LIPID_ID | FA0117 |
CHEM_NA | METHYL-8-[2-(2-FORMYLVINYL)-3-HYDROXY-5-O |
XOCYCLOPENTYL]OCTANOATE |
COMMON_NA |
MOL_FORMULA | C17H26O5 |
MOL_WT | 310 |
ABBREVIATION |
MELT_PT |
BOIL_PT |
OPT_ROT |
REFRA_IND |
DENSITY |
SOLUBILITY |
UV_SPEC |
IR_SPEC | KETO CARBONYL: 1740cm-1[ESTER |
CARBONYLとピークが重なる] CONJUGATED |
ALDEHYDE: 1688cm-1(103) |
NMR_SPEC |
MS_SPEC | GC-EI-MS(AFTER REDUCTION(NaBH4) AND |
TMS-DERIVATIZATION)(103): M/E=530[M]; |
515[M-CH3]; 440[M-HOTMS]; 425[440-CH3]; |
399[515-SMTO=CHCH2]; 324[440-SMTO= CHCH2]; |
311[M-SMTOC3H5OTMS]; 243[SMTOC5H5OTMS]; |
217[EMTOC3H3OTMS]; 191[SMT OCHOTMS]; |
167[C6H6OTMS] G |
NOTE_SPEC |
SOURCE | リノレンの自動酸化において12-HYDROPEROXY異性体よ |
りPGG様エンドペルオキシドを経て生成 (103) |
BIOL_ACTIV |
NOTE |
1998年8月24日 | 117 / 513 ページ |