LIPID_ID | FA0109 |
CHEM_NA | METHYL-8-[3,5-EPIDIOXY-2-(3-HYDROPEROXY-1- |
PENTENYL)CYCLOPENTYL]OCTANOATE |
COMMON_NA |
MOL_FORMULA | C19H32O6 |
MOL_WT | 356 |
ABBREVIATION |
MELT_PT |
BOIL_PT |
OPT_ROT |
REFRA_IND |
DENSITY |
SOLUBILITY |
UV_SPEC |
IR_SPEC | OOH GROUP:3620-3010cm-1[BONDED], |
3520cm-1[FREE];ISOLATED TRANS |
UNSATURATION:960cm-1(105) |
NMR_SPEC |
MS_SPEC | GC-EI-MS(AFTER REDUCTION AND |
HYDROGENATION AND |
TMS-DERIVATIZATION)(105):M/E=545[M-CH3]; |
455[545-HOTMS]; |
401[M-(CH2)2CH(OTMS)CH2CH3];131[SMTO=CHCH |
NOTE_SPEC |
SOURCE | リノレンの光増感酸化(TypeII).(019/021/105) |
リノレンの12ーPEROXY |
RADICALの1,3ーCYCLIZATIONにより生成(019/021/10 |
BIOL_ACTIV | 鉄イオンとアスコルビン酸の存在下でDNAと反応し,強い蛍光 |
を生ずる(111). |
NOTE |
1998年8月24日 | 109 / 513 ページ |