| LIPID_ID | FA0066 |
| CHEM_NA | (METHYL)-9,10-EPOXY-13-HYDROXY-11-OCTADE |
| CENOIC ACID (OCTADECENOATE) |
| COMMON_NA |
| MOL_FORMULA | C18H32O4 |
| MOL_WT | 312 |
| ABBREVIATION | 18:1(ω7)(9,10-Epoxy)(13-OH) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | λ=277 AND 316nm(VERY WEAK ABSORPTION)(034) |
| IR_SPEC | METYL ESTER(006/075/034): TRANS |
| OLEFIN(965-958cm-1), TRANS EPOXIDE(890-874 |
| cm-1),CIS EPOXIDE(WEAK ABSORPRION;845 AND |
| 830cm-1),FREE |
| OH(3600cm-1),BONDEDOH(3640-3380cm-1) |
| NMR_SPEC | 1H-NMR(METHYL |
| ESTER)(006/075/034):C9(2.83ppm),C10(3.09-3.1ppm |
| ;TRANS |
| EPOXIDE),C11(5.45-5.53ppm),C12(5.93-5.95ppm),C13 |
| (3.9-4.2ppm),C12,13(2.9-3.4ppm;CISEPOXIDE),OH |
| PROTON(3.6ppm), J11-12=15.6Hz(TRANS |
| UNSATURATION),J9-10=2-2.2Hz(TRANS EPOXIDE)" |
| MS_SPEC | GC-EI-MS(METHYL,TMS化後)(006/075/034/037):m |
| /e=398[M],383[M-CH3],367[M-OCH3],327[M-(CH2)4 |
| CH3],241[M-(CH2)7COOCH3],199[CH=CH-CH(OTMS |
| )-(CH2)4CH3 OR |
| CH(-O-)-CH(CH2)7COOCH3],173[SMTO=CH-(CH2)4 |
| CH3]GC/EI-MS(BF3-MeOH処理,TMS化後)(075) |
| NOTE_SPEC |
| SOURCE | 13-ヒドロペルオキシリノール酸メチルの分解物(075/07 |
| 6)． |
| リノール酸メチルの自動酸化で生ずるエポキシ-ヒドロキ |
| シ化合物の主要成分［エポキシド環および二重結合はト |
| ランス配置］(006/037)．リノール酸の小麦リポキシゲナ |
| ーゼ酸化により生成［エポキシ環はシス，二重結合 |
| BIOL_ACTIV |
| NOTE |
| 1998年8月24日 | 66 / 513 ページ |