| LIPID_ID | FA0067 |
| CHEM_NA | (METHYL)-12,13-EPOXY-9-HYDROXY-10-OCTADE |
| CENOIC ACID (OCTADECENOATE) |
| COMMON_NA |
| MOL_FORMULA | C18H32O4 |
| MOL_WT | 312 |
| ABBREVIATION | 18:1(ω8)(12,13-Epoxy)(10-OH) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | λ=277 AND 316nm(VERY WEAK ABSORPTION)(034) |
| IR_SPEC | METHYL ESTER(006/075/034/082/092):TRANS |
| OLEFIN(965-958cm-1),TRANS EPOXIDE( |
| 890-874cm-1),CIS EPOXIDE(WEAK |
| ABSORPTION;845 AND 830cm-1),FREE |
| OH(3600cm-1)BONDED OH(3640-3380cm-1) |
| NMR_SPEC | 1H-NMR(071/006/075/034):C9(3.9-4.2ppm),C10(5.9 |
| 3-5.95ppm),C11(5.41-5.53ppm),C12(3.09-3.1ppm;TRA |
| NS EPOXIDE),C13(2.81-2.83ppm;TRANS |
| EPOXIDE),C12,13(2.9- 3.4ppm;CIS EPOXIDE),OH |
| PROTON(3.6ppm), J10-11=15.6Hz(TRANS |
| UNSATURATION),J12-13=2-2.2Hz(TRANS EPOXIDE) |
| MS_SPEC | GC-EI-MS(METHYL,TMS化後)(006/075/034/037/03 |
| 9/092):m/e=398[M],383[M-CH3],367[M-OCH3],327[ |
| M-(CH2)4CH3],241[M-(CH2)7COOCH3],285[CH=CH- |
| CH(OTMS)-(CH2)7COOCH3],259[SMTO=CH-(CH2)7 |
| COOCH3]GC-EI-MS(酸性下でﾒﾁﾙ化,TMS化後(071) |
| GC-EI-MS(BF3-MeOH処理,TMS化後)(076) |
| NOTE_SPEC | ORD(082) |
| SOURCE | 13-ヒドロペルオキシリノール酸のFe(III)-CYSTEINE存 |
| 在下(082)およびヘモグロビ |
| ン存在下(039/073)での分解物． |
| 13-ヒドロペルオキシリノール酸メチルのラジカル分解物 |
| (075/076)リノール酸メチルの自動酸化で生ずるエポキ |
| シ-ヒドロキシ化合物の主要成分［エポキシド環およ |
| BIOL_ACTIV |
| NOTE |
| 1998年8月24日 | 67 / 513 ページ |