| LIPID_ID | FA0107 |
| CHEM_NA | METHYL-10,12,13,15-BISEPIDIOXY-16-HYDROPERO |
| XY-8-OCTADECENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O8 |
| MOL_WT | 388 |
| ABBREVIATION | 18:1(ω10)(10,12,13,15-Bisepidioxy)(16-OOH)(Me-Est |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC |
| IR_SPEC | OOH GROUP:3700-3150cm-1[BONDED], |
| 3530cm-1[FREE];ISOLATED TRANS |
| UNSATURATION:960cm-1(105) |
| NMR_SPEC | 1H-NMR(105):C2:2.3ppm; C8:5.35ppm; C9:5.88ppm; |
| C10,12,13,15:4.47ppm; C11,14:2.1-2.8ppm; |
| C16:3.88ppm[C15-16 ERYTHRO],4.17ppm[C15-16 |
| THREO]; C18:1.05ppm; OOH:8.73ppm[C15-16 |
| ERYTHRO],9.20ppm[C15-16 THREO] (105)" |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION(PH3P) AND |
| TMS-DERIVATIZATION)(105):M/E=313[M-131];131[S |
| MTO=CHCH2CH3]; GC-EI-MS(AFTER |
| REDUCTION,HYDROGENATION, AND |
| TMS-DERIVATIZATION)(105):M/E=349[SMTO=CHCH |
| 2CH(OTMS)CH(OTMS)CH2CH3]; |
| 273[SMTO=CH(CH2)8COOCH3]; |
| 145[SMTO=CH(CH2)2CH3] |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの一重項酸素酸化で生ずる10ｰPEROXY |
| RADICALの連続的1,3ｰCYCLIZATIONにより生成(019/ |
| 021/105) |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE |
| 1998年8月24日 | 107 / 513 ページ |