ๆ“ชƒy[ƒW‚ึ ’ผ‘O‚ฬƒy[ƒW‚ึ ŽŸ‚ฬƒy[ƒW‚ึ ลIƒy[ƒW‚ึ

Sterol

LIPID_ID

ST0460

CHEM_NA

3ƒภ-HYDROXY-16,28-SECOSOLANIDA-5,22(28)-DIE

N-24-ONE

COMMON_NA

TOMATILLIDINE

MOL_FORMULA

C27H41O2N

MOL_WT

411

MELT_PT

219-222฿C(methylene chloride +

BOIL_PT

OPT_ROT

[ƒฟ]/D=-18.1฿(chloroform)(1042)

REFRA_IND

DENSITY

SOLUBILITY

UV_SPEC

IR_SPEC

ƒษmax(KBr) 5.98ƒส(C=N and CO)(1042)

NMR_SPEC

t-CH3,0.64ppm; t-and sec-CH3,0.96ppm;

sec-CH3,1.08ppm; one olefinic proton,5.35ppm; teo

sec-CH3,0.90(J=5cps)and 1.12ppm(J=6cps); and one

olefinic proton,5.35ppm(1042)

MS_SPEC

m/e=140(1042)

NOTE_SPEC

O.R.D.inMeOH(C

0.12)[ƒฟ]/290=+366฿,[ƒฟ]/240=-666฿;in dioxane(C

0.19),[ƒฟ]/405=-48฿,[ƒฟ]/392=-15฿,[ƒฟ]/378=-48฿[ƒฟ]

/360=-3฿,[ƒฟ]/369=-18฿,[ƒฟ]/352=+42฿,[ƒฟ]/348=+33฿

SOURCE

EA•จB

Solanum tomatillo Phil., Solanaceae‚ฉ‚็’Šoก (1041)

BIOL_ACTIV

NOTE

•ชŽq—ส 411.61, (1042)

1998”N7ŒŽ17“๚

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