| LIPID_ID | FA0100 |
| CHEM_NA | METHYL-9,16-DIHYDROPEROXY-10,12,14-OCTADE |
| CATRIENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 18:3(ω4,6,8)(9,16-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | CONJUGATED TRIENE:λmax=258-260, 268-269, |
| 278-280nm(099/102/105) |
| IR_SPEC | OOH GROUP:3712-3140cm-1[BONDED], |
| 3530-3510cm-1[FREE]; OLEFINIC |
| PROTONS:3005cm-1; CONJUGATED |
| TRANS,CIS,TRANS TRIENE:960cm-1; CONJUGATED |
| TRANS,TRANS, TRANS |
| NMR_SPEC | 1H-NMR(102/105):C2:2.30-2.37ppm; |
| C8,17:1.50-1.85ppm; C9,16:4.34-4.42ppm; |
| C10,11,12,13,14,15:5.25-6.90ppm; C18:0.94-0.95ppm; |
| OOH:7.70-7.94ppm |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION AND |
| TMS-DERIVATIZATION)(105) GC-EI-MS(AFTER |
| REDUCTION, HYDROGENATION AND TMS |
| DERIVATIZATION)(099/102) GC-EIMS(AFTER |
| REDUCTION,HYDROGENATION AND |
| TBDMS-DERIVATIZATION)(099)CI-MS(110)" |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの自動酸化において，9ｰ OR |
| 16-HYDROPEROXY異性体より生成(018/019/099/10 |
| 2)ﾘﾉﾚﾝの鉄(II)−ｱｽｺﾙﾋﾞﾝ酸存在下での酸化(099) |
| ﾘﾉﾚﾝ酸ﾓﾉﾋﾄﾞﾛﾍﾟﾙｵｷｼﾄﾞの鉄(II)−ｱｽｺﾙﾋﾞﾝ酸存在下で |
| の酸化(099/100)．ﾘﾉﾚﾝの一重項酸素酸化において，9 |
| ｰおよび16ｰHYDROPEROXY異性体より生成(019/1 |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE |
| 1998年8月24日 | 100 / 513 ページ |