| LIPID_ID | FA0106 |
| CHEM_NA | METHYL-10,12,13,15-BISEPIDIOXY-9-HYDROPEROX |
| Y-16-OCTADECENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O8 |
| MOL_WT | 388 |
| ABBREVIATION | 18:1(ω2)(10,12,13,15-Bisepidioxy)(9-OOH)(Me-Ester |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC |
| IR_SPEC | OOH GROUP: 3700-3150cm-1[BONDED], |
| 3530cm-1[FREE] ISOLATED TRANS |
| UNSATURATION:960cm-1(105) |
| NMR_SPEC | 1H-NMR(105):C2:2.3ppm; C9:3.88ppm[C9-10 |
| ERYTHRO],4.17ppm[C9-10 THREO]; |
| C10,12,13,15:4.47ppm; C11,14:2.1-2.8ppm; |
| C16:5.88ppm; C17:5.35ppm; |
| C18:1.73ppm;OOH:8.73ppm[C9-10 |
| ERYTHRO],9.20ppm[C9-10 THREO] (105) |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION(PH3P) AND |
| TMS-DERIVATIZATION)(105):M/E=259[SMTO=CH(CH |
| 2)7COOCH3]; 185[M-259]; GC-EI-MS(AFTER |
| REDUCTION,HYDROGENATION, AND |
| TMS-DERIVATIZATION)(105):M/E=261[SMTO=CHCH |
| 2CH(OTMS)(CH2)2CH3];259[SMTO=CH(CH2)7COOC |
| H3]; 145[SMTO=CH(CH2)2CH3 |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの一重項酸素酸化で生ずる15ｰPEROXY |
| RADICALの連続的1,3ｰCYCLIZATIONにより生成(019/ |
| 021/105) |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE |
| 1998年8月24日 | 106 / 513 ページ |