| LIPID_ID | FA0108 |
| CHEM_NA | METHYL-11-(3,5-EPIDIOXY-2-ETHYLCYCLOPENTY |
| L)-9-HYDROPEROXY-10-UNDECENOATE |
| COMMON_NA |
| MOL_FORMULA | C19H32O6 |
| MOL_WT | 356 |
| ABBREVIATION | 11:1(ω1)(3,5-Epidioxy)(2-Ethylcyclopentyl)(9-OOH)( |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC |
| IR_SPEC | OOH GROUP:3620-3010cm-1[BONDED], |
| 3520cm-1[FREE];ISOLATED TRANS |
| UNSATURATION:960cm-1(105) |
| NMR_SPEC | 1H-NMR(107/108):C9:4.26-4.35;C10:5.47-5.52; |
| C11:5.44-6.03; C12:2.66-2.92; C13:4.42-4.53; |
| C15:4.53-4.66; C16:1.90-2.16; OOH:7.89-7.94; |
| 13C-NMR(107/108):C9:86.3-86.6; C10:129.8-132.4; |
| C11:132.4-135.0;C12:45.9-50.8;C13:79.8-80.5C14:3 |
| 9.3-44.1; C15:81.7-83.0; |
| MS_SPEC | EI-MS(AFTER REDUCTION AND |
| TMS)(108):M/E=543[M-CH3];468[M-HOTMS];401[M- |
| (CH2)7COOCH3];378[M-2xHOTMS];352[468-SMTO= |
| CHCH2];323[352-CH2CH3];285[CH=CHCH(OTMS)(C |
| H2)7COOCH3];259[SMTO=CH(CH2)7COOCH3];217[S |
| MTO-CH=CH-CH=OTMS]GC-EI-MS(AFTER |
| REDUCTION,HYDROGENATION A |
| NOTE_SPEC |
| SOURCE | ﾘﾉﾚﾝの光増感酸化(TypeII)．(019/021/105) |
| ﾘﾉﾚﾝの13ｰPEROXY |
| RADICALの1,3ｰCYCLIZATIONにより生成(019/021/10 |
| BIOL_ACTIV | 鉄ｲｵﾝとｱｽｺﾙﾋﾞﾝ酸の存在下でDNAと反応し，強い蛍光 |
| を生ずる(111)． |
| NOTE |
| 1998年8月24日 | 108 / 513 ページ |