| LIPID_ID | FA0101 |
| CHEM_NA | METHYL-13,16-DIHYDROPEROXY-9,11,14-OCTADE |
| CATRIENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 18:3(ω4,7,9)(13,16-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | CONJUGATED DIENE:λmax=233-235nm(102/105) |
| IR_SPEC | OOH GROUP:3712-3140cm-1[BONDED], |
| 3530-3510cm-1[FREE]; OLEFINIC |
| PROTONS:3005cm-1; CONJUGATED CIS,TRANS |
| DIENE: 988-979cm-1,953-935cm-1; ISOLATED |
| TRANS UNSATURATION: 968-960cm-1(102/105) |
| NMR_SPEC | 1H-NMR(102/105):C2:2.3ppm; C8,17:1.8-2.2ppm; |
| C9,10,11,12,14,15:5.26-6.28ppm |
| C13,16:4.40-4.42ppm; C18:1.02ppm; OOH:8.07ppm |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION AND |
| TMS-DERIVATIZATION)(105):M/E=453[M-CH3]; |
| 439[M -CH2CH3]; 437[M-OCH3]; 378[M-HOTMS]; |
| 143[(CH2)6C00CH3] GC-EI-MS(AFTER |
| REDUCTION, HYDROGENATION AND |
| TMS-DERIVATIZATION)(102) |
| M/E=443[M-OCH3];315[SMTO=CH(CH2)11COOCH3]; |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの自動酸化において，16-HYDROPEROXY異性体 |
| より生成(018/019/102) |
| ﾘﾉﾚﾝの一重項酸素酸化において，13ｰおよび16ｰHYDR |
| OPEROXY異性体より生成(019/105/106) |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE |
| 1998年8月24日 | 101 / 513 ページ |