| Sterol |
| LIPID_ID | ST0295 |
| CHEM_NA | 1,2,3,4,7a,10,11,11a,12,13-DECAHYDRO-14-(1-HYDR |
| OXYETHYL)-2,11a-DIMETHYL-7H-9,11b-EPOXY-13 |
| a,5a-PROPENOPHENANTHRO[2,1-F][1,4]OXAZEPINE- |
| 9,12(8H)-DIOL;3α,9α-EPOXY-14β,18β-(EPOXYE |
| THANO-N-METHYLIMINO)-5β-PREGNA-7,16-DIENE |
| -3β,11α,20α-TRIOL |
| COMMON_NA | BATRACHOTOXININ A |
| MOL_FORMULA | C24H35O5N |
| MOL_WT | 417 |
| MELT_PT |
| BOIL_PT |
| OPT_ROT |
| REFRA_IND |
| DENSITY |
| SOLUBILITY |
| UV_SPEC | END ABSORPTION(625) |
| IR_SPEC | 1645cm-1(625) |
| NMR_SPEC | 0.85,1.42,2.30,2.66,3.42(-2H),5.5-6.3(-4H)(REFERENC |
| E TMS δ=0.0,SOLVENT CDCl3); |
| 0.85(19-CH3),1.90(d)(6.5)(21-CH3),2.48(s)(N-CH3),2. |
| 89(s)(18-CH2),3.22(d)(18)(H-11),4.57(q)(6.5)(H-20),5. |
| 72(t)(2)(H-7), |
| 6.24(dd)(2.5,5)(H-16)(TMS,δ=0.0,CDCl3)(626) |
| MS_SPEC | M/E ION 399 C24H33NO4,370 |
| C23H32NO3,(342)(C22H32NO3),312 C20H24O3,294 |
| C20H22O2,286 C18H22O3,279 C19H19O2,276 |
| C20H20O,261 C19H17O,224 C16H16O,219 |
| C17H15,(206)? ,184 C13H12O,(166)C10H16NO,88 |
| C4H10NO,71 C4H9N (626) |
| NOTE_SPEC |
| SOURCE | 植物。 Columbian arrow poison frogs(KOKOI |
| FROG),genus Phyllobates bicolor の皮膚｡ (624) |
| PREPARATIVE |
| TLCによって,BATRACHOTOXIN,BATRACHOTOXININ |
| B, Cと分離｡(625) PHYLLOBATES |
| AVROTAENIAの皮膚｡(630) |
| BIOL_ACTIV | CARDIOTOXIN｡ |
| LD50 I,v,in mice: 1mg/kg(BATRACHOTOXINの 1/10)｡ |
| 4種の主要な TOXIC STEROIDAL ALKALOIDS |
| の中で最も毒性が弱い｡(625) |
| NOTE | 分子量 288.26, Rf=0.54 |
| COLOR REACTIONS |
| 1998年7月17日 | 181 / 486 ページ |