| LIPID_ID | FA0104 |
| CHEM_NA | METHYL-10,16-DIHYDROPEROXY-8,12,14-OCTADE |
| CATRIENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 18:3(ω4,6,10)(10,16-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | CONJUGATED DIENE:λmax=232nm(105) |
| IR_SPEC | OOH GROUP:3700-3140cm-1[BONDED], |
| 3520-3510cm-1[FREE]; CONJUGATED CIS,TRANS |
| DIENE:985-979cm-1,953-935cm-1; ISOLATED |
| TRANS UNSATURATION:968-960cm-1(105) |
| NMR_SPEC | 1H-NMR(105):C2:2.31ppm; C7,11,17:2.08ppm; |
| C8,9,12,13,15:5.25-6.25ppm; C10,16:4.34ppm; |
| C14:6.55ppm; C18:0.93ppm; OOH:8.04ppm(105) |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION AND |
| TMS-DERIVATIZATION)(105):M/E=468[M]; |
| 439[M-CH2CH3]; 437[M-OCH3]; 378[M-HOTMS]; |
| 349[439-HOTMS]; |
| 271[SMTO=CHCH=CH(CH2)6COOCH3]; 197[M-271]; |
| CI-MS(110): M/E=339[M+H-H20]; 323[M-OOH]; |
| 305[323-H2O];199[CHOCH=CH(CH2)6COOCH3+H]; |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの一重項酸素酸化において，10ｰおよび16ｰHYDR |
| OPEROXY異性体より生成(019/105/106) |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE |
| 1998年8月24日 | 104 / 513 ページ |