| LIPID_ID | FA0095 |
| CHEM_NA | METHYL-10,12-EPIDIOXY-9-HYDROPEROXY-13,15- |
| OCTADECADIENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 18:2(ω3,5)(10,12-Epidioxy)(9-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | CONJUGATED DIENE:λmax=231-236nm |
| (099/102/104/105) |
| IR_SPEC | OOH GROUP:3520 cm-1[FREE], |
| 3700-3100cm-1[BONDED]; OLEFINIC |
| PROTONS:3020-3000cm-1; CONJUGATE TRANS,CIS |
| DIENES: 990-980cm-1,955-947cm-1 |
| NMR_SPEC | 1H-NMR(102/104/105):C9:3.92-4.21;C10:4.45-4.47; |
| C11:2.19-2.47,2.81-2.87;C12:4.77-4.80;C13:5.57-5.6 |
| 2;C14:6.65-6.68;C15:5.96-6.65;C16:5.50-5.55;OOH:9. |
| 05-9.56ppm;J13-14=15Hz[C13-14:TRANS];J15-16=1 |
| 0Hz[C15-16:CIS]13C-NMR(102/105):C9:86.0;C10,12: |
| 83.8,83.0;C11:4 |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION(PH3P) AND |
| TMS)(102)): |
| M/E=397[M-CH3];259[SMTO=CH(CH2)7COOCH3]; |
| GC-EI-MS(AFTER REDUCTION WITH NaBH4 OR KI |
| AND TMS)(098): |
| M/E=259[SMTO=CH(CH2)7COOCH3]; |
| 183[SMTO=CH-CH=CH-CH=CH-CH2CH3]; |
| GC-EI-MS(AFTERREDUCTION,HYDROGENATION AND |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの自動酸化(102/104) |
| ﾘﾉﾚﾝの鉄(II)ｰｱｽｺﾙﾋﾞﾝ酸存在下での酸化(099) |
| ﾘﾉﾚﾝの光増感酸化[Type |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE | ﾘﾉﾚﾝの自動酸化の主要二次酸化生成物(019/102)．ﾘﾉ |
| ﾚﾝの12ｰPEROXY |
| RADICALの1,3-CYCLIZATIONを介して生成する(018-0 |
| 21/044/102/ |
| 104)．ﾘﾉﾚﾝの自動酸化で生ずるEPIDIOXY |
| 1998年8月24日 | 95 / 513 ページ |