" "023/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia erythropolisの菌体成分 (023)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0109" 15.00 "2-UNDECANOYL3-HYDROXY-TETRACOSANOIC ACID" "SATURATED" "C35H70O3" 35.00 70.00 3.00 0.00 0.00 0.00 538.00 " (REF:023)" " OH COOH" " | |" " CH3(CH2)20CH-CH(CH2)10CH3" "023/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia erythropolisの菌体成分 (023)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0110" 15.00 "2-DODECANOYL3-HYDROXY-DOCOSANOIC ACID (OR C23:0-C30:0, C32:0, C33:0)" "SATURATED" "C34H68O3" 34.00 68.00 3.00 0.00 0.00 0.00 524.00 " (REF:023)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)11CH3" " x=18, 19, 20, 21, 22, 23, 24, 25, 26, 28, 29 ※「分子式:C=34-45,H=68-90」" "023/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia erythropolisの菌体成分 (023)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0111" 15.00 "2-TRIDECANOYL3-HYDROXY-TETRACOSANOIC ACID (OR C26:0, C28:0)" "SATURATED" "C37H74O3" 37.00 74.00 3.00 0.00 0.00 0.00 566.00 " (REF:023)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)12CH3" " x=20, 22, 24 ※「分子式:C=37,39,41,H=74,78,82」" "023/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia erythropolisの菌体成分 (023)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0112" 15.00 "2-TETRADECANOYL3-HYDROXY-TETRACOSANOIC ACID (OR C26:0, C28:0-C32:0)" "SATURATED" "C38H74O3" 38.00 76.00 3.00 0.00 0.00 0.00 580.00 " (REF:023)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)13CH3" " x=20,22,24,25,26,27,28 ※「分子式:C=38,40,42-46,H=76,80,82-92」" "023/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia erythropolisの菌体成分 (023)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0113" 15.00 "2-DECANOYL3-HYDROXY-OCTACOSANOIC ACID" "SATURATED" "C38H74O3" 38.00 76.00 3.00 0.00 0.00 0.00 580.00 " (REF:021)" " OH COOH" " | |" " CH3(CH2)24CH-CH(CH2)9CH3" "021/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia rubbraの菌体成分 (021)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0114" 15.00 "2-DODECANOYL3-HYDROXY-HEXACOSANOIC ACID (OR C28:0, C30:0, C32:0)" "SATURATED" "C38H74O3" 38.00 76.00 3.00 0.00 0.00 0.00 580.00 " (REF:021)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)11CH3" " x=22, 24, 26, 28 ※「分子式:C=38-44,H=76-82」" "021/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia rubbraの菌体成分 (021)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0115" 15.00 "2-TETRADECANOYL3-HYDROXY-TETRACOSANOIC ACID (OR C26:0, C28:0, C30:0, C32:0, C34:0)" "SATURATED" "C38H74O3" 38.00 76.00 3.00 0.00 0.00 0.00 580.00 " (REF:021)" " OH COOH" " | |" " CH3(CH2)xCH-CH(CH2)13CH3" " x=20, 22, 24, 26, 28, 30 ※「分子式:C=38-48,H=76-96」" "021/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia rubbraの菌体成分 (021)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0116" 15.00 "2-DODECANOYL3-HYDROXY-OCTACOCENOIC ACID (OR C30:1, C32:1, C34:1)" "MONOENOIC" "C40H78O3" 40.00 78.00 3.00 0.00 0.00 0.00 606.00 " (REF:021)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CH(CH2)11CH3" " x+y= 22, 24, 26, 28, ※「分子式:C=40-46,H=78-90」" "021/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia rubbraの菌体成分 (021)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0117" 15.00 "2-TETRADECANOYL3-HYDROXY-HEXACOCENOIC ACID (OR C28:1, C30:1, C32:1, C34:1, C36:1)" "MONOENOIC" "C40H78O3" 40.00 78.00 3.00 0.00 0.00 0.00 606.00 " (REF:021)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH-CH(CH2)13CH3" " x+y=20, 22, 24, 26, 28, 30 ※「分子式:C=40-50,H=78-98」" "021/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia rubbraの菌体成分 (021)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0118" 15.00 "2-DODECANOYL3-HYDROXY-TRIACONTEDIENOIC(C30:2 ?) ACID (OR C32:2, C34:2, C36:2)" "DIENOIC" "C42H80O3" 42.00 80.00 3.00 0.00 0.00 0.00 632.00 " (REF:021)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)mCH-CH(CH2)11CH3" " x+y+m= 22, 24, 26, 28 ※「分子式:C=42-48,H=80-92」" "021/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia rubbraの菌体成分 (021)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0119" 15.00 "2-TETRADECANOYL3-HYDROXY-C28:2 ACID (OR C30:2, C32:2, C34:2, C36:2, C38:2, C40:2)" "DIENOIC" "C42H80O3" 42.00 80.00 3.00 0.00 0.00 0.00 632.00 " (REF:021)" " OH COOH" " | |" " CH3(CH2)xCH=CH(CH2)yCH=CH(CH2)mCH-CH(CH2)13CH3" " X = 20, 22, 24, 26, 28, 30 ※「分子式:C=42-52,H=80-100」" "021/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025" "021/" "Nocardia rubbraの菌体成分 (021)" "020/021/022/023/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0120" 15.00 "2-ALKYL,3-HYDROXYLONG-CHAIN FATTY ACID" "BACTERIONEMAMYCOLIC ACID" "C24H48O3" 24.00 48.00 3.00 0.00 0.00 0.00 384.00 " (REF:025)" " CH3(CH2)mCH-CH-COOH" " | |" " OH (CH2)n ※「分子式:C=24-37,H=48-74」" " |" " CH3" " m = 8,10,11,12,13,14,15,16,17" " n = 5, 7,10,11,12,13,14,15" "025/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Bacterionema matruchotii の成分 (025)" "025/" "･Nocardia asteroides のミコール酸について(022),　ミコール酸の構造と growth temperature による変動(高温では Saturated の分子種が増加) (020) ･Nocardia 15株についてのミコール酸は次の4つのグループに分けられる(022) @ C28-C48 主として Saturated(ex. N.erythropolis) A C34-C50 monoenoic,dienoic(N.rubra, N.corallina, N.lutea) B C44-C58 double bond が 1-4コ 存在(N.asteroides,'true'nocardia) C C56-C68 double bond が 1-5コ (N.polychromogenes) ･N.rubra には C32-C48,N.lutea には C36-C51 の分子種が存在(019)。　 結核治療薬イソニコケン酸ヒドラジン(INH)投与でdiene,短鎖の分子種が増加(019) ･N.rubra には C38-52 のものが存在,このうち C44:0,C46:1,C48:2が多い｡ C2位の アルキル鎖は C12:0または C14:0である(021)｡ Growth temperatureが影響する(021)。　 N.erythropolisのミコール酸は C32-46でほとんどが Saturated(023)" "019/020/021/022/023/" "MA0121" 15.00 "2-EICOSANOYL3-HYDROXY-C50:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C48:2(β-unit)+C22:0(α-unit)" "C70H136O3" 70.00 136.00 3.00 0.00 0.00 0.00 1024.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=42, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium diernhoferi (001/005) M.sp.strain 3707 (001)" "001/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0122" 15.00 "2-EICOSANOYL3-HYDROXY-C51:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C49:1(β-unit)+C22:0(α-unit)" "C71H138O3" 71.00 138.00 3.00 0.00 0.00 0.00 1038.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=43, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium diernhoferi (004/005)" "004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0123" 15.00 "2-EICOSANOYL3-HYDROXY-C52:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C50:2(β-unit)+C22:0(α-unit)" "C72H140O3" 72.00 140.00 3.00 0.00 0.00 0.00 1052.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=44, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium fortuitum (001) M.diernhoferi (001/004/005) M.parafortuitum (001/004/005) M.rhodesiae (001) M.sp.strain 3707 (001)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0124" 15.00 "2-EICOSANOYL3-HYDROXY-C53:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C51:2(β-unit)+C22:0(α-unit)" "C73H142O3" 73.00 142.00 3.00 0.00 0.00 0.00 1066.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=45, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium fortuitum (001) M.diernhoferi (004/005) M.parafortuitum (001/004/005) M.rhodesiae (001/004)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0125" 15.00 "2-EICOSANOYL3-HYDROXY-C54:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C52:2(β-unit)+C22:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=46, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001) M.chitae (001) M.fortuitum (001) M.smegmatis (001) M.diernhoferi (001/004/005) M.parafortuitum (001/004/005) M.rhodesiae (001/004) M.sp.strain 3707 (001)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0126" 15.00 "2-EICOSANOYL3-HYDROXY-C55:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C53:2(β-unit)+C22:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=47, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001) M.chitae (001) M.fortuitum (001) M.smegmatis (001) M.diernhoferi (004/005) M.parafortuitum (001/004/005) M.rhodesiae (001/004) M.nonchromogenicum (001)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0127" 15.00 "2-EICOSANOYL3-HYDROXY-C57:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C55:2(β-unit)+C22:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=49, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001) M.chitae (001) M.fortuitum (001) M.smegmatis (001) M.diernhoferi (004) M.parafortuitum (001/004/005) M.rhodesiae (001) M.novum (001) M.nonchromogenicum (001)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0128" 15.00 "2-EICOSANOYL3-HYDROXY-C56:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C54:2(β-unit)+C22:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=48, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chitae (001) M.fortuitum (001) M.smegmatis (001) M.diernhoferi (001/004/005) M.parafortuitum (001/004/005) M.rhodesiae (001/004) M.chelonae (001)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0129" 15.00 "2-EICOSANOYL3-HYDROXY-C58:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C56:2(β-unit)+C22:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:001)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=50, x=19" "001/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium parafortuitum (001/005) M.rhodesiae (001)" "001/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0130" 15.00 "2-EICOSANOYL3-HYDROXY-C59:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C57:2(β-unit)+C22:0(α-unit)" "C79H154O3" 79.00 154.00 3.00 0.00 0.00 0.00 1150.00 " (REF:001)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=51, x=19" "001/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium nonchromogenicum (001)" "001/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0131" 15.00 "2-DOCOSANOYL3-HYDROXY-C46:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C44:2(β-unit)+C24:0(α-unit)" "C68H132O3" 68.00 132.00 3.00 0.00 0.00 0.00 996.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=38, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium sp.strain 3707 (005)" "005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0132" 15.00 "2-DOCOSANOYL3-HYDROXY-C47:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C45:2(β-unit)+C24:0(α-unit)" "C69H134O3" 69.00 134.00 3.00 0.00 0.00 0.00 1010.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=39, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium sp.strain 3707 (005)" "005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0133" 15.00 "2-DOCOSANOYL3-HYDROXY-C48:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C46:2(β-unit)+C24:0(α-unit)" "C70H136O3" 70.00 136.00 3.00 0.00 0.00 0.00 1024.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=40, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium sp.strain 3707 (005)" "005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0134" 15.00 "2-DOCOSANOYL3-HYDROXY-C49:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C47:2(β-unit)+C24:0(α-unit)" "C71H138O3" 71.00 138.00 3.00 0.00 0.00 0.00 1038.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=41, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium sp.strain 3707 (005)" "005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0135" 15.00 "2-DOCOSANOYL3-HYDROXY-C50:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C48:2(β-unit)+C24:0(α-unit)" "C72H140O3" 72.00 140.00 3.00 0.00 0.00 0.00 1052.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=42, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (005) M.chitae (005) M.fortuitum (001/005) M. rhodesiae (001) M.sp.strain 3707 (001/005) M.szulgai (005)" "001/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0136" 15.00 "2-DOCOSANOYL3-HYDROXY-C51:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C49:2(β-unit)+C24:0(α-unit)" "C73H142O3" 73.00 142.00 3.00 0.00 0.00 0.00 1066.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=43, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (005) M.chitae (004/005) M.fortuitum (001/005) M.rhodesiae (001) M.sp.strain 3707 (005) M.szulgai (005)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0137" 15.00 "2-DOCOSANOYL3-HYDROXY-C52:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C50:2(β-unit)+C24:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=44, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001/004/005) M.chitae (004/005) M.fortuitum (001/004/005) M.smegmatis (001/005) M.diernhoferi (001) M.rhodesiae (001/004) M.nonchromogenicum (005) M.sp.strain 3707 (001/005) M.szulgai (005)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0138" 15.00 "2-DOCOSANOYL3-HYDROXY-C53:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C51:2(β-unit)+C24:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=45, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001/005) M.chitae (001/004/005) M.fortuitum (001/005) M.smegmatis (001/004/005) M.rhodesiae (001/004) M.nonchromogenicum (001/005) M.terrae (005) M.sp.strain 3707 (005) M.szulgai (005) M.novum (005)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0139" 15.00 "2-DOCOSANOYL3-HYDROXY-C54:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C52:2(β-unit)+C24:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=46, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001/004/005) M.chitae (001/004/005) M.peregrinum PE-1(004) M.fortuitum (001/004/005) M.smegmatis (001/005) M.rhodesiae (001/004) M.terrae (005) M.novum (005) M.sp.strain 3707 (005) M.scrofulaceum (005) M.szulgai (005) M.diernhoferi (001)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0140" 15.00 "2-DOCOSANOYL3-HYDROXY-C55:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C53:2(β-unit)+C24:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=47, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001/004/005) M.chitae (001/004/005) M.porcinum (004 M.fortuitum (001/005) M.smegmatis (001/004/005) M.parafortuitum (001) M.hodesiae (001) M.nonchromogenicum (001/004/005) M.terrae (005) M.novum (001/005) M.scrofulaceum (005) M.szulgai (005)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0141" 15.00 "2-DOCOSANOYL3-HYDROXY-C56:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C54:2(β-unit)+C24:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=48, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001/004/005) M.chitae (001/004/005) M.fortuitum (001/004/005) M.smegmatis (001/005) M.parafortuitum (001/005) M.rhodesiae (001/004) M.nonchromogenicum (005) M.terrae (005) M.novum (005) M.scrofulaceum (005) M.szulgai (005)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0142" 15.00 "2-DOCOSANOYL3-HYDROXY-C57:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C55:2(β-unit)+C24:0(α-unit)" "C79H154O3" 79.00 154.00 3.00 0.00 0.00 0.00 1150.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=49, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001) M.chitae (001/004/005) M.fortuitum (001/005) M.smegmatis (001/005) M.nonchromogenicum (001/005) M.terrae (004/005) M.novum (001/004/005) M.triviale (004) M.scrofulaceum (005) M.szulgai (005)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0143" 15.00 "2-DOCOSANOYL3-HYDROXY-C58:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C56:2(β-unit)+C24:0(α-unit)" "C80H156O3" 80.00 156.00 3.00 0.00 0.00 0.00 1164.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=50, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001) M.chirae (005) M.fortuitum (001/004) M.smegmatis (001/004) M.nonchromogenicum (001/005) M.terrae (005) M.novum (005) M.scrofulaceum (005) M.szulgai (005)" "001/004/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0144" 15.00 "2-DOCOSANOYL3-HYDROXY-C59:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C57:2(β-unit)+C24:0(α-unit)" "C81H158O3" 81.00 158.00 3.00 0.00 0.00 0.00 1178.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=51, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium chelonae (001) M.fortuitum (001/005) M.smegmatis (001/005) M.nonchromogenicum (001) M.terrae (005) M.novum (001/005) M.scrofulaceum (005)" "001/005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0145" 15.00 "2-DOCOSANOYL3-HYDROXY-C60:2 ACID" "DIENOIC-α-MYCOLIC ACID" "C58:2(β-unit)+C24:0(α-unit)" "C82H160O3" 82.00 160.00 3.00 0.00 0.00 0.00 1192.00 " (REF:005)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=52, x=21" "005/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium terrae (005) M.novum (005) M.scrofulaceum (005)" "005/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0146" 15.00 "2-EICOSANOYL3-HYDROXY-C46:2 ACID" "DIENOIC-α'-MYCOLIC ACID" "C44:2(β-unit)+C22:0(α-unit)" "C66H128O3" 66.00 128.00 3.00 0.00 0.00 0.00 968.00 " (REF:001)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=38, x=19" "001/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium fortuitum (001)" "001/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0147" 15.00 "2-DOCOSANOYL3-HYDROXY-C42:2 ACID" "DIENOIC-α'-MYCOLIC ACID" "C40:2(β-unit)+C24:0(α-unit)" "C64H124O3" 64.00 124.00 3.00 0.00 0.00 0.00 940.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=34, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium fortuitum (004) M.peregrinum PE-1 (004)" "004/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0148" 15.00 "2-DOCOSANOYL3-HYDROXY-C44:2 ACID" "DIENOIC-α'-MYCOLIC ACID" "C42:2(β-unit)+C24:0(α-unit)" "C66H128O3" 66.00 128.00 3.00 0.00 0.00 0.00 968.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=36, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium fortuitum (001/004) M.peregrinum PE-1 (004)" "001/004/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0149" 15.00 "2-DOCOSANOYL3-HYDROXY-C48:2 ACID" "DIENOIC-α'-MYCOLIC ACID" "C46:2(β-unit)+C24:0(α-unit)" "C70H136O3" 70.00 136.00 3.00 0.00 0.00 0.00 1024.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=40, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium fortuitum (001/004) M.peregrinum PE-1 (004)" "001/004/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0150" 15.00 "2-DOCOSANOYL3-HYDROXY-C46:2 ACID" "DIENOIC-α'-MYCOLIC ACID" "C44:2(β-unit)+C24:0(α-unit)" "C68H132O3" 68.00 132.00 3.00 0.00 0.00 0.00 996.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH=CH(CH2)nCH-CH(CH2)xCH3" " l+m+n=38, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(025)" "025/" "Mycobacterium fortuitum (001/004) M.peregrinum PE-1 (004) M.porcinum (004)" "001/004/" "M.smegumatis について ･l=15,17,19, =11,13, n=16,18,20, x=21 のミコール酸が存在 (007) ･C75-C79 で α-unit が C24:0 がある (003) ･growth temperature による変動 (010) M.phlei について ･growth temperature による変動 (010) ･C72,74,76-80 (または dicyclopropan ring をもつ) のミコール酸の存在とその growth temperature による変動 (014) M.bovisについて ･α-unitが C22:0または C24:0で C74-C88の even C numberedのミコール酸が存在 (015) Mycobacteria, Nocardia に double bond 0〜Tetraene のミコール酸が存在 (018)" "003/007/010/014/015/018/" "MA0151" 15.00 "2-EICOSANOYL3-HYDROXYMONOMETHYL-C51:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C49:2(β-unit)+C22:0(α-unit)" "C72H140O3" 72.00 140.00 3.00 0.00 0.00 0.00 1052.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=43, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium parafortuitum (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0152" 15.00 "2-EICOSANOYL3-HYDROXYMONOMETHYL-C52:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C50:2(β-unit)+C22:0(α-unit)" "C73H142O3" 73.00 142.00 3.00 0.00 0.00 0.00 1066.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=44, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chitae (004) M.fortuitum (001)" "001/004/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0153" 15.00 "2-EICOSANOYL3-HYDROXYMONOMETHYL-C53:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C51:2(β-unit)+C22:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=45, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium parafortuitum (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0154" 15.00 "2-EICOSANOYL3-HYDROXYMONOMETHYL-C54:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C52:2(β-unit)+C22:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=46, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001) M.chitae (001/004) M.fortuitum (001) M.smegmatis (001)" "001/004/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0155" 15.00 "2-EICOSANOYL3-HYDROXYMONOMETHYL-C55:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C53:2(β-unit)+C22:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=47, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium parafortuitum (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0156" 15.00 "2-EICOSANOYL3-HYDROXYMONOMETHYL-C56:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C54:2(β-unit)+C22:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=48, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001) M.chitae (001/004) M.fortuitum (001) M.smegmatis (001)" "001/004/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0157" 15.00 "2-EICOSANOYL3-HYDROXYMONOMETHYL-DIENOIC-C57 ACID / C57:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C55:2(β-unit)+C22:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=49, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium parafortuitum (001/004/005) M.rhodesiae (001/004/005)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0158" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C49:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C47:2(β-unit)+C24:0(α-unit)" "C72H140O3" 72.00 140.00 3.00 0.00 0.00 0.00 1052.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=41, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium rhodesiae (001/004/005)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0159" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C50:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C48:2(β-unit)+C24:0(α-unit)" "C73H142O3" 73.00 142.00 3.00 0.00 0.00 0.00 1066.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=42, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (005) M.chitae (004) M.fortuitum (001/005)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0160" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C51:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C49:2(β-unit)+C24:0(α-unit)" "C74H144O3" 74.00 144.00 3.00 0.00 0.00 0.00 1080.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=43, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium rhodesiae (001/004/005)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0161" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C52:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C50:2(β-unit)+C24:0(α-unit)" "C75H146O3" 75.00 146.00 3.00 0.00 0.00 0.00 1094.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=44, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001/005) M.chitae (001/004) M.fortuitum (001/005) M.smegmatis (001/004)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0162" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C53:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C51:2(β-unit)+C24:0(α-unit)" "C76H148O3" 76.00 148.00 3.00 0.00 0.00 0.00 1108.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=45, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium rhodesiae (001/004/005)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0163" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C54:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C52:2(β-unit)+C24:0(α-unit)" "C77H150O3" 77.00 150.00 3.00 0.00 0.00 0.00 1122.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=47, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001/004/005) M.chitae (001/004) M.fortuitum (001/004/005) M.smegmatis (001/004/005) M.porcinum (004)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0164" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C55:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C53:2(β-unit)+C24:0(α-unit)" "C78H152O3" 78.00 152.00 3.00 0.00 0.00 0.00 1136.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=47, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium parafortuitum (001) M.rhodesiae (001/004/005)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0165" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C56:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C54:2(β-unit)+C24:0(α-unit)" "C79H154O3" 79.00 154.00 3.00 0.00 0.00 0.00 1150.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=49, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001) M.chitae (001/004) M.fortuitum (001/005) M.smegmatis (001/004/005)" "001/004/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0166" 15.00 "2-DOCOSANOYL3-HYDROXYMONOMETHYL-C58:2 ACID" "MONOMETHYL,DIENOIC-α-MYCOLIC ACID" "CH3-C56:2(β-unit)+C24:0(α-unit)" "C81H158O3" 81.00 158.00 3.00 0.00 0.00 0.00 1178.00 " (REF:004)" " CH3 OH COOH" " | | |" " CH3(CH2)lCH=CH(CH2)m-1CH=CHCH(CH2)nCH-CH(CH2)xCH3" " l+m+n=51, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001) M.fortuitum (001/005) M.smegmatis (001/005)" "001/005/" "コードファクターと免疫学的性質 (017)" "017/" "M.smegumatis のミコール酸 : CH3-branched diene が存在する (007/013) M.chelonei のミコール酸 : CH3-branched diene が存在する (009) CH3-branch の diene についてのミコール酸の報告は(002)にもある｡" "002/007/009/013/" "MA0167" 15.00 "2-DOCOSANOYL3-HYDROXY-C38:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C36:1(β-unit)+C24:0(α-unit)" "C60H118O3" 60.00 118.00 3.00 0.00 0.00 0.00 886.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=32, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chitae (001/004) M.smegmatis (001/004) M.vaccae (001/004) M.duvalii (001/004) M.thermoresistibile Lab. (001/004) M.aurum (001/004) M.pulveris (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0168" 15.00 "2-DOCOSANOYL3-HYDROXY-C34:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C32:1(β-unit)+C24:0(α-unit)" "C57H108O6" 56.00 112.00 3.00 0.00 0.00 0.00 832.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=28, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chitae (001)" "001/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0169" 15.00 "2-DOCOSANOYL3-HYDROXY-C36:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C34:1(β-unit)+C24:0(α-unit)" "C58H114O3" 58.00 114.00 3.00 0.00 0.00 0.00 858.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=30, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chitae (001/004) M.vaccae (004) M.duvalii (001/004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0170" 15.00 "2-DOCOSANOYL3-HYDROXY-C37:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C35:1(β-unit)+C24:0(α-unit)" "C59H116O3" 59.00 116.00 3.00 0.00 0.00 0.00 872.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=31, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium pulveris (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0171" 15.00 "2-DOCOSANOYL3-HYDROXY-C39:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C37:1(β-unit)+C24:0(α-unit)" "C61H120O3" 61.00 120.00 3.00 0.00 0.00 0.00 900.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=33, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium pulveris (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0172" 15.00 "2-DOCOSANOYL3-HYDROXY-C40:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C38:1(β-unit)+C24:0(α-unit)" "C62H122O3" 62.00 122.00 3.00 0.00 0.00 0.00 914.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=34, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001/004) M.chitae (001/004) M.smegmatis (001/004) M.parafortuitum (001) M.vaccae (001/004) M.duvalii (001/004) M.thermoresistibile Lab. (001/004) M.aurum (001/004) M.pulveris (004) M.shimoidei (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0173" 15.00 "2-DOCOSANOYL3-HYDROXY-C41:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C39:1(β-unit)+C24:0(α-unit)" "C63H124O3" 63.00 124.00 3.00 0.00 0.00 0.00 928.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=35, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium pulveris (004) M.shimoidei(004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA017v4" 15.00 "2-DOCOSANOYL3-HYDROXY-MONOENOIC-C42 ACID OR 2-DOCOSANOYL,3-HYDROXY-C42:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C40:1(β-unit)+C24:0(α-unit)" "C64H126O3" 64.00 126.00 3.00 0.00 0.00 0.00 942.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=36, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001/004) M.chitae (001/004) M.smegmatis (001/004) M.vaccae (004) M.agri (004) M.duvalii (001/004) M.thermoresistibile Lab. (001/004) M.aurum (001/004) M..pulveris (004) M.shimoidei (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0175" 15.00 "2-DOCOSANOYL3-HYDROXY-C43:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C41:1(β-unit)+C24:0(α-unit)" "C65H128O3" 65.00 128.00 3.00 0.00 0.00 0.00 956.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=37, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium pulveris (004) M.shimoidei (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0176" 15.00 "2-DOCOSANOYL3-HYDROXY-C45:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C43:1(β-unit)+C24:0(α-unit)" "C67H132O3" 67.00 132.00 3.00 0.00 0.00 0.00 984.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=39, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium agri (004) M.shimoidei (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0177" 15.00 "2-DOCOSANOYL3-HYDROXY-C44:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C42:1(β-unit)+C24:0(α-unit)" "C66H130O3" 66.00 130.00 3.00 0.00 0.00 0.00 970.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=38, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001/004) M.chitae (001/004) M.smegmatis (001/004) M.agri (001/004) M.duvalii (001/004) M.thermoresistibile Lab. (001/004) M.aurum (001/004) M.pulveris (004) M.shimoidei (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0178" 15.00 "2-DOCOSANOYL3-HYDROXY-C46:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C44:1(β-unit)+C24:0(α-unit)" "C68H134O3" 68.00 134.00 3.00 0.00 0.00 0.00 998.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=40, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium smegmatis (001/004) M.agri (001/004) M.duvalii (004) M.thermoresistibile Lab. (001/004) M.aurum (004) M.shimoidei (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0179" 15.00 "2-DOCOSANOYL3-HYDROXY-C47:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C45:1(β-unit)+C24:0(α-unit)" "C69H136O3" 69.00 136.00 3.00 0.00 0.00 0.00 1012.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=41, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium agri (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0180" 15.00 "2-DOCOSANOYL3-HYDROXY-C48:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C46:1(β-unit)+C24:0(α-unit)" "C70H138O3" 70.00 138.00 3.00 0.00 0.00 0.00 1026.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=42, x=21" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium agri (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0181" 15.00 "2-EICOSANOYL3-HYDROXY-MONOENOIC C46 (C36:1) ACID" "MONOENOIC-α'-MYCOLIC ACID" "C34:1(β-unit)+C22:0(α-unit)" "C56H110O3" 56.00 110.00 3.00 0.00 0.00 0.00 830.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=30, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chirae (001) M.parafortuitum (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0182" 15.00 "2-EICOSANOYL3-HYDROXY-C38:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C36:1(β-unit)+C22:0(α-unit)" "C58H114O3" 58.00 114.00 3.00 0.00 0.00 0.00 858.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=32, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chitae (001/004) M.parafortuitum (001/004) M..vaccae(VA-1) (001/004) M.duvalii(DU-2) (001/004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0183" 15.00 "2-EICOSANOYL3-HYDROXY-C39:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C37:1(β-unit)+C22:0(α-unit)" "C59H116O3" 59.00 116.00 3.00 0.00 0.00 0.00 872.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=33, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium pulveris (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0184" 15.00 "2-EICOSANOYL3-HYDROXY-C40:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C38:1(β-unit)+C22:0(α-unit)" "C60H118O3" 60.00 118.00 3.00 0.00 0.00 0.00 886.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=34, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chitae (001/004) M.smegmatis (001) M.parafortuitum (001/004) M.vaccae (001/004) M.duvalii (001/004) M.thermoresistibile Lab. (001) M.aurum (001/004) M.pulveris (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0185" 15.00 "2-EICOSANOYL3-HYDROXY-C41:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C39:1(β-unit)+C22:0(α-unit)" "C61H120O3" 61.00 120.00 3.00 0.00 0.00 0.00 900.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=35, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium pulveris (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0186" 15.00 "2-EICOSANOYL3-HYDROXY-C42:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C40:1(β-unit)+C22:0(α-unit)" "C62H122O3" 62.00 122.00 3.00 0.00 0.00 0.00 914.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=36, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium chelonae (001/004) M.smegmatis (001) M.parafortuitum (001/004) M.vaccae (001/004) M.duvalii (001/004) M.thermoresistibile Lab. (001) M.aurum (001/004) M.pulveris (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0187" 15.00 "2-EICOSANOYL3-HYDROXY-C43:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C41:1(β-unit)+C22:0(α-unit)" "C63H124O3" 63.00 124.00 3.00 0.00 0.00 0.00 928.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=37, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium pulveris (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0188" 15.00 "2-EICOSANOYL3-HYDROXY-C44:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C42:1(β-unit)+C22:0(α-unit)" "C64H126O3" 64.00 126.00 3.00 0.00 0.00 0.00 942.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=38, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium parafortuitum (004) M.vaccae (004) M.duvalii (001/004) M.thermoresistibile Lab.(001) M.aurum (001/004) M.pulveris (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0189" 15.00 "2-EICOSANOYL3-HYDROXY-C45:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C43:1(β-unit)+C22:0(α-unit)" "C65H128O3" 65.00 128.00 3.00 0.00 0.00 0.00 956.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=39, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium pulveris (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0190" 15.00 "2-EICOSANOYL3-HYDROXY-C46:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C44:1(β-unit)+C22:0(α-unit)" "C66H130O3" 66.00 130.00 3.00 0.00 0.00 0.00 970.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=40, x=19" "004/" "M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium agri (001) M.duvalii (001/004) M.thermoresistibile Lab.(001) M.aurum (001/004) M.pulveris (004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0191" 15.00 "2-EICOSANOYL3-HYDROXY-C48:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C46:1(β-unit)+C22:0(α-unit)" "C68H134O3" 68.00 134.00 3.00 0.00 0.00 0.00 998.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=42, x=19" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium duvalii (001/004) M.thermoresistibile Lab.(001) M.aurum (001/004)" "001/004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0192" 15.00 "2-TETRCOSANOYL3-HYDROXY-C40:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C38:1(β-unit)+C26:0(α-unit)" "C64H126O3" 64.00 126.00 3.00 0.00 0.00 0.00 942.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=34, x=23" "004/" "M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium simiae (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0193" 15.00 "2-TETRACOSANOYL3-HYDROXY-C42:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C40:1(β-unit)+C26:0(α-unit)" "C66H130O3" 66.00 130.00 3.00 0.00 0.00 0.00 970.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=36, x=23" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid este resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium simiae (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0194" 15.00 "2-TETRACOSANOYL3-HYDROXY-C44:1 ACID" "MONOENOIC-α'-MYCOLIC ACID" "C42:1(β-unit)+C26:0(α-unit)" "C68H134O3" 68.00 134.00 3.00 0.00 0.00 0.00 998.00 " (REF:004)" " OH COOH" " | |" " CH3(CH2)lCH=CH(CH2)mCH-CH(CH2)xCH3" " l+m=38, x=23" "004/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(004)" "004/" "Mycobacterium simiae (004)" "004/" "α'-mycolic acid の存在について次のような報告がある｡ 1.M.smegumatis には @ x=21, l=17,19, m=15,17,19,21 (012) A x=21, C60,62,64,66,68,74-83 (013) B x=21, C60-66 (003) C growth temperature による α'-mycolic acid の変動 (002)　 2.M.phlei の growth temperature による α'-mycolic acid の変動 (010) 3.M.chelonei には x=21, l=15,17, m=17,19 で C60-64 (009)" "003/009/010/012/013/" "MA0195" 15.00 "2-DOCOSANOYL3,32-DIHYDROXY,33-METHYL-C50:1 ACID" "HYDROXY-MYCOLIC ACID" "C73H144O4" 73.00 144.00 4.00 0.00 0.00 0.00 1084.00 " (REF:002)" " OH COOH" " | |" " CH3-(CH2)16-CH−CH-(CH2)x-CH=CH-(CH2)y-CH-CH-C22H45" " | |" " x+y=26 CH3 OH" "002/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(002)" "002/" "Mycobacterium smegumatis (002)" "002/" "Mycobacterium smegumatis の成分で, epoxy mycolates から生成 (002), epoxy mycolates から polar mycolate が生ずる｡ (006) M.smegumatis の growth tmperature による変動｡ (002)" "002/006/" "MA0196" 15.00 "2-DOCOSANOYL3,34-DIHYDROXY,35-METHYL-C52:1 ACID" "HYDROXY-MYCOLIC ACID" "C75H148O3" 75.00 148.00 4.00 0.00 0.00 0.00 1112.00 " (REF:002)" " OH COOH" " | |" " CH3-(CH2)16-CH−CH-(CH2)x-CH=CH-(CH2)y-CH-CH-C22H45" " | |" " x+y=28 CH3 OH" "002/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(002)" "002/" "Mycobacterium smegumatis の菌体成分 (002)" "002/" "Mycobacterium smegumatis の成分で, epoxy mycolates から生成 (002), epoxy mycolates から polar mycolate が生ずる｡ (006) M.smegumatis の growth tmperature による変動｡ (002)" "002/006/" "MA0197" 15.00 "2-DOCOSANOYL3,36-DIHYDROXY,37-METHYL-C54:1 ACID" "HYDROXY-MYCOLIC ACID" "C77H152O4" 77.00 152.00 4.00 0.00 0.00 0.00 1140.00 " (REF:002)" " OH COOH" " | |" " CH3-(CH2)16-CH−CH-(CH2)x-CH=CH-(CH2)y-CH-CH-C22H45" " | |" " x+y=30 CH3 OH" "002/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(002)" "002/" "Mycobacterium smegumatis の菌体成分 (002)" "002/" "Mycobacterium smegumatis の成分で, epoxy mycolates から生成 (002), epoxy mycolates から polar mycolate が生ずる｡ (006) M.smegumatis の growth tmperature による変動｡ (002)" "002/006/" "MA0198" 15.00 "2-DOCOSANOYL3,38-DIHYDROXY,39-METHYL-C56:1 ACID" "HYDROXY-MYCOLIC ACID" "C79H156O4" 79.00 156.00 4.00 0.00 0.00 0.00 1168.00 " (REF:002)" " OH COOH" " | |" " CH3-(CH2)16-CH−CH-(CH2)x-CH=CH-(CH2)y-CH-CH-C22H45" " | |" " x+y=32 CH3 OH" "002/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(002)" "002/" "Mycobacterium smegumatis の菌体成分 (002)" "002/" "Mycobacterium smegumatis の成分で, epoxy mycolates から生成 (002), epoxy mycolates から polar mycolate が生ずる｡ (006) M.smegumatis の growth tmperature による変動｡ (002)" "002/006/" "MA0199" 15.00 "2-ALKYL3-HYDROXY-FATTY ACID" "EPOXY MYCOLIC ACID" " (REF:028)" " [例] CH3 OH COOH" " | | |" " CH3-(CH2)15-CH−CH-(CH2)m-CH=CH-(CH2)n-CH-CH" " ＼／ |" " m+n=32 CH3 (CH2)21" " |" " CH3" "028/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(002)" "002/" "Mycobacterium smegumatis, M.fortuitum, M.chitaeに epoxy mycolatesが存在する｡(003)" "003/" "Mycobacterium smegumatis に C77,79 で double ｂｏｎｄ 1ｺ のもの, M.fortuitum に C76〜79 で double ｂｏｎｄ 1ｺ , M.chitaeに C77,79 で double ｂｏｎｄ 1ｺ の epoxy mycolate が存在する。(003) M.fortuitum, M.perogrinum, M.smegmatis に存在。(006)" "003/006/" "MA0200" 15.00 "METHOXY MYCOLIC ACID" 0.00 0.00 0.00 0.00 0.00 0.00 " (REF:008)" " CH3 OCH3 CH3 OH COOH" " | | ／＼ | |" " CH3-(CH2)15-CH−CH-(CH2)y-CH−CH-(CH2)z-CH-CH-C24H49" " y+z=27, 29, 31, 33, 35, 37" "008/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(008)" "008/" "Mycobacterium microti の菌体成分｡ (008)" "008/" "Mycobacterium smegumatis の成分で, epoxy mycolates から生成 (002), epoxy mycolates から polar mycolate が生ずる｡ (006) M.smegumatis の growth tmperature による変動｡ (002)" "002/006/" "MA0201" 15.00 "DICARBOXY-MYCOLIC ACID" 0.00 0.00 0.00 0.00 0.00 0.00 " (REF:011)" " OH COOH" " | |" " HOOC-(CnH2n-2)-CH−CH-(CH2)21-CH3" " n = 32 〜 39" "011/" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+)(008)" "008/" "Mycobacterium avium, M.intracellulare, M.johnei, M.phlei に存在｡ (011)" "011/" "Mycobacterium parafortuitum, M.vaccaeに C56,58で double bond 1コのもの, M.phleiに C60,62で double bond 1コのもの｡ (003) ･M.phlei に C61-64のものが存在し, growth temperatureにより異なる(010/014) ･M.phlei HOOC(CH2)14-CH-CH=CH(CH2)16-CH-CH-C22H45 が存在｡(017) | | | CH3 OH COOH" "003/010/014/017/" "MA0202" 15.00 "KETO MYCOLIC ACID" 0.00 0.00 0.00 0.00 0.00 0.00 " (REF:008)" " CH3 C2H OH COOH" " | ／＼ | |" " CH3-(CH2)x-CH-CO-(CH2)y-CH−CH-(CH2)2-CH-CH" " |" " x+y+z= 48, 50, 52, 54 C24H49" "008/" "CYCLOPROPAN RINGS:1025cm-1,3060cm-1(008)" "-0.3,0.6ppm(2H,6H FOR α,0.7H,2-1H FOR METHOXY,0.8H,2.4H FOR KETO),METHOXYMYCOLATE:3.0ppm(1H,BROAD),3.34ppm(3H,SINGLET)→CHOCH3,0.2ppm(1･2H FOR METHOXY),KETOMYCOLATE:1.07ppm(3H,DOUBLET)→CH3CHCO 0.2ppm(0.8H FOR KETO),CIS-CYCLOPROPAN RING(016),3.67ppm,METHYL GROUP(METHYL MYCOLATE IN CDCl3) (008)" "[M]+(molecular ion), [M-15]+ (loss of -CH3), [M-90]+ (loss of trimethylsilanol), [A]+ (TMS-alkoxy ion resulting from C2 -C3 cleavage),[A-90]+ (loss of trimethylsilanol from [A]+) ,[B]+ (TMS-oxymethylene carboxylic acid ester resulting from C3 -C4 cleavage), [B-29]+ (loss of CHO from [B]+),(メチルエステル化,トリメチルシリル化後,またはさらに HYDROGENATION後)(001/004/005)" "NMR(013):MYCOLIC ACID PHENACYLATE(D2O)(009/007)" "016/008/014/010/002/003/012/009/007/" "Mycobacterium microti (008)" "008/" "ﾐｺｰﾙ酸は,ｺｰﾄﾞﾌｧｸﾀｰ(TREHALOSE 6.6'-DIMYCOLATE)の構成成分である｡ 結核菌(Mycobacterium tuberculosis)等の Mycobacteriumの他に,Nocardia, Rhodococcus. Corynebacterium. Gordonaなどの菌種にﾐｺｰﾙ酸の存在が報告されている｡ ﾐｺｰﾙ酸は菌種により,C30-C88以上の長鎖のものがあり, 2-branched alkyl chain(α-unit) には C20:0,C22:0,C24:0(or C26:0)が存在することが報告されている｡ また,β-unitについても,double bondが 0〜6個, cyclopropanringが 1〜2個有するものなど構造がさまざまで,したがってそれらの分子種はきわめて多い｡ これらは薄層クロマトグラム上の移動度により, a,a',keto,methoxy-mycolic acidなど,subclassに分類し,それぞれの炭素(C)数値により構造が同定あるいは推定されている｡ この方法は主として GC-MS法による｡ したがって,二重結合やﾒﾁﾙ基, ｼｸﾛﾊﾟﾝﾘﾝｸﾞの位置まではっきりと同定されていないものが多い｡ ﾐｺｰﾙ酸含有糖脂質の生物活性については毒性,抗腫瘍性,免疫との関連などいろいろと報告されている(028,029)｡ 主として GC-MS法による｡したがって,二重結合やﾒﾁﾙ基, ｼｸﾛﾊﾟﾝﾘﾝｸﾞの位置まではっきりと同定されていないものが多い｡ ﾐｺｰﾙ酸含有糖脂質の生物活性については毒性,抗腫瘍性,免疫との関連などいろいろと報告されている(028,029)｡" "028/029/"