| LIPID_ID | FA0113 |
| CHEM_NA | METHYL-10,13-EPIDIOXY-9-HYDROPEROXY-11,15- |
| OCTADECADIENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 18:2(ω3,7)(10,13-Epidioxy)(9-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC |
| IR_SPEC | OOH GROUP: 3635-3300cm-1[BONDED]; OLEFINIC |
| PROTONS: 3005cm-1;ISOLATED TRANS |
| UNSATURATION: 965cm-1(106) |
| NMR_SPEC | 1H-NMR(106): C8:1.6ppm; C9:4.22ppm; C10:4.65ppm; |
| C11,12:5.98ppm; C13:4.48ppm; C14:2.0ppm; |
| C15,16:5.45ppm; C17:2.05ppm; OOH:8.65ppm" |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION(PH3P) AND |
| TMS-DERIVATIZATION)(106): M/E=412[M]; |
| 322[M-HOTMS]; 259[SMTO=CH(CH2)7COOCH3]; |
| 153[M-259]; 69[CH2CH=CHCH2CH3]; |
| 55[CH=CHCH2CH3]; GC-EI-MS(AFTER |
| RDUCTION,HYDROGENATION, AND |
| TMS-DERIVATIZATION)(106): |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの9-HYDROPEROXIDE異性体への一重項酸素の1 |
| ,4-付加で生成(019,106) |
| BIOL_ACTIV |
| NOTE |
| 1998年8月24日 | 113 / 513 ページ |