| LIPID_ID | FA0096 |
| CHEM_NA | METHYL-13,15-EPIDIOXY-16-HYDROPEROXY-9,11- |
| OCTADECADIENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 18:2(ω7,9)(13,15-Epidioxy)(16-OOH)(Me-Ester) |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | CONJUGATED CIS,TRANS DIENE:λmax=234-237nm |
| CONJUGATED TRANS,TRANS |
| DIENE:λmax=231-234nm (099/102/104/105/109) |
| IR_SPEC | OOH GROUP:3720-3140cm-1[BONDED], |
| 3530-3520cm-1[FREE]; OLEFINIC |
| PROTONS:3020-3000cm-1; CONJUGATED |
| CIS,TRANS DIENE : 989-980cm-1,955-947cm-1; |
| CONJUGATEDTRANS,TRANS DIENE: |
| 992-984cm-1,955cm-1 |
| NMR_SPEC | 1H-NMR(102/104/105/109):C9:5.46-5.78;C10:5.99- |
| 6.05;C11:6.26-6.67;C12:5.53- |
| 5.62;C13:4.75-4.84;C14:2.23-2.47,2.79-2.88;C15:4.4 |
| 7-4.49;C16:3.86-4.15;OOH:8.98-9.55ppm;J9-15=10.0 |
| -11.0[CIS];J9-10=15.1-15.5[TRANS];J11-12=14.5-1 |
| 5.4Hz[TRANS],13C-NMR(102/105):C9-1 |
| MS_SPEC | GC-EI-MS(AFTER REDUCTION(PH3P) AND |
| TMS-DERIVATIZATION)(102)):M/E=397[M-CH3]131[ |
| SMTO=CHCH2CH3]; GC-EI-MS(AFTER |
| REDUCTION(NaBH4 OR KI) AND |
| TMS-DERIVATIZATION)(098): |
| M/E=311[SMTO=CH-CH=CH-CH=CH-(CH2)7COOCH |
| 3]; 131[SMTO=CHCH2CH3]GC-EI-MS(AFTER |
| REDUCTION,HYDRO |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの自動酸化(102/104)．ﾘﾉﾚﾝの鉄(II)ｰｱｽｺﾙﾋﾞﾝ酸 |
| 存在下での酸化(099) ﾘﾉﾚﾝの光増感酸化[Type |
| II](105/106)．生成機構(019/021) |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE | ﾘﾉﾚﾝの自動酸化の主要二次酸化生成物(019/102)．ﾘﾉ |
| ﾚﾝの13ｰPEROXY |
| RADICALの1,3-CYCLIZATIONを介して生成する(018-0 |
| 1998年8月24日 | 96 / 513 ページ |