| LIPID_ID | FA0114 |
| CHEM_NA | METHYL-12,15-EPIDIOXY-16-HYDROPEROXY-9,13- |
| OCTADECADIENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 18:2(ω5,9)(12,15-Epidioxy)(16-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC |
| IR_SPEC | OOH GROUP: 3635-3300cm-1[BONDED]; OLEFINIC |
| PROTONS: 3005cm-1;ISOLATED TRANS |
| UNSATURATION: 965cm-1(106) |
| NMR_SPEC | 1H-NMR(106): C8:2.05ppm; C9,10:5.45ppm; |
| C11:2.0ppm; C12:4.48ppm;C13,14:5.98ppm; |
| C15:4.65ppm; C16:4.22ppm; C17:1.6ppm; |
| OOH:8.65ppm" |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION(PH3P) AND |
| TMS-DERIVATIZATION)(106): M/E=412[M]; |
| 322[M-HOTMS]; 281[M-131]; |
| 197[CH2CH=CH(CH2)7COOCH3]; |
| 183[CH=CH(CH2)7COOCH3]; |
| 131[SMTO=CHCH2CH3]; GC-EI-MS(AFTER |
| REDUCTION,HYDROGENATION, AND |
| TMS-DERIVATIZATION)(106): M/E=457[M-CH3- |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの16-HYDROPEROXIDE異性体への一重項酸素の |
| 1,4-付加で生成(019,106) |
| BIOL_ACTIV |
| NOTE |
| 1998年8月24日 | 114 / 513 ページ |