| LIPID_ID | FA0103 |
| CHEM_NA | METHYL-13,15-DIHYDROPEROXY-9,11,16-OCTADE |
| CATRIENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 18:3(ω2,7,9)(13,15-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | CONJUGATED DIENE:λmax=234-235nm(105) |
| IR_SPEC | OOH GROUP:3700-3140cm-1[BONDED], |
| 3520-3510cm-1[FREE]; CONJUGATED CIS,TRANS |
| DIENE:985-979cm-1,953-935cm-1; ISOLATED |
| TRANS UNSATURATION:968-960cm-1(105) |
| NMR_SPEC | 1H-NMR(105):C2:2.31-2.32ppm; C8,14:1.8-2.2ppm; |
| C9,10,12,16,17:5.25-6.20ppm; C11:6.63ppm; |
| C13,15:4.48-4.50ppm; C18:1.8ppm; |
| OOH:7.94-8.08ppm(105) |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION AND |
| TMS-DERIVATIZATION)(105): M/E=468[M]; |
| 453[M-OCH3]; 437[M-OCH3]; 378[M-HOTMS]; |
| 311[SMTO=CHCH=CHCH=CH(CH2)7COOCH3]; |
| 143[SMTO=CHCH=CHCH3] |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの一重項酸素酸化において，13ｰおよび15ｰHYDR |
| OPEROXY異性体より生成(019/105/106) |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE |
| 1998年8月24日 | 103 / 513 ページ |